Herbicidal pyrrolesulfonylureas

ABSTRACT

This invention relates to certain herbicidal pyrrolesulfonylureas, compositions thereof and a method for their use as herbicides or plant growth regulants.

CROSS-REFERENCE TO RELATED APPLICATION

This is a division of application Ser. No. 08/527,053, filed Sep. 12, 1995 now U.S. Pat. No. 5,585,328, which is a divisional of application Ser. No. 07/974,581, filed Feb. 24, 1993, now U.S. Pat. No. 5,472,933 which is a continuation-in-part of application Ser. No. 573,074 filed Aug. 29, 1990, now abandoned.

BACKGROUND OF THE INVENTION

The present invention relates to herbicidal pyrrolesulfonylureas, compositions thereof and a method for their use as preemergence and/or postemergence herbicides or plant growth regulants.

New compounds effective for controlling the growth of undesired vegetation are in constant demand. In the most common situation, such compounds are sought to selectively control the growth of weeds in useful crops such as cotton, rice, corn, wheat and soybeans, to name a few. Unchecked weed growth in such crops can cause significant losses, reducing profit to the farmer and increasing costs to the consumer. In other situations, herbicides are desired which will control all plant growth. Examples of areas in which complete control of all vegetation is desired are areas around railroad tracks, storage tanks and industrial storage areas. There are many products commercially available for these purposes, but the search continues for products which are more effective, less costly and environmentally safe.

The "sulfonylurea" herbicides are an extremely potent class of herbicides discovered within the last few years which generally consist of a sulfonylurea bridge, --SO₂ NHCONH--, linking two aromatic or heteroaromatic rings.

U.S. Pat. No. 4,368,067 discloses herbicidal sulfonylureas of the formula ##STR1## wherein: R₁ is H, C₁ -C₄ alkyl, NO₂, CN, C(O)CCl₃, SO₂ R₁₁, C(O)R₅ or CO₂ H;

R₂ is H or C₁ -C₄ alkyl;

R₃ is H, C₁ -C₄ alkyl, Cl or Br;

R₄ is H, C₁ -C₄ alkyl, cyanoethyl, C₅ -C₆ cycloalkyl, benzyl, phenyl substituted with Cl or NO₂, or C(O)R⁶ ;

R₅ is C₁ -C₄ alkyl or C₁ -C₄ alkoxy;

R₆ is C₁ -C₄ alkyl, C₁ -C₄ alkoxy or NR⁷ R⁸ ; and

R₇ and R₈ are independently C₁ -C₂ alkyl.

U.S. Pat. No. 4,549,898 discloses herbicidal sulfonamides of the formula ##STR2## wherein: X is O, S, NR₄ or --C(R⁵)═N--;

R₂ is H, C₁ -C₃ alkyl, C₁ -C₃ haloalkyl, halogen, NO₂, C₁ -C₃ alkoxy, C(W)R⁸, SO₂ NR⁶ R⁷, S(O)_(n) -C₁ -C₃ alkyl or C(O)R⁹ ;

R⁴ is H, C₁ -C₄ alkyl, C₁ -C₄ cyanoalkyl, C₃ -C₆ cycloalkyl, benzyl, C(O)C₁ -C₄ alkoxy, C(O)NR⁶ R₇ or C(O)C₁ -C₄ alkyl which is unsubstituted or substituted by 1 to 3 halogen atoms;

R₆ is H, C₁ -C₆ alkyl, C₁ -C₄ cyanoalkyl, OCH₃ or OCH₂ CH₃ ;

R₇ is H, C₁ -C₆ alkyl or C₃ -C₆ alkenyl; or

R₆ and R⁷, together with the nitrogen atom to which they are attached, form a 5- or 6-membered saturated heterocyclic ring which may contain an oxygen; and

Y is O or S.

EP-A-126,711 discloses herbicidal sulfonamides of the formula ##STR3## wherein: Q is halogen, C₁ -C₄ alkyl, C₁ -C₄ haloalkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, NO₂, NH₂, C₁ -C₄ alkylamino, C₁ -C₄ dialkylamino, CN, C₁ -C₄ alkoxycarbonyl, CHO, C₂ -C₄ alkoxyalkyl, C₁ -C₄ alkylthio, C₁ -C₄ alkylsulfinyl, C₁ -C₄ alkylsulfonyl, C₁ -C₄ alkenyl or C₁ -C₄ alkynyl;

R₁ is H, halogen, NO₂, CR₆ (OC₁ -C₄ alkyl)₂, ##STR4## SO₂ NR₇ R₈, C(O)R₉ or (Y)mR₁₀ ; X is O, S, NR₅, C(R₅)═N, CH═CH or ##STR5## R₅ is H, C₁ -C₄ alkyl or C₃ -C₄ alkenyl.

EP-A-161,211 discloses herbicidal sulfonamides of the formula ##STR6## wherein: ##STR7##

R² is ##STR8## Q is O, S or NR⁷ ; A is O, S, SO, SO₂ or --(CR¹⁰ R₁₁)_(m) --;

m is 0, 1 or 2;

R⁷ is H, C₁ -C₄ alkyl, C₃ -C₆ cycloalkyl, benzyl or phenyl; and

R¹⁰ and R¹¹ are independently H or C₁ -C₄ alkyl.

SUMMARY OF THE INVENTION

The invention comprises compounds of Formula I, agriculturally suitable compositions thereof and a method of use as preemergence and/or postemergence herbicides or plant growth regulants. ##STR9## wherein: ##STR10## W is O or S; R is H or CH₃ ;

R¹ is H; CH₃ ; CH₂ OCH₃ ; CH₂ OC₂ H₅ ; CH₂ CN; CH₂ SCH₃, CH₂ SC₂ H₅ ; C₂ -C₆ alkyl optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; C₃ -C₄ alkenyl; C₃ -C₄ haloalkenyl; C₃ -C₆ cycloalkyl; C(O)R⁵ ; N(CH₃)₂ ; or Q¹ ;

R² is C₁ -C₄ alkyl optionally substituted with one CN, C₂ -C₃ alkylcarbonyl, methoxycarbonyl, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, C₁ -C₂ alkylsulfonyl, S(O)₂ NR⁶ R⁷, OH or one or more halogens; C₂ -C₄ alkenyl optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; (CH₂)_(m) Q² ; CN; C(O)R⁸ ; C(O)OR⁹ ; C(O)NR¹⁰ R¹¹ ; C(R¹²)═NOR¹³ ; C(R¹⁴)(OR¹⁵)(OR¹⁶); S(O)_(n) R¹⁷ ; S(O)₂ NR¹⁸ R¹⁹ ; NO₂ ; halogen or OR⁷³ ;

R³ is H, halogen or C₁ -C₄ alkyl;

R⁴ is H, C₁ -C₄ alkyl optionally substituted with one CN, C₂ -C₃ alkylcarbonyl, methoxycarbonyl, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, C₁ -C₂ alkylsulfonyl, S(O)₂ NR⁶ R⁷, OH or one or more halogens; C₂ -C₄ alkenyl optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; CN; C(O)R⁸ ; C(O)OR⁹ ; C(O)NR¹⁰ R¹¹ ; C(R¹²)═NOR¹³ ; S(O)_(n) R¹⁷ ; S(O)₂ NR¹⁸ R¹⁹ ; or halogen;

R⁵ is C₁ -C₄ alkyl, C₁ -C₄ alkoxy or NR²⁰ R²¹ ;

R⁶ is H, C₁ -C₂ alkyl or OCH₃ ;

R⁷ is C₁ -C₂ alkyl; or

R⁶ and R⁷ can be taken together as --(CH₂)₃ -- or --(CH₂)₄ --;

R⁸ is H, C₁ -C₃ alkyl or cyclopropyl;

R⁹ is CH₃ ; C₂ -C₃ alkyl optionally substituted with one C₁ -C₂ alkoxy, OH, CN or one or more halogens; C₃ -C₄ alkenyl; or propargyl;

R¹⁰ is H, C₁ -C₈ alkyl or OCH₃ ;

R¹¹ is C₁ -C₃ alkyl; or

R¹⁰ and R¹¹ can be taken together as --(CH₂)₃ --, --(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₂ O(CH₂)₂ --;

R¹² is H, C₁ -C₃ alkyl, allyl, halogen, CN, N₃, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio or SCN;

R¹³ is C₁ -C₃ alkyl or allyl;

R¹⁴ is H or C₁ -C₃ alkyl;

R¹⁵ and R¹⁶ are independently C₁ -C₂ alkyl;

R¹⁷ is C₁ -C₄ alkyl, optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; C₃ -C₄ alkenyl; or cyclopropylmethyl;

R¹⁸ is H, C₁ -C₃ alkyl or OCH₃ ;

R¹⁹ is H or C₁ -C₂ alkyl; or

R¹⁸ and R¹⁹ can be taken together as --(CH₂)₃ --, --(CH₂)₄ -- or --(CH₂)₅ --;

R²⁰ and R²¹ are independently C₁ -C₂ alkyl; or

R²⁰ and R²¹ can be taken together as --(CH₂)₃ --, --(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₂ O(CH₂)₂ --;

R⁷¹ is H, halogen or CF₃ ;

R⁷³ is C₁ -C₄ alkyl optionally substituted with one or more halogens, CN, C₁ -C₂ alkoxy, or C₁ -C₂ alkylthio; C(O)R⁷⁴ ; SO₂ R⁷⁵ ; C₃ -C₄ alkenyl; or propargyl;

R⁷⁴ is C₁ -C₄ alkyl optionally substituted with C₁ -C₂ alkoxy, one or more halogens, or CN; C₃ -C₄ alkenyl; or C₁ -C₃ alkoxy;

R⁷⁵ is C₁ -C₃ alkyl or CF₃ ;

m is 0 or 1;

n is 0, 1 or 2;

Q¹ is phenyl, phenyl substituted with one to two groups selected from halogen and CH₃, a fully unsaturated 5- or 6-membered heterocyclic ring containing 1 to 4 heteroatoms selected from 0-1 S, 0-1 O and 0-4 N and a fully unsaturated 5- or 6-membered heterocyclic ring substituted with one to two groups selected from C₁ -C₄ alkyl, C₃ -C₄ alkenyl, halogen, C₁ -C₃ alkoxy, C₁ -C₂ haloalkoxy, C₁ -C₃ alkylthio, C₃ -C₄ alkenylthio and C₁ -C₂ haloalkylthio, said Q¹ bound through a carbon atom;

Q² is phenyl, a saturated heterocyclic ring containing 1 to 2 heteroatoms selected from 0-2 O and 0-2 S, a partially saturated heterocyclic ring containing 1 to 2 heteroatoms selected from 0-2 O, 0-2 S and 0-2 N, a fully unsaturated 5- or 6-membered heterocyclic ring containing 1 to 4 heteroatoms selected from 0-1 S, 0-1 O and 0-4 N, phenyl substituted with one to two groups selected from halogen and CH₃, a saturated heterocyclic ring containing 1 to 2 heteroatoms selected from 0-2 O and 0-2 S substituted with one to two C₁ -C₃ alkyl groups, a partially saturated heterocyclic ring containing 1 to 2 heteroatoms selected from 0-2 O, 0-2 S and 0-2 N substituted with one to two C₁ -C₃ alkyl groups, and an unsaturated 5- or 6-membered heterocyclic ring containing 1 to 4 heteroatoms selected from 0-1 S, 0-1 O and 0-4 N substituted with one to two groups selected from C₁ -C₄ alkyl, C₃ -C₄ alkenyl, halogen, C₁ -C₃ alkoxy, C₁ -C₂ haloalkoxy, C₁ -C₃ alkylthio, C₃ -C₄ alkenylthio and C₁ -C₂ haloalkylthio; ##STR11## X is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkyl, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, halogen, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino or di(C₁ -C₃ alkyl)amino;

Y is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ alkylthio, C₁ -C₄ haloalkylthio, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino, di(C₁ -C₃ alkyl)amino, C₃ -C₄ alkenyloxy, C₃ -C₄ alkynyloxy, C₂ -C₅ alkylthioalkyl, C₂ -C₅ alkylsulfinylalkyl, C₂ -C₅ alkylsulfonylalkyl, C₁ -C₄ haloalkyl, C₂ -C₄ alkynyl, C₃ -C₅ cycloalkyl, azido, cyano, ##STR12## or N(OCH₃)CH₃ ; p is 2 or 3;

Q³ and Q⁴ are independently O or S;

R²² is H or C₁ -C₃ alkyl;

R²³ and R²⁴ are independently C₁ -C₃ alkyl;

Z is CH or N;

Z¹ is CH or N;

Y¹ is O or CH₂ ;

X¹ is CH₃, OCH₃ or OCF₂ H;

X² is CH₃, CH₂ CH₃ or CH₂ CF₃ ;

Y² is OCH₃, OCH₂ CH₃, SCH₃, SCH₂ CH₃, CH₃ or CH₂ CH₃ ;

X³ is CH₃ or OCH₃ ;

Y³ is H or CH₃ ;

X⁴ is CH₃, OCH₃, OCH₂ CH₃, CH₂ OCH₃ or Cl; and

Y⁴ is CH₃, OCH₃, OCH₂ CH₃ or Cl;

and their agriculturally suitable salts; provided that:

(a) when X and/or Y is C₁ haloalkoxy, then Z is CH;

(b) when m is zero, Q² is bound through carbon to the pyrrole ring in J;

(c) when X is F, Cl, Br or I, then Z is CH and Y is OCH₃, OCH₂ CH₃, N(OCH₃)CH₃, NHCH₃, N(CH₃)₂ or OCF₂ H;

(d) when W is S, then R is H, A is A-1 and Y is CH₃, OCH₃, OCH₂ CH₃, CH₂ OCH₃, CH₂ CH₃, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C═CH, OCH₂ CH₂ OCH₃, CH(OCH₃)₂ or ##STR13## (e) when the total number of carbon atoms of X and Y is greater than four, then the number of carbons of Q¹ and Q² for each is less than or equal to eight;

(f) when A is A-2, A-3, A-4, A-5, A-6 or A-7, then R is H;

(g) when J is J-1, A is A-1 and X or Y is alkyl, then R² is other the CN or NO₂ ;

(h) when J is J-1, A is A-2, A-3 or A-4 and R¹ is C(O)R⁵, then R² is other the alkyl; and

(i) when J is J-1, A is A-1 and X or Y is C₁ haloalkoxy, then R² is other the C(O)OR⁹.

In the above definitions, the term "alkyl", used either alone or in compound words such as "alkylthio" or "haloalkyl", includes straight chain and branched alkyl, e.g., methyl, ethyl, n-propyl, isopropyl and the different butyl isomers.

Alkoxy includes methoxy, ethoxy, n-propyloxy, isopropyloxy and the different butoxy isomers.

Alkenyl includes straight chain and branched alkenes, e.g., 1-propenyl, 2-propenyl, 3-propenyl and the different butenyl isomers.

Alkylsulfonyl includes methylsulfonyl and ethylsulfonyl.

Alkylthio, etc. are used analogously to the above examples.

Cycloalkyl includes cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl.

The term "halogen", either alone or in compound words such as "haloalkyl", means fluorine, chlorine, bromine or iodine. Further, when used in compound words such as "haloalkyl" said alkyl may be partially or fully substituted with halogen atoms, which may be the same or different. Examples of haloalkyl include CH₂ CH₂ F, CF₂ CF₃ and CH₂ CHFCl.

The total number of carbon atoms in a substituent group is indicated by the C_(i) -C_(j) prefix where i and j are numbers from 1 to 6. For example, C₁ -C₂ alkylsulfonyl would designate methylsulfonyl through ethylsulfonyl; C₂ -C₃ alkoxycarbonyl would designate methoxy and ethoxy attached through a carbonyl radical.

Compounds of the invention preferred for reasons including ease of synthesis and/or greater herbicidal efficacy are:

1. Compounds of Formula I wherein Q¹ is the fully unsaturated substituted or unsubstituted heterocyclic ring, and Q¹ is selected from pyridinyl, pyridinyl, thienyl, furanyl, 1,2,4-triazolyl, 1,2,3-thiadiazolyl, oxazolyl, thiazolyl, imidazolyl or tetrazolyl, and Q² is the substituted or unsubstituted heterocyclic ring containing 1 to 2 heteroatoms or the substituted or unsubstituted partially saturated heterocyclic ring containing 1 to 2 heteroatoms and Q² is elected from 1,3-dioxolanyl, 1,3-dioxanyl, pyridinyl, pyrimidinyl, thienyl, furanyl, 1,2,4-triazolyl, 1,2,3-thiadiazolyl, oxazolyl, thiazolyl, imidazolyl or tetrazolyl.

2. Compounds of Preferred 1 wherein: Q¹ is ##STR14## q is 0 or 1; R²⁵ and R²⁶ are independently H, CH₃ or Cl;

R²⁷ and R²⁸ are independently H, F, or CH₃ ;

R²⁹ is H, CH₃ or OCH₃ ;

R³⁰ is H or CH₃ ;

R³¹, R³² and R³³ are independently H, CH₃ or OCH₃ ;

R³⁴, R³⁵ and R³⁶ are independently H, CH₃, CH₂ CH₃, Cl, Br, OCH₃ or OCH₂ CH₃ ;

R³⁷ is H or C₁ -C₂ alkyl;

R³⁸ is CH₃ ;

R³⁹ is H, C₁ -C₂ alkyl, OCH₃ or SCH₃ ;

R⁴⁰ is H, CH₃ or CH₂ CH₃ ;

R⁴¹ and R⁴² are independently H or CH₃ ;

R⁴³ is H, CH₃, CH₂ CH₃ or C₃ H₇ ;

W¹ is O or S;

W² is O, S or NR⁴⁴ ;

R⁴⁴ is H or CH₃ ;

Q² is ##STR15## r is 0 or 1; R⁴⁵ and R⁴⁶ are independently H, CH₃ or Cl;

R⁴⁷ is H or C₁ -C₃ alkyl;

R⁴⁸ is H or CH₃ ;

R⁴⁹ and R⁵⁰ are independently H or CH₃ ;

R⁵¹ is H, CH₃ or OCH₃ ;

R⁵² is H or CH₃ ;

R⁵³ R⁵⁴ and R⁵⁵ are independently H, CH₃ or OCH₃ ;

R⁵⁶, R⁵⁷ and R⁵⁸ are independently H, CH₃, CH₂ CH₃, Cl, Br, OCH₃ or OCH₂ CH₃ ;

R⁵⁹ is H or C₁ -C₂ alkyl;

R⁶⁰ is CH₃ ;

R⁶¹ is H, C₁ -C₂ alkyl, OCH₃ or SCH₃ ;

R⁶² is H, CH₃ or CH₂ CH₃ ;

R⁶³ and R⁶⁴ are independently H or CH₃ ;

R⁶⁵ is H, CH₃, CH₂ CH₃ or C₃ H₇ ;

W³ is O or S;

W⁴ is O, S or NR⁶⁶ ; and

R⁶⁶ is H or CH₃.

3. Compounds of Preferred 2 wherein:

W is O;

R¹ is H, C₁ -C₆ alkyl, allyl, CH₂ OCH₃, CH₂ OC₂ H₅, CH₂ SCH₃ phenyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, C(O)OCH₃ or C(O)N(CH₃)₂ ;

X is C₁ -C₂ alkyl, C₁ -C₂ alkoxy, F, C₁, Br, I, OCF₂ H, CH₂ F, CF₃, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃, CH₂ Cl or CH₂ Br; and

Y is H, C₁ -C₂ alkyl, C₁ -C₂ alkoxy, CH₂ OCH₃, CH₂ OCH₂ CH₃, NCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C--CH, OCH₂ CH₂ OCH₃, CH₂ SCH₃, C(O)R²², ##STR16## OCF₂ H, SCF₂ H, cyclopropyl, C.tbd.CH or C.tbd.CCH₃.

4. Compounds of Preferred 3 wherein:

R³ is H, CH₃, Cl or Br; and

R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)NR¹⁰ R¹¹, C(R¹²)═NOR¹³, C(R¹⁴)(OR¹⁵)(OR¹⁶), S(O)_(n) R¹⁷, S(O)₂ NR¹⁸ R¹⁹, F, Cl or Br;

R⁸ is H or C₁ -C₂ alkyl;

R⁹ is C₁ -C₂ alkyl or CH₂ CH₂ Cl;

R¹⁰ is H or CH₃ ;

R¹¹ is CH₃ ;

R¹² is H, CH₃, C₂ H₅ or Cl;

R¹³ is CH₃ ;

R¹⁴ is H or C₁ -C₂ alkyl;

R¹⁵ and R¹⁶ are CH₃ ;

R¹⁷ is C₁ -C₂ alkyl;

R¹⁸ is H or CH₃ ;

R¹⁹ is CH₃ ; and

n is 0 or 2.

5. Compounds of Preferred 4 wherein:

R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)NR¹⁰ R¹¹, C(R¹²)═NOR¹³, C(R¹⁴)(OR¹⁵)(OR¹⁶), S(O)_(n) R¹⁷, S(O)₂ NR¹⁸ R¹⁹, F, Cl, Br or OR⁷³.

6. Compounds of Preferred 5 wherein:

R is H; and

R⁷¹ is H.

7. Compounds of Preferred 6 wherein:

J is 5-1.

8. Compounds of Preferred 6 wherein:

J is J-2.

9. Compounds of Preferred 6 wherein:

J is J-3.

10. Compounds of Preferred 7 wherein:

R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H5, S(O)₂ N(CH₃)₂, C₁ -C₂ alkoxy, OC(O)CH₃, or OSO₂ CH₃ ;

R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹ ; C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H₅ or S(O)₂ N(CH₃)₂ ;

R⁸ is C₁ -C₂ alkyl;

R⁹ is C₁ -C₂ alkyl;

Q² is Q² -1, Q² -4,

Q² -5, Q² -6, Q² -10, Q² -11, Q² -20 or Q² -21;

R⁴⁵, R⁴⁶, R⁴⁹, R⁵⁰, R⁵⁶, R⁵⁷ and R⁵⁸ are H;

R⁶⁵ is CH₃ ;

W³ is S; and

r is 0.

11. Compounds of Preferred 8 wherein:

R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H₅, S(O)₂ N(CH₃)₂, C₁ -C₂ alkoxy, OC(O)CH₃, or OSO₂ CH₃ ;

R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃ or S(O)₂ N(CH₃)₂ ;

R⁸ is C₁ -C₂ alkyl;

R⁹ is C₁ -C₂ alkyl; Q² is Q² -1, Q² -4, Q² -5, Q² -6, Q² -10, Q² -11, Q² -20 or Q² -21;

R⁴⁵, R⁴⁶, R⁴⁹, R⁵⁰, R⁵⁶, R⁵⁷ and R⁵⁸ are H;

R⁶⁵ is CH₃ ;

W³ is S; and

r is 0.

12. Compounds of Preferred 9 wherein:

R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H₅, S(O)₂ N(CH₃)₂, C₁ -C₂ alkoxy, OC(O)CH₃, or OSO₂ CH₃ ;

R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃ or S(O)₂ N(CH₃)₂ ;

R⁸ is C₁ -C₂ alkyl;

R⁹ is C₁ -C₂ alkyl;

Q² is Q² -1, Q² -4, Q² -5, Q² -6, Q² -10, Q² -11, Q² -20 or Q² -21;

R⁴⁵, R⁴⁶, R⁴⁹, R⁵⁰, R⁵⁶, R⁵⁷ and R⁵⁸ are H;

R⁶⁵ is CH₃ ;

W³ is S; and

r is 0.

13. Compounds of Preferred 10 wherein:

A is A-1;

X is CH₃, OCH₃, OCH₂ CH₃, OCH₂ CF₃ or Cl; and

Y is CH₃, OCH₃, NHCH₃ or N(CH₃)₂.

14. Compounds of Preferred 11 wherein:

A is A-1;

X is CH₃, OCH₃, OCH₂ CH₃, OCH₂ CF₃ or Cl; and

Y is CH₃, OCH₃, NHCH₃ or N(CH₃)₂.

15. Compounds of Preferred 12 wherein

A is A-1;

X is CH₃, OCH₃, OCH₂ CH₃, OCH₂ CF₃ or Cl; and

Y is CH₃, OCH₃, NHCH₃ or N(CH₃)₂.

Compounds of the invention specifically preferred for reasons of greatest ease of synthesis and/or greatest herbicidal efficacy are:

Methyl 3- (4,6-dimethoxy-2-pyramidinyl)amino!carbonyl!-amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate;

Methyl 3- 4-ethoxy-6-(methylamino)-1,3,5-triazin-2-yl!-amino!carbonyl!amino!-sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate;

N³ - (4-ethyl-6-methoxy-1,3,5-triazin-2-yl)-amino!carbonyl!-N²,N²,1-trimethyl-1H-pyrrole-2,3-disulfonamide;

N³ - (4,6-dimethoxy-2-pyrimidinyl)amino!carbonyl!-N²,N²,1-trimethyl-1H-pyrrole-2,3-disulfonamide;

Methyl 1-ethyl-2- (4-methoxy-6-methyl-1,3,5-triazin-2-yl)-amino!-carbonyl!amino!sulfonyl!-1H-pyrrole-3-carboxylate;

2-(ethylsulfonyl)-N- -(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino!-carbonyl!-1-methyl-1H-pyrrole-3-sulfonamide; and

2- (4,6-dimethoxy-2 pyrimidinyl)amino!carbonyl!-amino!sulfonyl!-N,N,1-trimethyl-1H-pyrrole-3-carboxamide.

The invention also comprises novel compounds, such as the bromopyrrolesulfonamides of Formula II, useful as intermediates to the compounds of Formula I. ##STR17## wherein: R⁶⁷ is H, C(CH₃)₃ or Si(CH₃)₂ C(CH₃)₃ ; and

R⁷² is H or Si(CH(CH₃)₂)₃.

Another embodiment of the invention is the process for preparing any of the above compounds, said process comprising reacting

(a) the compounds of Equation 1 in an inert polar aprotic solvent for 5 minutes to 24 hours or more at 20° to 80° C. ##STR18##

(b) the compounds of Equation 2 in an inert solvent followed by treatment with aqueous acid ##STR19##

(c) the compounds of Equation 3 in an inert solvent for 0.5 to 24 hours ##STR20##

(d) the compounds of Equation 4 in an inert solvent at 20° to 80° C. for 0.5 to 24 hours and in the presence of 1 to 1.4 equivalents of a base ##STR21##

DETAILED DESCRIPTION OF THE INVENTION

Synthesis

The sulfonylureas of Formula I can be prepared by a number of methods. These methods are described below along with the appropriate references for greater detail. ##STR22##

One of the methods of synthesis of sulfonylureas of Formula I is depicted in Equation 1 where J, R, and A are as defined above. A sulfonylisocyanate of Formula 2 is contacted with a heterocyclic amine of Formula 3 in an inert polar aprotic solvent, such as acetonitrile, dichloromethane, etc. for periods of several minutes to 24 hours or more, preferably at a temperature in the range of 20° to 80° C. to afford a sulfonylurea of Formula I.

U.S. Pat. Nos. 4,127,405; 4,257,802; and 4,221,585 disclose this equation and are herein incorporated by reference. ##STR23##

Another method of synthesis of compounds of Formula I is depicted in Equation 2 where J, R, and A are as defined previously and R⁶⁸ is lower alkyl such as methyl or ethyl. A sulfonamide of Formula 4 is contacted with an alkyl carbamate of Formula 5 in the presence of a trialkylaluminum in an inert solvent such as dichloromethane, 1,2-dichloroethane, etc., and subsequently treated with aqueous acid to afford a sulfonylurea of Formula I. This reaction is taught in European Patent Publication EP-A-83,975 (published Jul. 20, 1983). ##STR24##

Alternatively, compounds of Formula I can be prepared by the method shown in Equation 3 where A, J, and R are as defined previously and Ar represents an aryl group, for example a phenyl group. In this reaction, a sulfonylcarbamate of Formula 6 is contacted with a heterocyclic amine of Formula 3 in an inert solvent such as p-dioxane for a period of 0.5 to 24 hours, as taught in European Patent Publication EP-A-44,807. ##STR25##

A fourth method of preparation for compounds of Formula I is depicted in Equation 4 where A, R, and J are as defined previously and Ar represents an aryl group, for example a phenyl or substituted phenyl group. In this reaction, a sulfonamide of Formula 4 is contacted with a heterocyclic carbamate of Formula 7 in an inert solvent such as p-dioxane or acetonitrile preferably at temperatures in the range of from 20° to 80° C. for periods of 0.5 to 24 hours in the presence of 1 to 1.4 equivalents of a base such as 1,8-diazabicyclo 5.4.0!undec-7-ene (DBU). The resultant products are isolated by dilution of the reaction mixture with aqueous acid to afford sulfonylureas of Formula I. The reaction is taught in European Patent Publications EP-A-44,807, and EP-A-85,028.

Intermediate Compounds

Heterocyclic sulfonyl isocyanates of Formula 2 can be prepared by treatment of sulfonamides of Formula 4 by the procedures taught in U.S. Pat. No. 4,127,405. Heterocyclic carbamates of Formula 5 are prepared by procedures taught in European Patent Publication EP-A-83,975.

The sulfonylcarbamates of Formula 6 and heterocyclic carbamates of Formula 7 can be prepared by procedures taught in European Patent Publications EP-A-44,807, EP-A-72,347, EP-A-173,498 and U.S. Pat. No. 4,666,506 and references cited therein.

The intermediate pyrrole sulfonamides of Formula 4 can be prepared by a variety of methods, some of which are described in the sequence of reactions shown in Equations 5 through 24.

The sulfonamides of Formula 4 of this invention where J is J-1, J-2 or J-3 as defined above can be synthesized from the precursor sulfonamides of Formula 88 where J is as defined above and R⁶⁹ is a suitable protecting group such as tert-alkyl or trialkylsilyl, by appropriate methods known to one skilled in the art, as depicted in Equation 5. ##STR26##

Sulfonamides of Formula 8 where J is J-2 or J-3, R¹ is as defined above or is a masked synthon thereof, R² is as defined above or is a masked synthon thereof, R⁶⁹ is as previously defined and R⁴ is other than H, X⁵ is a suitable leaving group such as but not limited to chloro, bromo, iodo, alkyl- or arylsulfonate, may be prepared by methods similar to the depiction in Equation 6. The general methodology described for the instance when J is J-2 is directly applicable to the instances where J is J-3. Further, the synthetic necessity, and selection of specific masked synthons for specific definitions of R¹ and R² are known to one skilled in the art, for the introduction of R⁴ into the sulfonamide of Formula 9. ##STR27##

A sulfonamide of Formula 9 can be metalated on carbon using an excess of an organometallic base, preferably an organolithium reagent such as n-butyllithium, n-butyllithium/tetramethylethylenediamine (TMEDA) or lithium diisopropylamide in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C., followed by quenching with the appropriate electrophilic reagent (R⁴ -X⁵) affording sulfonamide of Formula 8 after standard aqueous workup.

A sulfonamide of Formula 9 where J is J-2, R¹, R² and R⁶⁹ are as previously defined, X⁵ is a suitable leaving group such as but not limited to chloro, bromo, iodo, alkyl- or arylsulfonate, acid chloride or N,N-dialkylamide, can be prepared by methods similar to those depicted in Equation 7. ##STR28##

A sulfonamide of Formula 10 can be metalated on carbon using an excess of organometallic base, as described in J. Org. Chem., vol. 50, p-4368, (1985) and J. Chem Soc. Perkin Trans., I, p. 1343, (1982) and the references cited therein, preferably an organolithium reagent such as n-butyllithium, n-butyllithium/tetramethylethylenediamine (TMEDA) or lithium diisopropylamide, in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C., followed by quenching with an appropriate electrophilic reagent (R² -X⁵) affording sulfonamide of Formula 8 after standard aqueous workup. A sulfonamide of Formula 9 where J is J-3, R¹, R² and R⁶⁹ are as previously defined, X⁵ is a suitable leaving group such as but not limited to chloro, bromo, iodo, alkyl- or arylsulfonate, can be prepared by methods similar to those depicted in Equation 8. ##STR29##

A sulfonamide of Formula 11 can be treated with a base such as an alkali metal alkoxide, hydride or tertiary amine and an appropriate electrophilic reagent (R¹ -X⁵) as shown in an inert solvent, preferably a polar aprotic solvent such as dimethylformamide (DMF) to afford a sulfonamide of Formula 9.

Sulfonamides of Formula 10, where J is J-2, R¹, R⁶⁹ and X⁵ are as previously defined, can be prepared by methods similar to those depicted in Equation 9. ##STR30##

A sulfonamide of Formula 12 is treated with a base such as an alkali metal alkoxide, hydride or tertiary amine and an appropriate electrophilic reagent (R¹ -X⁵) as shown in an inert solvent, preferably a polar aprotic solvent such as dimethylformamide (DMF), at a temperature in the range of 20° to 80° C., for a period of 1 to 24 hours to afford a sulfonamide of Formula 10.

Pyrrole sulfonamides of Formula 12, where R⁶⁹ is a suitable protecting group as defined above are available from the corresponding bromopyrroles 18 as outlined in Equation 10, where R⁷⁰ is lower such as isopropyl. ##STR31##

N-Silyl-protected pyrrole 13 where R⁷⁰ is preferably an isopropyl group, is treated with an alkyllithium reagent such as n-butyllithium as described in Chem. Ber., Vol 122 p.169 (1989), and references cited therein. The resultant metalated species is treated with sulfur dioxide to afford sulfinate salt 14 which can be converted to sulfonamide 15 by any of several known methods, for example treatment with N-chlorosuccinimide followed by amination with an appropriate primary amine as disclosed in U.S. Pat. No. 4,481,029. The N-silyl group is then removed, most conveniently with an alkali fluoride or quaternary ammonium fluoride salt to afford pyrrole-3-sulfonamide 1.2.

Sulfonamides of Formula 11, where J is J-3, R², R⁶⁹ and X⁵ are as previously defined, can be prepared by methods similar to those depicted in Equation 11, where R⁷⁰ is lower alkyl, such as isopropyl. ##STR32##

A sulfonamide of Formula 16 undergoes metal-halogen exchange on carbon using an excess of organometallic base, as described in J. Org. Chem., vol. 50, p. 4362-4368, (1985) and J. Chem Soc. Perkin Trans., I, p. 1343, (1982) and the references cited therein, preferably an organolithium reagent such as n-butyllithium, n-butyl-lithium/tetramethylethylenediamine (TMEDA) in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C., followed by quenching with an appropriate electrophilic reagent (R² -X⁵) affording intermediate sulfonamide of Formula 17. The N-silyl group is then removed, most conveniently with an alkali fluoride or quaternary ammonium fluoride salt to afford sulfonamide 11.

A pyrrole sulfonamide of Formula 16, where R⁶⁹ is a suitable protecting group as defined above can be prepared from the corresponding bromopyrrole 13 as outlined in Equation 12, where R⁷⁰ is lower alkyl, such as isopropyl. ##STR33##

N-silyl-protected pyrrole 13 where R⁷⁰ is preferably an isopropyl group, is treated with an alkyllithium reagent such as n-butyllithium as described in Chem. Ber., Vol. 122, p. 169 (1989), and references cited therein. The resultant metalated species is treated with sulfur dioxide to afford sulfinate salt 18 which can be converted to sulfonamide 19 by any of several known methods, for example treatment with N-chloro-succinimide in a solvent such as acetic acid, methylene chloride/H₂ O, 1,1,2-trichlorotrifluoroethene/H₂ O at a temperature from 0° C. to ambient temperature followed by amination with an appropriate primary amine as disclosed in U.S. Pat. No. 4,481,029. Sulfonamide 19 can be converted to a compound of Formula 16 by treatment with N-bromosuccinimide in an inert solvent such as tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C. as described in J. Org. Chem., Vol. 55, No. 26, pp. 637-28 (1990) and the references cited therein.

In the cases where R² is not directly obtainable as an electrophilic reagent (R² -X5), wherein R² is defined as --S(O)₂ NR¹⁸ R¹⁹, --CONR¹⁰ R¹¹, C(R¹²)═NOR¹³, --S(O)_(n) --R¹⁷, C(O)R⁸, (CH₂)_(m) --Q² or --CN the desired compounds can be obtained through a series of functional group transformations known to one skilled in the art. The general methodology described for the instance when J is J-2 is directly applicable to the instances where J is J-1 or J-3 with modifications known to one skilled in the art. Therefore, only the instances where J is J-2, R¹ is CH₈ and R⁶⁹ is a suitable protecting group such as tert-alkyl or trialkylsilyl will be described in Equations 13 to 19.

Equation 13 depicts a sequence of reactions whereby one can obtain a sulfonamide of Formula 21 where J is J-2, R¹ and R⁶⁹ are as previously defined and R² is --S(O)₂ NR¹⁸ R¹⁹ wherein R¹⁸ and R¹⁹ are as defined above. ##STR34##

A precursor sulfonamide of Formula 10 can be metalated on carbon using an excess of organometallic base, similar to that described in J. Org. Chem., vol. 50, p. 4362-4368, (1985) and J. Chem Soc. Perkin Trans., I, p. 1343, (1982) and the references cited therein, preferably an organolithium reagent such as n-butyllithium, n-butyllithium/tetramethylethylenediamine (TMEDA) or lithium diisopropylamide, in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C. The resultant metalated species is treated with sulfur dioxide to afford sulfinate salt 20 which can be converted to sulfonamide 21 by any of several known methods, for example treatment with N-chlorosuccinimide followed by amination with an appropriate amine in an analogous manner to that disclosed in U.S. Pat. No. 4,481,029.

In an analogous manner Equation 14 outlines a sequence wherein one can prepare a sulfonamide of Formula 22 where J is J-2, R¹ and R⁶⁹ are as previously defined and R² is --C(O)NR¹⁰ R¹¹. ##STR35##

A precursor sulfonamide of Formula 9 where R² is defined for example as --C(O)OR⁹ where R⁹ is preferably methyl or ethyl, can be converted to amide 22 by any of several known methods, for example contacting the ester with an appropriate amine in the presence of an organometallic base in an analogous manner to that disclosed in Tetrahedron Letters, No. 21, p. 1791, (1970).

Equation 15 outlines a sequence whereby one can prepare a sulfonamide of Formula 23 where J is J-2, R¹ and R⁶⁹ are as previously defined and R² is --CN. ##STR36##

A precursor sulfonamide of Formula 9 where R² is defined for example as --CONH₂ can be converted to nitrile 23 by any of several known methods, for example contacting the amide with triphenylphosphine and CCl₄ in an inert solvent, in an analogous manner to that disclosed in Tetrahedron Letters, No. 21, p. 4383, (1970), or by dehydration with thionyl chloride as described in Org. Syn., coll. vol. IV, p. 436, (1963).

Equation 16 depicts a sequence whereby one can prepare a sulfonamide of Formula 25 where J is J-2, R¹ and R⁶⁹ are as previously defined, R² is (CH₂)_(m) -Q², Q² is Q² -1, Q² -4, Q² -5, Q² -6, Q² -7, Q² -S, Q² -9, Q² -10 or Q² -11, r is 0, m is 0 and M is ZnCl_(x), ZnBr_(x), or B(OH)₂. ##STR37##

A sulfonamide of Formula 10 can be metalated on carbon using an excess of organometallic base, similar to that described in J. Org. Chem., vol. 50, p. 4362-4368, (1985) and J. Chem Soc. Perkin Trans., I, p. 1343, (1982) and the references cited therein, preferably an organolithium reagent such as n-butyllithium, n-butyllithium/tetramethylethylenediamine (TMEDA) or lithium diisopropylamide, in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofurau (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C. The metalated species can be transmetalated with anhydrous zinc chloride, by methods similar to those described in Tetrahedron Letters, Vol.29, No.39, pp. 5013-5016, (1988). The transmetalated species 24 can be coupled to an arylhalide substrate, for instance 2-bromopyridine, in the presence of excess zinc chloride anda palladium catalyst to afford the biaryl species of Formula 25. Alternatively, the metalated species can be quenched with an alkyl borate, for instance trimethylborate affording the corresponding 2-boronic acid species 24 upon hydrolysis. The pyrrole boronic acid species can be coupled to an arylhalide substrate by methods similar to those described in Tetrahedron Letters, vol. 26, No. 49, pp. 5997-6000, (1985) and Tetrahedron Letters., vol. 29, No. 43, p. 5459-5462, (1988) and the references cited therein, for instance 2-bromopyridine in the presence of a palladium catalyst and a base, in an inert solvent such as toluene or dimethoxyethane (DME), at reflux temperature for periods of 1 to 24 hours affording the biaryl species of Formula 25.

Equation 17 outlines a sequence whereby one can prepare a sulfonamide of Formula 27 where J is J-2, R¹ and R⁶⁹ are as previously defined, R² is --C(R¹²)═NOR¹³, R¹² is H and R¹³ is as previously defined. ##STR38##

A sulfonamide of Formula 10 can be metalated on carbon using an excess of organometallic base, similar to that described in J. Org. Chem., vol. 50, p. 4362-4368, (1985) and J. Chem Soc. Perkin Trans., I, p. 1343, (1982) and the references cited therein, preferably an organolithium reagent such as n-butyllithium, n-butyllithium/tetramethylethylenediamine (TMEDA) or lithium diisopropylamide, in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C. The metalated species, quenched with dimethylformamide (DMF) affords the corresponding pyrrole-2-aldehyde 26 following aqueous workup. The aldehyde species 26 is contacted with an alkoxy amine (H₂ N--OR¹³), for instance methoxylamine hydrochloride in the presence of a base, for example sodium acetate, in an inert solvent such as acetone, tetrahydrofuran, dioxane or methanol. The reaction is carried out at temperatures in the range of 20° C. to reflux for a period of 1 to 24 hours and optionally in the presence of a phase transfer catalyst such as a crown ether.

Equation 18 depicts a sequence whereby one can prepare a sulfonamide of Formula 29 where J is J-2, R¹ and R⁶⁹ are as previously defined and R² is --C(O)R⁸ where R⁸ is as defined above. ##STR39##

A sulfonamide of Formula 10 can be metalated on carbon using an excess of organometallic base, similar to that described in J. Org. Chem., vol. 50, p. 4362-4368, (1985) and J. Chem Soc. Perkin Trans., I, p. 1343, (1982) and the references cited therein, preferably an organolithium reagent such as n-butyllithium, n-butyllithium/tetramethyl-ethylenediamine (TMEDA) or lithium diisopropylamide, in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C. The metalated species, quenched with an aldehyde (R⁸ CHO) affords the alcohol 28 following aqueous workup. Alcohol 28 can be oxidized to a ketone of Formula 29 by contact with one of several oxidants known to one skilled in the art, for example tetra-n-propylammonium perruthenate/N-methylmorpholine N-oxide as described in Aldrichimica Acta., Vol. 23, No. 1, p. 13-17, (1990) and the references cited therein.

Equation 19 outlines a sequence whereby one can prepare a sulfonamide of Formula 31 where J is J-2, R¹ and R⁶⁹ are as previously defined and R² is --S(O)_(n) --R¹⁷, where R¹⁷ is as defined above and n is 1 or 2. ##STR40##

A sulfonamide of Formula 10 can be metalated on carbon using an excess of organometallic base, similar to that described in J. Org. Chem., vol. 50, p. 4362-4368, (1985) and J. Chem Soc. Perkin Trans., I, p. 1343, (1982) and the references cited therein, preferably an organolithium reagent such as n-butyllithium, n-butyllithium/tetramethylethylenediamine (TMEDA) or lithium diisopropylamide, in an inert solvent such as diethyl ether, dimethoxyethane (DME) or tetrahydrofuran (THF), under anhydrous conditions, preferably at a temperature in the range of -100° to -70° C. The metalated species, quenched with an appropriate disulfide (R¹⁷ -S-S-R¹⁷) affords thioether 30 following aqueous workup. The thioether can be oxidized selectively to the corresponding sulfoxide or sulfone of Formula 31 by contact with one of several suitable oxidants such as a peroxy acid or hydrogen peroxide.

Pyrrole sulfonamide precursors of Formula 36 where J is J-1, R³ is H or alkyl and R⁶⁹ is a trialkylsilyl protecting group can be prepared from the corresponding N-substituted pyrrole 32 as outlined in Equation 20. ##STR41##

Pyrroles of Formula 32 are generally known in the art or can be prepared by a variety of known alkylation or acylation procedures such as those reviewed in "Pyrroles", R. Alan Jones, Ed., "The Chemistry of Heterocyclic Compounds", Vol. 48, Part 1 (John Wiley & Sons, Inc., 1990, New York) p. 397. Metalation of pyrroles 32 is likewise known to produce reactive 2-lithio intermediates as described in Synthetic Communications, Vol. 12, p. 231 (1982) and in J. Org. Chem., Vol. 46, p. 157 (1981) and references cited therein. Treatment of these reactive metalated species with sulfur dioxide affords sulfinate salts 33. These can be converted to sulfonamides 34 by methods described above, or directly by treatment with hydroxylamine-O-sulfonic acid in aqueous media as described in Synthesis, p. 1031 (1986). Treatment of sulfonamides 34 with a base and a trialkylsilyl chloride such as t-butyldimethylsilyl chloride affords the protected sulfonamides 35. Metalation of 35 with two equivalents of an organometallic base such as n-butyllithium, lithium diisopropylamide or lithium 2,2,6,6-tetramethylpiperidide (LTMP) and quenching with an appropriate electrophilic reagent R² X⁵ affords substituted sulfonamides 36. Directed metalations of this type on 1,2-disubstituted pyrroles have been described in J. Org. Chem., Vol. 50, p. 4362 (1985) and J. Chem. Soc. Perkin Trans. I, p. 1343 (1982) and references cited therein. When 32 contains R¹ groups that are incompatible with strongly basic conditions of the subsequent reactions, such as when R¹ is CO₂ CH₃ or C(O)CH₃, a suitable protecting group in place of R¹ can be substituted such as those described in J. Org. Chem., Vol 46, p. 157 (1981), ibid., p. 3760, and in Tetrahedron, Vol. 42, p. 3723 (1986). This protecting group can be removed at a suitable point in the synthesis, such as after the synthesis of sulfonamide 36, and replaced with the appropriate R¹ group by standard alkylation or acylation methods as described above. Intermediates 34 or 35 where R³ is hydrogen can be directly halogenated to afford the corresponding substituted sulfonamides 34 or 35 where R³ is halogen. Conversion of these intermediates to sulfonamides of Formula 36 where R³ is halogen is best carried out using a substituted lithium amide base, such as lithium diisopropylamide, followed by treatment with an electrophilic reagent as described above.

Intermediate sulfonamides of Formula 38 where J is J-1 and R⁷¹ is other than H can be prepared as depicted in Equation 21 from the corresponding sulfonamides 36, where X⁶ is chloro, bromo or iodo. ##STR42##

Treatment of sulfonamides 36 with a halogenating agent affords sulfonamides 37 where X⁶ is chloro, bromo, or iodo. Further treatment of 37 where X⁶ is bromo or iodo with an alkyllithium in an inert solvent followed by an alkyl halide affords sulfonamides 38 where R⁷¹ is lower alkyl. Likewise treatment of 37 with an alkyllithium reagent and subsequently with a mild fluorinating agent such as that described in J. Am. Chem. Soc., Vol. 106, p. 452 (1984) affords sulfonamides 38 wherein R⁷¹ is a fluoro substituent. Compounds of 37 where X⁶ is bromo or iodo to 38 where R⁷¹ is CF₃ can be accomplished by first treatment with an alkyllithium reagent followed by quenching with carbon dioxide to afford an intermediate acid 37 where R⁷¹ is COOH, and subsequent reaction with sulfur tetrafluoride or the like.

An intermediate pyrrole of Formula 40 where R¹ is defined as Q¹ above, can be prepared by the method outlined in Equation 22. ##STR43##

Amine 39 can be condensed with 2,5-dimethoxy tetrahydrofuran by the method described in Org. Syn., coll. vol. V, pp. 716-717, affording pyrrole 40.

Intermediate sulfonamides of Formula 44 where J is J-1, R³ is H, R¹ is Q¹ and R⁶⁹ is a trialkylsilyl protective group can be prepared from the corresponding N-substituted pyrrole 40 as depicted in Equation 23. ##STR44##

Pyrroles of Formula 40 can be metalated on carbon using an organometallic base, as described in Org. React., vol. 26, p. 21 (1979) and the references cited therein, preferably using an organolithium reagent such as n-butyllithium, lithium diisopropyl amide, or n-butyllithium/tetramethylethylenediamine. Treatment of the metalated species with sulfur dioxide affords the sulfinate salts 41. These can be converted to sulfonamides 42 by methods described above. Treatment of 42 with a base and a trialkylsilyl chloride affords protected sulfonamides 43. Metalation of 43 with two equivalents of an organometallic base as described above, and quenching with an appropriate electrophilic reagent R² X⁵ affords substituted sulfonamides 44.

Intermediate sulfonamides of Formula 49 where J is J-2, R⁴ is H, R¹ is Q¹ and R⁶⁹ is a trialkylsilyl protecting group can be prepared from the corresponding N-substituted pyrrole 40 as outlined in Equation 24. ##STR45##

Pyrroles of Formula 40 can be brominated by methods similar to those reviewed in "Pyrroles," R. Alan Jones, Ed., "The Chemistry of Heterocyclic Compounds," vol. 48, Prt. 1 (John Wiley & Sons, Inc., 1990, New York) p. 372, affording 3-bromo pyrroles of Formula 45. Pyrroles of Formula 45 can undergo metal halogen exchange by the methods described above with an organometallic base, preferably an organolithium reagent. Treatment of the metalated species with sulfur dioxide affords sulfate salts 46. These salts can be converted to sulfonamides 47 by methods described above. Treatment of 47 with a base and a trialkylsilyl chloride affords protected sulfonamides 48. Metalation of 48 with two equivalents of an organometallic base such as n-butyllithium, lithium diisopropyl amide or n-butyllithium/tetramethylethylenediamine and quenching with an appropriate electrophilic reagent R² X⁵ affords substituted sulfonamides 49. Directed metalation of 1,3-disubstituted pyrroles is described above.

Compounds of Formula 53 can be prepared by the method outlined in Equation 25. ##STR46##

Compound 50, prepared by the method described in J. Org. Chem., 55, 6317 (1990), is treated with 1 equivalent of an alkyllithium reagent such as n-butyllithium, and the resulting metalated species is treated with sulfur dioxide to obtain sulfinate salt 51 which can be converted to sulfonamide 52. by any of several known methods. For example treatment with N-chlorosuccinimide in acetic acid, followed by stagnation. The sulfonamide 52 is treated with a base such as an alkali metal alkoxide, hydride or tertiary amine and an appropriate electrophilic reagent (R¹ -X⁵) as shown in an inert solvent, to give a sulfonamide of Formula 53.

Sulfonamides of Formula 54 or 55 can be prepared by methods similar to those depicted in Equation 26. ##STR47##

Sulfonamide 53 can be treated with cupric cyanide in a polar aprotic solvent preferably DMF, at a temperature in the range of 100° to 155° C. For a period of 6 to 28 hours to afford a sulfonamide of Formula 54. Treatment of sulfonamide 53 with an aryl boronic acid in the presence of a palladium (O) catalyst, such as tetrakis (triphenylphosphine) palladium, and an inorganic base, such as sodium carbonate, by methods similar to those described in Synthetic Comm., 11 513 (1981), affords sulfonamides of Formula 55.

Sulfonamides of Formula 11 may also be prepared by the method depicted in Equation 27. ##STR48##

N-Silyl-protected pyrrole 50 where R⁷⁰ is preferably an isopropyl group, is treated with an alkyllithium reagent such as n-butyllithium, and the resulting metalated species is treated with an appropriate electrophilic reagent (R² -X⁵) as shown in an inert solvent to afford compound 56. Similar treatment of compound 56 with an alkyllithium reagent such as n-butyllithium and quenching of the metalated species thus formed with sulfur dioxide affords the sulfinate salt 57 which can be converted to sulfonamide 11 by any of several known methods as described above.

The synthesis of heterocyclic amine derivatives such as those depicted in Formulas 3, 5 and 7 are either known, or can be prepared by obvious methods known to one skilled in the art. For a review of the synthesis and reactions of 2-amino- and 2-methylaminopyrimidines see The Chemistry of Heterocyclic Compounds, vol 16, Wiley-Interscience, New York (1962). For a review of the synthesis and reactions of 2-amino- and 2-methylamino-s-triazines, see The Chemistry of Heterocyclic Compounds, vol 13, Wiley-Interscience, New York (1959), F. C. Schaefer U.S. Pat. No. 3,154,537 and F. C. Schaefer and K. R. Huffman J. Org. Chem., 28, 1812 (1963). J. Chem. Soc., 2031 (1966), EP-A-173,498 and U.S. Pat. No. 4,666,506 describes further methods. The synthesis of the bicyclic amines of Formula 3 where A is A-2 and A-3 is taught in U.S. Pat. No. 4,339,267. The synthesis of bicyclic amines of Formula 3, where A is A-4 is taught in European Patent Publication EP-A-46,667.

The synthesis of compounds of Formula 3 where A is A-5 are described European Patent Publication EP-A-73,562. The synthesis of compounds of Formula 3 where A is A-6 are described European Patent Publication EP-A-94,260.

The compounds of Formula 3 where A is A-7 can be prepared by methods taught in EP-A-125,864 (published Nov. 21, 1984) or by suitable modifications that would be obvious to one skilled in the art.

The amines of Formula A where X¹ is OCF₂ H can be prepared by methods taught in EP-A-72,347, or by suitable modifications that would be obvious to one skilled in the art.

The pyrimidines of Formula 3 where A is A-1 (Z=CH) and where Y is ##STR49## can be prepared according to the method taught in European Patent Publication EP-A-84,224 or suitable modifications thereof known to one skilled in the art.

Agricultural suitable salts of compounds of Formula I are also useful herbicides and can be prepared in a number of ways known to the art. For example, metal salts can be made by contacting compounds of Formula I with a solution of an alkali or alkaline earth metal salt having a sufficiently basic anion (e.g., hydroxide, alkoxide, carbonate or hydroxides). Quaternary amine salts can be made by similar techniques.

Salts of compounds of Formula I can also be prepared by exchange of one cation for another. Cationic exchange can be effected by direct contact of an aqueous solution of a salt of a compound of Formula I (e.g., alkali or quaternary amine salt) with a solution containing the cation to be exchanged. This method is most effective when the desired salt containing the exchanged cation is insoluble in water and can be separated by filtration.

Exchange may also be effected by passing an aqueous solution of a salt of a compound of Formula I (e.g., alkali metal or quaternary amine salt) through a column packed with a cation exchange resin containing the cation to be exchanged for that of the original salt and the desired product is eluted from the column. This method is particularly useful when the desired salt is water-soluble, e.g., potassium, sodium or calcium salt.

Acid addition salts useful in this invention, can be obtained by reacting a compound of Formula I with a suitable acid, e.g., p-toluenesulfonic acid, trichloroacetic acid or the like.

The preparation of the compounds of this invention is further illustrated by the following specific examples. Abbreviations for nuclear magnetic resonance (NMR) signals are: s=singlet, bs=broad singlet, d=doublet, t=triplet, m=multiplet, q=quartet, and peak positions are reported as parts per million downfield from internal tetramethylsilane. Infrared (IR) peak positions are given in reciprocal centimeters (cm⁻¹) and sh denotes shoulder.

EXAMPLE 1

N-(1,1-Dimethylethyl)-1- tris-(1-methylethyl)silyl!-1H-3-sulfonamide

A solution of 30.25 g (0.10 mol) of 3-bromo-N-triisopropylsilylpyrrole in 500 mL of anhydrous tetrahydrofuran (THF) under nitrogen atmosphere was cooled to -78° C. The colorless solution was treated with 44 mL of 2.38M n-butyllithium in hexanes (0.105 mol) dropwise at such a rate as to keep the temperature below -65° C. After ca. 1 hour at -78° C., liquified sulfur dioxide was added (25.8 ml, 0.6 mol). The amber solution was warmed to room temperature and stirred for ca. 1 hour. The THF was removed under reduced pressure. The resulting amber oil was dissolved in 500 mL glacial acetic acid, cooled to 20° C. and then treated with 13.35 g (0.1 mol) of N-chlorosuccinimide. After ca. 1 hour at room temperature the acetic acid was evaporated at reduced pressure and the residue was dissolved in ethyl acetate. This solution was washed successively with water, NaHCO₃ solution, brine, then dried (MgSO₄) and evaporated in vacuo. The resulting amber oil residue was dissolved in methylene chloride 500 mL cooled to -20° C. and treated with t-butylamine. The resulting dark brown turbid solution was allowed to warm to room temperature and stir overnight ca. 16 hours. The solution was washed with 1N HCl, dried (MgSO₄) and evaporated to a dark oil. Chromatography on silica gel (20% ethyl acetate/80% hexanes) afforded 10.48 g of the title compound as a cream colored solid, m.p. 103°-104° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 7.28 (d, 1H), 6.74(m,1H), 6.56(bs,1H), 4.39(bs,1H), 1.45(m,3H), 1.23(s,9H), 1.08(d,18H).

EXAMPLE 2 N-(1,1-Dimethylethyl)-1H-pyrrole-3-sulfonamide

A solution of N-(1,1-dimethylethyl)-1- tris-(1-methylethyl)silyl!-1H-3-sulfonamide (10.48 g, 0.0293 mol) in 100 mL diethyl ether under a nitrogen atmosphere was treated with tetrabutylammoniumfluoridehydrate 10.16 g (0.0388 mol) followed by 1.8 mL of glacial acetic acid. After stirring ca. 1.5 hours at room temperature, the reaction mixture was filtered through silica with diethyl ether rinse. The filtrate was concentrated in vacuo affording 4.1 g of the title compound as a white solid, m.p. 146°-148° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 8.58(bs,1H), 7.32(s,1H), 6.79(d,1H), 6.52(d, 1H), 4.34(bs,1H), 1.26(s,9H).

EXAMPLE 3 N-(1,1-Dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide

A solution of N-(1,1-dimethylethyl)-1H-pyrrole-3 -sulfonamide 9 g (0.044 mol) in 90 mL N,N-dimethylforamide was cooled to 15° C. under a nitrogen atmosphere. To this was added 3.2 mL (0.053 mol) of methyl iodide followed by 5.43 g (0.048 mol) of potassium t-butoxide. The mixture was warmed at ca. 60° C. for 2 hours then allowed to cool to room temperature and stirred for ca. 2 hours. The reaction mixture was diluted with ethyl acetate, washed three times with 1N HCl, once with brine, dried (MgSO₄) and evaporated to an oily solid which was triturated with 5% diethyl ether/95% hexanes affording 6 g of the title compound as a beige solid, m.p. 134°-135° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 7.11(s,1H), 6.59(d,1H), 6.41(d,1H), 4.32(bs,1H), 3.67(s,3H), 1.26(s,9H).

EXAMPLE 4 Methyl 3- (1,1-dimethylethyl)amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate

To a solution of I g (4.62 mol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 150 mL THF under a nitrogen atmosphere cooled to -78° C. was added dropwise at such a rate as to keep the temperature below -65° C. 4.1 mL (9.48 mmol) 2.32M n-butyllithium in hexanes. The resulting amber turbid solution was stirred at -78° C. for ca. 30 minutes. Methyl chloroformate (0.37 mL, 4.86 mmol) was added in one portion and the resulting gold reaction mixture was allowed to warm to room temperature and stirred for ca. 1.5 hours. The gold reaction mixture was cooled to 0° C. and acidified with 1N HCl. The THF phase was separated washed with brine, dried (MgSO₄) and concentrated to an ember oil. The NMR of the crude reaction product was consistent with the title compound, additionally the NMR indicated that a trace of the starting material was also present. The crude material was combined with the product from a similar reaction run on the scale described below and chromatographed to give the title compound.

To a solution of 5 g (23 mmol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 150 mL THF under nitrogen atmosphere cooled to -78° C. was added dropwise, at such a rate as to keep the temperature below -65° C., 20 mL (47.4 mmol) 2.32M n-butyllithium in hexanes. The resulting amber turbid solution was stirred at -78° C. for ca. 30 minutes. 1.87 mL (24.3 mmol) of methyl chloroformate was add in one portion and the resulting gold reaction mixture was allowed to warm to room temperature and stir for ca. 1.5 hours. The gold reaction mixture was cooled to 0° C. and acidified with 1N HCl. The THF phase was separated, washed with brine, dried (MgSO₄) and concentrated to an amber oil. The oil was combined with the crude product from the previous example and chromatographed on silica (30% ethyl acetate/70% hexanes) affording 3.53 g of the title compound as a solid.

¹ H NMR (CDCl₃, 200 MHz.) δ: 6.71(dd,2H), 5.72(bs,1H), 3.95(s,3H), 3.91(s,3H), 1.24(s,9H).

EXAMPLE 5 Methyl 3-(aminosulfonyl)-1-methyl-1H-pyrrole-2-carboxylate

To a solution of 3.53 g of methyl 3- (1,1-dimethylethyl)amino!-sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate in 40 mL, of methylene chloride under an nitrogen atmosphere was added 80 mL of trifluoroacetic acid (TFA). The gold solution was stirred at room temperature overnight ca. 16 hours. The gold solution was concentrated to an oily residue. Diethyl ether was added to the residue and removed by evaporation to remove residual TFA. The resulting solid was suspended in diethyl ether and filtered affording the title compound as a tan solid, m.p. 105°-107° C.

¹ H NMR (Acetone-d₆, 200 MHz.) δ: 7.01(d,1H), 6.51(d,1H), 6.28(bs,2H), 3.95(s,3H), 3.93(s,3H).

EXAMPLE 6 Methyl 3- (4,6-dimethoxy-2-pyramidinyl)-amino!carbonyl!amino!sulfonyl-1-methyl-1H-pyrrole-2-carboxylate

0.22 g (1 mmol) of methyl 3-(aminosulfonyl)-1-methyl-1H-pyrrole-2-carboxylate and 0.28 g (1 mmol) of phenyl (4,6-dimethoxy-2-pyrimidinyl)carbamate were combined in 4 mL of acetonitrile, 0.2 mL (1.33 mmol) of 1,8-diazabicyclo 5.4.0!undec-7-ene (DBU) was added and the resulting amber reaction mixture was allowed to stand at room temperature overnight ca. 16 hours. The reaction mixture was diluted with 6 mL of water and ca. 2 mL of shaved ice, acidified with conc. HCl (ca. 8 drops) to pH 4. The resulting precipitate was filtered washed with water followed by diethyl ether and air dried affording 0.2 g of the title compound as a solid m.p. 182.5°-186.5° C.

¹ H NMR (Me2SO-d6, 200 MHz.) δ: 12.45(bs,1H), 10.45(bs,1H), 7.21(d,1H), 6.65(d,1H), 6.01(s,1H), 3.93(s,6H), 3.85(s,3H), 3.7(s,3H).

EXAMPLE 7

N-(1,1-Dimethylethyl)-1-methyl-2-(methylthio)-1H-pyrrole-3-sulfonamide

To a solution of 6.48 g (30 mmol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 150 mL THF under nitrogen atmosphere cooled to -78° C. was added dropwise at such a rate as to keep the temperature below -65° C. 25.52 mL (61.5 mmol) 2.41M n-butyllithium in hexanes. The reaction was stirred at -78° C. for ca. 30 minutes. To the reaction mixture was added 2.97 mL (33 mmol) of dimethyldisulfide in one portion and the resulting reaction mixture was allowed to warm to room temperature and stir for ca. 1.5 hours. The reaction mixture was cooled to 0° C. and acidified with 1N HCl. The THF phase was separated washed with brine, dried (MgSO₄) and concentrated in vacuo. The crude residue was chromatographed on silica (20% ethyl acetate/80% hexanes) affording 4.63 g of the title compound as an off white solid, m.p. 116°-119° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 6.72(d,1H), 6.58(d,1H), 4.96(bs,1H), 3.74(s,3H), 2.35(s,3H), 1.23(s,9H).

EXAMPLE 8

1-Methyl-2-(methylthio)-1H-pyrrole-3-sulfonamide

To a solution of 4.63 g (17.66 mmol) N-(1,1-dimethylethyl)-1-methyl-2-(methylthio)-1H-pyrrole-3-sulfonamide in 50 mL of methylene chloride was added 50 mL of trifluoroacetic acid (TFA) under a nitrogen atmosphere. The orange reaction mixture was stirred at room temperature overnight ca. 16 hours. The reaction mixture was concentrated to a tan solid. Diethyl ether was added to the tan solid and was removed by evaporation to remove residual TFA. The solid was suspended in diethyl ether and filtered giving 2.9 g of the title compound as a solid, m.p. 135°-137° C.

¹ H NMR (Acetone-d₆, 200 MHz.) δ: 6.93(d,1H), 6.45(d,1H), 6.19(bs,2H), 3.78(s,3H), 2.33(s,3H).

EXAMPLE 9 2-Bromo-N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide

To a solution of 8.85 g (41 mmol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 200 mL diethyl ether under a nitrogen atmosphere cooled to -78° C. was added dropwise, at such a rate as to keep the temperature below -65° C., 36.0 mL (85 mmol) 2.41M n-butyllithium in hexanes. The reaction was stirred at -78° C. for ca. 15 minutes. To the reaction mixture was added 2.2 mL (41 mmol) of bromine dropwise. The light orange reaction mixture was allowed to warm to room temperature and stir for ca. 2 hours. The reaction mixture darkened as it stirred at room temperature. The reaction mixture was cooled to 0° C. and acidified with 1N HCl. The ether phase was separated, washed with brine, dried (MgSO₄) and concentrated in vacuo. The crude residue was chromatographed on silica (25% ethyl acetate/80% hexanes) affording 7.11 g of the title compound as an orange oil.

¹ H NMR (CDCl₃, 200 MHz.) δ: 6.73(d,1H), 6.62(d,1H), 3.63(s,3H), 1.24(s,9H).

EXAMPLE 10 2-Bromo-1-methyl-1H-pyrrole-3-sulfonamide

To a solution of 7.11 g (24 mmol) of 2-bromo-N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 50 mL methylene chloride under a nitrogen atmosphere was added 50 mL of TFA. The reaction mixture was allowed to stir at room temperature overnight ca. 16 hours. The reaction mixture was concentrated in vacuo. Three portions of diethyl ether were added to the crude residue and was removed by evaporation to remove residual TFA, which yielded 1.23 g of the title compound as a light brown solid.

¹ H NMR (Acetone-d₆, 200 MHz.) δ: 7.36(d,1H), 6.49(d,1H), 6.3(bs,2H) 3.68(s,3H).

EXAMPLE 11

N-(1,1-Dimethylethyl)-2-formyl-1-methyl-1H-pyrrole-3-sulfonamide

To a solution of 12.96 g (60 mmol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 300 mL THF under a nitrogen atmosphere cooled to -78° C. was added dropwise, at such a rate as to keep the temperature below -65° C., 52.35 mL (123 mmol) 2.35M n-butylithium in hexanes. The reaction was stirred at -78° C. for ca. 30 minutes. To the reaction mixture was added 4.64 mL (60 mmol) of N,N-dimethylformamide dropwise. The reaction mixture was allowed to warm to room temperature and stir for ca. 2 hours. The reaction mixture was cooled to 0° C. and acidified with 1N HCl. The THF phase was separated, washed with brine, dried (MgSO₄) and concentrated in vacuo. The crude residue was chromatographed on silica (25% ethyl acetate/80% hexanes) affording 5.72 g of the title compound as a white solid, m.p. 101.5°-103° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 10.25(s,1H), 6.81(d, 1H), 6.6(d,1H), 4.93(bs,1H), 3.98(s,3H), 1.27(s,9H).

EXAMPLE 12 N-(1,1-Dimethylethyl)-2- (methoxyimino)-methyl!-1H-pyrrole-3-sulfonamide

To a suspension of 3.91 g (46.8 mmol) of methoxyamine hydrochloride in 60 mL of methanol was added 3.84 g (46.8 mmol) of sodium acetate. After stirring the white suspension for ca. 15 minutes 5.72 g (23 mmol) of N-(1,1-dimethylethyl)-2-formyl-1-methyl-1H-pyrrole-3-sulfonamide was added in one portion. The white suspension was heated at a gentle reflux overnight ca. 16 hours. The reaction mixture was cooled to room temperature and poured into 500 mL of water. The aqueous mixture was extracted with four 100 mL portions of methylene chloride. The combined extracts were washed with water, dried (MgSO₄) and concentrated in vacuo yielding 5.74 g of the title compound as a white solid, m.p. 99°-101° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 8.51(s,1H), 6.66(d,1H), 6.54(d,1H), 4.82(bs,1H), 3.97(s,3H), 3.82(s,3H), 1.24(s,9H).

EXAMPLE 13 2- (Methoxyimino)methyl!-1-methyl-1H-pyrrole-3-sulfonamide

To a solution of 5.74 g (21.9 mmol) of N-(1,1-dimethylethyl)-2- (methoxyimino)-methyl!-1H-pyrrole-3-sulfonamide in 75 mL methylene chloride under a nitrogen atmosphere was add 75 mL of TFA. The clear orange reaction mixture was allowed to stir at room temperature overnight ca. 16 hours. The orange reaction mixture was concentrated in vacuo. Three portions of diethyl ether were added to the residue and removed by evaporation to remove residual TFA, affording 3.49 g of the title compound as a gray solid, m.p. 120°-122° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 8.43(s,1H), 6.66(d,1H), 6.54(d,1H), 6.1-6.7(bs,2H), 3.96(s,3H), 3.79(s,3H).

EXAMPLE 14 N³ -(1,1-Dimethylethyl)-N²,N²,1-trimethyl-1H-pyrrole-2,3-disulfonamide

A solution of 6.48 g (30 mmol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 150 mL of anhydrous tetrahydrofuran (THF) under nitrogen atmosphere was cooled to -78° C. The colorless reaction was treated with 61.5 mmol of 2.38M n-butyllithium in hexanes dropwise at such a rate as to keep the temperature below -65° C. After ca. 1 hour at -78° C., liquified sulfur dioxide was added (180 mmol). The amber solution was warmed to room temperature and stirred for ca. 1 hour. The THF was removed under reduced pressure. The residue was dissolved in 150 mL glacial acetic acid, cooled to 20° C. and then treated with 31 mmol of N-chlorosuccinimide. After ca. 1 hour at room temperature the acetic acid was evaporated at reduced pressure and the residue was dissolved in ethyl acetate. This solution was washed successively with water, NaHCO₃ solution, brine, dried (MgSO₄) and evaporated invacuo. The residue was dissolved in methylene chloride (150 mL), cooled to -20° C. and treated with 75 mmol of liquefied dimethylimine. The reaction mixture was allowed to warm to room temperature and stir overnight ca. 16 hours. The solution was washed with 1N HCl, dried (MgSO₄) and evaporated. The crude material was dissolved in acetonitrile and treated with activated charcoal, filtered and concentrated. The residue was triturated with hexanes/n-butyl chloride to yield 6.95 g of the title compound as a light brown solid, m.p. 98°-101° C.

¹ H NMR (CDCl₃, 200 MHz.) δ: 6.79(d, 1H), 6.69(d,1H), 5.77(bs, 1H), 3.89(s,3H), 2.92(s,6H), 1.23(s,9H).

EXAMPLE 15 N²,N²,1-Trimethyl-1H-pyrrole-2,3-disulfonamide

To a solution of 6.95 g (21 mmol) of N³ -(1,1-dimethylethyl)-N²,N²,1-trimethyl-1H-pyrrole-2,3-disulfonamide in 75 mL of methylene chloride under a nitrogen atmosphere was added 75 mL of TFA. The reaction mixture was allowed to stir at room temperature overnight ca. 16 hours. The reaction mixture was concentrated in vacuo. Three portions of diethyl ether were added to the solid residue and removed by evaporation to remove residual TFA. The solids were suspended in diethyl ether and filtered to yield 4.52 g of the title compound as a solid, m.p. 146°-148° C.

¹ H NMR (Acetone-d₆, 200 MHz.) δ: 7.1(d,1H), 6.59(d,1H), 6.28(bs,2H), 3.95(s,3H), 2.93(s,6H).

EXAMPLE 16 N- -(4-Ethyl-6-methoxy-1,3,5-triazinyl-2-yl)amino!-carbonyl-N,N,1-trimethyl-2,3-disulfonamide

0.27 g (1 mmol) of N²,N²,1-trimethyl-1H-pyrrole-2,3-disulfonamide and 0.28 g (1 mmol) of phenyl (4-ethyl-6-methoxy-2-triazinyl) carbamate were combined in 4 mL of acetonitrile 0.2 mL (1.33 mmol) of 1,8-diazabicyclo 5.4.0!undec-7-ene was added and the resulting amber reaction mixture was allowed to stand at room temperature overnight ca. 16 hours. The reaction mixture was diluted with 6 mL of water and ca. 2 mL of shaved ice, and was acidified with conc. HCl. The resulting precipitate was filtered, washed with water followed by diethyl ether, and air dried affording 0.19 g of the title compound as a solid, m.p. 159°-160.5° C.

¹ H NMR (Me₂ SO-d₆, 200 1MHz.) δ: 12.52(bs,1H), 11.0(s,1H), 7.27(d,1H), 6.75(d,1H), 3.97(s,3H), 3.85(s,3H), 2.80(s,6H), 2.73(q,2H), 1.25(t,3H).

EXAMPLE 17 3- -(1,1-Dimethylethyl)amino!sulfonyl!-N,N,1-trimethyl-1H-pyrrole-2-carboxamide

To a solution of 6.48 g (30 mmol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-3-sulfonamide in 150 mL THF under a nitrogen atmosphere cooled to -78° C. was added dropwise, at such a rate as to keep the temperature below -60° C., 25 mL (61.5 mmol) 2.46M n-butyllithium in hexanes. The reaction mixture was stirred at -78° C. for ca. 30 minutes. To the reaction mixture was added dropwise a solution of 3.1 mL (33 mmol) of N,N-dimethylcarbamyl chloride in 10 mL of THF at such a rate as to maintain the temperature below -65° C. The reaction mixture was allowed to warm to room temperature and stir for ca. 1.5 hours. The reaction mixture was cooled to ca. 5° C. and 60 mL of 50% ammonium chloride solution was added. The reaction mixture was stirred for ca. 15 minutes. The pH was adjusted to ca. 3 with 1N HCl (ca. 30 mL), and the aqueous phase was separated from the THF phase and extracted with ethyl acetate. The combined THF and ethyl acetate extracts were washed with brine, dried (MgSO₄) and concentrated in vacuo to an oil. The oil was chromatographed on silica with (20% ethyl acetate/80% n-butyl chloride) affording 4.33 g of the title compound as a pale yellow solid.

¹ H NMR(CDCl₃, 200 MHz.) δ: 6.61(d,1H), 6.46(d,1H), 4.62(bs,1H), 3.59(s,3H), 3.1(s,3H), 2.95(s,3H), 1.24(s,9H).

EXAMPLE 18 3 -(Aminosulfonyl)-N,N,1-trimethyl-1H-pyrrole-2-carboxamide

To a solution of 5.63 g of 3- (1,1-dimethylethyl)amino!sulfonyl!-N,N,1-trimethyl-1H-pyrrole-2-carboxamide in 75 mL of methylene chloride was added 75 mL of TFA. The reaction mixture was allowed to stir at room temperature overnight ca. 16 hours. The reaction mixture was concentrated in vacuo. Three portions of diethyl ether were added to the residue and removed by evaporation to remove residual TFA, affording 4.21 g of the title compound as a gray solid, m.p. 185°-190.5° C.

¹ H NMR(Me₂ SO-d₆, 200 MHz.) δ: 6.99(bs,2H), 6.88(d,1H), 6.34(d,1H), 3.47(s,3H), 2.96(s,3H), 2.81(s,3H).

EXAMPLE 19 N-(1,1-Dimethylethyl)-1-methyl-1H-pyrrole-2-sulfonamide

A solution of 10 g (0.12 mol) of N-methyl-pyrrole in 120 mL of anhydrous THF under nitrogen atmosphere was cooled to below -70° C. then treated with 56 mL of 2.4M n-butyllithium in hexanes (0.13 mol) dropwise at such a rate as to keep the temperature below -60° C. The resulting brown colored mixture was stirred for 16 h at ambient temperature, then recooled to below -70° C. at which time liquified sulfur dioxide (9.0 mL, 0.21 mol) was added rapidly, causing an exotherm at -20° C. and the formation of a thick golden colored precipitate. After stirring for 1 h at ambient temperature, the THF was removed under reduced pressure. The solids were triturated with ether and collected by filtration with an ether rinse then dried under nitrogen. This intermediate sulfinate salt was added to a well stirred mixture of 350 mL water and 250 mL dichloromethane chilled to 0° C. N-Chlorosuccinimide was then added in portions so as to keep the temperature below 3° C. The mixture was stirred vigorously for 30 min at ambient temperature, after which time, the layers were separated and the organic layer was washed successively with 10% aq NaHSO₃, twice with aq NaHCO₃, dried (MgSO₄) and filtered. This dichloromethane solution was then cooled to 0° C. and stirred while 82 mL (0.30 mol) of t-butylamine was added over 2 min. After stirring for 1 h at ambient temperature, solids had precipitated from the brown solution which was then left stirring for 3 days. The mixture was diluted with more dichloromethane then washed three times with 1N HCl, once with saturated aq NaCl, dried (MgSO₄) and evaporated. The resulting solid residue was triturated and collected with a mixture of hexanes and n-chlorobutane to afford 7.4 g of the title compound as tan crystals, m.p. 125°-126° C.

¹ H NMR (CDCl₃, 200 MHz.) δ:6.82 (m, 1H), 6.78 (m, 1H), 6.10 (m,1H), 4.53 (bs,1H), 3.83 (s,3H), 1.23 (s,9H).

EXAMPLE 20 Methyl 2- (1,1-Dimethylethyl)amino!sulfonyl!-1-methyl-1H-pyrrole-3-carboxylate

To a solution of 2.5 g (11.5 mmol) of N-(1,1-dimethylethyl)-1-methyl-1H-pyrrole-2-sulfonamide in 50 mL THF under nitrogen atmosphere cooled to below -70° C. was added dropwise 13 mL (32.5 mmol) of 2.5M n-butyllithium at such a rate as to keep the temperature below -58° C. After stirring at -20° C. to -10° C. for 30 min then 1 h at 0° C., the mixture was recooled to -70° C. and treated with a solution of 1.63 g (17.3 mmol) of methyl chloroformate in 6 mL THF causing an exotherm to -57° C. The reaction mixture was stirred overnight at ambient temperature then diluted with 200 mL of ethyl acetate. This solution was washed successively with two 60 mL portions of 1N HCl, brine, then dried (Na₂ SO₄) and evaporated to a dark oil. The crude product was purified by chromatography on silica gel (30% ethyl acetate/70% hexanes) then collected from hexanes to afford 0.45 g of the title compound, m.p. 105°-108° C.

¹ H NMR (CDCl₃, 200 MHz.) δ:7.00 (bs,1H), 6.61 (m,2H), 3.94 (s,3H), 3.85 (s,3H), 1.21 (s,9H).

EXAMPLE 21

Methyl 2-(Aminosulfonyl)-1-methyl-1H-pyrrole-3-carboxylate

A solution of 0.45 g (1.64 mmol) of methyl 2- (1,1-dimethylethyl)amino!sulfonyl!-1-methyl-1H-pyrrole-3-carboxylate in 20 mL TFA was prepared and stirred at ambient temperature for 3 hours. The TFA was then removed under reduced pressure and chloroform added to the residue and evaporated again to remove residual TFA. The resulting solid was suspended in water, filtered, and dried under vacuum to afford 0.25 g of the title compound, m.p. 119°-121° C., (dec).

¹ H NMR (Me₂ SO-d₆, 200 MHz.) δ:7.40 (bs,2H), 7.02 (d,1H), 6.48 (d, 1H), 3.84 (s,3H), 3.76 (s,3H).

EXAMPLE 22 Methyl 2- (4,6-Dimethoxy-2-pyrmidinyl)amino!-carbonyl!amino!sulfonyl-1-methyl-1H-pyrrole-3-carboxylate

Methyl 2-(aminosulfonyl)-1-methyl-1H-pyrrole-3-carboxylate -(0.10 g, 0.46 mmol) and 0.13 g (0.50 mmol) of phenyl (4,6-dimethoxy-2-pyrimidinyl)carbamate were combined in 2 mL of acetonitrile and 0.075 mL of DBU was added and the resulting amber solution was stirred at ambient temperature for 30 min. The reaction mixture was diluted with 15 mL of water and acidified with 0.5 ml, 1N HCl and the resulting precipitate was collected by filtration and rinsed successively with water and ether, then dried to afford 0.15 g of the title compound as a white solid, m.p. 192°-193° C. (dec).

¹ H NMR (Me₂ SO-d₆, 200 MHz.) δ12.7 (NH), 10.7 (NH), 7.22 (d,1H), 6.60 (d,1H), 6.02 (s,1H), 3.98 (s,3H), 3.96 (s,6H), 3.68 (s,3H).

EXAMPLE 23 Methyl 2- (4-Methoxy-6-methyl-1,3,6-triazin-2-yl)amino!carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-3-carboxylate

Methyl 2-(aminosulfonyl)-1-methyl-1H-pyrrole-3-carboxylate (0.10 g, 0.46 mmol) and 0.13 g (0.50 mmol) of phenyl (4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamate were combined in 2 mL of acetonitrile and 0.075 mL of DBU was added and the resulting amber solution was stirred at ambient temperature for 30 min. The reaction mixture was diluted with 15 mL of water and acidified with 0.5 mL 1N HCl and the resulting precipitate was collected by filtration and rinsed successively with water and ether, then dried to afford 0.13 g oil the title compound as a white solid, m.p. 189°-190° C. (dec).

¹ H NMR (Me₂ SO-d₆, 200 MHz.) δ: 12.5 (NH), 11.1 (NH), 7.22 (d,1H), 6.60 (d,1H), 4.01 (s,3H), 3.98 (s,3H), 3.71 (s,3H), 2.49 (s,3H).

By applying the procedures of Examples 1 through 23 and Equations 1 through 24, one skilled in the art can prepare the compounds in Tables 1 through 5. In the following tables, abbreviations for various alkyl chains and rings have been used with the following corresponding definitions.

Et=ethyl=CH₂ CH₃,

iPr=isopropyl=CH(CH₃)₂,

nPr=n-propyl=CH₂ CH₂ CH₃,

cPr=cyclopropyl=CH(CH₂)₂,

cBu=cyclobutyl=CH(CH₂)₃,

cC₅ H₉ =cyclopentyl=CH(CH₂)₄.

t-Bu=tert-butyl=C(CH₃)₃

n-Bu=n-butyl=(CH₂)₃ CH₃

cC₆ H₁₁ =cyclohexyl=CH(CH₂)₅

                  TABLE 1                                                          ______________________________________                                          ##STR50##                                                                     R = H, R.sup.1 = CH.sub.3, R.sup.2 = CO.sub.2 CH.sub.3, R.sup.4 = H,           R.sup.71 = H                                                                   X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         Z = CH                                                                         X                  Y                                                           ______________________________________                                         (CH.sub.2).sub.3 CH.sub.3                                                                         OCH.sub.3                                                   iPr                OCH.sub.3                                                   (CH.sub.2).sub.4 Cl                                                                               OCH.sub.3                                                   SEt                SEt                                                         S(CH.sub.2).sub.3 CH.sub.3                                                                        OCH.sub.3                                                   OCH.sub.2 OEt      CH.sub.3                                                    O(CH.sub.2).sub.2 OiPr                                                                            OCH.sub.3                                                   O(CH.sub.2).sub.2 OCH.sub.3                                                                       OC.sub.2 H.sub.5                                            CH.sub.2 CH.sub.2 OCH.sub.3                                                                       Et                                                          H                  H                                                           Cl                 N(CH.sub.3).sub.2                                           Br                 NHCH.sub.3                                                  OCH.sub.3          CN                                                          CH.sub.3           CH.sub.2 C CH                                               CH                 OCH.sub.2 C CH                                              OCH.sub.3          OCH.sub.2 CHCH.sub.2                                        NEt.sub.2          OCH.sub.3                                                   OCH.sub.2 iPr      OCH.sub.3                                                   NH.sub.2           CH.sub.3                                                    N(CH.sub.3)Et      OCH.sub.3                                                   Cl                 OC.sub.2 H.sub.5                                            Br                 OCH.sub.3                                                   OCF.sub.2 H        OCF.sub.2 H                                                 OCH.sub.2 CF.sub.3 OCF.sub.2 H                                                 OCH.sub.2 CF.sub.3 CH.sub.3                                                    OCH.sub.2 CH.sub.2 CH.sub.2 F                                                                     OCH.sub.3                                                   OiPr               OCH.sub.3                                                   CH.sub.3           N(OCH.sub.3)CH.sub.3                                        O(CH.sub.2).sub.3 CH.sub.3                                                                        O(CH.sub.2).sub.3 CH.sub.3                                  iPr                iPr                                                         OCH.sub.3          cPr                                                         OCH.sub.3          CH.sub.2 SO.sub.2 CH.sub.3                                  OCH.sub.3          cBu                                                         CH.sub.3           O(CH.sub.2).sub.2 CHCH.sub.2                                SCH.sub.2 CF.sub.3 OCH.sub.3                                                   SCHF.sub.2         CH.sub.3                                                    CF.sub.3           CF.sub.3                                                    CH.sub.2 Cl        OCH.sub.3                                                   CH.sub.2 Br        OCH.sub.3                                                   CH.sub.2 F         OEt                                                         I                  OCH.sub.3                                                   OCH.sub.2 CHF.sub.2                                                                               CH.sub.3                                                    NHiPr              CH.sub.3                                                    N(iPr).sub.2       CH.sub.3                                                    OCH.sub.2 CF.sub.3 OCH.sub.2 CF.sub.3                                          NEt.sub.2          NEt.sub.2                                                   OCH.sub.3          N.sub.3                                                     CH.sub.3           cPr                                                         CH.sub.3           CH.sub.2 SEt                                                OCH.sub.3          cC.sub.5 H.sub.9                                            O(CH.sub.2).sub.3 Cl                                                                              O(CH.sub.2).sub.3 Cl                                        ______________________________________                                         Z = N                                                                          N(CH.sub.3).sub.2  N(CH.sub.3).sub.2                                           OEt                NHnBu                                                       OCH.sub.3          NHiPr                                                       OCH.sub.2 F        NHtBu                                                       OCH.sub.3          OCF.sub.2 Br                                                NEt.sub.2          NEt.sub.2                                                   OCH.sub.3          NEt.sub.2                                                   OEt                NHCH.sub.2 CF.sub.3                                         OCH.sub.3          N(CH.sub.2 CF.sub.3).sub.2                                  OCH.sub.3          StBu                                                        OCH.sub.3          CN                                                          OCH.sub.3          N.sub.3                                                     OEt                cPr                                                         OCH.sub.3          OCH.sub.2 CHCH.sub.2                                        CH.sub.3           CH.sub.3                                                    ______________________________________                                          ##STR51##                                                                     X              R.sup.22       Z                                                ______________________________________                                         CH.sub.3       CH.sub.3       CH                                               OCH.sub.3      CH.sub.3       CH                                               CH.sub.3       H              CH                                               OCH.sub.3      H              CH                                               CH.sub.3       (CH.sub.2).sub.2 CH.sub.3                                                                     CH                                               CH.sub.3       CH.sub.3       N                                                OCH.sub.3      CH.sub.3       N                                                CH.sub.3       H              N                                                OEt            H              CH                                               OCH.sub.3      Et             N                                                ______________________________________                                          ##STR52##                                                                     X          R.sup.22 Q.sup.3 R.sup.23                                                                          Q.sup.4 R.sup.24                                                                       Z                                       ______________________________________                                         OCH.sub.3  CH3      OCH.sub.3  OCH.sub.3                                                                              CH                                      CH.sub.3   CH.sub.3 OCH.sub.3  OCH.sub.3                                                                              CH                                      OCH.sub.3  Et       OCH.sub.3  OCH3    N                                       OCH.sub.3  CH.sub.3 SEt        SEt     CH                                      CH.sub.3   CH.sub.3 S-nPr      SCH.sub.3                                                                              CH                                      OCH.sub.3  nPr      OCH.sub.3  OiPr    CH                                      ______________________________________                                          ##STR53##                                                                     X          R.sup.22 Q.sup.3  Q.sup.4                                                                              p     Z                                     ______________________________________                                         OCH.sub.3  CH.sub.3 S        S     2     CH                                    CH.sub.3   CH.sub.3 O        O     2     CH                                    CH.sub.3   CH.sub.3 O        O     3     CH                                    OCH.sub.3  CH.sub.3 S        O     2     N                                     OEt        CH.sub.3 O        O     2     CH                                    OCH.sub.3  Et       S        O     3     N                                     ______________________________________                                         Z = CH                                                                          ##STR54##                                                                     X             R.sup.22   Q.sup.3   Q.sup.4                                     ______________________________________                                         OCH.sub.3     CH.sub.3   O         O                                           CH.sub.3      Et         O         O                                           OCH.sub.3     nPr        O         O                                           CH.sub.3      CH.sub.3   S         S                                           OCH.sub.3     Et         O         O                                           OCH.sub.3     CH.sub.3   S         O                                           ______________________________________                                         R.sup.2 = CO.sub.2 CH.sub.3, R.sup.71 = H, R = R.sup.4 = H,                    R.sup.1 = CH.sub.2 OCH.sub.3                                                   X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = CO.sub.2 C.sub.2            H.sub.5,                                                                       R.sup.4 = H                                                                    CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = R.sup.4 = H, R.sup.71 = H, R.sup.2 = SO.sub.2 CH.sub.3,                    R.sup.1 = CH.sub.3                                                             CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.4 = H, R.sup.1 = CH.sub.3, R.sup.71 = H,                          R.sup.2 = SO.sub.2 N(CH.sub.3).sub.2                                           CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         R.sup.1 = C.sub.2 H.sub.5, R.sup.71 = H, R.sup.2 = CO.sub.2 CH.sub.3,          R.sup.4 = Br                                                                   R           X           Y           Z                                          ______________________________________                                         H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = C.sub.2 H.sub.5, R.sup.71 = H, R.sup.2 = 2-thienyl, R.sup.4 =        H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = 2-pyridyl             H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = S(O)C.sub.2           H.sub.5                                                                        H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          ______________________________________                                         R = H, R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H,                          R.sup.2 = C(O)CH.sub.3                                                         X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H,                          R.sup.2 = C(H) = NOCH.sub.3                                                    CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         R.sup.4 = H, R.sup.71 = H, R.sup.1 = C.sub.2 H.sub.5, R.sup.2 = NO.sub.2       R           X           Y           Z                                          ______________________________________                                         H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = CH.sub.2 OC(O)CH.sub.3,            R.sup.4 = H                                                                    H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CH.sub.2              OCH.sub.3                                                                      H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CH.sub.2              SCH.sub.3                                                                      H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = CH.sub.2 SO.sub.2 CH.sub.3,        R.sup.4 = H                                                                    H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = CHF.sub.2, R.sup.4 = H             H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = C.sub.2 H.sub.5, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CH.sub.2       OH                                                                             H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CN                    H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          ______________________________________                                         R = H, R.sup.4 = CH.sub.3, R.sup.71 = H, R.sup.1 = CH.sub.3                     ##STR55##                                                                     X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.4 = H, R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = CHO            CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.4 = H, R.sup.71 = H, R.sup.1 = CH.sub.3, R.sup.2                  = SCH.sub.3                                                                    CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.4 = H, R.sup.1 = CH.sub.3, R.sup.71 = H,                          R.sup.2 = C(O)N(CH.sub.3).sub.2                                                CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = CH.sub.2 CH.sub.2 OCH.sub.3,       R.sup.4 = H                                                                    R           X           Y           Z                                          ______________________________________                                         H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H,                                  ##STR56##                                                                     H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.2 N(CH.sub.3).sub.2, R.sup.4 = H, R.sup.71 = H,               R.sup.2 = CO.sub.2 CH.sub.3                                                    H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H,                                  ##STR57##                                                                     H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = H, R.sup.71 = H, R.sup.2 = CO.sub.2 CH.sub.3, R.sup.4 = H            H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = R.sup.4 = H, R.sup.71 = H, R.sup.2 = CHO                             H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = H, R.sup.4 = H, R.sup.71 = H, R.sup.2 = SO.sub.2 N(CH.sub.3).sub     .2                                                                             H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          R.sup.1 = R.sup.4 = H, R.sup.71 = H, R.sup.2 = CO.sub.2 Et                     H           CH.sub.3    CH.sub.3    CH                                         H           CH.sub.3    OCH.sub.3   CH                                         H           OCH.sub.3   OCH.sub.3   CH                                         H           Cl          OCH.sub.3   CH                                         CH.sub.3    OCH.sub.3   OCH.sub.3   CH                                         H           CH.sub.3    OCH.sub.3   N                                          H           OCH.sub.3   OCH.sub.3   N                                          H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                           N                                          H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                           N                                          CH.sub.3    OCH.sub.3   OCH.sub.3   N                                          ______________________________________                                         X = Y = OCH.sub.3, Z = CH, R = H, R.sup.71 = H                                 R.sup.1      R.sup.2          R.sup.4                                          ______________________________________                                         CH.sub.2 SCH.sub.3                                                                          CO.sub.2 CH.sub.3                                                                               Br                                               CH.sub.2 CH.sub.2 OCH.sub.3                                                                 CO.sub.2 CH.sub.3                                                                               H                                                CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                         CO.sub.2 CH.sub.3                                                                               H                                                c-C.sub.5 H.sub.9                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                      F                                                CH.sub.2 CF.sub.3                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                      H                                                CH.sub.2 CH.sub.2 CH.sub.2 Cl                                                               SO.sub.2 N(CH.sub.3).sub.2                                                                      H                                                CH.sub.2 CHCH.sub.2                                                                         SCH.sub.3        Cl                                               CO.sub.2 -t-Bu                                                                              SCH.sub.3        Br                                               N(CH.sub.3).sub.2                                                                           SCH.sub.3        H                                                C(O)N(CH.sub.3).sub.2                                                                       SO.sub.2 CH.sub.3                                                                               H                                                 ##STR58##   SO.sub.2 CH.sub.3                                                                               Br                                               C(O)-n-Pr    SO.sub.2 CH.sub.3                                                                               H                                                CO.sub.2 CH.sub.3                                                                           CH.sub.3         F                                                CH.sub.3     CO.sub.2 CH.sub.3                                                                               CO.sub.2 CH.sub.3                                CH.sub.3     CH.sub.2 SO.sub.2 N(CH.sub.3).sub.2                                                             CO.sub.2 CH.sub.3                                CH.sub.3     n-Bu             Br                                               CH.sub.2 SCH.sub.3                                                                          CH.sub.2 CO.sub.2 CH.sub.3                                                                      CH.sub.3                                         CH.sub.3     CH.sub.2 CH.sub.2 CO.sub.2 CH.sub.3                                                             H                                                CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3                                                   H                                                CH.sub.3     CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.3                                                            H                                                CH.sub.2 CH.sub.2 F                                                                         CH.sub.2 SO.sub.2 CH.sub.2 CH.sub.3                                                             H                                                CH.sub.3     CH.sub.2 OH      Et                                               H            CH.sub.2 Br      CO.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.2 Cl      F                                                Et           CHF.sub.2        Et                                               CH.sub.3                                                                                     ##STR59##       H                                                ______________________________________                                         X = CH.sub.3, Y = OCH.sub.3, Z = N, R = H, R.sup.1 = CH.sub.3, R.sup.4 =       H,                                                                             R.sup.2 = (CH.sub.2).sub.m Q.sup.2, R.sup.71 = H                               m      Q.sup.2  R.sup.45  R.sup.46                                                                              R.sup.47                                                                              R.sup.48                               ______________________________________                                         0      Q.sup.2 -1                                                                              H         H      --     --                                     1      Q.sup.2 -1                                                                              H         H      --     --                                     0      Q.sup.2 -1                                                                              4-Cl      H      --     --                                     0      Q.sup.2 -1                                                                              4-CH.sub.3                                                                               H      --     --                                     0      Q.sup.2 -1                                                                              4-CH.sub.3                                                                               2-Cl   --     --                                     1      Q.sup.2 -1                                                                              2-Cl      4-Cl   --     --                                     0      Q.sup.2 -1                                                                              3-Cl      4-Cl   --     --                                     0      Q.sup.2 -2                                                                              --        --     CH.sub.3                                                                              CH.sub.3                               0      Q.sup.2 -2                                                                              --        --     n-Pr   H                                      0      Q.sup.2 -2                                                                              --        --     Et     H                                      0      Q.sup.2 -3                                                                              --        --     H      --                                     0      Q.sup.2 -3                                                                              --        --     CH.sub.3                                                                              --                                     0      Q.sup.2 -3                                                                              --        --     Et     --                                     ______________________________________                                         X = OCH.sub.3, Y = OCH.sub.3, Z = N, R = H, R.sup.1 = CH.sub.3,                R.sup.4 = H, R.sup.2 = (CH.sub.2).sub.m Q.sup.2, R.sup.71 = H                  m   r     Q.sup.2                                                                               R.sup.49                                                                             R.sup.50                                                                            R.sup.51                                                                             R.sup.52                                                                            R.sup.53                                                                             R.sup.54                                                                            R.sup.55                     ______________________________________                                         0   0     Q.sup.2 -4                                                                            H     H    --    --   --    --   --                           0   1     Q.sup.2 -4                                                                            4-CH.sub.3                                                                           H    --    --   --    --   --                           0   0     Q.sup.2 -4                                                                            5-CH.sub.3                                                                           H    --    --   --    --   --                           0   0     Q.sup.2 -4                                                                            4-CH.sub.3                                                                           6-   --    --   --    --   --                                                  CH.sub.3                                                0   1     Q.sup.2 -4                                                                            6-CH.sub.3                                                                           H    --    --   --    --   --                           0   1     Q.sup.2 -5                                                                            H     H    --    --   --    --   --                           0   0     Q.sup.2 -5                                                                            6-CH.sub.3                                                                           H    --    --   --    --   --                           0   0     Q.sup.2 -5                                                                            5-CH.sub.3                                                                           H    --    --   --    --   --                           0   1     Q.sup.2 -6                                                                            H     H    --    --   --    --   --                           0   0     Q.sup.2 -6                                                                            2-CH.sub.3                                                                           H    --    --   --    --   --                           0   --    Q.sup.2 -7                                                                            --    --   H     H    H     --   --                           1   --    Q.sup.2 -7                                                                            --    --   CH.sub.3                                                                             H    OCH.sub.3                                                                            --   --                           0   --    Q.sup.2 -7                                                                            --    --   OCH.sub.3                                                                            H    H     --   --                           0   --    Q.sup.2 -7                                                                            --    --   H     CH.sub.3                                                                            H     --   --                           0   --    Q.sup.2 -8                                                                            --    --   --    --   --    H    H                            0   --    Q.sup.2 -9                                                                            --    --   --    --   --    2-   H                                                                         CH.sub.3                          ______________________________________                                         X = Y = OCH.sub.3, Z = CH, R = R.sup.4 = H,                                    R.sup.1 = CH.sub.3, R.sup.2 = (CH.sub.2).sub.m Q.sup.2, R.sup.71 = H           m      Q.sup.2   W.sup.3 R.sup.56                                                                              R.sup.57                                                                              R.sup.58                                ______________________________________                                         0      Q.sup.2 -10                                                                              O       H      H      H                                       0      Q.sup.2 -10                                                                              O       H      H      OCH.sub.3                               0      Q.sup.2 -10                                                                              O       H      CH.sub.3                                                                              H                                       0      Q.sup.2 -10                                                                              S       H      H      H                                       0      Q.sup.2 -10                                                                              S       CH.sub.3                                                                              H      H                                       1      Q.sup.2 -10                                                                              S       H      H      OEt                                     0      Q.sup.2 -10                                                                              S       Cl     H      H                                       0      Q.sup.2 -10                                                                              S       H      H      Et                                      0      Q.sup.2 -10                                                                              S       H      H      Br                                      0      Q.sup.2 -11                                                                              O       H      H      H                                       0      Q.sup.2 -11                                                                              O       H      H      CH.sub.3                                0      Q.sup.2 -11                                                                              O       CH.sub.3                                                                              H      H                                       0      Q.sup.2 -11                                                                              S       H      H      H                                       0      Q.sup.2 -11                                                                              S       H      CH.sub.3                                                                              H                                       0      Q.sup.2 -11                                                                              S       H      H      Cl                                      ______________________________________                                         X = CH.sub.3, Y = OCH.sub.3, Z = CH, R = R.sup.4 = H, R.sup.1                  = CH.sub.3,                                                                    R.sup.2 = (CH.sub.2).sub.m Q.sup.2, m = O, R.sup.71 = H                        Q.sup.2                                                                              W.sup.4 R.sup.59                                                                              R.sup.60                                                                            R.sup.61                                                                             R.sup.62                                                                            R.sup.63                                                                            R.sup.64                                                                            R.sup.65                        ______________________________________                                         Q.sup.2 -12                                                                          --      H      CH.sub.3                                                                            --    --   --   --   --                              Q.sup.2 -12                                                                          --      CH.sub.3                                                                              CH.sub.3                                                                            --    --   --   --   --                              Q.sup.2 -13                                                                          --      --     --   H     --   --   --   --                              Q.sup.2 -13                                                                          --      --     --   CH.sub.3                                                                             --   --   --   --                              Q.sup.2 -13                                                                          --      --     --   OCH.sub.3                                                                            --   --   --   --                              Q.sup.2 -14                                                                          --      --     --   H     --   --   --   --                              Q.sup.2 -14                                                                          --      --     --   OCH.sub.3                                                                            --   --   --   --                              Q.sup.2 -15                                                                          --      --     --   --    H    --   --   --                              Q.sup.2 -15                                                                          --      --     --   --    Et   --   --   --                              Q.sup.2 -16                                                                          --      --     --   --    H    --   --   --                              Q.sup.2 -16                                                                          --      --     --   --    CH.sub.3                                                                            --   --   --                              Q.sup.2 -17                                                                          NH      --     --   --    --   H    H    --                              Q.sup.2 -17                                                                          NCH.sub.3                                                                              --     --   --    H    H    H    --                              Q.sup.2 -18                                                                          NCH.sub.3                                                                              --     --   --    --   H    H    --                              Q.sup.2 -19                                                                          NH      --     --   SCH.sub.3                                                                            --   --   H    --                              Q.sup.2 -19                                                                          NCH.sub.3                                                                              --     --   OCH.sub.3                                                                            --   --   H    --                              Q.sup.2 -20                                                                          --      --     --   --    --   --   --   H                               Q.sup.2 -20                                                                          --      --     --   --    --   --   --   CH.sub.3                        Q.sup.2 -20                                                                          --      --     --   --    --   --   --   OEt                             Q.sup.2 -21                                                                          --      --     --   --    --   --   --   Et                              Q.sup.2 -21                                                                          --      --     --   --    --   --   --   H                               Q.sup.2 -21                                                                          --      --     --   --    --   --   --   OCH.sub.3                       ______________________________________                                         X = Y = OCH.sub.3, Z = CH, R = R.sup.4 = H, R.sup.2 = CO.sub.2 CH.sub.3,       R.sup.71 = H                                                                   Q.sup.1 -1     R.sup.25 = R.sup.26 = H                                         Q.sup.1 -1     R.sup.25 = 4-Cl, R.sup.26 = H                                   Q.sup.1 -2     q = O, R.sup.27 = R.sup.28H                                     Q.sup.1 -3     q = O, R.sup.27 = 6-CH.sub.3, R.sup.28 = H                      Q.sup.1 -4     q = O, R.sup.27 = R.sup.28 = H                                  Q.sup.1 -5     R.sup.29 = R.sup.30 = R.sup.31 = H                              Q.sup.1 -6     R.sup.32 = R.sup.33 = H                                         Q.sup.1 -8     W.sup.1 = O, R.sup.34 = R.sup.35 = R.sup.36 = H                 Q.sup.1 -8     W.sup.1 = S, R.sup.34 = R.sup.35 = R.sup.36 = H                 Q.sup.1 -9     W.sup.1 = S, R.sup.34 = R.sup.35 = R.sup.36 = H                 Q.sup.1 -10    R.sup.37 = H, R.sup.38 = CH.sub.3                               Q.sup.1 -11    R.sup.39 = SCH.sub.3                                            Q.sup.1 -15    W.sup.2 = S, R.sup.63 = R.sup.64 = H                            Q.sup.1 -21    R.sup.65 = CH.sub.3                                             ______________________________________                                    

                  TABLE 2                                                          ______________________________________                                          ##STR60##                                                                     ______________________________________                                         R = H, R.sup.1 = CH.sub.3, R.sup.2 = SO.sub.2 N(CH.sub.3).sub.2, R.sup.4       = H, R.sup.71 = H                                                              X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         Z = CH                                                                         X                  Y                                                           ______________________________________                                         (CH.sub.3).sub.3 CH.sub.3                                                                         OCH.sub.3                                                   iPr                OCH.sub.3                                                   (CH.sub.2).sub.4 Cl                                                                               OCH.sub.3                                                   SEt                SEt                                                         S(CH.sub.2).sub.3 CH.sub.3                                                                        OCH.sub.3                                                   OCH.sub.2 OEt      CH.sub.3                                                    O(CH.sub.2).sub.2 OiPr                                                                            OCH.sub.3                                                   O(CH.sub.2).sub.2 OCH.sub.3                                                                       OC.sub.2 H.sub.5                                            CH.sub.2 CH.sub.2 OCH.sub.3                                                                       Et                                                          H                  H                                                           Cl                 N(CH.sub.3).sub.2                                           Br                 NHCH.sub.3                                                  OCH.sub.3          CN                                                          CH.sub.3           CH.sub.2 CCH                                                CH.sub.3           OCH.sub.2 CCH                                               OCH.sub.3          OCH.sub.2 CHCH.sub.2                                        NEt.sub.2          OCH.sub.3                                                   OCH.sub.2 iPr      OCH.sub.3                                                   NH.sub.2           CH.sub.3                                                    N(CH.sub.3)Et      OCH.sub.3                                                   Cl                 OC.sub.2 H.sub.5                                            Br                 OCH.sub.3                                                   OCF.sub.2 H        OCF.sub.2 H                                                 OCH.sub.2 CF.sub.3 OCF.sub.2 H                                                 OCH.sub.2 CF.sub.3 CH.sub.3                                                    OCH.sub.2 CH.sub.2 CH.sub.2 F                                                                     OCH.sub.3                                                   OiPr               OCH.sub.3                                                   CH.sub.3           N(OCH.sub.3)CH.sub.3                                        O(CH.sub.2).sub.3 CH.sub.3                                                                        N(CH.sub.2).sub.3 CH.sub.3                                  iPr                iPr                                                         OCH.sub.3          cPr                                                         OCH.sub.3          CH.sub.2 SO.sub.2 CH.sub.3                                  OCH.sub.3          cBu                                                         CH.sub.3           O(CH.sub.2).sub.2 CHCH.sub.2                                SCH.sub.2 CF.sub.3 OCH.sub.3                                                   SCHF.sub.2         CH.sub.3                                                    CF.sub.3           CF.sub.3                                                    CH.sub.2 Cl        OCH.sub.3                                                   CH.sub.2 Br        OCH.sub.3                                                   CH.sub.2 F         OEt                                                         I                  OCH.sub.3                                                   OCH.sub.2 CHF.sub.2                                                                               CH.sub.3                                                    NHiPr              CH.sub.3                                                    N(iPr).sub.2       CH.sub.3                                                    OCH.sub.2 CF.sub.3 OCH.sub.2 CF.sub.3                                          NEt.sub.2          NEt.sub.2                                                   OCH.sub.3          N.sub.3                                                     CH.sub.3           cPr                                                         CH.sub.3           CH.sub.2 SEt                                                OCH.sub.3          cC.sub.5 H.sub.9                                            O(CH.sub.2).sub.3 Cl                                                                              O(CH.sub.2).sub.3 Cl                                        ______________________________________                                         R.sup.2 = CO.sub.2 CH.sub.3, R.sup.71 = H, R = R.sup.4 = H, R.sup.1 =          CH.sub.3                                                                       X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = CO.sub.2 C.sub.2            H.sub.5, R.sup.4 = H                                                           CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = R.sup.4 = H, R.sup.71 = H, R.sup.2 = SO.sub.2 CH.sub.3, R.sup.1 =          CH.sub.3                                                                       CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = R.sup.4 = H, R.sup.1 = CH.sub.3, R.sup.2 = Br, R.sup.71 = H                CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = C(O)CH.sub.3          R           X           Y          Z                                           ______________________________________                                         H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                            ##STR61##                                                                     H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = C(H)NOCH.sub.3        H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = SCH.sub.3             H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CHO                   H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CH.sub.2              OCH.sub.3                                                                      H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CHF.sub.2             H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.4 = H, R.sup.71 = H, R.sup.2 = CH.sub.2 CN           H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           ______________________________________                                         X = Y = OCH.sub.3, Z = CH, R = H, R.sup.71 = H                                 R.sup.1         R.sup.2       R.sup.4                                          ______________________________________                                         CH.sub.3        S(O)CH.sub.3  CO.sub.2 CH.sub.3                                H               S(O)CH.sub.3  H                                                CH.sub.2 OCH.sub.3                                                                             CH.sub.2 CO.sub.2 CH.sub.3                                                                   H                                                CH.sub.3        CH.sub.2 OH   Cl                                               H               CH.sub.2 OH   CH.sub.3                                         CH.sub.3        CH.sub.2 Cl   Br                                               CH.sub.3                                                                                        ##STR62##    H                                                CH.sub.3        CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3                                                         Cl                                               CO.sub.2 -t-Bu  Cl            H                                                C(O)NH-t-Bu     Br            H                                                C(O)Et          n-Pr          H                                                c-C.sub.6 H.sub.11                                                                             CHF.sub.2     H                                                CH.sub.2 CH.sub.2 Cl                                                                           CO.sub.2 Et   Br                                               Et              CH(OCH.sub.3).sub.2                                                                          CH.sub.3                                         CH.sub.3        C(O)N(CH.sub.3).sub.2                                                                        H                                                CH.sub.2 OCH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                        H                                                CH.sub.2 CHCH.sub.2                                                                            CH.sub.2 CH.sub.2 OCH.sub.3                                                                  H                                                CH.sub.2 N(CH.sub.3).sub.2                                                                     CH.sub.2 CO.sub.2 CH.sub.3                                                                   H                                                CH.sub.2 SCH.sub.3                                                                             CO.sub.2 CH.sub.2 OCH.sub.3                                                                  H                                                CH.sub.2 -c-Pr  S(O)CH.sub.2 CHCH.sub.2                                                                      H                                                CH.sub.2 CF.sub.2 H                                                                            NO.sub.2      H                                                CH.sub.2 CH.sub.2 C(OCH.sub.3)CH.sub.3                                                         CH.sub.2 CH.sub.2 CN                                                                         H                                                CH.sub.3        CH.sub.2C.sub.6 H.sub.5                                                                      Br                                               CH.sub.3        CN            H                                                CH.sub.3        CH.sub.2 CH.sub.2 C(O)CH.sub.3                                                               H                                                ______________________________________                                    

                  TABLE 3                                                          ______________________________________                                          ##STR63##                                                                     ______________________________________                                         R = H, R.sup.1 = CH.sub.3, R.sup.2 = CO.sub.2 CH.sub.3, R.sup.3 = H,           R.sup.71 = H                                                                   X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         Z = CH                                                                         X                  Y                                                           ______________________________________                                         (CH.sub.2).sub.3 CH.sub.3                                                                         OCH.sub.3                                                   iPr                OCH.sub.3                                                   (CH.sub.2).sub.4 Cl                                                                               OCH.sub.3                                                   SEt                SEt                                                         S(CH.sub.2).sub.3 CH.sub.3                                                                        OCH.sub.3                                                   OCH.sub.2 OEt      CH.sub.3                                                    O(CH.sub.2).sub.2 OiPr                                                                            OCH.sub.3                                                   O(CH.sub.2).sub.2 OCH.sub.3                                                                       OC.sub.2 H.sub.5                                            CH.sub.2 CH.sub.2 OCH.sub.3                                                                       Et                                                          H                  H                                                           Cl                 N(CH.sub.3).sub.2                                           Br                 NHCH.sub.3                                                  OCH.sub.3          CN                                                          CH.sub.3           CH.sub.2 CCH                                                CH.sub.3           OCH.sub.2 CCH                                               OCH.sub.3          OCH.sub.2 CHCH.sub.2                                        NEt.sub.2          OCH.sub.3                                                   OCH.sub.2 iPr      OCH.sub.3                                                   NH.sub.2           CH.sub.3                                                    N(CH.sub.3)Et      OCH.sub.3                                                   Cl                 OC.sub.2 H.sub.5                                            Br                 OCH.sub.3                                                   OCF.sub.2 H        OCF.sub.2 H                                                 OCH.sub.2 CF.sub.3 OCF.sub.2 H                                                 OCH.sub.2 CF.sub.3 CH.sub.3                                                    OCH.sub.2 CH.sub.2 CH.sub.2 F                                                                     OCH.sub.3                                                   OiPr               OCH.sub.3                                                   CH.sub.3           N(OCH.sub.3)CH.sub.3                                        O(CH.sub.2).sub.3 CH.sub.3                                                                        O(CH.sub.2).sub.3 CH.sub.3                                  iPr                iPr                                                         OCH.sub.3          cPr                                                         OCH.sub.3          CH.sub.2 SO.sub.2 CH.sub.3                                  OCH.sub.3          cBu                                                         CH.sub.3           O(CH.sub.2).sub.2 CHCH.sub.2                                SCH.sub.2 CF.sub.3 OCH.sub.3                                                   SCHF.sub.2         CH.sub.3                                                    CF.sub.3           CF.sub.3                                                    CH.sub.2 Cl        OCH.sub.3                                                   CH.sub.2 Br        OCH.sub.3                                                   CH.sub.2 F         OEt                                                         I                  OCH.sub.3                                                   OCH.sub.2 CHF.sub.2                                                                               CH.sub.3                                                    NHiPr              CH.sub.3                                                    N(iPr).sub.2       CH.sub.3                                                    OCH.sub.2 CF.sub.3 OCH.sub.2 CF.sub.3                                          NEt.sub.2          NEt.sub.2                                                   OCH.sub.3          N.sub.3                                                     CH.sub.3           cPr                                                         CH.sub.3           CH.sub.2 SEt                                                OCH.sub.3          cC.sub.5 H.sub.9                                            O(CH.sub.2).sub.3 Cl                                                                              O(CH.sub.2).sub.3 Cl                                        ______________________________________                                         R = R.sup.3 = H, R.sup.71 = H, R.sup.1 = CH.sub.2 OCH.sub.2 CH.sub.3,          R.sup.2 = CO.sub.2 Et                                                          X              Y               Z                                               ______________________________________                                         CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = H, R.sup.1 = CH.sub.3, R.sup.71 = Cl, R.sup.3 = H, R.sup.2 = CO.sub.2      Et,                                                                            CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = R.sup.3 = H, R.sup.71 = H, R.sup.1 = CH.sub.3, R.sup.2 = SO.sub.2          CH.sub.3                                                                       CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = R.sup.3 = H, R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = SO.sub.2          N(CH.sub.3).sub.2                                                              CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = R.sup.3 = H, R.sup.71 = H, R.sup.2 = C(O)CH.sub.3                          CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               R = R.sup.3 = H, R.sup.1 = CH.sub.3, R.sup.71 = H, R.sup.2 = C(OCH.sub.3)      = NOCH.sub.3                                                                   CH.sub.3       CH.sub.3        CH                                              CH.sub.3       OCH.sub.3       CH                                              OCH.sub.3      OCH.sub.3       CH                                              Cl             OCH.sub.3       CH                                              CH.sub.3       OC.sub.2 H.sub.5                                                                               CH                                              C.sub.2 H.sub.5                                                                               OCH.sub.3       CH                                              H              OCH.sub.3       CH                                              H              OC.sub.2 H.sub.5                                                                               CH                                              OCH.sub.3      CH.sub.2 OCH.sub.3                                                                             CH                                              CH.sub.3       CH(OCH.sub.3).sub.2                                                                            CH                                              OCHF.sub.2     OCH.sub.3       CH                                              OCH.sub.3      SCH.sub.3       CH                                              CH.sub.3       OCH.sub.3       N                                               OCH.sub.3      OCH.sub.3       N                                               NHCH.sub.3     OCH.sub.3       N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.3       N                                               C.sub.2 H.sub.5                                                                               OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OC.sub.2 H.sub.5                                                                               N                                               N(CH.sub.3).sub.2                                                                             OC.sub.2 H.sub.5                                                                               N                                               NHCH.sub.3     OCH.sub.2 CF.sub.3                                                                             N                                               N(CH.sub.3).sub.2                                                                             OCH.sub.2 CF.sub.3                                                                             N                                               CH.sub.3       OC.sub.2 H.sub.5                                                                               N                                               CF.sub.3       OCH.sub.3       N                                               OCF.sub.2 H    OCH.sub.3       N                                               CH.sub.3       OCH.sub.2 CHCH.sub.2                                                                           N                                               ______________________________________                                         R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = NO.sub.2              R           X           Y          Z                                           ______________________________________                                         H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = CHO                   H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = S(O)Et                H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = C(O)N(CH.sub.3).s     ub.2                                                                           H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = Cl                    H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = SC.sub.2              H.sub.5                                                                        H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = CH.sub.2              OCH.sub.3                                                                      H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = H, R.sup.71 = H, R.sup.2 = CHF.sub.2             H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = C.sub.2 H.sub.5 R.sup.3 = R.sup.71 = H, R.sup.2 = OCH.sub.3          H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = R.sup.71 = H, R.sup.2 = OSO.sub.2 CH.sub.3       H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = R.sup.71 = H, R.sup.2 = OC(O)CH.sub.3            H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           R.sup.1 = CH.sub.3, R.sup.3 = R.sup.71 = H, R.sup.2 = OiPr                     H           CH.sub.3    CH.sub.3   CH                                          H           CH.sub.3    OCH.sub.3  CH                                          H           OCH.sub.3   OCH.sub.3  CH                                          H           Cl          OCH.sub.3  CH                                          CH.sub.3    OCH.sub.3   OCH.sub.3  CH                                          H           CH.sub.3    OCH.sub.3  N                                           H           OCH.sub.3   OCH.sub.3  N                                           H           NHCH.sub.3  OC.sub.2 H.sub.5                                                                          N                                           H           N(CH.sub.3).sub.2                                                                          OC.sub.2 H.sub.5                                                                          N                                           CH.sub.3    OCH.sub.3   OCH.sub.3  N                                           ______________________________________                                         X = Y = OCH.sub.3, Z = CH, R = H, R.sup.71 = H                                 R.sup.1         R.sup.2        R.sup.3                                         ______________________________________                                         CH.sub.3        CO.sub.2 Et    F                                               CH.sub.3        CO.sub.2 Et    CH.sub.3                                        CH.sub.2 OCH.sub.3                                                                             SO.sub.2 Et    Cl                                              CH.sub.3        CH.sub.2 CH.sub.2 C(O)CH.sub.3                                                                H                                               Et              CO.sub.2 CH.sub.2 OCH.sub.3                                                                   H                                               CH.sub.2 CH.sub.2 F                                                                            NO.sub.2       H                                               CH.sub.2 CH.sub.2 OCH.sub.3                                                                    SO.sub.2 NHEt  H                                               Et              CH(OCH.sub.3).sub.2                                                                           Br                                              CH.sub.3        C(O)-N-Pr      F                                               CH.sub.3        CH.sub.2 C(O)CH.sub.3                                                                         H                                               CH.sub.3        CN             H                                               CH.sub.2 OCH.sub.3                                                                             CN             H                                               ______________________________________                                    

                  TABLE 4                                                          ______________________________________                                          ##STR64##                                                                     ______________________________________                                         R = H, R.sup.1 = CH.sub.3, R.sup.3 = R.sup.4 = H, R.sup.2 = CO.sub.2           CH.sub.3, R.sup.71 = H                                                         J         A        X.sup.1    Y.sup.1 Y.sup.3                                  ______________________________________                                         J-1       A-2      CH.sub.3   O       --                                       J-1       A-2      OEt        O       --                                       J-2       A-2      OCH.sub.3  O       --                                       J-2       A-2      OCH.sub.3  CH.sub.3                                                                               --                                       J-1       A-3      CH.sub.3   --      --                                       J-3       A-3      CH.sub.3   --      --                                       J-1       A-4      CH.sub.3   --      CH.sub.3                                 J-2       A-4      OCH.sub.3  --      CH.sub.3                                 ______________________________________                                         J         A        X.sup.2    Y.sup.2 Y.sup.3                                  ______________________________________                                         J-1       A-5      CH.sub.3   CH.sub.3                                                                               --                                       J-1       A-6      --         --      OCH.sub.3                                J-2       A-5      CH.sub.3   SCH.sub.3                                                                              --                                       J-2       A-6      --         --      CH.sub.3                                 J-3       A-5      CH.sub.3   OCH.sub.3                                                                              --                                       J-3       A-5      CH.sub.2 CF.sub.3                                                                         OCH.sub.3                                                                              --                                       ______________________________________                                         J         A        X.sup.4    Y.sup.4 Z.sup.1                                  ______________________________________                                         J-1       A-7      CH.sub.3   CH.sub.3                                                                               CH                                       J-1       A-7      OCH.sub.3  Ch.sub.3                                                                               CH                                       J-2       A-7      OCH.sub.3  OCH.sub.3                                                                              N                                        J-2       A-7      CH.sub.3   OC.sub.2 H.sub.5                                                                       CH                                       J-3       A-7      Cl         CH.sub.3                                                                               CH                                       J-3       A-7      CH.sub.3   CH.sub.3                                                                               N                                        ______________________________________                                    

                  TABLE 5                                                          ______________________________________                                          ##STR65##                                                                     ______________________________________                                         R.sup.3 = R.sup.4 = H, R.sup.1 = CH.sub.3, R.sup.71 = H,                       J         R.sup.2       Z.sup.1  X.sup.3                                       ______________________________________                                         J-1       CO.sub.2 CH.sub.3                                                                            CH       OCH.sub.3                                     J-1       CO.sub.2 CH.sub.3                                                                            N        CH.sub.3                                      J-1       SO.sub.2 N(CH.sub.3).sub.2                                                                   CH       OCH.sub.3                                     J-1       SO.sub.2 CH.sub.3                                                                            N        CH.sub.3                                      J-2       CO.sub.2 CH.sub.3                                                                            CH       Cl                                            J-2       CO.sub.2 CH.sub.3                                                                            CH       OCH.sub.3                                     J-2       SO.sub.2 N(CH.sub.3).sub.2                                                                   N        CH.sub.3                                      J-2       CHO           N        OCH.sub.3                                     J-2       CO.sub.2 CH.sub.3                                                                            CH       OCH.sub.3                                     J-3       CO.sub.2 CH.sub.3                                                                            CH       CH.sub.3                                      J-3       SO.sub.2 N(CH.sub.3).sub.2                                                                   N        CH.sub.3                                      J-3       C(O)CH.sub.3  N        OCH.sub.3                                     ______________________________________                                    

The procedures of Examples 1 through 18 and Equations 1 through 21 were followed in the synthesis of the following compounds.

    __________________________________________________________________________     INDEX TABLE                                                                     ##STR66##                                                                     __________________________________________________________________________     J is J-2, R.sup.1 is CH.sub.3, R.sup.4 and R.sup.71 are H                      CMPD                                                                               R.sup.2   X         Y         Z     m.p.(°C.)                       __________________________________________________________________________     1   CO.sub.2 CH.sub.3                                                                        CH.sub.3  CH.sub.3  CH    188-190                                2   CO.sub.2 CH.sub.3                                                                        CH.sub.3  OCH.sub.3 CH    186-188                                3   CO.sub.2 CH.sub.3                                                                        OCH.sub.3 OCH.sub.3 CH    182.5-186.5                            4   CO.sub.2 CH.sub.3                                                                        Cl        OCH.sub.3 CH    186-188.5                              5   CO.sub.2 CH.sub.3                                                                        CH.sub.3  OCH.sub.3 N     189-190                                6   CO.sub.2 CH.sub.3                                                                        OCH.sub.3 OCH.sub.3 N     182-183                                7   CO.sub.2 CH.sub.3                                                                        NHCH.sub.3                                                                               OEt       N     173-179                                8   CO.sub.2 CH.sub.3                                                                        OEt       OEt       N     179-180.5                              9   SCH.sub.3 CH.sub.3  CH.sub.3  CH    140-154                                10  SCH.sub.3 CH.sub.3  OCH.sub.3 CH    176-178                                11  SCH.sub.3 OCH.sub.3 OCH.sub.3 CH    181-183                                12  SCH.sub.3 Cl        OCH.sub.3 CH    165-167                                13  SCH.sub.3 CH.sub.3  OCH.sub.3 N     180-183                                14  SCH.sub.3 OCH.sub.3 OCH.sub.3 N     174-176                                15  SCH.sub.3 NHCH.sub.3                                                                               OEt       N     124-126                                16  SCH.sub.3 NHCH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                       N     165-169                                17  SCH.sub.3 N(CH.sub.3).sub.2                                                                        OCH.sub.2 CF.sub.3                                                                       N     116-125                                18  SCH.sub.3 Et        OEt       N     120-123                                19  SCH.sub.3 Et        OCH.sub.3 N     129-130.5                              20  Br        CH.sub.3  OCH.sub.3 CH    172-177.5                              21  Br        OCH.sub.3 OCH.sub.3 CH    149-151.5                              22  Br        Cl        OCH.sub.3 CH    168-175.5                              23  Br        OCH.sub.3 OCH.sub.3 N     185-188                                24  Br        OCH.sub.3 OCH.sub.3 H     180-186                                25  SO.sub.2 N(CH.sub.3).sub.2                                                               CH.sub.3  CH.sub.3  CH    200-205                                26  SO.sub.2 N(CH.sub.3).sub.2                                                               CH.sub.3  OCH.sub.3 CH    211-216                                27  SO.sub.2 N(CH.sub.3).sub.2                                                               OCH.sub.3 OCH.sub.3 CH    175.5-181                              28  SO.sub.2 N(CH.sub.3).sub.2                                                               Cl        OCH.sub.3 CH    169-172                                29  SO.sub.2 N(CH.sub.3).sub.2                                                               CH.sub.3  OCH.sub.3 N     184-190                                30  SO.sub.2 N(CH.sub.3).sub.2                                                               OCH.sub.3 OCH.sub.3 N     176.5-178.5                            31  SO.sub.2 N(CH.sub.3).sub.2                                                               NHCH.sub.3                                                                               OEt       N     128-132                                32  SO.sub.2 N(CH.sub.3).sub.2                                                               NHCH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                       N     144-146                                33  SO.sub.2 N(CH.sub.3).sub.2                                                               N(CH.sub.3).sub.2                                                                        OCH.sub.2 CF.sub.3                                                                       N     143-145                                34  SO.sub.2 N(CH.sub.3).sub.2                                                               N(CH.sub.3).sub.2                                                                        OCH.sub.3 N     189-191                                35  SO.sub.2 N(CH.sub.3).sub.2                                                               Et        OEt       N     138-140                                36  SO.sub.2 N(CH.sub.3).sub.2                                                               Et        OCH.sub.3 N     159-160.5                              37  C(H)NOCH.sub.3                                                                           CH.sub.3  CH.sub.3  CH    193-196                                38  C(H)NOCH.sub.3                                                                           CH.sub.3  OCH.sub.3 CH    195-197                                39  C(H)NOCH.sub.3                                                                           OCH.sub.3 OCH.sub.3 CH    172-174                                40  C(H)NOCH.sub.3                                                                           Cl        OCH.sub.3 CH    166-168                                41  C(H)NOCH.sub.3                                                                           CH.sub.3  OCH.sub.3 N     168-170.5                              42  C(H)NOCH.sub.3                                                                           OCH.sub.3 OCH.sub.3 N     187-189                                43  C(H)NOCH.sub.3                                                                           NHCH.sub.3                                                                               OEt       N     193-195                                44  C(H)NOCH.sub.3                                                                           OEt       OEt       N     189-192                                45  C(H)NOCH.sub.3                                                                           NHCH.sub.3                                                                               OCH.sub.2 CF.sub.3                                                                       N     119-122                                46  C(H)NOCH.sub.3                                                                           N(CH.sub.3).sub.2                                                                        OCH.sub.2 CF.sub.3                                                                       N     158-160                                47  C(H)NOCH.sub.3                                                                           N(CH.sub.3).sub.2                                                                        OCH.sub.3 N     173-176                                48  C(H)NOCH.sub.3                                                                           Et        OEt       N     155-156.5                              49  C(H)NOCH.sub.3                                                                           Et        OCH.sub.3 N     137.5-145                              __________________________________________________________________________     J is J-1, R.sup.3 is H                                                         CMPD                                                                               R.sup.1                                                                              R.sup.2  R.sup.71                                                                              X    Y    Z   m.p.(°C.)                       __________________________________________________________________________     50  CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  192-193                                51  CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   189-190                                52  CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  120-122                                53  CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  112-114                                54  CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   185-187                                55  CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  209-210                                56  CH.sub.3                                                                             CO.sub.2 Et                                                                             H      CH.sub.3                                                                            CH.sub.3                                                                            CH  210-211                                57  CH.sub.3                                                                             CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  197-198                                58  CH.sub.3                                                                             CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  176-179                                59  CH.sub.3                                                                             CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   179-180                                60  CH.sub.3                                                                             CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   175-176                                61  CH.sub.3                                                                             CO.sub.2 Et                                                                             H      Cl   OCH.sub.3                                                                           CH  192-194                                62  CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  209-120                                63  CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  209-210                                64  CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  197-198                                65  CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   192-193                                66  CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   194-195                                67  CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  212-214                                68  CH.sub.3                                                                             Cl       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  187-188                                69  CH.sub.3                                                                             Cl       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  180-183                                70  CH.sub.3                                                                             Cl       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   167-168                                71  CH.sub.3                                                                             Cl       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   181-182                                72  CH.sub.3                                                                             Cl       H      Cl   OCH.sub.3                                                                           CH  190-192                                73  CH.sub.3                                                                             SCH.sub.3                                                                               H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  181-183                                74  CH.sub.3                                                                             SCH.sub.3                                                                               H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  178-179                                75  CH.sub.3                                                                             SCH.sub.3                                                                               H      CH.sub.3                                                                            OCH.sub.3                                                                           N   173-174                                76  CH.sub.3                                                                             SCH.sub.3                                                                               H      CH.sub.3                                                                            OCH.sub.3                                                                           N   182-184                                77  CH.sub.3                                                                             S(O)CH.sub.3                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  134-135                                78  CH.sub.3                                                                             S(O)CH.sub.3                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  150d                                   79  CH.sub.3                                                                             S(O)CH.sub.3                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           N   176d                                   80  CH.sub.3                                                                             S(O)CH.sub.3                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   129d                                   81  CH.sub.3                                                                             SO.sub.2 Et                                                                             H      CH.sub.3                                                                            CH.sub.3                                                                            CH  206-209                                82  CH.sub.3                                                                             SO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  176-179                                83  CH.sub.3                                                                             SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  157-164                                84  CH.sub.3                                                                             SO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   180-182                                85  CH.sub.3                                                                             SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   178-182                                86  CH.sub.3                                                                             SO.sub.2 Et                                                                             H      Cl   OCH.sub.3                                                                           CH  205-207                                87  CH.sub.3                                                                             SO.sub.2 n-Pr                                                                           H      CH.sub.3                                                                            CH.sub.3                                                                            CH  198-200                                88  CH.sub.3                                                                             SO.sub.2 n-Pr                                                                           H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  192-194                                89  CH.sub.3                                                                             SO.sub.2 n-Pr                                                                           H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  196-199                                90  CH.sub.3                                                                             SO.sub.2 n-Pr                                                                           H      CH.sub.3                                                                            OCH.sub.3                                                                           N   190-192                                91  CH.sub.3                                                                             SO.sub.2 n-Pr                                                                           H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   179-184                                92  CH.sub.3                                                                             SO.sub.2 n-Pr                                                                           H      Cl   OCH.sub.3                                                                           CH  201-203                                93  CH.sub.3                                                                             SEt      H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  164-165                                94  CH.sub.3                                                                             SEt      H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  161-166                                95  CH.sub.3                                                                             SEt      H      CH.sub.3                                                                            OCH.sub.3                                                                           N   161-162                                96  CH.sub.3                                                                             SEt      H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   169-171                                97  CH.sub.3                                                                             S(n-Pr)  H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  149-150                                98  CH.sub.3                                                                             S(n-Pr)  H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  159-160                                99  CH.sub.3                                                                             S(n-Pr)  H      CH.sub.3                                                                            OCH.sub.3                                                                           N   154-155                                100 CH.sub.3                                                                             S(n-Pr)  H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   151-153                                101 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            CH.sub.3                                                                            CH  181-186                                102 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  160-162                                103 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  192-194                                104 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           N   167-169                                105 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   186-187                                106 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      Cl   OCH.sub.3                                                                           CH  178-181                                107 Et    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   175-176                                108 Et    CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   173-174                                109 Et    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  212-213                                110 Et    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  190-191                                111 Et    CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  178-180                                112 Et    CO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  194-196                                113 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      CH.sub.3                                                                            CH.sub.3                                                                            CH  199-200                                114 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  203-204                                115 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  194-195                                116 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           N   183-184                                117 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   186-187                                118 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      Cl   OCH.sub.3                                                                           CH  200-202                                119 CH.sub.2 OCH.sub.3                                                                   CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  166-167                                120 CH.sub.2 OCH.sub.3                                                                   CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  145-146                                121 CH.sub.2 OCH.sub.3                                                                   CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   165-166                                122 CH.sub.2 OCH.sub.3                                                                   CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   165-166                                123 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Cl     CH.sub.3                                                                            CH.sub.3                                                                            CH  200-201                                124 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Cl     CH.sub.3                                                                            OCH.sub.3                                                                           CH  194-195                                125 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Cl     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  182-183                                126 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Cl     CH.sub.3                                                                            OCH.sub.3                                                                           N   188-189                                127 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Cl     OCH.sub.3                                                                           OCH.sub.3                                                                           N   188-189                                128 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Cl     Cl   OCH.sub.3                                                                           CH  185-186                                129 CH.sub.3                                                                             CO.sub.2 Et                                                                             Cl     CH.sub.3                                                                            CH.sub.3                                                                            CH  193-194                                130 CH.sub.3                                                                             CO.sub.2 Et                                                                             Cl     CH.sub.3                                                                            OCH.sub.3                                                                           CH  191-192                                131 CH.sub.3                                                                             CO.sub.2 Et                                                                             Cl     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  159-161                                132 CH.sub.3                                                                             CO.sub.2 Et                                                                             Cl     CH.sub.3                                                                            OCH.sub.3                                                                           N   166-167                                133 CH.sub.3                                                                             CO.sub.2 Et                                                                             Cl     OCH.sub.3                                                                           OCH.sub.3                                                                           N   167-169                                134 CH.sub.3                                                                             CO.sub.2 Et                                                                             Cl     Cl   OCH.sub.3                                                                           CH  175-177                                135 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      NHCH.sub.3                                                                          OCH.sub.2 CH.sub.3                                                                  N   183-185                                136 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   189-191                                137 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      N(CH.sub.3).sub.2                                                                   OEt  N   171-173                                138 Et    CO.sub.2 CH.sub.3                                                                       H      NHCH.sub.3                                                                          OEt  N   193-195                                139 Et    CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   196-197                                140 Et    CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3).sub.2                                                                   OEt  N   175-177                                141 Et    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  212-213                                142 Et    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  184-185                                143 Et    SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  195-196                                144 Et    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   201-202                                145 Et    SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   186-187                                146 Et    SO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  204-205                                147 Et    SO.sub.2 Et                                                                             H      CH.sub.3                                                                            CH.sub.3                                                                            CH  214-215                                148 Et    SO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  196-197                                149 Et    SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  205-206                                150 Et    SO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   191-192                                151 Et    SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   191-192                                152 Et    SO.sub.2 Et                                                                             H      Cl   OCH.sub.3                                                                           CH  189-197                                153 Et    CO.sub.2 Et                                                                             H      CH.sub.3                                                                            CH.sub.3                                                                            CH  209-210                                154 Et    CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  161-162                                155 Et    CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  160-161                                156 Et    CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   185-186                                157 Et    CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   166-167                                158 Et    CO.sub.2 Et                                                                             H      Cl   OCH.sub.3                                                                           CH  166-167                                159 Et    C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            CH.sub.3                                                                            CH  169-171                                160 Et    C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  150-159                                161 Et    C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  192-194                                162 Et    C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           N   174-175                                163 Et    C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   176-178                                164 Et    C(O)N(CH.sub.3).sub.2                                                                   H      Cl   OCH.sub.3                                                                           CH  197-198                                __________________________________________________________________________     J is J-3, R.sup.71 is H                                                        CMPD                                                                               R.sup.1                                                                              R.sup.2  R.sup.4                                                                               X    Y    Z   m.p.(°C.)                       __________________________________________________________________________     165 CH.sub.3                                                                             Br       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  197-199                                166 CH.sub.3                                                                             Br       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  206-208                                167 CH.sub.3                                                                             Br       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  203-205                                168 CH.sub.3                                                                             Br       H      Cl   OCH.sub.3                                                                           CH  180-183                                169 CH.sub.3                                                                             Br       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   168-173                                170 CH.sub.3                                                                             Br       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   200-202                                171 CH.sub.3                                                                             Br       H      NHCH.sub.3                                                                          OEt  N   214-217                                172 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  239-240.5                              173 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  245-248                                174 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  232-234                                175 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   152-156                                176 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      NHCH.sub.3                                                                          OEt  N   240-242                                177 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3).sub.2                                                                   OEt  N   197-199                                178 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      OEt  OEt  N   180-182                                179 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   204-206                                180 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      Et   OEt  N   181-183                                181 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       H      Et   OCH.sub.3                                                                           N   216-218                                182 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      CH.sub.3                                                                            CH.sub.3                                                                            CH  223-225                                183 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  207-209                                184 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  204-206                                185 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      Cl   OCH.sub.3                                                                           CH  206-208                                186 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      CH.sub.3                                                                            OCH.sub.3                                                                           N   185-187                                187 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   176-178                                188 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      NHCH.sub.3                                                                          OEt  N   166-168                                189 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      N(CH.sub.3).sub.2                                                                   OEt  N   143-145                                190 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      OEt  OEt  N   174-176                                191 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   178-180                                192 CH.sub.3                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                              H      N(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                           N   213-215                                193 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  190-196                                194 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  170-176                                195 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  193-197                                196 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      Cl   OCH.sub.3                                                                           CH  143-145                                197 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           N   123-125                                198 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   139.5-142.5                            199 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      NHCH.sub.3                                                                          OEt  N   189-196                                200 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      N(CH.sub.3).sub.2                                                                   OEt  N   154.5-162                              201 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OEt  OEt  N   183-185                                202 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   127-129                                J is J-2, R.sup.71 is H                                                        203 CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  215-216                                204 CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  211-212                                205 CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  224-226                                206 CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   206-208                                207 CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   198-201                                208 CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  228-230                                209 CH.sub.3                                                                             SO.sub.2 CH.sub.3                                                                       H      NHCH.sub.3                                                                          OEt  N   248-249                                210 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      CH.sub.3                                                                            CH.sub.3                                                                            CH  205-206                                211 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  192-194                                212 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  172-175                                213 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   192-194                                214 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   171-173                                215 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      Cl   OCH.sub.3                                                                           CH  197-198                                216 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      NHCH.sub.3                                                                          OEt  N   184-187                                217 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      CH.sub.3                                                                            CH.sub.3                                                                            CH  181-183                                218 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  180-181                                219 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  152-156                                220 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           N   152-156                                221 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   184-186                                222 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      Cl   OCH.sub.3                                                                           CH  180-182                                223 CH.sub.3                                                                             C(CH.sub.3)NOCH.sub.3                                                                   H      CH.sub.3                                                                            COH.sub.3                                                                           CH  160-163                                224 CH.sub.3                                                                             C(CH.sub.3)NOCH.sub.3                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  206-209                                225 CH.sub.3                                                                             C(CH.sub.3)NOCH.sub.3                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           N   168-170                                226 CH.sub.3                                                                             C(CH.sub.3)NOCH.sub.3                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   90-113                                 227 CH.sub.3                                                                             C(CH.sub.3)NOCH.sub.3                                                                   H      Cl   OCH.sub.3                                                                           CH  179-182                                228 Et    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  204-206                                229 Et    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  189-191                                230 Et    CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  178-180                                231 Et    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   175-177                                232 Et    CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   173-176                                233 Et    CO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  198-200                                234 Et    C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            CH.sub.3                                                                            CH  174-186                                235 Et    C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  134-136                                236 Et    C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  170-176                                237 Et    C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           N   168-170                                238 Et    C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   147-149                                239 Et    C(O)N(CH.sub.3).sub.2                                                                   H      Cl   OCH.sub.3                                                                           CH  116-117                                240 Et    SO.sub.2 Et                                                                             H      CH.sub.3                                                                            CH.sub.3                                                                            CH  204-205                                241 Et    SO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  200-201                                242 CH.sub.3                                                                             SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  199-208                                243 CH.sub.3                                                                             SO.sub.2 et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   194-195                                244 CH.sub.3                                                                             SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   189-190                                245 CH.sub.3                                                                             SO.sub.2 Et                                                                             H      Cl   OCH.sub.3                                                                           CH  200-202                                246 CH.sub.3                                                                             SEt      H      CH.sub.3                                                                            CH.sub.3                                                                            CH  178-179                                247 CH.sub.3                                                                             SEt      H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  164-169                                248 CH.sub.3                                                                             SEt      H      CH.sub.3                                                                            OCH.sub.3                                                                           N   168-170                                249 CH.sub.3                                                                             SEt      H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   175-177                                250 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      CH.sub.3                                                                            CH.sub.3                                                                            CH  212-213                                251 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  188-194                                252 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  158-162                                253 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           N   202-205                                254 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   184-185                                255 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      Cl   OCH.sub.3                                                                           CH  191-192                                256 Et    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  184-188                                257 Et    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  202-203                                258 Et    SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  186-188                                259 Et    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   175-178                                260 Et    SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   172-176                                261 Et    SO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  198-201                                262 Et    SCH.sub.3                                                                               H      OCH3 OCH.sub.3                                                                           CH  150-155                                263 Et    SCH.sub.3                                                                               H      CH.sub.3                                                                            OCH.sub.3                                                                           N   140-150                                264 Et    CO.sub.2 Et                                                                             H      CH.sub.3                                                                            CH.sub.3                                                                            CH  179-180                                265 Et    CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  168-170                                266 Et    CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  167-168                                267 Et    CO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   158-159                                268 Et    CO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   174-175                                269 Et    CO.sub.2 Et                                                                             H      Cl   OCH.sub.3                                                                           CH  181-182                                270 CH.sub.2 OCH.sub.3                                                                   SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  182-189                                271 CH.sub.2 OCH.sub.3                                                                   SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  162-169                                272 CH.sub.2 OCH.sub.3                                                                   SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  179-187                                273 CH.sub.2 OCH.sub.3                                                                   SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   167-170                                274 CH.sub.2 OCH.sub.3                                                                   SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   195-198                                275 CH.sub.2 OCH.sub.3                                                                   SO.sub.2 CH.sub.3                                                                       H      Cl   COH.sub.3                                                                           CH  187-192                                276 Et    CO.sub.2 CH.sub.3                                                                       H      NHCH.sub.3                                                                          OEt  N   188-190                                277 Et    CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3).sub.2                                                                   OEt  N   171-174                                278 Et    CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   186-188                                279 CH.sub.3                                                                             CO.sub.2 iPr                                                                            H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   167-169                                280 Et    CO.sub.2 Et                                                                             H      NHCH.sub.3                                                                          OEt  N   162-164                                281 Et    CO.sub.2 Et                                                                             H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   178-180                                282 CH.sub.3                                                                             CO.sub.2 Et                                                                             H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   173-174                                283 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     CH.sub.3                                                                            CH.sub.3                                                                            CH  148-150                                284 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     CH.sub.3                                                                            OCH.sub.3                                                                           CH  137-140                                285 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  154-156                                286 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     CH.sub.3                                                                            OCH.sub.3                                                                           N   150-151                                287 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     OCH.sub.3                                                                           OCH.sub.3                                                                           N   157-160                                288 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     Cl   OCH.sub.3                                                                           CH  152-155                                289 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     N(CH.sub.3).sub.2                                                                   OEt  N   145-147                                J is J-3, R.sup.71 is H                                                        290 CH.sub.3                                                                             SCH.sub.3                                                                               H      CH.sub.3                                                                            COH.sub.3                                                                           CH  217-220                                291 CH.sub.3                                                                             SCH.sub.3                                                                               H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  230-235                                292 CH.sub.3                                                                             SCH.sub.3                                                                               H      CH.sub.3                                                                            OCH.sub.3                                                                           N   186-189                                293 CH.sub.3                                                                             SCH.sub.3                                                                               H      Cl   OCH.sub.3                                                                           CH  188-190                                294 CH.sub.3                                                                             SCH.sub.3                                                                               H      N(CH.sub.3).sub.2                                                                   OEt  N   170-174                                295 CH.sub.3                                                                             Ph       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  180-184                                296 CH.sub.3                                                                             Ph       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  223-226                                297 CH.sub.3                                                                             Ph       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   190-195                                298 CH.sub.3                                                                             Ph       H      Cl   OCH.sub.3                                                                           CH  219-221                                299 CH.sub.3                                                                             Ph       H      N(CH.sub.3).sub.2                                                                   OEt  N   117-120                                300 CH.sub.3                                                                             SCH.sub.3                                                                               CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            CH.sub.3                                                                            CH  169-171                                301 CH.sub.3                                                                             SCH.sub.3                                                                               CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            OCH.sub.3                                                                           CH  140-145                                302 CH.sub.3                                                                             SCH.sub.3                                                                               CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  153-155                                303 CH.sub.3                                                                             SCH.sub.3                                                                               CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            OCH.sub.3                                                                           N   193-195                                304 CH.sub.3                                                                             SCH.sub.3                                                                               CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           N   158-160                                305 CH.sub.3                                                                             SCH.sub.3                                                                               CO.sub.2 CH.sub.3                                                                     Cl   OEt  N   187-190                                306 CH.sub.3                                                                             SCH.sub.3                                                                               CO.sub.2 CH.sub.3                                                                     NHCH.sub.3                                                                          OEt  N   158-160                                307 CH3   Ph       CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            CH.sub.3                                                                            CH  126-128                                308 CH.sub.3                                                                             Ph       CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            OCH.sub.3                                                                           CH  218-221                                309 CH.sub.3                                                                             Ph       CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  224-226                                310 CH.sub.3                                                                             Ph       CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            OCH.sub.3                                                                           N   201-204                                311 CH.sub.3                                                                             Ph       CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           N   201-204                                312 CH3   Ph       CO.sub.2 CH.sub.3                                                                     Cl   OCH.sub.3                                                                           CH  194-196                                313 CH.sub.3                                                                             Ph       CO.sub.2 CH.sub.3                                                                     NHCH.sub.3                                                                          OEt  N   135-138                                314 CH.sub.3                                                                             Ph       CO.sub.2 CH.sub.3                                                                     N(CH.sub.3).sub.2                                                                   OEt  N   189-193                                J is J-2, R.sup.71 is H                                                        315 Ph    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  209-212                                316 Ph    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  212-215                                317 Ph    CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  185-188                                318 Ph    CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   165-170                                319 Ph    CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   160-164                                320 Ph    CO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  215-220                                321 Ph    CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3).sub.2                                                                   OEt  N   154-160                                322 CH.sub.3                                                                             CN       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  218-221                                323 CH.sub.3                                                                             CN       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  212-215                                324 CH.sub.3                                                                             CN       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  201-204                                325 CH.sub.3                                                                             CN       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   213-216                                326 CH.sub.3                                                                             CN       H      OCH.sub.3                                                                           OCH3 N   216-220                                327 CH.sub.3                                                                             CN       H      Cl   OCH.sub.3                                                                           CH  219-220                                328 CH.sub.3                                                                             CN       H      NHCH.sub.3                                                                          OEt  N   159-161                                329 CH.sub.3                                                                             CN       H      N(CH.sub.3).sub.2                                                                   OEt  N   211-215                                330 Ph    SCH.sub.3                                                                               H      CH.sub.3                                                                            CH.sub.3                                                                            CH  216-220                                331 Ph    SCH.sub.3                                                                               H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  204-206                                332 Ph    SCH.sub.3                                                                               H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  189-191                                333 Ph    SCH.sub.3                                                                               H      CH.sub.3                                                                            OCH.sub.3                                                                           N   187-190                                334 Ph    SCH.sub.3                                                                               H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   208-211                                335 Ph    SCH.sub.3                                                                               H      Cl   OCH.sub.3                                                                           CH  190-193                                336 Ph    SCH.sub.3                                                                               H      NHCH.sub.3                                                                          OEt  N   189-191                                337 Ph    SCH.sub.3                                                                               H      N(CH.sub.3).sub.2                                                                   OEt  N   185-187                                J is J-3, R.sup.71 is H                                                        338 CH.sub.3                                                                             CN       CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            OCH.sub.3                                                                           CH  >260                                   339 CH.sub.3                                                                             CN       CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  183-185                                340 CH.sub.3                                                                             CN       CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            OCH.sub.3                                                                           N   180-183                                341 CH.sub.3                                                                             CN       CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           N   231-235                                342 CH.sub.3                                                                             CN       CO.sub.2 CH.sub.3                                                                     Cl   OCH.sub.3                                                                           CH  >255                                   J is J-2, R.sup.71 is H                                                        343 Ph    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  225-226                                344 Ph    SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  212-216                                345 Ph    SO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   199-201                                346 Ph    SO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           Cl   CH  209-211                                J is J-3, R.sup.71 is H                                                        347 CH.sub.3                                                                             CN       CHO    CH.sub.3                                                                            OCH.sub.3                                                                           CH  179-180                                348 CH.sub.3                                                                             CN       CHO    OCH.sub.3                                                                           OCH.sub.3                                                                           CH  181-184                                349 CH.sub.3                                                                             CN       CHO    CH.sub.3                                                                            OCH.sub.3                                                                           N   229-233                                350 CH.sub.3                                                                             CN       CHO    Cl   COH.sub.3                                                                           CH  155-159                                J is J-2, R.sup.71 is H                                                        351 Ph    CHO      H      CH.sub.3                                                                            CH.sub.3                                                                            CH  149-151                                352 Ph    CHO      H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  171-174                                353 Ph    CHO      H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  146-150                                354 Ph    CHO      H      CH3  OCH.sub.3                                                                           N   160-164                                355 Ph    CHO      H      OCH3 OCH.sub.3                                                                           N   147-150                                356 Ph    CHO      H      Cl   OCH.sub.3                                                                           CH  161-165                                357 Ph    CHO      H      N(CH.sub.3).sub.2                                                                   OEt  N   135-137                                J is J-3, R.sup.71 is H                                                        358 CH.sub.3                                                                             CN       CON(CH.sub.3).sub.2                                                                   CH.sub.3                                                                            OCH.sub.3                                                                           CH  92-95                                  359 CH.sub.3                                                                             CN       CON(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                           CH  168-171                                360 CH.sub.3                                                                             CN       CON(CH.sub.3).sub.2                                                                   CH.sub.3                                                                            OCH3 N   120-125                                361 CH.sub.3                                                                             CN       CON(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                           Cl   CH  165-170                                362 CH.sub.3                                                                             CN       CON(CH.sub.3).sub.2                                                                   N(CH.sub.3).sub.2                                                                   OEt  N   129-131                                363 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                           CH  190-193                                364 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                           CH  125-127                                365 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                           N   183-185                                366 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             Cl   OCH.sub.3                                                                           CH  168-170                                367 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             N(CH.sub.3).sub.2                                                                   OEt  N   210-215                                368 H     CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            CH.sub.3                                                                            CH  215-217                                369 H     CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  200-202                                370 H     CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  218-220                                371 H     CO.sub.2 CH.sub.3                                                                       H      Cl   OCH.sub.3                                                                           CH  221-223                                372 H     CO.sub.2 CH.sub.3                                                                       H      CH.sub.3                                                                            OCH.sub.3                                                                           N   138-142                                373 H     CO.sub.2 CH.sub.3                                                                       H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   230-234                                374 H     CO.sub.2 CH.sub.3                                                                       H      NHCH.sub.3                                                                          OEt  N   146-148                                375 H     CO.sub.2 CH.sub.3                                                                       H      N(CH.sub.3)2                                                                        OEt  N   185-187                                376 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      CH.sub.3                                                                            CH.sub.3                                                                            CH  247-249                                377 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  245-247                                378 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  233-235                                379 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      Cl   OCH.sub.3                                                                           CH  237-239                                380 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      CH.sub.3                                                                            OCH.sub.3                                                                           N   204-206                                381 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   216-218                                382 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      NHCH.sub.3                                                                          OEt  N   249-252                                383 CH.sub.3                                                                             C(O)CH.sub.3                                                                            H      N(CH.sub.3).sub.2                                                                   OEt  N   225-227                                J is J-2, R.sup.71 is H                                                        384 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            CH.sub.3                                                                            CH  159-166                                385 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  131-136                                386 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  140-147                                387 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      Cl   OCH.sub.3                                                                           CH  103-107                                388 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      CH.sub.3                                                                            OCH.sub.3                                                                           N   oil                                    389 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   oil                                    390 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      NHCH.sub.3                                                                          OEt  N   140-142                                391 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      N(CH.sub.3).sub.2                                                                   OEt  N   178-180                                392 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      OEt  OEt  N   121-125                                393 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      NHCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                  N   155-160                                394 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      N(CH.sub.3).sub.2                                                                   OCH.sub.2 CF.sub.3                                                                  N   250                                    395 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      N(CH.sub.3).sub.2                                                                   OCH.sub.3                                                                           N   gum                                    396 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      Et   OEt  N   gum                                    397 CH.sub.3                                                                             C(O)N(CH.sub.3).sub.2                                                                   H      Et   OCH.sub.3                                                                           N   gum                                    398 CH.sub.3                                                                             CHO      H      CH.sub.3                                                                            OCH.sub.3                                                                           CH  140-141.5                              399 CH.sub.3                                                                             CHO      H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  172-174.5                              400 CH.sub.3                                                                             CHO      H      Cl   OCH.sub.3                                                                           CH  172-175                                401 CH.sub.3                                                                             CHO      H      CH.sub.3                                                                            OCH.sub.3                                                                           N   156-160                                402 CH.sub.3                                                                             CHO      H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   173-177                                403 CH.sub.3                                                                             CHO      H      NHCH.sub.3                                                                          OEt  N   176-179                                404 CH.sub.3                                                                             CHO      H      OEt  OEt  N   102-104                                405 CH.sub.3                                                                             CHO      H      Et   OEt  N   149-151.5                              406 CH.sub.3                                                                             CHO      H      Et   OCH.sub.3                                                                           N   148-150                                __________________________________________________________________________     J is J-1, R.sup.3 and R.sup.71 is H                                            CMPD                                                                               R.sup.1                                                                               R.sup.2                                                                               X     Y      Z        m.p.(°C.)                       __________________________________________________________________________     407 (CH.sub.2).sub.3 CH.sub.3                                                             CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             CH.sub.3                                                                              CH       188-189                                408 (CH.sub.2).sub.3 CH.sub.3                                                             CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             OCH.sub.3                                                                             CH       138-140                                409 (CH.sub.2).sub.3 CH.sub.3                                                             CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                                                                             CH       139-140                                410 (CH.sub.2).sub.3 CH.sub.3                                                             CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             OCH.sub.3                                                                             N        137-138                                411 (CH.sub.2).sub.3 CH.sub.3                                                             CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                                                                             N        152-155                                412 (CH.sub.2).sub.3 CH.sub.3                                                             CO.sub.2 CH.sub.3                                                                     Cl    OCH.sub.3                                                                             CH       162-164                                413 CH.sub.3                                                                              OC.sub.2 H.sub.5                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             CH       180-181°d                       414 CH.sub.3                                                                              OC.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            OCH.sub.3                                                                             CH       170-172°d                       415 CH.sub.3                                                                              OC.sub.2 H.sub.5                                                                      CH.sub.3                                                                             OCH.sub.3                                                                             N        178-179°d                       416 CH.sub.3                                                                              OC.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            OCH.sub.3                                                                             N        175-177°d                       417 CH.sub.3                                                                              CN     CH.sub.3                                                                             CH.sub.3                                                                              CH       198-200°d                       418 CH.sub.3                                                                              CN     CH.sub.3                                                                             OCH.sub.3                                                                             CH       178-184°d                       419 CH.sub.3                                                                              CN     OCH.sub.3                                                                            OCH.sub.3                                                                             CH       199-201°d                       420 CH.sub.3                                                                              CN     CH.sub.3                                                                             OCH.sub.3                                                                             N        184-186°d                       421 CH.sub.3                                                                              CN     OCH.sub.3                                                                            OCH.sub.3                                                                             N        180-182°d                       422 CH.sub.3                                                                              CN     Cl    OCH.sub.3                                                                             CH       199-201°d                       __________________________________________________________________________     J is J-3, R.sup.71 is H                                                        CMPD                                                                               R.sup.1                                                                              R.sup.2  R.sup.4                                                                               X    Y    Z   m.p.(°C.)                       __________________________________________________________________________     423 CH.sub.3                                                                             CN       CHO    OCH.sub.3                                                                           CH.sub.3                                                                            CH  179-180                                424 CH.sub.3                                                                             CN       CHO    OCH.sub.3                                                                           OCH.sub.3                                                                           CH  181-184                                425 CH.sub.3                                                                             CN       CHO    OCH.sub.3                                                                           CH.sub.3                                                                            N   229-233                                426 CH.sub.3                                                                             CN       CHO    OCH.sub.3                                                                           Cl   CH  155-159                                427 CH.sub.3                                                                             CN       C(O)N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                           CH.sub.3                                                                            CH  92-95                                  428 CH.sub.3                                                                             CN       C(O)N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                           CH  168-171                                429 CH.sub.3                                                                             CN       C(O)N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                           CH.sub.3                                                                            N   120-123                                430 CH.sub.3                                                                             CN       C(O)N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                           Cl   CH  165-170                                431 CH.sub.3                                                                             CN       C(O)N(CH.sub.3).sub.2                                                                 OEt  N(CH.sub.3).sub.2                                                                   N   129-131                                432 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             OCH.sub.3                                                                           CH.sub.3                                                                            CH  190-193                                433 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                           CH  125-127                                434 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             OCH.sub.3                                                                           CH.sub.3                                                                            N   183-185                                435 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             OCH.sub.3                                                                           Cl   CH  168-170                                436 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       SCH.sub.3                                                                             OEt  N(CH.sub.3).sub.2                                                                   N   210-215                                437 CH.sub.3                                                                             CN       Br     CH.sub.3                                                                            CH.sub.3                                                                            CH  153-156                                438 CH.sub.3                                                                             CN       Br     OCH.sub.3                                                                           CH.sub.3                                                                            CH  168-171                                439 CH.sub.3                                                                             CN       Br     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  150-153                                440 CH.sub.3                                                                             CN       Br     OCH.sub.3                                                                           CH.sub.3                                                                            N   159-162                                441 CH.sub.3                                                                             CN       Br     OCH.sub.3                                                                           OCH.sub.3                                                                           N   164-167                                442 CH.sub.3                                                                             CN       Br     OCH.sub.3                                                                           Cl   CH  >210                                   443 CH.sub.3                                                                             CN       Br     OEt  N(CH.sub.3).sub.2                                                                   N   >210                                   444 CH.sub.3                                                                             CH.sub.3 CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                            CH.sub.3                                                                            CH  205-209                                445 CH.sub.3                                                                             CH.sub.3 CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           CH.sub.3                                                                            CH  196-200                                446 CH.sub.3                                                                             CH.sub.3 CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           CH  186-188                                447 CH.sub.3                                                                             CH.sub.3 CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           CH.sub.3                                                                            N   201-202                                448 CH.sub.3                                                                             CH.sub.3 CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                           N   185-186                                449 CH.sub.3                                                                             CH.sub.3 CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                           Cl   CH  175-178                                450 CH.sub.3                                                                             CH.sub.3 CO.sub.2 CH.sub.3                                                                     OEt  CN(CH.sub.3).sub.2                                                                  N   154-157°                        451 CH.sub.3                                                                             CN       C(O)CH.sub.3                                                                          OCH.sub.3                                                                           CH.sub.3                                                                            CH  159-162                                452 CH.sub.3                                                                             CN       C(O)CH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                           CH  175-178                                453 CH.sub.3                                                                             CN       C(O)CH.sub.3                                                                          OCH.sub.3                                                                           CH.sub.3                                                                            N   180-182                                454 CH.sub.3                                                                             CN       C(O)CH.sub.3                                                                          OCH.sub.3                                                                           Cl   CH  >240                                   455 CH.sub.3                                                                             CN       SO.sub.2 Et                                                                           OCH.sub.3                                                                           CH.sub.3                                                                            CH  168-170                                456 CH.sub.3                                                                             CN       SO.sub.2 Et                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                           CH  161-164                                457 CH.sub.3                                                                             CN       SO.sub.2 Et                                                                           OCH.sub.3                                                                           CH.sub.3                                                                            N   170-174                                458 CH.sub.3                                                                             CN       SO.sub.2 Et                                                                           OCH.sub.3                                                                           Cl   CH  195-200                                459 CH.sub.3                                                                             CN       SO.sub.2 Et                                                                           OEt  N(CH.sub.3).sub.2                                                                   N   >200                                   460 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     OCH.sub.3                                                                           CH.sub.3                                                                            N   192-193                                461 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     OCH.sub.3                                                                           OCH.sub.3                                                                           N   193-197                                462 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                       Br     OCH.sub.3                                                                           Cl   CH  194-195                                463 CH.sub.3                                                                             SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           CH.sub.3                                                                            CH  172-173                                464 CH.sub.3                                                                             SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           CH  183-184                                465 CH.sub.3                                                                             SO.sub.2 Et                                                                             H      CH.sub.3                                                                            OCH.sub.3                                                                           N   189-190                                466 CH.sub.3                                                                             SO.sub.2 Et                                                                             H      OCH.sub.3                                                                           OCH.sub.3                                                                           N   193-194                                __________________________________________________________________________

Formulations

Useful formulations of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates ad the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulations, broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid inert diluent(s). More specifically, they will contain these ingredients in the following approximate proportions:

    ______________________________________                                                            Weight Percent*                                                           Active                                                                         Ingredient                                                                            Diluent(s)                                                                              Surfactant(s)                                    ______________________________________                                         Wettable Powders                                                                               20-90     0-74    1-10                                         Oil Suspensions,                                                                                3-50    40-95    0-15                                         Emulsions, Solutions,                                                          (including Emulsifiable                                                        Concentrates)                                                                  Aqueous Suspension                                                                             10-50    40-84    1-20                                         Dusts            1-25    70-99    0-5                                          Granules and Pellets                                                                           0.1-95     5-99.9 1-15                                         High Strength Compositions                                                                     90-99     0-10    0-2                                          ______________________________________                                          *Active ingredient plus at least one of a Surfactant or a Diluent equals       100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are some-times desirable, and are achieved by incorporation into the formulation or by tank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books, Caldwell, N.J., but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferably stable against phase separation at 0° C., "McCutcheon's Detergents and Emulsifiers Annual", MC Publishing Corp., Ridgewood, N.J., as well as Sisely and Wood, "Encyclopedia of Surface Active Agents", Chemical Publishing Co., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor mounts of additives to reduce foaming, caking, corrosion, microbiological growth, etc.

The methods of making such compositions are well known solutions are prepared by simply mixing the ingredients. Fine solid. compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning, "Agglomeration", Chemical Engineering, Dec. 4, 1967, pp. 147ff. and "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York, 1963, pp. 8-57ff.

For further information regarding the art of formulation, see for example:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16 through Col. 7, line 19 and Examples 10 through 41; R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138-140, 162-164, 166, 167 and 169-182; H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, Jun. 23, 1959, Col. 3, line 66 through Col. 5, line 17 and Examples 1-4; G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pp. 81-96; and J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pp. 101-103.

In the following examples, all parts are by weight unless otherwise indicated.

Example A

High Strength Concentrate

    ______________________________________                                         methyl 3-    (4,6-dimethoxy-2-pyrimidinyl)amino!-                                                           99%                                               carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate                     trimethylnonyl polyethylene   1%                                               glycol ether                                                                   ______________________________________                                    

The surfactant is sprayed upon the active ingredient in a blender and the mixture sired through a U.S. S. no. 40 sieve (0.42 mm openings) prior to packaging. The concentrate may be formulated further for practical use.

Example B

Wettable Powder

    ______________________________________                                         methyl 3     4-ethoxy-6-(methylamino)-1,3,5-triazin-2-                                                     65%                                                yl!amino!carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-                         2-carboxylate                                                                  dodecylphenol polyethylene glycol ether                                                                    2%                                                 sodium ligninsulfonate      4%                                                 sodium silicoaluminate      6%                                                 montmorillonite (calcinded) 23%                                                ______________________________________                                    

The ingredients are thoroughly Mended. The liquid surfactant is added by spraying upon the solid ingredients in the blender. After grinding in a hammer mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) and packaged.

Example C

Aqueous Suspension

    ______________________________________                                         methyl 3-    (4,6-dimethoxy-2-pyrimidinyl)amino!-                                                           50.0%                                             carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate                     polyacrylic acid thickener   0.3%                                              dodecylphenol polyethylene glycol ether                                                                     0.5%                                              disodium phosphate           1%                                                monosodium phosphate         0.5%                                              polyvinyl alcohol            1.0%                                              water                        56.7%                                             ______________________________________                                    

The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.

Example D

Oil Suspension

    ______________________________________                                         methyl 3     4-ethoxy-6-(methylamino)-1,3,5-triazin-2-                                                     35%                                                yl!amino!carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-                         2-carboxylate                                                                  blend of polyalcohol carboxylic esters                                                                      6%                                                and oil soluble petroleum sulfonates                                           xylene                      59%                                                ______________________________________                                    

The ingredients are combined and ground together in a sand mill to produce particles essentially all below 3 microns. The product can be used directly, extended with oils, or emulsified in water.

Example E

Oil Suspension

    ______________________________________                                         methyl 3-    4,6-dimethoxy-2-pyrimidinyl)amino!-                                                            25%                                               carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate                     polyoxyethylene sorbitol hexaoleate                                                                          5%                                               highly aliphatic hydrocarbon oil                                                                            70%                                               ______________________________________                                    

The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water.

Example F

Aqueous Suspension

    ______________________________________                                         methyl 3     4-ethoxy-6-(methylamino)-1,3,5-triazin-2-                                                   25%                                                  yl!amino!carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole                          2-carboxylate                                                                  hydrated attapulgite      3%                                                   crude calcium ligninsulfonate                                                                            10%                                                  sodium dihydrogen phosphate                                                                              0.5%                                                 water                     61.5%                                                ______________________________________                                    

The ingredients are ground together in a ball or roller mill until the solid particles have been reduced to diameters under 10 microns.

Example G

Wettable Powder

    ______________________________________                                         methyl 3-    4,6-dimethoxy-2-pyrimidinyl)amino!-                                                            40.0%                                             carbonyl!amino!sulfonly!-1-methyl-1H-pyrrole-2-carboxylate                     dioctyl sodium sulfosuccinate                                                                               1.5%                                              sodium ligninsulfonate       3%                                                low viscosity methyl cellulose                                                                              1.5%                                              attapulgite                  54%                                               ______________________________________                                    

The ingredients are thoroughly blended, passed through an air mill, to produce an average particle size under 15 microns, reblended, and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) before packaging.

All compounds of the invention may be formulated in the same manner.

Example H

Granule

    ______________________________________                                         wettable powder of Example G                                                                        15%                                                       gypsum               69%                                                       potassium sulfate    16%                                                       ______________________________________                                    

The ingredients are blended in a rotating mixer and water sprayed on to accomplish granulation. When most of the material has reached the desired range of 1.0 to 0.42 cm (U.S-S.#18 to 40 sieves), the granules are removed, dried, and screened. Oversized material is crushed to produce additional material in the desired range. These granules contain % active ingredient.

Example I

Wettable Powder

    ______________________________________                                         methyl 3     4-ethoxy-6-(methylamino)-1,3,5-triazin-2-                                                     50%                                                yl!amino!carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-                         2-carboxylate                                                                  sodium alkylnaphthalenesulfonate                                                                            2%                                                low viscosity methyl cellulose                                                                              2%                                                diatomaceous earth          46%                                                ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and the air milled to produce particles of active essentially all below 10 microns in diameter. The product is reblended before packaging.

Example J

Extruded Pellet

    ______________________________________                                         methyl 3-    (4,6-dimethoxy-2-pyrimidinyl)amino!-                                                           25%                                               carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate                     anhydrous sodium sulfate     10%                                               crude calcium ligninsulfonate                                                                                5%                                               sodium alkylnaphthalenesulfonate                                                                             1%                                               calcium/magnesium bentonite  59%                                               ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.

Example K

Wettable powder

    ______________________________________                                         methyl 3     4-ethoxy-6-(methylamino)-1,3,5-triazin-2-                                                    80%                                                 yl!amino!carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-2-                       carboxylate                                                                    sodium alkylnaphthalenesulfonate                                                                          2%                                                  sodium ligninsulfonate     2%                                                  synthetic amorphous silica 3%                                                  kaolinite                  13%                                                 ______________________________________                                    

The ingredients are blended and then ground in ahammermill to produce particles with an average particle size less than 25 microns in diameter. The material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) before being packaged.

Example L

High Strength Concentrate

    ______________________________________                                         methyl 3-    4,6-dimethoxy-2-pyrimidinyl)amino!-                                                            98.5%                                             carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate                     silica aerogel               0.5%                                              synthetic amorphous fine silica                                                                             1.0%                                              ______________________________________                                    

The ingredients are blended and ground in a hammer mill to produce a high strength concentrate essentially all passing a U.S.S. No. 50 sieve (0.3 mm openings). This material may then be formulated in a variety of ways.

Example M

Solution

    ______________________________________                                         methyl 3     4-ethoxy-6-(methylamino)-1,3,5-triazin-2-                                                        5%                                              yl!amino!carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-                         2-carboxylate                                                                  sodium salt                    5%                                              water                         95%                                              ______________________________________                                    

The salt is added directly to the water with stirring to produce the solution, which may then be packaged for use.

Example N

Solution

    ______________________________________                                         methyl 3-    4,6-dimethoxy-2-pyrimidinyl)amino!-                                                             5%                                               carbonyl!amino!sulfonyl!-1-methyl-1H-pyrrole-2-carboxylate                     sodium salt                   5%                                               water                        95%                                               ______________________________________                                    

The salt is added directly to the water with stirring to produce the solution, which may then be packaged for use.

Utility

Test results indicate compounds of this invention are active postemergence and preemergence herbicides. Compounds in this invention are useful for the control of selected grass and broadleaf weeds with tolerance to important agronomic crops which include, but are not limited to barley (Hordeum vulgare), cotton (Gossypium hirsutum), rape (Brassica napus), rice (Oryza sativa), and wheat (Triticum aestivum). Grass and broadleaf weed species controlled include, but are not limited to, bedstraw (Galium spp.), brome (Bromus spp.), lambsquarters (Chenopodium spp.), and umbrella sedge (Cyperus spp.). A few compounds in this invention are useful for the control of selected broadleaf weeds such as umbrella sedge in upland and paddy rice.

These compounds also have utility for control of vegetation in specified areas such as around storage tanks, parking lots, highways, and raftways; in fallow crop areas; and in citrus and plantation crops such as banana, coffee, oil palm, and rubber. Alternatively, these compounds are useful to modify plant growth or as citrus abscission agents.

A herbicidally effective amount of the compounds of this invention is determined by a number of factors. These factors include: formulation selected, method of application, amount and type of vegetation present, growing conditions, etc. In general, a herbicidally effective amount of the subject compounds is applied at rates from 0.001 to 20 kg/ha with a preferred rate range of 0.004 to 0.25 kg/ha. One skilled in the art can easily determine application rates necessary for the desired level of weed control.

Compounds of this invention may be used alone or in combination with other commercial herbicides, insecticides, or fungicides, The following list exemplifies some of the herbicides suitable for use in mixtures. A combination of a compound from this invention with one or more of the following herbicides may be particularly useful for weed control.

    ______________________________________                                         Common Name  Chemical Name                                                     ______________________________________                                         acetochlor   2-chloro-N-(ethoxymethyl)-N-                                                   (2-ethyl-6-methylphenyl)acetamide                                 acifluorfen  5- 2-chloro-4-(trifluoromethyl)-                                               phenoxy!-2-nitrobenzoic acid                                      acrolein     2-propenal                                                        alachlor     2-chloro-N-(2,6-diethylphenyl)-N-                                              (methoxymethyl)acetamide                                          anilofos     S-4-chloro-N-isopropylcarbaniloyl-                                             methyl-O,O-dimethyl phosphorodi-                                               thioate                                                           ametryn      N-ethyl-N'-(1-methylethyl)-6-                                                  (methylthio)-1,3,5-triazine-2,4-                                               diamine                                                           amitrole     1H-1,2,4-triazol-3-amine                                          AMS          ammonium sulfamate                                                asulam       methyl (4-aminophenyl)sulfonyl!-                                               carbamate                                                         atrazine     6-chloro-N-ethyl-N'-(1-methylethyl)-                                           1,3,5-triazine-2,4-diamine                                        barban       4-chloro-2-butynyl 3-chlorocarbamate                              benefin      N-butyl-N-ethyl-2,6-dinitro-4-(tri-                                            fluoromethyl)benzenamine                                          bensulfuron  2-     (4,6-dimethoxy-2-pyrimi-                                   methyl       dinyl)amino!methylcarbonyl!-                                                   amino!sulfonyl!methyl!benzoic                                                  acid, methyl ester                                                bensulide    O,O-bis(1-methylethyl) S- 2-                                                    (phenylsulfonyl)amino!-                                                       ethyl!phosphorodithioate                                          bentazon     3-(1-methylethyl)-(1H)-2,1,3-                                                  2,2-dioxide                                                       benzofluor   N- 4-(ethylthio)-2-(trifluoro-                                                 methyl)phenyl!methanesulfonamide                                  benzoylprop  N-benzoyl-N-(3,4-dichlorophenyl)-DL-                                           alanine                                                           bifenox      methyl 5-(2,4-dichlorophenoxy)-2-                                              nitrobenzoate                                                     bromacil     5-bromo-6-methyl-3-(1-methylpropyl)-                                           2,4(1H,3H)pyrimidinedione                                         bromoxynil   3,5-dibromo-4-hydroxybenzonitrile                                 butachlor    N-(butoxymethyl)-2-chloro-N-(2,6-                                              diethylphenyl)acetamide                                           buthidazole  3- 5-(1,1-dimethylethyl)-1,3,4-thia-                                           diazol-2-yl!-4-hydroxy-1-methyl-2-                                             imidazolidinone                                                   butralin     4-(1,1-dimethylethyl)-N-(1-methyl-                                             propyl)-2,6-dinitrobenzenamine                                    butylate     S-ethyl bis(2-methylpropyl)-                                                   carbamothioate                                                    cacodylic    dimethyl arsinic oxide                                            acid                                                                           CDAA         2-chloro-N,N-di-2-propenylacetamide                               CDEC         2-chloroallyl diethyldithiocarbamate                              CGA 142,464  3-(4,6-dimethoxy-1,3,5-triazin-2-yl)-                                          1- 2-(2-methoxyethoxy)-pehnyl-                                                 sulfonyl!-urea                                                    chloramben   3-amino-2,5-dichlorobenzoic acid                                  chlorbromuron                                                                               3-(4-bromo-3-chlorophenyl)-1-methoxy-1-                                        methylurea                                                        chlorimuron  2-    (4-chloro-6-methoxy-2-pyrimi-                               ethyl        dinyl)ethylamine)carbonyl!-                                                    amino!sulfonyl!benzoic                                                         acid, ethyl ester                                                 chlormethoxy-                                                                               2,4-dichlorophenyl 4-nitro-3-                                     nil          methoxyphenyl ether                                               chlornitrofen                                                                               2,4,6-trichlorophenyl-4-nitro-                                                 phenyl ether                                                      chloroxuron  N'- 4-(4-chlorophenoxy)phenyl!-N,N-                                            dimethylurea                                                      chlorpropham 1-methylethyl 3-chlorophenylcarbamate                             chlorsulfuron                                                                               2-chloro-N-  (4-methoxy-6-methyl-1,3,5-                                        triazin-2-yl)amino!carbonyl!benzene-                                           sulfonamide                                                       chlortoluron N'-(3-chloro-4-methylphenyl)-N,N-                                              dimethylurea                                                      cinmethylin  exo-1-methyl-4-(1-methylethyl)-2- (2-                                          methylphenyl)methoxy!-7-oxabicyclo-                                             2.2.1!heptane                                                    clethodim    (E,E)-(±)-2- 1-  (3-chloro-2-propenyl)-                                     oxy!imino!propyl!-5- 2-(ethylthio)-                                            propyl!-3-hydroxy-2-cyclohexen-1-one                              clomazone    2- (2-chlorophenyl)methyl!-4,4-dimethyl-                                       3-isoxazolidinone                                                 cloproxydim  (E,E)-2- 1-  (3-chloro-2-propenyl)oxy)-                                        imino!butyl!-5- 2-(ethylthio)propyl!-                                          3-hydroxy-2-cyclohexen-1-one                                      clopyralid   3,6-dichloro-2-pyridinecarboxylic acid                            CMA          calcium salt of MAA                                               cyanazine    2-  4-chloro-6-(ethylamino)-1,3,5-tri-                                         azin-2-yl!amino!-2-methylpropanenitrile                           cycloate     S-ethyl cyclohexylethylcarbamothioate                             cycluron     3-cyclooctyl-1,1-dimethylurea                                     cyperquat    1-methyl-4-phenylpyridinium                                       cyprazine    2-chloro-4-(cyclopropylamino)-6-(iso-                                          propylamino)-s-triazine                                           cyprazole    N- 5-(2-chloro-1,1-dimethylethyl)-1,3,4-                                       thiadiazol-2-yl!cyclopropanecarbox-                                            amide                                                             cypromid     3',4'-dichlorocyclopropanecarboxanilide                           dalapon      2,2-dichloropropanoic acid                                        dazomet      tetrahydro-3,5-dimethyl-2H-1,3,5-thia-                                         diazine-2-thione                                                  DCPA         dimethyl 2,3,5,6-tetrachloro-1,4-benzene-                                      dicarboxylate                                                     desmediphan  ethyl  3-  (phenylamino)carbonyl!oxy!-                                         phenyl!carbamate                                                  desmetryn    2-(isopropylamino)-4-(methylamino)-6-                                          (methylthio)-s-triazine                                           diallate     S-(2,3-dichloro-2-propenyl)bis(1-                                              methylethyl)carbamothioate                                        dicamba      3,6-dichloro-2-methoxybenzoic acid                                dichlobenil  2,6-dichlorobenzonitrile                                          dichlorprop  (±)-2-(2,4-dichlorophenoxy)propanoic                                        acid                                                              dichlofop    (±)-2- 4-(2,4-dichlorophenoxy)phenoxy!-                                     propanoic acid, methyl ester                                      diethatyl    N-(chloroacetyl)-N-(2,6-diethylphenyl)-                                        glycine                                                           difensoquat  1,2-dimethyl-3,5-diphenyl-1H-pyrazolium                           dimepiperate S-1-methyl-1-phenylethylpiperidine-                                            1-carbothioate                                                    dinitramine  N.sup.3,N.sup.3 -diethyl-2,4-dinitro-6-(trifluoro-                             methyl)-1,3-benzenediamine                                        dinoseb      2-(1-methylpropyl)-4,6-dinitrophenol                              diphenamid   N,N-dimethyl-a-phenylbenzeneacetamide                             dipropetryn  6-(ethylthio)-N,N'-bis(1-methylethyl)-                                         1,3,5-triazine-2,4-diamine                                        diquat       6,7-dihydrodipyrido 1,2-a:2',1'-c!-                                            pyrazinedium ion                                                  diuron       N'-(3,4-dichlorophenyl)-N,N-dimethylurea                          DNOC         2-methyl-4,6-dinitrophenol                                        DSMA         disodium salt of MAA                                              dymron       N-(4-methylphenyl)-N'-(1-methyl-                                               1-phenylethyl)urea                                                endothall    7-oxabicyclo 2.2.1!heptane-2,3-dicarbox-                                       ylic acid                                                         EPTC         S-ethyl dipropylcarbamothioate                                    esprocarb    S-benzyl-N-ethyl-N-(1,2-dimethyl)-                                (SC2957)     propyl)thiolcarbamate                                             ethalfluralin                                                                               N-ethyl-N-(2-methyl-2-propenyl)-2,6-                                           dinitro-4-(trifluoromethyl)-                                                   benzenamine                                                       ethofumesate (±)-2-ethoxy-2,3-dihydro-3,3-dimethyl-                                      5-benzofuranyl methanesulfonate                                   fenac        2,3,6-trichlorobenzeneacetic acid                                 fenoxaprop   (±)-2- 4- (6-chloro-2-benzoxazolyl)oxy!-                                    phenoxy!propanoic acid                                            fenuron      N,N-dimethyl-N'-phenylurea                                        fenuron TCA  Salt of fenuron and TCA                                           flamprop     N-benzoyl-N-(3-chloro-4-fluorophenyl)-                                         DL-alanine                                                        fluazifop    (±)-2- 4-  5-(trifluoromethyl)-2-pyri-                                      dinyl!oxy!phenoxy!propanoic acid                                  fluazifop-P  (R)-2- 4-  5-(trifluoromethyl)-2-pyri-                                         dinyl!oxy!phenoxy!propanoic acid                                  fluchloralin N-(2-chloroethyl)-2,6-dinitro-N-propyl-                                        4-(trifluoromethyl)benzenamine                                    fluometuron  N,N-dimethyl-N'- 3-(trifluoromethyl)-                                          phenyl!urea                                                       fluorochlor- 3-chloro-4-(chloromethyl)-1- 3-(tri-                              idone        fluoromethyl)phenyl!-2-pyrrolidinone                              fluorodifen  p-nitrophenyl a,a,a-trifluoro-2-nitro-                                         p-tolyl ether                                                     fluorogly-   carboxymethyl 5- 2-chloro-4-(tri-                                 cofen        fluoromethyl)phenoxy!-2-nitrobenzoate                             fluridone    1-methyl-3-phenyl-5- 3-(trifluoro-                                             methyl)phenyl!-4(1H)-pyridinone                                   fomesafen    5- 2-chloro-4-(trifluoromethyl)phenoxy!-                                       N-(methylsulfonyl)-2-nitrobenzamide                               fosamine     ethyl hydrogen (aminocarbonyl)-                                                phosphate                                                         glyphosate   N-(phosphonomethyl)glycine                                        haloxyfop    2- 4-  3-chloro-5-(trifluoromethyl)-2-                                         pyridinyl!oxy!phenoxy!propanoic acid                              hexaflurate  potassium hexafluoroarsenate                                      hexazinone   3-cyclohexyl-6-(dimethylamino)-1-methyl-                                       1,3,5-triazine-2,4(1H,3H)-dione                                   imazametha-  6-(4-isopropyl-4-methyl-5-oxo-2-                                  benz         imidazolin-2-yl)-m-toluic acid,                                                methyl ester and 6-(4-isopropyl-                                               4-methyl-5-oxo-2-imidazolin-2-yl)-                                             p-toluic acid, methyl ester                                       imazapyr     (±)-2- 4,5-dihydro-4-methyl-4-(1-methyl-                                    ethyl)-5-oxo-1H-imidazol-2-yl!-3-                                              pyridinecarboxylic acid                                           imazaquin    2- 4,5-dihydro-4-methyl-4-(1-methyl-                                           ethyl)-5-oxo-1H-imidazol-2-yl!-3-                                              quinolinecarboxylic acid                                          imazethapyr  (±)-2- 4,5-dihydro-4-methyl-4-(1-methyl-                                    ethyl)-5-oxo-1H-imidazol-2-yl!-5-                                              ethyl-3-pyridinecarboxylic acid                                   ioxynil      4-hydroxy-3,5-diiodobenzonitrile                                  isopropalin  4-(1-methylethyl)-2,6-dinitro-N,N-                                             dipropylbenzenamine                                               isoproturon  N-(4-isopropylphenyl)-N',N'-dimethylurea                          isouron      N'- 5-(1,1-dimethylethyl)-3-isoxazolyl!-                                       N,N-dimethylurea                                                  isoxaben     N- 3-(1-ethyl-1-methylpropyl)-5-                                               isoxazolyl!-2,6-dimethoxybenzamide                                karbutilate  3-  (dimethylamino)carbonyl!amino!-                                            phenyl-(1,1-dimethylethyl)carbamate                               lactofen     (±)-2-ethoxy-1-methyl-2-oxoethyl 5- 2-                                      chloro-4-(trifluoromethyl)phenoxy!-                                            2-nitrobenzoate                                                   lenacil      3-cyclohexyl-6,7-dihydro-1H-cyclopenta-                                        pyrimidine-2,4(3H,5H)-dione                                       linuron      N'-(3,4-dichlorophenyl)-N-methoxy-N-                                           methylurea                                                        MAA          methylsarsonic acid                                               MAMA         monoammonium salt of MAA                                          MCPA         (4-chloro-2-methylphenoxy)acetic acid                             MCPB         4-(4-chloro-2-methylphenoxy)butanoic                                           acid                                                              MON 7200     S,S-dimethyl-2-(difluoromethyl)-4-                                             (2-methylpropyl)-6-(trifluoromethyl)-                                          3,5-pyridinedicarbothionate                                       mecoprop     (±)-2-(4-chloro-2-methylphenoxy)-                                           propanoic acid                                                    mefenacet    2-(2-benzothiazolyloxy-N-methyl-N-                                             phenylacetamide                                                   mefluidide   N- 2,4-dimethyl-5-  (trifluoromethyl)-                                         sulfonyl!amino!phenyl!acetamide                                   methal-      N-(2-methyl-2-propenyl)-2,6-dinitro-N-                            propalin     propyl-4-(trifluoromethyl)benzenamide                             methabenz-   1,3-dimethyl-3-(2-benzothiazolyl)urea                             thiazuron                                                                      metham       methylcarbamodithioic acid                                        methazole    2-(3,4-dichlorophenyl)-4-methyl-1,2,4-                                         oxadiazolidine-3,5-dione                                          methoxuron   N'-(3-chloro-4-methoxyphenyl)-N,N-                                             dimethylurea                                                      metolachlor  2-chloro-N-(2-ethyl-6-methylphenyl)-N-                                         (2-methoxy-1-methylethyl)acetamide                                metribuzin   4-amino-6-(1,1-dimethylethyl)-3-(methyl-                                       thio)-1,2,4-triazin-5(4H)-one                                     metsulfuron  2-    (4-methoxy-6-methyl-1,3,5-tri-                              methyl       azin-2-yl)amino!carbonyl!-                                                     amino!sulfonyl!benzoic acid,                                                   methyl ester                                                      MH           1,2-dihydro-3,6-pyridazinedione                                   molinate     S-ethyl hexahydro-1H-azepine-1-carbo-                                          thioate                                                           monolinuron  3-(p-chlorophenyl)-1-methoxy-1-methyl-                                         urea                                                              monuron      N'-(4-chlorophenyl)-N,N-dimethylurea                              monuron TCA  Salt of monuron and TCA                                           MSMA         monosodium salt of MAA                                            napropamide  N,N-diethyl-2-(1-naphthalenyloxy)-                                             propanamide                                                       naptalam     2- (1-naphthalenylamino)carbonyl!-                                             bonzoic acid                                                      neburon      1-butyl-3-(3,4-dichlorophenyl)-1-methyl-                                       urea                                                              nicosulfuron 2-  (4,6-dimethoxypyrimidin-2-yl)-                                             aminocarbonyl!aminosulfonyl!-N,N-                                              dimethyl-3-pyridinecarboxamide                                    nitralin     4-(methylsulfonyl)-2,6-dinitro-N,N-                                            dipropylaniline                                                   nitrofen     2,4-dichloro-1-(4-nitrophenoxy)benzene                            nitrofluorfen                                                                               2-chloro-1-(4-nitrophenoxy)-4-(tri-                                            fluoromethyl)benzene                                              norea        N,N-dimethyl-N'-(octahydro-4,7-methano-                                        1H-inden-5-yl)urea 3aa,-                                                       4a,5a,7a,7aa-isomer                                               norflurazon  4-chloro-5-(methylamino)-2- 3-(tri-                                            fluoromethyl)phenyl!-3(2H)-                                                    pyridazinone                                                      oryzalin     4-(dipropylamino)-3,5-dinitro-                                                 benzenesulfonamide                                                oxadiazon    3- 2,4-dichloro-5-(1-methylethoxy)-                                            phenyl!-5-(1,1-dimethylethyl)-                                                 1,3,4-oxadiazol-2(3H)-one                                         oxyfluorfen  2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-                                        (trifluoromethyl)benzene                                          paraquat     1,1'-dimethyl-4,4'-dipyridinium ion                               pebulate     S-propyl butylethylcarbamothioate                                 pendimethalin                                                                               N-(1-ethylpropyl)-3,4-dimethyl-2,6-                                            dinitrobenzenamine                                                perfluidone  1,1,1-trifluoro-N- 2-methyl-4-(phenyl-                                         sulfonyl)phenyl!methanesulfonamide                                phenmedipham 3- (methoxycarbonyl)amino!phenyl (3-                                           methylphenyl)carbamate                                            picloram     4-amino-3,5,6-trichloro-2-pyridine-                                            carboxylic acid                                                   PPG-1013     5- 2-chloro-4-(trifluoromethyl)-                                               phenoxy!-2-nitroacetophenone                                                   oxime-O-acetic acid, methyl ester                                 pretilachlor a-chloro-2,6-diethyl-N-(2-propoxy-                                             ethyl)acetanilide                                                 procyazine   2-  4-chloro-6-(cyclopropylamino)-1,3,5-                                       triazine-2-yl!amino!-2-methylpropane-                                          nitrile                                                           profluralin  N-(cyclopropylmethyl)-2,6-dinitro-N-                                           propyl-4-(trifluoromethyl)benzenamine                             prometon     6-methoxy-N,N'-bis(1-methylethyl)-1,3,5-                                       triazine-2,4-diamine                                              prometryn    N,N'-bis(1-methylethyl)-6-(methylthio)-                                        1,3,5-triazine-2,4-diamine                                        pronamide    3,5-dichloro-N-(1,1-dimethyl-2-propyn-                                         yl)benzamide                                                      propachlor   2-chloro-N-(1-methylethyl)-N-                                                  phenylacetamide                                                   propanil     N-(3,4-dichlorophenyl)propanamide                                 propazine    6-chloro-N,N'-bis(1-methylethyl)-                                              1,3,5-trizine-2,4-diamine                                         propham      1-methylethyl phenylcarbamate                                     prosulfalin  N-  4-(dipropylamino)-3,5-dinitro-                                             phenyl!sulfonyl!-S,S-dimethylsulfil-                                           imine                                                             prynachlor   2-chloro-N-(1-methyl-2-propynyl)acet-                                          anilide                                                           pyrazolate   4-(2,4-dichlorobenzoyl)-1,3-dimethyl-                                          pyrazol-5-yl-p-toluenesulphonate                                  pyrazon      5-amino-4-chloro-2-phenyl-3(2H)-                                               pyridazinone                                                      pyrazosulfuron                                                                              ethyl S- 3-(4,6-dimethoxypyrimidin-2-                             ethyl        yl)ureadosulfonyl!-1-methylpyrazole-                                           4-carboxylate                                                     quinclorac   3,7-dichloro-8-quinoline carboxylic acid                          quizalofop   (±)-2- 4- (6-chloro-2-quinoxalinyl)-                           ethyl        oxy!phenoxy!propanoic acid, ethyl                                              ester                                                             secbumeton   N-ethyl-6-methoxy-N'-(1-methylpropyl)-                                         1,3,5-triazine-2,4-diamine                                        sethoxydim   2- 1-(ethoxyimino)butyl!-5- 2-(ethyl-                                          thio)propyl!-3-hydroxy-2-cyclohexen-                                           1-one                                                             siduron      N-(2-methylcyclohexyl)-N'-phenylurea                              simazine     6-chloro-N,N'-diethyl-1,3,5-triazine-                                          2,4-diamine                                                       SK-233       1-(a,a-dimethylbenzyl)-3-(4-methyl-                                            phenyl)urea                                                       sulfometuron 2-    (4,6-dimethyl-2-pyrimidinyl)-                               methyl       amino!carbonyl!amino!sulfonyl!-                                                benzoic acid, methyl ester                                        TCA          trichloroacetic acid                                              tebuthiuron  N- 5-(1,1-dimethylethyl)-1,3,4-thiadi-                                         azol-2-yl!-N,N'-dimethylurea                                      terbacil     5-chloro-3-(1,1-dimethylethyl)-6-                                              methyl-2,4(1H,3H)-pyrimidinedione                                 terbuchlor   N-(butoxymethyl)-2-chloro-N- 2-(1,1-                                           dimethylethyl)-6-methylphenyl!-                                                acetamide                                                         terbutyl-    2-(tert-butylamino)-4-chloro-6-(ethyl-                            azine        amino)-s-triazine                                                 terbutol     2,6-di-tert-butyl-p-tolyl methylcar-                                           bamate                                                            terbutryn    N-(1,1-dimethylethyl)-N'-ethyl-6-                                              (methylthio)-1,3,5-triazine-                                                   2,4-diamine                                                       thifensul-   3-    (4-methoxy-6-methyl-1,3,5-triazin-                          furon        2-yl)amino!carbonyl!amino!sulfonyl!-                              methyl       2-thiophenecarboxylic acid, methyl                                             ester                                                             thiobencarb  S- (4-chlorophenyl)methyl! diethylcar-                                         bamothioate                                                       triallate    S-(2,3,3-trichloro-2-propenyl)bis(1-                                           methylethyl)carbamothioate                                        tribenuron   2-    N-(4-methoxy-6-methyl-1,3,5-                                methyl       triazine-2-yl)-N-methylamino!-                                                 carbonyl!amino)sulfonyl!benzoic                                                acid, methyl ester                                                triclopyr     (3,5,6-trichloro-2-pyridinyl)-                                                oxy!acetic acid                                                   tridiphane   2-(3,5-dichlorophenyl)-2-(2,2,2-                                               trichloroethyl)oxirane                                            trifluralin  2,6-dinitro-N,N-dipropyl-4-(tri-                                               fluoromethyl)benzenamine                                          trimeturon   1-(p-chlorophenyl)-2,3,3-trimethylpseu-                                        dourea                                                            2,4-D        (2,4-dichlorophenoxy)acetic acid                                  2,4-DB       4-(2,4-dichlorophenoxy)butanoic acid                              vernolate    S-propyl dipropylcarbamothioate                                   xylachlor    2-chloro-N-(2,3-dimethylphenyl)-N-                                             (1-methylethyl)acetamide                                          ______________________________________                                    

Herbicidal properties of the subject compounds were discovered in a number of greenhouse tests. Test procedures and results follow.

TEST A

Seeds of barley (Hordeum vulgare), barnyardgrass (Echinochloa crus-galli), blackgrass (Alopecurus myosuroides), cheatgrass (Bromus secalinus), chickweed (Stellaria media), cocklebur (Xanthium pensylvanicum), corn (Zea mays), cotton (Gossypium hirsutum), crabgrass (Digitaria spp.), bedstraw (Galium aparine). giant foxtail (Setaria faberii), lambsquarters (Chenopodium album), morningglory (Ipomoea hederacea), rape (Brassica napus), rice (Oryza sativa), sorghum (Sorghum bicolor), soybean (Glycine max), sugar beet (Beta vulgaris), velvetleaf (Abutilon theophrasti), wheat (Triticum aestivum), wild buckwheat (Polygonum convolvulus), and wild oat (Avena fatua) and purple nutsedge (Cyperus rotundus) tubers were planted and treated preemergence with test chemicals dissolved in a non-phytotoxic solvent. At the same time, these crop and weed species were also treated with postemergence applications of test chemicals. Plants ranged in height from two to eighteen cm (one to four leaf stage) for postemergence treatments. Treated plants and controls were maintained in a greenhouse for twelve to sixteen days, after which all species were compared to controls and visually evaluated. Plant response ratings, summarized in Table A, are based on a scale of 0 to 10 where 0 is no effect and 10 is complete control. A dash (-) response means no test result.

    TABLE A                                                                           - TEST A                                                                        COMPOUND                                                                         165 166 167 168 169 170 171 93 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16         17 18 19                                                                         POSTEMERGENCE  Rate (200 g/ha) Rate (100 g/ha) Rate (50 g/ha)                   Barley 9 9 9 7 9 9 9 4 9 8 7 7 8 9 9 9 8 8 9 8 9 9 2 4 0 7 8                    Barnyardgrass 9 9 10 9 9 9 9  9 9 9 9 10 9 9 9 9 9 10 10 10 9 2 3 2 7 9         Bedstraw 8 9 9 9 10 10 8 6 9 9 10 9 10 9 7 9 4 5 8 4 7 5 5 3 0 2 5                   Blackgrass 9 9 9 9 10 10 9 5 8 8 9 8 9 9 9 8 8 9 9 9 9 9 7 4 3 8 9         Cheatgrass 8 10 9 8 9 9 9 4 9 9 9 7 9 9 9 9 8 9 9 9 9 5 6 4 5 7 7                     Chickweed 9 10 10 9 9 9 3 2 9 8 9 8 9 9 6 9 10 10 10 -- -- 10 --         -- -- -- 10                                                                      Cocklebur 9 9 9 -- 10 10 7  9 9 6 5 8 3 0 3 9 9 9 8 9 2 0 8 7 3 5                     Corn 10 10 10 10 9 10 9  9 9 10 9 10 9 9 9 9 9 9 9 10 9 7 7 7 9 9         Cotton 9 10 10 9 9 10 9  9 9 9 9 9 9 10 9 9 9 9 9 9 9 4 5 0 4 9                         Crabgrass 9 10 8 5 10 10 8  9 9 90 6 10 5 6 6 -- -- -- -- -- --        -- -- -- -- --                                                                   Giant foxtail 9 10 9 9 10 10 9  9 9 9 6 9 9 9 7 9 8 10 8 10 10 7 3 2 7         8                                                                                Lambsquarter 10 10 10 10 10 10 9 9 9 9 9 10 9 9 9 9 9 9 10 10 9 4 8 7 6        7                                                                                Morningglory 10 10 10 10 10 10 8  9 9 10 9 10 9 9 9 7 9 10 9 10 9 8 5 7        7 9                                                                              Nutsedge 9 9 9 10 10 9 0  9 9 10 9 10 9 3 7 8 9 5 6 2 5 0 0 0 0 2                     Rape 9 9 10 9 9 9 5 4 6 9 9 8 9 9 0 0 7 9 9 8 9 9 0 8 2 0 9                     Rice 9 9 9 9 9 10 0  9 9 9 9 9 9 9 9 9 9 9 9 10 9 9 6 8 9 9                     Sorghum 9 10 10 10 10 10 9  9 9 9 9 9 9 9 9 9 9 9 10 9 9 7 6 6 9         9                                                                                Soybean 9 9 9 9 9 9 9  9 9 9 7 9 9 8 9 9 9 9 9 9 9 3 3 4 5 6                    Sugar beet 9 9 10 9 9 9 10 8 9 10 9 7 9 9 7 9 8 9 9 8 9 9 2 3 3 3 8                 Velvetleaf 9 9 9 9 9 9 7  9 9 9 9 10 7 6 9 4 8 9 7 9 9 2 0 0 6 9               Wheat 10 8 9 8 9 9 9 5 9 8 6 7 7 9 8 8 9 9 9 8 9 9 2 1 0 8 9                         Wild buckwheat 10 10 10 9 9 10 8 9 9 9 9 9 9 9 6 9 7 7 9 8 7 8         0 0 0 3 3                                                                        Wild oat 9 9 10 8 9 10 10 5 9 9 9 7 8 9 9 8 9 10 9 9 10 9 4 1 0 7              7                                                                                COMPOUND                                                                         20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42          43 44 45 46 47                                                                   POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 4 5 3 9 8 9 9 9 9 9 9 9 8 8 9 8 9 6 6 3 0 8 5 3 0 0 0 4                  Barnyardgrass 7 2 7 9 8 9 9 9 9 10 9 9 9 8 9 9 9 2 8 3 3 9 6 1 3 1 3 1           Bedstraw 6 6 6 7 9 8 9 8 8 10 8 7 6 6 5 8 9 4 7 9 5 9 7 0 5 0 0 3                   Blackgrass 3 8 5 10 8 10 10 9 9 8 7 8 7 6 9 10 9 0 3 2 0 4 3 4 2 2        0 3                                                                              Cheatgrass 4 8 3 9 6 9 10 9 9 9 9 8 7 8 9 8 8 4 5 3 0 6 5 2 3 0 3 5                 Chickweed 8 9 7 10 10 10 10 10 7 10 9 6 6 9 10 8 10 6 9 -- 3 10 10         -- 10 0 2 9                                                                      Cocklebur 3 3 0 8 0 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- --                                                                Corn 9 6 7 10 9 9 9 10 9 10 10 9 9 9 9 9 9 8 9 9 4 9 9 3 7 1 6 9                       Cotton 5 3 1 9 9 9 9 10 9 9 10 9 9 8 8 9 9 0 7 9 5 9 9 0 3 0 0 2         Crabgrass 5 3 0 7 9 8 9 9 7 9 9 7 1 2 7 8 9 3 0 0 0 3 1 0 0 3 0 0                     Giant foxtail 6 8 8 9 9 9 9 9 9 10 10 9 7 7 9 9 9 2 4 2 0 8 4 1 0        0 0 3                                                                            Lambsquarter 9 9 8 9 7 10 10 10 10 10 10 8 10 9 9 9 10 9 9 9 9 -- 8 4 7        9 8 2                                                                            Morningglory 8 2 3 9 9 10 9 9 9 10 9 9 9 9 9 9 9 8 9 8 4 10 9 5 8 6 6 5         Nutsedge 4 7 0 3 5 -- 9 9 9 -- -- 2 0 0 0 0 8 -- 6 8 0 5 0 0 0 0 -- 0             Rape 7 9 7 9 10 9 9 9 9 9 10 7 3 8 8 1 9 7 8 8 8 10 10 2 2 0 4 6                   Rice 9 9 9 9 9 9 9 9 9 9 9 9 9 9 10 9 9 8 8 7 2 9 9 4 3 1 3 9                   Sorghum 9 9 6 9 9 9 9 10 9 10 10 9 9 9 9 9 9 4 8 2 0 9 4 1 1 0 0 3         Soybean 8 7 0 9 9 9 9 9 9 9 9 9 9 5 8 8 9 4 8 7 2 9 9 2 3 0 2 3                         Sugar beet 9 9 4 9 10 10 10 10 9 10 10 9 8 9 9 9 9 9 10 8 9 10         9 3 9 8 8 9                                                                      Velvetleaf 6 8 2 9 9 9 9 10 9 9 9 7 8 7 6 8 9 9 9 9 2 9 8 1 7 2 0 1                 Wheat 4 5 3 9 9 8 9 9 8 9 9 8 7 8 9 8 9 2 3 2 0 8 6 1 1 1 2 3                     Wild buckwheat 8 8 3 8 8 9 9 9 9 10 10 3 0 6 3 6 8 8 7 9 9 9 9 0         3 2 0 5                                                                          Wild oat 6 7 2 9 9 9 10 10 9 10 10 9 9 9 9 9 3 6 4 0 9 6 1 0 0 0               5                                                                                COMPOUND                                                                         48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70          71 72 73 74 75                                                                   POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 2 4 7 8 9 9 6 3 7 8 7 8 7 2 8 9 8 8 6 3 9 0 5 0 0 7 7 4                  Barnyardgrass 1 6 9 9 -- 9 9 9 9 9 9 8 7 5 9 9 9 9 8 9 9 8 9 5 3 9 9 4           Bedstraw 2 6 9 10 2 7 8 7 8 9 9 9 10 8 5 8 8 7 8 8 5 7 9 9 6 7 9 8                 Blackgrass 0 0 9 9 2 9 7 7 8 9 9 8 8 5 9 10 10 9 9 8 7 1 7 5 3 9 9         6                                                                                Cheatgrass 0 2 9 9 3 9 7 6 7 8 9 9 8 6 9 10 10 9 7 9 9 8 3 2 3 9 9 2               Chickweed 4 9 9 10 4 10 10 8 3 10 9 10 10 8 5 10 9 9 0 9 -- 9 9 9 --        9 9 10                                                                           Cocklebur -- -- 10 10 -- 10 10 9 9 10 9 10 10 9 9 10 10 9 9 10 9 9 -- 9        8 9 9 9                                                                          Corn 7 9 9 9 -- 9 9 5 9 9 9 9 9 3 0 9 9 9 9 3 9 5 9 9 2 7 9 9                   Cotton 0 9 9 9 -- 9 9 9 9 9 9 9 9 9 9 9 10 9 9 9 9 9 9 9 8 9 9 10                     Crabgrass 2 1 3 9 -- 9 4 0 0 4 1 6 0 0 5 5 9 10 4 2 6 2 6 3 0 4 5        2                                                                                Giant foxtail 0 2 9 9 -- 9 7 1 3 9 9 8 5 0 7 9 9 9 5 5 8 5 8 2 1 9 10 8         Lambsquarters 5 9 10 10 7 10 8 7 -- 10 9 9 7 9 10 10 9 9 10 9 -- 9 9 8         9 9 9                                                                            Morningglory 7 9 10 10 -- 9 10 9 0 9 9 9 9 9 9 10 10 9 9 9 9 9 9 10 7 9        10 7                                                                             Nutsedge 0 0 9 10 -- 9 9 -- 9 9 10 10 10 9 9 9 10 6 7 9 -- 9 9 -- 5 8          10 5                                                                             Rape 0 9 9 10 8 9 9 9 9 9 10 9 9 10 9 10 9 9 8 10 9 9 10 9 7 9 9 9                   Rice 4 8 9 10 -- 9 9 8 9 9 9 9 9 8 9 9 9 9 9 8 9 7 9 8 4 9 9 9                 Sorghum 1 3 8 9 -- 9 9 3 9 9 9 9 9 3 10 9 10 9 8 9 9 3 4 1 2 9 9 3           Soybean 2 9 9 9 -- 9 9 6 8 9 9 9 9 7 9 9 9 9 1 9 9 8                           Sugar beet 8 9 10 9 7 9 9 8 7 9 9 9 9 10 9 9 9 9 9 9 10 10 10 10 10 9 9        10                                                                               Velvetleaf 4 5 9 10 -- 9 8 9 9 10 10 9 9 9 9 9 10 9 9 9 9 9 9 9 8 9 9 9         Wheat 0 3 7 9 8 9 2 2 3 7 7 7 3 1 9 9 9 9 9 2 6 0 0 0 0 7 7 3                   Wild buckwheat 2 6 7 10 2 8 8 7 -- 8 7 9 9 9 10 9 9 9 8 10 7 7 10 4 0 8        9 7                                                                              Wild oat 0 3 8 9 8 8 7 0 8 8 7 8 7 0 9 9 9 10 9 3 8 0 2 0 0 9 9                8                                                                                COMPOUND                                                                         76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98          99 100 101 102 103                                                               POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 2 8 6 5 2 9 9 9 8 8 8 -- 4 7 8 8 3 3 8 8 9 8 8 8 6 4 7 9                         Barnyardgrass 1 9 9 7 0 9 9 9 9 4 9 4 9 9 7 0 5 9 9 9 9 8 8 7 7        6 9 9                                                                            Bedstraw 8 6 8 4 2 6 8 9 8 8 -- 3 8 -- 8 8 7 8 9 9 8 7 9 7 7 5 9 9                   Blackgrass 2 9 9 8 3 9 9 10 9 9 -- 8 8 9 9 9 9 9 9 9 9 9 9 9 9 8 9        9                                                                                Cheatgrass 3 9 9 4 2 9 9 10 9 8 -- 8 8 9 8 7 9 9 9 9 6 8 9 4 3 6 9 9               Chickweed 9 10 9 4 0 9 10 10 9 7 -- 2 10 9 9 10 3 9 9 9 10 9 9 9 9 3        9 10                                                                             Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --          -- -- -- -- -- -- -- --                                                          Corn 7 5 9 6 2 0 7 9 9 9 1 0 5 9 9 9 0 9 9 9 9 9 9 9 7 0 0 0                    Cotton 9 9 9 6 2 9 9 9 9 9 9 9 9 10 9 9 9 9 9 9 10 9 9 9 9 2 8 9                       Crabgrass 0 6 7 0 0 5 7 -- 6 3 3 2 5 6 6 2 0 8 7 8 5 3 5 2 1 2 3        1                                                                                Giant foxtail 6 9 9 7 0 8 9 9 9 3 6 2 5 8 8 3 0 9 9 9 9 8 9 5 4 3 7 7             Lambsquarters 8 9 9 8 3 10 10 10 10 9 -- 7 8 9 9 -- 5 9 9 10 9 9 -- 8        7 8 9 10                                                                         Morningglory 8 9 9 7 5 10 10 10 9 9 10 9 10 9 9 9 9 9 10 9 9 9 10 9 9 8        9 9                                                                              Nutsedge 0 10 10 0 0 3 9 10 7 0 8 0 9 9 -- 0 -- -- -- -- -- -- -- -- --        -- 10 8                                                                          Rape 9 9 9 9 7 9 9 9 9 9 -- 8 9 9 9 9 6 9 9 9 9 9 9 9 9 9 9 9                   Rice 7 9 9 9 8 9 9 9 10 9 9 8 9 8 9 9 9 9 9 9 9 9 9 9 9 9 10 9                  Sorghum 2 9 9 3 0 9 9 9 9 9 9 8 9 9 9 9 9 9 9 9 9 9 9 9 9 5 9 9                         Soybean 8 9 9 6 3 9 9 9 9 9 9 6 9 8 9 9 3 9 9 9 9 8 9 9 9 0 3 9         Sugar beet 9 10 9 9 7 9 9 9 9 9 -- 7 9 10 9 10 5 10 9 9 9 9 9 9 9 9 9 9         Velvetleaf 8 9 9 5 0 9 10 10 9 9 9 9 10 10 8 9 6 9 9 9 9 8 9 10 9 7 7 9         Wheat 0 8 9 8 2 8 9 9 9 8 -- 4 4 4 4 4 1 9 9 9 9 9 9 3 3 6 9 9                  Wild buckwheat 1 8 9 5 0 9 9 9 9 9 -- 7 7 9 9 9 5 -- -- -- -- 9 -- 9 9         6 9 --                                                                           Wild oat 2 9 9 9 2 9 8 4 9 9 -- 3 4 2 7 7 0 9 9 9 9 9 9 9 8 6 9                9                                                                                COMPOUND                                                                         104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120           121 122 123 124 125 126 127 128 129 130 131                                      POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 9 9 3 9 9 9 9 9 8 7 8 7 6 3 0 9 8 9 9 7 8 4 3 0 2 0 1 1                  Barnyardgrass 9 8 4 9 9 9 9 9 9 9 9 9 9 7 5 9 9 9 9 5 9 3 9 0 2 0 5 0             Bedstraw 7 8 7 9 9 9 9 8 9 8 9 10 8 9 8 8 7 8 9 3 2 3 7 9 2 3 6 7                 Blackgrass 9 9 5 9 9 9 10 9 9 9 9 9 10 8 9 9 9 9 9 4 7 4 6 4 4 2 6         6                                                                                Cheatgrass 9 9 5 9 9 9 9 9 9 9 8 9 8 8 5 9 9 9 9 7 8 7 5 2 2 0 6 6                   Chickweed 3 7 2 10 9 10 9 10 -- 2 7 9 9 9 4 10 9 10 9 4 9 8 9 5 2         4 10 9                                                                           Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 6 9         10 10 6 10 4 9 10                                                                Corn 0 9 0 9 9 9 9 9 6 9 9 9 9 4 0 9 9 9 9 0 5 2 9 7 0 0 6 5                    Cotton 5 8 4 10 9 10 10 10 10 9 9 10 10 10 9 9 10 10 9 9 9 10 10 9 9 9         9 9                                                                              Crabgrass 5 7 0 9 9 9 9 8 -- 5 8 4 6 0 3 9 8 9 9 2 4 2 2 2 0 0 0 0                   Giant foxtail 7 8 0 9 7 9 10 9 6 7 9 7 8 2 2 9 9 9 9 2 3 1 3 1 0 0        2 2                                                                              Lambsquarters 3 8 -- 10 10 10 10 10 9 -- -- 9 9 9 7 -- -- 10 -- 9 10 --        10 9 9 7 9 10                                                                    Morningglory 9 9 8 9 9 8 10 10 9 8 9 10 10 10 9 10 10 10 10 5 9 10 9 10        9 1 6 9                                                                          Nutsedge 0 0 0 10 9 9 9 10 9 -- 9 9 10 7 9 9 9 9 9 -- 8 9 9 7 8 -- 8 10         Rape 9 5 7 9 9 9 10 9 8 9 9 9 9 9 9 9 9 10 9 8 9 9 9 9 9 8 8 9                  Rice 10 9 7 9 10 9 10 9 9 9 9 8 9 9 7 9 9 9 9 8 8 7 9 9 4 0 8 2                         Sorghum 9 9 8 9 9 9 9 9 9 9 9 9 9 9 7 9 9 9 9 1 5 3 8 8 9 0 6 7         Soybean 0 2 1 9 9 9 9 9 9 2 9 9 9 9 1 9 9 9 9 7 9 8 8 8 3 6 9 9                         Sugar beet 8 9 9 9 9 9 9 9 8 5 9 8 10 9 7 9 9 9 9 8 10 10 10 10        9 8 9 9                                                                          Velvetleaf 5 5 2 10 9 10 10 10 10 9 10 10 10 10 9 10 10 10 9 10 9 9 10         2 9 9 9 10                                                                       Wheat 9 9 4 9 9 9 9 9 8 3 5 7 3 0 0 9 9 9 9 2 2 0 0 0 2 0 0 0                   Wild buckwheat -- -- -- 10 10 10 -- -- 9 5 8 9 9 9 7 9 9 9 9 7 8 9 9 9         9 6 7 9                                                                          Wild oat 9 9 0 9 9 9 9 7 6 9 9 9 8 5 2 9 7 9 9 7 6 2 3 2 2 1 0 3                COMPOUND                                                                         132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148           149 150 151 152 165 166 167 168 169 170 171                                      POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 3 1 2 9 7 8 9 7 9 8 9 8 9 5 7 9 9 9 9 7 5 8 8 9 3 7 4 9                  Barnyardgrass 0 0 0 9 7 9 9 7 9 9 9 9 9 0 9 9 9 9 8 5 8 9 9 9 9 9 10 9           Bedstraw 8 8 7 9 9 9 9 8 7 8 9 9 9 7 8 9 9 9 9 9 9 7 9 9 9 8 10 6                   Blackgrass 7 6 3 9 4 8 9 7 9 9 9 9 9 8 9 9 9 9 9 9 9 8 9 8 7 9 10         9                                                                                Cheatgrass 3 2 0 9 8 9 9 8 9 8 9 9 9 3 9 9 9 9 9 8 9 8 9 9 7 8 8 8                   Chickweed 10 2 0 8 0 8 8 4 7 4 9 10 8 4 7 9 10 10 9 8 7 9 10 9 8 9        9 2                                                                              Cocklebur 10 9 9 9 9 8 9 9 9 9 10 10 9 8 10 10 10 10 10 9 10 9 9 9 8 9         9 7                                                                              Corn 9 7 2 8 8 9 9 5 9 2 9 9 9 8 8 0 6 9 9 9 3 9 10 10 9 10 10 9                       Cotton 9 9 2 9 9 9 9 9 9 9 9 10 9 9 9 10 10 9 9 9 9 9 10 10 9 9         9 8                                                                              Crabgrass 0 0 0 2 2 3 6 0 2 1 6 9 3 0 2 3 2 6 2 2 2 9 8 4 3 9 9 8                     Giant foxtail 0 0 0 7 4 7 9 6 9 3 8 9 9 2 5 7 6 9 9 6 3 9 9 9 9 9        10 9                                                                             Lambsquarters 10 10 -- 8 9 9 9 -- 9 9 9 10 9 9 10 10 10 10 10 9 9 10 9         10 9 10 9 9                                                                      Morningglory 10 10 9 9 9 10 9 10 10 2 9 9 9 9 9 10 9 10 10 10 10 5 10          10 10 10 10 9                                                                    Nutsedge 9 7 3 6 8 9 -- 6 8 9 9 10 9 0 9 9 9 9 9 7 8 8 9 9 9 7 3 0                   Rape 9 9 9 2 9 7 2 2 3 9 9 9 9 9 9 9 10 9 9 9 9 9 9 9 9 9 9 2                   Rice 8 9 0 9 9 9 9 9 9 9 9 10 10 9 9 9 9 10 9 10 9 9 9 9 9 9 10 9           Sorghum 8 9 0 9 9 9 9 7 9 9 9 10 10 9 9 9 9 9 9 9 9 9 9 10 9 10 10 9             Soybean 9 9 1 9 9 8 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9                     Sugar beet 9 9 6 9 8 9 9 8 9 9 8 10 9 9 9 8 9 9 9 9 9 9 10 10 9 9        9 9                                                                              Velvetleaf 10 6 9 9 9 7 9 9 9 9 10 10 8 4 10 10 10 10 9 9 9 9 9 9 8 9 9        6                                                                                Wheat 2 1 0 8 8 9 9 8 9 9 9 9 9 9 8 9 9 9 9 8 4 7 8 8 6 9 9 9                   Wild buckwheat 9 8 9 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- 9 7 9 8 9 10 6                                                                Wild oat 4 3 2 9 8 9 9 5 9 9 9 9 9 9 8 9 8 9 9 9 3 8 9 9 4 9 9 8                COMPOUND                                                                         172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188           189 190 191 192 203 204 205 206 207 208 209                                      POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 9 9 8 9 8 9 9 7 8 8 9 9 9 9 9 9 8 9 9 9 9 9 10 9 9 9 9 9                         Barnyardgrass 7 9 9 9 4 6 9 9 9 9 10 10 10 10 10 9 9 9 9 8 6 9         10 9 9 10 9 1                                                                    Bedstraw 8 9 8 7 2 3 5 7 7 7 8 9 9 9 9 9 8 8 8 7 7 9 9 9 9 9 9 5                       Blackgrass 9 9 9 9 9 8 9 9 9 9 9 9 9 9 9 10 9 -- 9 8 9 9 9 9 9 9        9 9                                                                              Cheatgrass 9 9 8 8 7 7 8 8 7 7 9 9 9 9 9 9 7 9 8 7 8 9 9 9 9 9 9 9                   Chickweed 8 8 5 9 3 3 9 7 8 8 4 8 9 9 8 9 4 4 9 3 9 10 10 10 10 9         9 0                                                                              Cocklebur 9 9 9 7 2 6 2 6 1 9 10 10 10 10 10 9 3 9 9 9 9 -- 9 10 9 7 9         1                                                                                Corn 9 10 10 9 9 9 9 8 10 10 10 10 10 9 10 10 9 9 9 9 9 10 10 10 10 10         9 7                                                                              Cotton 9 9 8 9 0 2 9 2 8 9 9 10 9 9 9 9 8 9 9 9 9 9 9 10 9 9 9 5                       Crabgrass 8 9 7 9 6 7 9 6 9 9 9 10 10 9 10 9 8 9 8 2 9 9 10 10 9        10 9 3                                                                           Giant foxtail 9 9 9 9 8 9 9 6 9 9 9 10 10 9 10 9 9 9 9 8 9 9 10 10 10          10 10 7                                                                          Lambsquarters 10 10 10 10 5 7 7 7 6 7 10 10 10 10 9 10 7 8 9 9 -- 10 10        10 10 10 10 5                                                                    Morningglory 9 9 9 9 2 6 8 5 9 9 9 10 10 10 10 9 9 9 9 9 9 9 9 10 9 10         9 7                                                                              Nutsedge 9 8 9 3 0 0 9 -- 2 -- 8 9 9 9 9 -- 2 9 5 6 5 9 9 -- 8 10 10 --         Rape 7 9 8 8 0 0 2 7 2 7 9 9 9 9 10 9 0 3 0 7 7 10 9 9 9 9 9 0                  Rice 9 9 10 10 7 9 9 8 9 9 10 10 10 10 10 10 9 9 9 9 10 9 10 10 10 9 9         9                                                                                Sorghum 9 9 9 9 6 8 9 6 9 9 9 9 10 9 10 9 9 9 9 9 9 10 10 10 10 10 10 9         Soybean 9 9 9 9 1 8 9 7 9 9 9 9 9 9 9 9 6 8 9 9 9 9 9 9 9 8 9 1                         Sugar beet 9 9 8 8 0 7 8 7 8 9 9 10 9 8 9 9 9 8 9 7 9 10 9 10          10 10 10 0                                                                       Velvetleaf 9 9 9 9 0 2 6 3 9 9 9 10 10 9 9 9 6 6 7 6 7 9 10 9 9 9 9 5             Wheat 9 9 4 9 8 8 9 8 8 9 9 9 9 7 9 9 7 8 8 8 9 10 10 9 10 9 9 8                   Wild buckwheat 9 9 9 -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- 9 10 10 10 9 9 0                                                        Wild oat 9 9 3 9 9 7 9 8 8 8 9 9 9 9 9 9 9 9 9 8 9 9 9 9 10 9 9                9                                                                                COMPOUND                                                                         210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226           227 228 229 230 231 232 233 234 235 236 237                                      POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 9 9 9 9 9 7 9 9 9 6 8 5 0 9 9 9 9 8 8 8 7 9 9 8 0 5 8 0                  Barnyardgrass 9 9 9 9 9 7 9 9 9 6 8 5 0 9 9 9 9 9 9 9 7 9 6 7 2 7 9 0             Bedstraw 8 10 10 10 10 9 6 7 8 8 8 6 7 8 8 8 7 7 7 9 9 9 8 8 0 6 7 0           Blackgrass 9 9 9 9 9 7 9 9 8 8 9 9 0 7 8 9 9 3 9 9 9 9 9 9 2 8 9 0                 Cheatgrass 9 10 9 9 9 8 9 9 9 9 9 2 3 8 8 9 7 5 8 9 9 9 9 8 0 8 8 0         Chickweed 7 9 9 10 10 3 3 7 9 10 9 2 4 9 7 10 9 1 2 9 7 9 9 3 0 5 6 0             Cocklebur 9 -- 9 9 8 -- -- 7 2 9 5 0 4 9 10 9 9 -- -- -- -- -- -- --         -- -- -- --                                                                      Corn 9 9 10 10 9 9 9 9 9 8 10 9 8 9 9 10 10 9 9 9 9 9 9 6 0 5 9 0                     Cotton 9 10 10 10 10 10 9 10 10 9 9 8 9 9 10 10 8 9 9 9 9 9 9 8 0        3 5 0                                                                            Crabgrass 8 6 7 6 3 2 2 8 5 2 6 6 0 2 8 2 5 2 6 2 6 7 7 0 2 2 7 0                     Giant foxtail 9 9 10 9 8 7 9 9 8 7 9 6 4 8 6 9 8 5 9 9 9 9 8 8 0         8 8 0                                                                            Lambsquarters 9 10 10 10 10 9 9 10 10 9 9 5 10 9 9 10 9 9 9 9 9 9 9 9 0        4 7 0                                                                            Morningglory 9 9 10 9 10 9 9 10 10 10 9 7 10 10 9 10 9 9 9 9 10 9 9 9 0        7 9 0                                                                            Nutsedge 9 10 -- 9 -- 9 0 9 10 10 4 -- -- 9 9 5 0 -- 5 5 7 3 0 5 0 3 0          Rape 8 9 9 9 10 9 2 9 9 9 9 9 9 8 9 10 10 9 5 8 9 9 9 9 0 7 8 0                         Rice 9 10 10 10 9 9 9 9 9 9 9 9 9 9 9 9 9 9 10 9 9 9 10 9 9 9 9         Sorghum 9 9 10 10 9 9 9 9 9 5 9 9 6 9 8 10 9 8 9 9 9 9 9 9 3 3 9 0                   Soybean 9 9 9 9 9 9 7 9 9 9 9 9 8 9 8 9 9 8 9 9 8 9 9 8 0 1 4 0               Sugar beet 9 9 9 10 10 9 9 10 10 10 9 9 9 9 9 10 9 7 3 5 5 9 9 4 0 3        7 3                                                                              Velvetleaf 9 10 10 9 7 9 6 9 10 10 9 4 7 9 9 9 9 8 9 9 10 9 8 8 0 6 8 0         Wheat 9 9 9 9 9 8 8 9 9 6 9 9 2 9 8 9 9 7 9 8 7 9 10 5 0 5 7 0                  Wild buckwheat 9 9 9 10 10 9 6 9 8 9 8 7 8 6 8 9 8 7 -- -- 9 10 9 9 2 7        -- --                                                                            Wild oat 9 10 10 9 9 9 9 10 9 9 9 9 3 9 9 9 9 9 9 9 9 9 9 9 0 3 9               COMPOUND                                                                         238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254           255 256 257 258 259 260 261 262 263 264 265                                      POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 0 0 10 9 9 9 9 9 9 9 9 9 7 7 8 8 8 4 9 9 9 9 9 9 7 9 9 9                         Barnyardgrass 0 3 9 9 10 9 10 9 9 9 9 9 8 9 9 9 7 8 9 9 10 9 9         9 9 9 8 9                                                                        Bedstraw 0 3 9 9 9 9 9 10 8 9 8 7 7 9 8 8 8 8 9 9 9 8 8 9 7 10 8 8                   Blackgrass 2 2 9 9 9 10 10 9 9 10 9 9 9 9 9 9 9 9 9 10 9 9 9 9 8 5        9 9                                                                              Cheatgrass 0 0 9 9 10 9 9 9 8 9 8 5 5 8 9 8 8 7 10 10 9 9 9 10 8 8 8 9           Chickweed 0 0 9 9 10 10 10 9 8 9 10 9 0 8 5 9 10 3 10 10 10 8 8 10 9 9        5 5                                                                              Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- 2 3 9 9 9 2 5 8 10 5 0 10        4 8 7 9                                                                          Corn 0 1 9 9 9 10 9 9 9 9 9 9 9 9 10 9 9 8 10 10 10 10 10 10 9 10 9 9             Cotton 0 -- 9 9 -- 10 10 10 10 10 9 10 8 9 9 10 10 8 9 8 9 9 8 8 4 10        8 7                                                                              Crabgrass 0 2 9 10 10 10 10 -- 9 9 -- 8 2 6 7 7 2 0 9 8 9 7 9 8 0 3 2 2         Giant foxtail 0 5 9 9 10 10 10 10 9 10 9 9 6 9 9 9 7 4 9 9 9 9 9 9 9 8         7 9                                                                              Lambsquarters 2 0 9 10 10 10 10 10 10 10 10 9 5 8 8 10 10 -- -- 10 --          10 10 10 -- -- -- --                                                             Morningglory 0 3 10 10 9 10 10 10 9 9 9 10 8 10 10 10 10 10 10 10 10 9         9 9 10 10 9 9                                                                    Nutsedge -- 0 10 8 10 9 9 10 8 10 7 8 0 -- -- 9 9 8 9 -- -- 0 0 -- -- 0        5 --                                                                             Rape 0 5 9 9 9 9 9 9 6 8 9 8 5 9 9 9 10 7 9 9 9 9 9 9 10 9 7 7                  Rice 0 8 10 9 10 10 10 10 10 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9                   Sorghum 0 3 9 9 10 10 10 10 8 9 9 9 9 9 10 9 9 9 9 9 10 9 9 9 10 9        9 9                                                                              Soybean 0 0 9 9 9 9 9  5 8 9 9 7 9 9 9 9 7 9 9 9 9 9 9 9 9 9 9                  Sugar beet 0 0 9 9 9 9 10 9 8 9 8 7 1 8 3 9 9 3 9 9 9 9 8 9 9 9 3 5                 Velvetleaf 0 0 10 10 10 9 10 10 6 9 10 10 8 9 9 9 7 8 9 9 9 9 8 9 9        9 9 9                                                                            Wheat 0 0 9 8 9 9 9 9 8 8 9 9 7 8 8 6 5 3 9 9 9 9 9 9 5 9 9 8                   Wild buckwheat -- -- -- 10 -- 10 -- -- -- -- -- -- 5 -- 9 9 9 8 9 9 9 8        8 9 8 8 8 8                                                                      Wild oat 0 2 9 9 9 9 9 9 9 9 8 9 7 8 9 9 8 3 10 9 9 10 9 9 8 9 9               9                                                                                COMPOUND                                                                         266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282           283 284 285 286 287 288 289 290 291 292                                          POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 9 9 9 8 9 9 9 9 9 9 8 7 5 3 9 0 6 9 9 9 9 9 9 9 9 9 8                    Barnyardgrass 9 9 4 8 9 9 9 9 9 9 6 8 5 7 9 3 8 10 9 9 10 10 10 9 9 9 9         Bedstraw 8 9 9 8 9 10 9 7 6 9 5 7 4 7 6 8 8 9 9 9 9 9 9 8 7 8 7                         Blackgrass 10 9 9 9 9 9 9 9 9 9 9 8 7 7 9 7 9 9 9 9 9 9 9 9 9 9        9                                                                                Cheatgrass 9 9 9 9 9 9 9 9 9 9 8 7 7 4 8 5 8 9 9 9 10 9 9 9 8 9 8                     Chickweed 7 9 9 2 7 9 9 7 5 9 0 3 0 1 2 0 0 9 9 10 9 10 9 9 9 8 9         Cocklebur 7 9 10 0 5 7 8 0 1 10 2 3 0 4 6 0 7 -- -- -- -- -- -- -- --          -- --                                                                            Corn 9 9 9 9 10 10 10 9 9 9 9 7 0 0 8 2 6 9 9 9 9 9 9 9 9 9 7                   Cotton 9 9 9 6 9 9 9 7 7 10 4 5 0 1 6 3 7 10 10 9 10 9 10 9 9 9 9                     Crabgrass 2 4 4 0 9 9 9 8 3 9 3 3 0 0 3 0 0 9 9 9 9 9 10 8 6 8 8           Giant foxtail 9 9 8 5 9 9 9 8 9 9 5 3 0 0 9 2 4 10 9 10 10 10 10 9 9 9        8                                                                                Lambsquarters 9 10 10 8 10 10 10 8 7 10 9 8 5 7 -- 7 10 10 10 10 10 10         10 10 9 10 9                                                                     Morningglory 9 9 10 9 9 10 9 8 7 9 8 8 3 7 6 5 7 9 10 10 9 9 9 9 9 10 8         Nutsedge -- -- -- 3 9 9 -- -- -- 9 0 0 0 3 9 0 4 -- 9 6 9 9 9 7 3 8 3             Rape 7 9 9 9 9 9 9 9 8 9 0 0 3 3 0 4 7 9 9 9 9 9 9 2 9 9 10                   Rice 9 9 9 9 9 9 9 9 9 10 9 9 9 9 9 9 8 10 9 10 10 10 9 9 9 9 8                         Sorghum 9 9 9 9 9 9 9 9 9 9 9 9 8 6 8 8 8 9 9 10 10 10 10 9 9 9        9                                                                                Soybean 9 9 9 8 9 9 9 8 7 9 2 3 5 8 7 6 9 9 9 9 9 9 9 9 8 9 1                   Sugar beet 6 9 9 1 9 9 9 7 7 9 8 9 8 3 7 7 8 9 9 9 9 9 9 9 9 9 9                       Velvetleaf 9 9 9 8 9 9 9 3 3 8 3 5 2 2 4 0 7 10 9 10 10 9 10 8 9        9 9                                                                              Wheat 8 9 9 4 9 9 9 9 9 9 8 6 2 0 7 0 6 9 9 9 9 9 9 9 8 9 8                     Wild buckwheat 9 9 9 9 9 10 9 8 7 9 2 -- 0 0 0 2 0 -- 9 9 9 9 9 9 8 9 9         Wild oat 9 9 9 6 9 9 9 9 9 9 9 8 5 0 8 0 7 9 9 9 9 9 9 9 9 9 8                  COMPOUND                                                                         293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309           310 311 312 313 314 315 316 317 318 319                                          POSTEMERGENCE  Rate (50 g/ha)                                                   Barley 9 7 5 8 5 4 6 9 9 9 9 9 9 8 9 8 8 8 9 8 8 5 0 0 0 1 0                    Barnyardgrass 9 6 6 8 9 7 0 9 9 9 9 9 9 9 9 8 9 9 9 9 6 6 0 0 0 0 0                 Bedstraw 7 6 7 7 7 5 3 7 8 8 6 6 7 7 7 8 6 9 9 8 7 6 0 6 7 6 5                   Blackgrass 9 8 8 8 8 6 4 9 9 9 9 9 9 8 9 9 9 9 9 9 9 6 0 3 2 3 0             Cheatgrass 8 6 6 8 7 4 3 9 9 9 9 9 9 8 7 8 -- 7 8 7 7 5 0 0 1 5 2                 Chickweed 6 5 6 5 9 3 5 9 9 10 9 8 9 9 2 0 2 4 2 3 3 5 0 2 0 0 0               Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- 7 8 9 9 9 9 3 --        0 7 8 9 9                                                                        Corn 9 9 8 9 9 7 4 9 9 10 9 3 9 9 8 9 9 9 9 8 4 0 0 0 0 6 6                     Cotton 10 8 8 9 9 9 0 9 9 9 9 9 9 9 9 9 9 9 9 9 1 4 0 7 3 6 2                   Crabgrass 8 3 1 1 1 0 0 9 9 9 8 7 9 6 6 2 6 3 3 3 0 0 0 0 0 0 0                         Giant foxtail 9 5 5 7 8 3 5 9 9 10 9 8 9 9 9 6 9 8 8 9 6 2 0 0         0 3 0                                                                            Lambsquarters 10 7 7 10 10 7 4 -- -- 10 10 10 10 7 10 9 9 10 10 -- 7 6         0 7 8 7 4                                                                        Morningglory 8 8 8 5 9 4 3 9 9 10 10 9 9 7 9 8 10 10 10 9 8 4 0 8 7 7 7         Nutsedge 5 2 0 -- 1 0 0 5 9 9 5 0 -- 5 8 9 9 9 9 9 0 0 0 0 0 0 0                       Rape 9 2 7 8 9 5 0 9 10 9 9 9 9 5 9 7 10 10 10 7 4 4 0 5 7 7 7             Rice 9 5 8 9 9 9 4 10 9 9 9 8 9 9 9 9 10 9 9 9 9 9 0 7 5 9 9                  Sorghum 9 9 9 9 9 6 4 9 9 9 9 9 9 9 9 8 9 10 9 9 8 8 0 0 0 7 2                  Soybean 8 2 7 5 9 3 2 9 9 9 8 6 9 9 9 8 9 9 9 8 8 6 0 0 0 5 2                   Sugar beet 9 7 8 9 9 6 3 9 9 9 9 8 9 7 7 7 9 8 9 8 5 7 0 3 2 6 7                       Velvetleaf 8 6 8 8 9 3 0 9 9 10 9 9 9 9 9 9 8 9 6 9 0 2 0 6 2 3         4                                                                                Wheat 7 5 4 5 8 2 2 9 9 9 8 9 9 8 8 7 8 6 8 5 5 3 0 0 0 3 0                     Wild buckwheat 9 3 7 8 9 7 0 9 9 7 9 9 7 7 8 7 -- 9 9 9 0 -- -- ---- --        -- --                                                                            Wild oat 8 5 8 8 7 2 5 9 9 9 8 9 9 9 9 8 9 9 9 7 7 5 0 0 0 0 0                  COMPOUND                                                                         320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336           337 338 339 340 341 342 1 2 3 4                                                  POSTEMERGENCE  Rate (50 g/ha) Rate (10 g/ha)                                    Barley 0 0 9 9 9 9 9 8 5 8 0 0 0 0 0 0 0 0 9 9 9 9 9 8 7 6 5                    Barnyardgrass 0 0 9 9 9 9 7 9 2 4 0 0 0 0 0 0 0 0 10 10 9 9 10 9 9 8 9           Bedstraw 2 0 8 9 9 8 8 9 7 8 0 0 0 2 0 0 0 2 9 9 8 9 9 8 8 9 8                         Blackgrass 0 0 9 9 9 9 9 9 6 9 0 0 0 0 0 0 0 0 9 9 9 9 10 7 8 9        2                                                                                Cheatgrass 0 0 9 9 9 9 9 9 9 9 0 0 0 0 0 0 0 0 9 9 9 9 9 8 8 9 4                       Chickweed 0 0 9 10 9 9 7 10 1 4 0 0 0 0 3 2 0 2 10 10 7 2 9 8 7         8 7                                                                              Cocklebur 8 0 9 10 10 7 2 10 0 6 0 0 0 0 0 0 0 0 10 10 5 0 10 3 5 5 0             Corn 0 0 9 9 9 9 9 9 9 9 0 0 0 0 0 0 0 0 10 10 9 9 10 9 9 9 9                         Cotton 0 0 9 10 9 9 9 9 8 7 0 0 0 0 0 0 0 0 9 9 5 3 10 9 9 9 9           Crabgrass 0 0 9 9 9 7 4 5 0 7 0 0 0 0 0 0 0 0 9 10 5 3 7 9 7 9 0                     Giant foxtail 0 0 9 9 9 9 4 9 8 9 0 0 0 0 0 0 0 0 9 10 9 8 10 8 9        7 3                                                                              Lambsquarters 0 0 10 10 10 9 7 10 -- 7 -- 0 0 2 0 0 0 2 10 10 7 7 10 9         9 9 8                                                                            Morningglory 2 0 9 10 10 9 6 9 2 7 0 0 0 0 0 0 0 0 10 9 7 6 10 9 9 9 9           Nutsedge 0 0 9 9 9 3 -- 4 0 0 0 0 0 0 0 0 4 0 9 9 3 1 10 8 8 9 7                     Rape 2 2 10 10 9 9 9 9 0 0 0 0 0 2 4 0 0 1 9 9 8 8 9 5 7 8 7                   Rice 4 0 9 10 10 9 9 9 9 9 0 0 0 4 0 0 0 0 9 9 9 9 10 9 9 9 9                   Sorghum 0 0 9 9 9 9 9 9 9 9 0 0 0 0 0 0 0 0 9 9 9 9 10 9 9 9 9                 Soybean 0 0 9 9 9 9 9 9 7 9 0 0 0 0 0 0 0 0 9 9 7 5 9 9 9 8 6                     Sugar beet 0 2 9 9 10 9 9 9 7 9 0 0 0 1 2 0 0 1 10 9 7 5 9 6 8 8         5                                                                                Velvetleaf 0 0 9 9 10 7 2 9 5 6 0 0 0 0 0 0 0 0 10 9 3 0 10 9 9 7 7                 Wheat 0 0 9 9 9 9 9 8 7 9 0 0 0 0 0 0 0 0 9 9 9 9 9 7 7 7 3                         Wild buckwheat -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- 9 8 8 7                                                     Wild oat 2 0 9 9 9 9 9 7 9 9 0 0 0 0 0 0 0 0 9 9 9 9 9 8 9 9 3                  COMPOUND                                                                         5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29         30 31                                                                            POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 7 8 7 8 7 7 8 7 8 4 2 3 3 2 4 0 0 0 0 2 8 8 8 8 9 9 8                    Barnyardgrass 9 7 6 8 4 7 6 6 7 7 1 0 0 2 5 2 0 0 8 6 8 9 9 9 9 9 8                 Bedstraw 9 9 2 8 2 3 3 3 5 3  0 0 0 2 5 3 2 2 5 7 5 8 7 8 9 7                     Blackgrass 9 6 6 3 3 8 9 7 8 5 3 4 2 2 3 0 2 3 2 2 9 9 9 9 7 8 4           Cheatgrass 8 8 8 8 3 7 8 6 7 2 3 4 3 2 3 2 2 0 3 2 9 9 9 8 8 8 8                     Chickweed 8 9 1 9 5 -- -- -- -- 9 4 -- -- 9 -- 3 6 3 7 10 9 7 9 6        -- 9 7                                                                           Cocklebur 2 2 0 3 9 9 6 2 7 0 0 3 4 3 3 2 0 0 7 0 -- -- -- -- -- 9 4               Corn 9 9 9 9 9 9 9 9 10 9 7 4 1 8 9 7 3 1 9 9 9 9 9 9 10 -- --                     Cotton 9 9 9 9 2 6 8 2 7 6 0 0 0 3 0 0 0 0 1 2 8 8 9 9 9 10 9                 Crabgrass 2 2 2 4 -- -- -- -- -- -- -- -- -- -- -- 2 0 0 2 6 5 2 8         4 8 9 2                                                                          Giant foxtail 7 5 7 4 7 7 9 8 6 7 4 0 0 5 7 3 2 2 7 6 9 8 9 8 9 7 2                 Lambsquarters 8 9 8 9 9 8 8 9 8 7 3 7 5 4 4 5 5 3 8 3 10 10 8 8 10         9 8                                                                              Morningglory 9 8 8 9 5 8 9 0 6 8 5 2 1 6 7 2 1 0 1 4 9 9 10 9 10 9 --             Nutsedge 9 5 3 0 5 -- 5 2 2 3 0 0 0 0 0 0 2 0 2 2 9 7 9 7 7 10 8                   Rape 9 9 0 0 4 6 8 6 9 9 0 2 0 0 7 6 7 5 8 9 7 7 8 9 9 5 --                       Rice 9 9 9 9 9 9 9 9 10 9 8 3 2 9 9 7 7 3 9 9 9 9 9 9 9 10 2                 Sorghum 9 9 9 7 9 9 7 9 9 9 5 2 2 7 9 5 4 0 9 8 9 9 9 9 9 9 9                     Soybean 9 9 3 8 6 6 9 5 9 8 1 1 2 3 3 1 1 0 5 4 8 8 9 9 9 10 9               Sugar beet 9 9 2 9 6 7 8 3 7 4 0 2 2 0 0 7 7 3 8 8 9 8 9 9 9 9 4                 Velvetleaf 0 3 2 8 2 2 6 0 7 8 0 0 0 3 2 2 0 0 6 2 8 9 9 8 9 10 7             Wheat 7 7 7 8 6 7 9 6 9 6 1 2 0 3 4 2 2 2 3 3 8 9 8 8 9 9 3                   Wild buckwheat 8 9 1 5 4 2 9 2 5 3 0 0 0 0 0 3 7 2 0 5 9 4 8 8 9 8 7               Wild oat 8 8 8 2 7 8 9 6 6 3 0 0 0 2 1 1 0 0 2 5 9 9 9 8 10 8                COMPOUND                                                                         32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54          55 56 57 58                                                                      POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 7 7 7 7 8 2 5 2 0 4 2 3 0 0 2 3 0 2 4 5 8 8 2 2 6 7 4                    Barnyardgrass 5 3 3 9 9 0 1 1 0 7 2 0 0 0 0 0 0 2 9 9 9 9 7 7 8 8 8                 Bedstraw 6 4 3 6 7 2 3 2 2 3 2 0 2 0 0 3 0 3 7 9 -- 6 7 5 4 7 7                 Blackgrass 4 2 7 8 9 0 0 0 0 2 3 2 3 2 0 0 0 0 9 8 -- 8 2 4 4 8 5             Cheatgrass 7 6 8 5 5 0 0 2 0 2 3 0 3 0 0 2 0 2 9 7 -- 7 3 3 5 7 6                 Chickweed -- 8 7 4 9 0 6 8 0 9 9 3 5 0 0 0 0 9 9 9 4 9 10 7 0 7 5             Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 9 10         9 10 9 1 10 9 9                                                                  Corn 3 2 9 8 9 5 7 3 2 9 2 0 1 0 0 5 0 7 8 9 4 8 8 3 8 9 9                      Cotton 3 0 5 9 9 0 0 0 0 1 5 0 0 0 0 0 0 0 9 9 9 9 9 8 9 9 9                    Crabgrass 0 0 5 4 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 4 6 0 0 0 3 0                         Giant foxtail 6 4 8 7 9 0 1 0 0 1 0 0 0 0 0 0 0 0 8 8 7 9 2 0 3        8 6                                                                              Lambsquarters 7 8 5 9 9 3 3 7 7 9 -- 0 3 7 7 0 3 3 9 10 6 8 9 5 2 8 --           Morningglory 8 8 9 9 9 4 5 1 2 6 2 0 5 0 0 0 7 7 9 10 2 9 10 9 0 3 9             Nutsedge 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 9 9 4 9 8 -- 9 9 9                     Rape 2 5 7 0 9 6 5 7 6 9 8 2 0 0 4 4 0 6 9 9 7 9 9 8 9 8 9                       Rice 9 7 9 9 9 2 2 0 0 9 9 0 0 0 0 2 0 0 9 9 9 9 9 8 8 9 8                     Sorghum 4 3 7 9 9 0 1 0 0 5 1 0 0 0 0 1 0 0 8 9 9 9 7 3 7 9 8                 Soybean 9 2 4 5 9 1 2 0 1 9 4 0 1 0 0 1 3 3 9 9 7 9 9 6 8 9 9                     Sugar beet 5 6 8 7 9 7 8 8 8 9 8 2 7 6 7 0 4 9 8 10 3 8 9 7 7 7 8         Velvetleaf 1 1 2 8 9 3 5 5 0 3 2 0 0 0 0 0 0 2 9 10 9 9 5 8 9 8 9                     Wheat 5 4 7 8 8 0 3 0 0 3 3 0 1 0 0 1 0 1 4 7 8 7 0 0 3 5 2                     Wild buckwheat 0 2 2 2 5 5 4 5 7 8 7 0 0 0 0 3 2 2 5 10 -- 4 8 6         3 -- 4                                                                           Wild oat 7 7 9 9 9 0 2 0 0 4 2 0 1 0 0 1 0 0 5 9 8 7 2 0 6 4 0                  COMPOUND                                                                         59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81          82 83 84 85                                                                      POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 4 2 0 7 7 5 4 3 1 9 0 5 0 0 3 3 0 0 4 3 2 0 7 7 7 6 3                    Barnyardgrass 6 3 1 8 9 9 7 3 8 9 3 9 0 0 5 7 0 0 6 9 0 0 8 9 9 3 0                 Bedstraw 8 8 -- 2 8 7 4 7 5 3 7 7 6 0 5 7 4 5 4 7 0 0 3 6 9 7 7                 Blackgrass 5 5 0 7 9 9 8 4 3 1 0 2 0 0 2 4 5 0 5 8 5 0 9 9 9 9 8               Cheatgrass 7 7 -- 9 10 9 6 3 6 7 7 0 0 0 8 8 0 0 8 9 0 0 9 9 9 6 4             Chickweed 10 9 2 0 6 8 5 0 4 -- -- -- -- -- 5 7 8 3 -- 9 0 0 4 9 10 9        3                                                                                Cocklebur 10 10 9 5 9 9 7 7 9 9 6 9 9 2 -- 9 9 7 9 9 0 -- -- -- -- --          --                                                                               Corn 8 5 0 0 7 9 9 7 0 9 2 9 7 0 3 7 6 2 0 7 1 1 0 1 5 7 7                      Cotton 10 9 9 7 9 9 6 4 7 9 6 9 9 2 6 9 5 5 7 9 2 0 8 9 9 8 7                   Crabgrass 1 0 0 3 8 3 2 0 0 3 0 1 0 0 0 1 0 0 1 3 0 0 1 5 5 4 3                         Giant foxtail 2 0 0 6 9 8 7 0 4 4 3 3 2 0 7 9 5 0 7 9 3 0 6 9 7        4 0                                                                              Lambsquarters 9 9 3 9 10 9 7 5 9 8 9 10 7 7 8 9 9 2 9 9 5 0 9 9 -- 9 9           Morningglory 9 10 8 7 9 10 8 6 9 10 9 9 10 2 9 9 0 1 9 9 2 0 9 9 9 9 8         Nutsedge 9 8 9 6 8 9 0 0 7 -- -- 0 0 5 0 9 -- 0 -- 5 0 0 0 -- -- 0 0               Rape 9 9 9 9 9 9 7 5 6 8 8 9 8 5 9 8 8 8 9 9 7 0 9 9 9 9 5                   Rice 9 9 6 9 8 9 9 9 4 8 4 8 5 0 7 8 1 0 9 9 9 0 9 9 9 9 9                      Sorghum 7 6 2 9 9 9 8 4 9 9 1 3 0 0 5 8 0 0 7 9 0 0 9 9 9 9 9                   Soybean 9 9 3 9 9 9 9 7 7 5 8 9 9 1 8 8 6 3 8 9 1 0 8 8 9 7 8                   Sugar beet 9 9 9 8 9 9 6 4 7 9 9 10 10 9 9 9 8 9 -- 9 5 2 8 9 10 9 9               Velvetleaf 9 9 9 9 9 9 6 4 9 9 9 9 9 5 6 8 7 6 7 9 0 0 9 10 10 8 6             Wheat 2 2 0 8 7 4 8 5 0 2 0 0 0 0 1 0 0 0 5 3 2 0 8 6 5 5 3                   Wild buckwheat 9 8 0 10 7 8 8 5 7 2 7 6 2 0 0 8 2 0 4 9 0 0 7 7 7 8 --           Wild oat 4 2 0 8 7 4 8 5 0 5 0 0 0 0 6 3 7 0 7 6 2 0 8 5 3 7 5                 COMPOUND                                                                         86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106         107 108 109 110 111 112                                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 2 2 3 5 3 3 2 -- 4 5 4 5 5 2 0 3 8 8 6 6 2 8 6 9 9 7 4                   Barnyardgrass 8 2 7 8 2 0 1 7 6 5 2 2 2 1 1 2 8 8 1 2 2 8 6 9 9 9 8                 Bedstraw 7 0 7 8 5 7 7 -- 2 8 6 5 7 5 1 2 8 9 4 4 4 9 9 8 9 8 8                 Blackgrass 9 4 9 -- 5 7 -- -- 7 6 5 8 8 5 6 5 9 9 6 9 -- 9 8 9 9 9         --                                                                               Cheatgrass 8 4 9 9 3 2 3 -- 5 0 0 4 5 2 0 3 9 8 5 7 3 9 8 9 9 9 8                     Chickweed 3 2 4 6 7 8 2 -- 3 9 3 1 2 2 2 2 8 8 0 2 0 9 9 9 9 9 8           Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- --                                                             Corn 0 0 0 5 4 6 0 7 6 9 7 8 7 6 3 0 0 0 0 2 0 9 8 8 9 8 5                      Cotton 8 6 9 9 6 7 8 9 9 9 9 9 9 9 9 0 7 9 0 0 4 10 9 9 9 10 10                         Crabgrass 2 0 2 3 3 -- 0 4 1 1 0 0 0 0 0 0 0 0 3 2 0 3 6 -- 9 7        4                                                                                Giant foxtail 4 0 2 4 3 0 0 7 8 6 4 5 7 2 2 3 3 4 3 4 0 7 5 9 9 8 5                 Lambsquarters 8 1 8 7 8 9 0 -- 7 4 9 9 8 5 -- 7 9 9 -- 1 6 10 -- 9         10 10 9                                                                          Morningglory 9 9 9 10 9 9 8 6 6 5 4 9 8 2 2 7 9 9 7 7 7 9 9 9 10 10 9             Nutsedge -- 0 8 9 0 0 0 -- -- -- -- -- -- -- 0 0 8 8 -- 0 -- 8 8 9 9         7 3                                                                              Rape 8 8 8 7 8 7 7 -- 3 7 8 7 6 8 8 8 9 6 6 0 2 9 9 7 10 9 7                    Rice 9 3 5 9 9 9 7 8 9 9 9 8 8 8 7 7 9 9 9 9 4 9 9 9 9 9 8                      Sorghum 9 5 9 9 8 6 6 8 9 9 7 8 9 9 5 2 9 9 9 8 4 9 9 9 9 9 9                   Soybean 7 0 8 9 7 7 0 6 8 8 7 3 6 5 6 0 1 5 0 1 0 9 9 9 9 9 8                   Sugar beet 9 0 9 8 8 9 3 -- 9 9 9 9 8 9 9 8 9 9 0 5 8 9 9 7 8 9 8                     Velvetleaf 8 5 9 9 6 4 0 6 7 8 7 9 4 9 7 4 5 8 1 2 0 10 8 10 10          10 10                                                                            Wheat 0 0 2 2 2 3 0 -- 4 3 0 2 2 0 0 3 8 7 6 5 2 8 4 9 9 7 6                    Wild buckwheat 7 3 7 6 9 7 3 -- 9 8 -- -- -- -- -- -- -- -- 4 1 -- --          -- 9 9 -- --                                                                     Wild oat 0 0 2 0 7 7 0 -- 2 4 3 7 6 3 2 2 7 3 9 8 0 9 9 9 9 5 4                 COMPOUND                                                                         113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129           130 131 132 133 134 135 136 137 138 139                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 4 7 2 2 0 2 8 5 7 7 3 2 0 2 0 0 0 0 0 0 2 0 8 2 5 8 5                    Barnyardgrass 6 9 7 7 1 1 9 9 9 8 1 8 2 4 0 0 0 0 0 0 0 0 7 4 8 7 3                 Bedstraw 6 7 8 9 7 7 7 7 7 7 0 0 0 2 7 0 3 3 4 7 8 -- 8 9 7 8 7                 Blackgrass 8 8 8 8 6 5 9 9 8 9 3 5 2 2 0 0 0 5 2 4 3 0 7 0 7 9 3               Cheatgrass 8 8 9 5 0 2 9 8 9 8 5 5 3 2 0 0 0 3 0 0 0 0 7 8 8 9 8                 Chickweed 0 5 3 9 9 2 9 8 9 9 0 0 4 9 -- 0 0 2 4 8 0 0 5 0 4 7 0               Cocklebur -- -- -- -- -- -- -- -- -- -- 3 7 9 9 4 5 1 5 9 9 7 2 8 6         6 7 2                                                                            Corn 4 9 7 2 0 0 9 9 9 9 0 0 0 5 3 0 0 0 0 2 1 0 3 3 7 6 3                      Cotton 9 9 9 9 9 7 9 9 9 9 9 9 9 10 8 8 6 6 6 7 4 0 9 6 9 9 7                   Crabgrass 0 7 0 2 0 0 5 6 6 5 6 2 2 1 1 0 0 0 0 0 0 0 0 0 2 3 0                         Giant foxtail 3 7 5 2 0 0 9 8 8 3 1 2 0 1 1 0 0 0 0 0 0 0 3 2 4        7 2                                                                              Lambsquarters 2 -- 5 -- -- 3 -- 10 9 9 8 9 -- -- 9 7 -- 7 -- 9 9 3 4 5         5 8 8                                                                            Morningglory 7 9 10 10 9 6 10 10 10 9 0 8 9 8 9 9 0 1 6 6 9 1 9 7 9 10         9                                                                                Nutsedge 0 7 -- -- 0 2 9 9 -- 5 -- 8 9 9 -- 3 0 7 9 -- -- -- 4 -- 6 9 0         Rape 8 9 8 9 9 8 8 9 9 9 4 8 9 9 7 7 5 8 9 8 6 5 0 3 3 0 0                      Rice 8 9 7 8 8 3 9 9 9 9 8 7 3 9 9 2 0 2 0 0 9 0 9 8 9 9 9                      Sorghum 7 9 9 9 7 3 9 9 9 9 0 0 0 7 8 6 0 2 0 0 2 0 9 8 9 9 4                   Soybean 0 8 9 9 9 0 9 9 9 9 5 6 6 6 7 2 4 7 9 9 9 0 8 9 6 8 9                   Sugar beet 2 6 5 9 9 4 9 9 9 9 5 7 9 9 9 5 5 6 6 9 8 4 9 7 9 9 8                       Velvetleaf -- 9 9 9 9 7 10 10 10 9 9 9 9 9 0 9 8 5 9 9 0 0 6 7 6        8 9                                                                              Wheat 2 5 0 0 0 2 9 4 9 7 0 0 0 0 0 0 0 0 0 1 0 0 8 3 7 8 6                     Wild buckwheat 5 3 5 9 9 6 7 8 -- 9 6 5 8 9 8 8 5 3 7 7 7 6 -- -- -- --        --                                                                               Wild oat 4 7 1 3 2 0 8 3 8 8 4 3 0 1 5 0 0 0 1 1 1 2 9 3 8 9 3                  COMPOUND                                                                         140 141 142 143 144 145 146 147 148 149 150 151 152 165 166 167 168           169 170 171 172 173 174 175 176 177 178                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 6 7 7 8 7 3 5 7 7 8 7 2 2 6 9 9 0 0 0 0 2 0 8 2 5 8 5                    Barnyardgrass 7 6 9 9 2 0 6 9 9 9 3 0 4 8 9 9 9 9 10 7 3 3 8 9 4 0 8               Bedstraw 6 5 7 7 7 8 7 7 8 9 8 9 7 3 7 8 8 8 8 7 5 8 7 5 2 2 0                     Blackgrass 9 8 9 9 9 8 9 9 9 9 9 9 9 8 8 9 0 8 9 8 9 9 7 8 8 7 2           Cheatgrass 9 7 7 9 6 3 8 9 9 9 9 7 7 8 9 10 4 7 8 9 9 9 5 8 7 7 0                   Chickweed 5 5 6 8 6 0 3 7 9 10 9 7 3 5 8 10 3 10 9 2 5 7 2 7 3 3 7         Cocklebur 7 9 9 10 9 7 10 9 10 10 9 9 9 8 9 7 7 7 9 2 5 6 6 2 0 0 0                 Corn 6 0 8 9 8 3 2 0 5 8 6 8 0 9 9 9 9 9 10 9 8 9 9 9 8 3 5                         Cotton 9 8 9 9 8 8 9 9 9 9 9 9 9 7 9 9 9 9 9 6 8 9 5 6 0 0 0               Crabgrass 2 0 3 3 0 0 0 0 0 3 1 0 0 5 4 2 0 6 9 7 7 8 4 8 5 3 2                   Giant foxtail 7 2 5 8 6 0 2 2 3 9 6 2 0 7 7 8 4 8 10 6 8 9 8 9 6 5        9                                                                                Lambsquarters 8 7 10 10 8 8 8 9 10 10 9 10 7 9 9 10 9 10 10 9 10 10 8 8        2 3 2                                                                            Morningglory 9 1 6 9 9 9 9 10 10 10 9 9 9 5 9 9 9 9 10 7 8 8 7 7 0 0 0           Nutsedge 5 8 9 9 9 0 9 9 9 9 9 7 9 6 7 9 7 0 2 0 9 7 5 3 -- -- 6                     Rape 0 8 9 8 9 8 9 9 9 9 9 9 9 7 8 9 8 9 9 5 4 7 7 7 0 0 0                       Rice 8 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 8 9 9 9 5 5 0                     Sorghum 8 9 9 9 9 7 9 9 9 9 9 8 9 8 9 9 7 9 10 9 8 9 9 9 0 3 0               Soybean 8 9 8 9 9 8 8 9 9 9 9 9 9 9 9 9 8 9 9 2 8 9 7 5 0 6 2                       Sugar beet 8 7 9 9 9 9 9 7 9 9 9 9 7 7 10 7 6 9 10 6 9 9 8 8 0 2        7                                                                                Velvetleaf 8 9 9 10 6 3 9 10 10 10 9 8 9 9 9 9 8 9 9 4 8 7 7 8 0 0 0               Wheat 7 6 7 8 9 4 3 7 9 9 8 3 0 8 9 8 0 8 9 7 9 9 2 7 7 5 4                  Wild buckwheat -- -- -- -- -- -- -- -- -- -- -- -- -- 7 7 10 8 10 9 6 9        9 9 -- -- -- --                                                                  Wild oat 7 7 6 8 9 8 5 8 5 7 9 4 2 7 9 9 1 5 8 8 9 9 0 7 7 7 2                  COMPOUND                                                                         179 180 181 182 183 184 185 186 187 188 189 190 191 192 203 204 205           206 207 208 209 210 211 212 213 214 215                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 4 4 3 8 8 9 8 9 9 8 8 8 8 8 9 9 9 9 9 8 8 7 9 9 7 7 2                    Barnyardgrass 3 9 6 9 9 9 9 10 8 6 6 8 6 2 9 9 9 9 9 9 0 9 9 9 9 2 9               Bedstraw 0 3 6 8 9 9 7 8 8 7 7 7 7 7 8 8 9 9 9 8 3 7 9 9 9 9 8                     Blackgrass 3 7 7 9 9 9 8 9 -- 7 8 9 7 9 9 9 9 9 9 9 8 7 9 9 9 8 5         Cheatgrass 2 6 5 9 9 9 7 9 9 7 7 7 5 7 9 9 10 9 7 9 7 9 9 9 9 9 7                     Chickweed 2 6 7 3 5 7 5 7 7 2 3 4 0 6 9 9 9 9 9 9 0 2 4 7 10 10 3         Cocklebur 0 0 0 9 9 10 9 9 8 0 8 8 7 4 8 -- 8 -- -- -- -- 0 -- 8 8 -- 0         Corn 1 9 9 9 9 9 9 9 9 9 9 9 6 9 9 9 10 10 9 9 2 9 9 10 9 9 8                   Cotton 0 0 7 9 9 9 9 9 9 6 7 8 7 8 8 8 9 9 8 9 0 7 9 10 10 10 9                         Crabgrass 2 6 8 9 8 9 7 9 8 5 5 5 0 8 9 9 9 9 7 6 2 3 3 5 2 0 0         Giant foxtail 2 8 9 9 9 9 9 9 9 7 7 8 6 9 6 9 10 10 10 9 2 7 9 9 8 3 2           Lambsquarters 5 4 -- 10 10 10 10 9 7 7 8 8 9 7 9 10 10 10 7 10 3 9 9 9        9 10 7                                                                           Morningglory 0 8 9 9 10 10 10 9 9 7 9 9 8 9 9 10 10 9 9 9 5 9 10 9 10 9        7                                                                                Nutsedge 4 0 3 8 9 8 9 3 2 2 4 5 3 3 -- 9 10 4 2 9 0 -- 2 10 9 -- --               Rape 0 0 6 8 9 9 9 9 7 0 2 0 5 5 9 10 9 9 9 9 0 5 8 9 10 10 9                       Rice 0 9 9 9 9 10 9 10 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9                 Sorghum 0 9 9 9 9 10 9 9 9 9 9 9 6 9 9 9 10 10 9 9 4 9 9 10 9 9 9             Soybean 0 5 8 8 9 9 6 9 9 1 9 7 7 9 9 9 9 8 9 6 0 8 9 9 9 9 3                         Sugar beet 5 7 8 8 7 8 7 8 7 7 7 8 7 8 9 10 9 10 10 10 0 4 7 8         10 9 7                                                                           Velvetleaf 0 2 8 9 9 9 9 8 8 4 3 6 5 2 8 9 9 9 9 9 0 9 9 9 9 6 9                       Wheat 3 7 7 8 8 8 2 9 9 7 8 8 5 8 10 10 9 9 10 9 7 9 8 9 8 6 3             Wild buckwheat -- -- -- -- -- -- -- -- -- -- -- -- -- -- 9 8 9 9 9 9         0 8 6 8 9 9 8                                                                    Wild oat 3 6 4 9 9 9 7 9 9 8 8 8 7 9 9 9 9 10 9 9 7 9 9 10 9 9 3                COMPOUND                                                                         216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232           233 234 235 236 237 238 239 240 241 242                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 8 9 4 3 1 0 2 6 7 9 5 5 5 2 7 8 8 5 0 0 8 0 0 0 9 8 9                    Barnyardgrass 8 9 8 9 8 2 6 6 7 9 3 5 7 7 3 8 1 3 0 0 2 0 0 0 8 9 9                 Bedstraw 5 5 6 6 3 3 3 4 7 7 3 3 5 0 9 8 9 7 0 3 7 0 0 3 9 9 9                   Blackgrass 9 9 3 5 8 8 0 3 3 8 6 0 9 7 9 9 9 9 0 3 8 0 0 0 9 9 9             Cheatgrass 8 8 8 5 5 0 2 7 5 5 2 5 5 7 8 9 9 8 0 2 8 0 0 0 9 9 9                   Chickweed 0 0 5 7 3 0 0 2 1 8 7 0 2 2 3 3 5 0 0 2 5 0 0 0 9 9 9               Cocklebur -- -- -- -- -- 0 0 -- 8 9 -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- --                                                                Corn 8 9 8 8 9 8 6 8 8 10 8 7 7 7 8 7 7 4 0 2 0 0 0 0 9 9 9                     Cotton 6 6 9 9 2 0 4 9 9 8 7 8 5 7 7 9 8 7 0 0 2 0 -- 2 9 9 9                   Crabgrass 0 3 2 0 0 0 0 0 3 2 2 0 4 0 -- -- 3 0 0 -- -- 0 0 0 8 8 9                 Giant foxtail 7 7 6 5 4 0 2 4 5 6 4 4 6 0 8 7 5 2 0 2 7 0 0 0 9 9          10                                                                               Lambsquarters 9 9 9 9 9 2 8 9 8 9 9 7 8 5 8 9 7 4 0 3 7 0 0 0 9 10 10             Morningglory 9 9 9 9 3 0 4 9 9 9 8 8 9 9 9 9 9 7 0 1 7 0 0 0 9 9 10             Nutsedge 0 7 7 9 0 -- 0 0 -- -- 0 -- 5 -- 0 0 0 0 0 0 0 0 0 0 9 -- 9           Rape 0 8 7 8 9 8 8 6 8 9 9 8 3 0 7 9 9 5 0 1 5 0 0 0 9 8 9                     Rice 9 9 9 9 9 8 7 9 8 9 9 8 9 9 9 9 9 9 3 5 9 0 0 0 9 9 9                      Sorghum 9 9 6 2 8 4 0 7 4 8 3 3 8 9 9 9 9 7 0 0 8 0 0 0 9 9 10                  Soybean 3 6 8 8 9 5 4 8 9 8 9 5 7 8 7 9 9 7 0 0 0 0 0 0 8 9 9                   Sugar beet 8 9 9 9 8 4 8 6 6 9 7 5 0 2 4 8 6 0 0 2 5 0 0 0 9 8 10                     Velvetleaf 3 9 9 9 2 0 5 9 9 9 7 5 9 9 9 9 7 1 0 0 3 0 0 0 9 9 10         Wheat 9 9 4 3 9 0 0 5 5 9 2 2 4 3 6 9 9 3 0 0 5 0 0 0 8 8 9                     Wild buckwheat 2 9 7 9 0 3 9 2 7 9 8 5 7 0 8 -- -- -- -- 3 7 -- 3 9 --         -- 10                                                                            Wild oat 9 10 9 9 2 0 0 8 7 9 6 0 7 5 8 9 9 7 0 1 8 0 0 0 9 9 9                 COMPOUND                                                                         243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259           260 261 262 263 264 265 266 267 268 269                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 8 8 9 7 9 8 6 3 5 7 5 4 2 9 8 8 8 8 8 5 5 6 7 8 9 8 4                    Barnyardgrass 9 9 9 6 8 6 6 4 9 7 8 2 2 8 9 9 9 7 9 3 8 6 7 5 7 1 5                 Bedstraw -- 9 9 5 7 7 7 7 7 7 7 7 7 8 9 8 7 7 7 6 5 7 7 7 9 8 7                 Blackgrass 9 10 9 7 9 8 -- 7 9 9 7 7 7 9 9 9 9 9 9 8 2 7 8 9 9 9 8           Cheatgrass 9 9 9 6 8 4 3 6 8 9 7 6 5 9 9 9 9 5 9 8 4 7 8 8 9 9 7                     Chickweed 10 10 5 -- 7 9 7 0 5 5 8 9 0 6 9 9 6 5 6 5 5 0 4 4 8 8          Cocklebur -- -- -- -- -- -- -- 0 2 8 7 7 0 1 3 2 3 1 8 0 1 4 7 7 8 9 0           Corn 9 9 9 9 7 9 8 8 9 9 9 5 1 10 9 9 9 9 9 7 7 8 9 9 8 8 7                    Cotton 0 9 9 9 10 9 9 2 8 8 8 9 5 1 5 4 2 2 4 1 9 2 5 8 9 9 1                   Crabgrass 9 8 -- 5 8 -- 6 0 5 5 2 0 0 6 7 8 5 7 5 0 0 3 0 0 2 0 0                     Giant foxtail 10 10 9 9 4 9 7 6 4 8 8 6 2 0 8 9 9 8 9 7 2 4 8 8 5        5 0                                                                              Lambsquarters 10 10 10 9 9 10 10 -- 7 -- -- 10 5 10 10 10 -- -- 7 7 8 7        9 -- -- -- --                                                                    Morningglory 10 10 10 7 9 9 9 5 9 9 9 9 7 10 10 10 7 8 10 9 9 9 9 9 9 9        7                                                                                Nutsedge 3 5 10 -- 9 4 -- 0 3 0 -- -- -- -- 5 9 0 0 -- -- -- 0 5 -- 0 0        --                                                                               Rape 9 9 9 5 5 8 8 5 7 9 9 9 7 9 7 7 8 7 8 7 9 5 5 6 9 9 7                      Rice 9 9 9 9 9 9 9 8 9 9 9 9 8 9 9 9 10 10 9 7 9 8 9 9 9 9 5                    Sorghum 10 9 9 4 9 9 7 8 9 9 9 8 8 9 9 9 9 9 9 7 9 8 9 9 9 9 8                  Soybean 9 9 4 1 6 7 7 6 9 9 9 9 2 8 9 9 9 9 8 8 9 5 9 9 9 9 3                   Sugar beet 9 9 9 8 9 8 8 -- 5 3 9 8 0 4 5 7 7 5 6 5 7 0 3 5 9 9 0                     Velvetleaf 9 9 9 2 8 9 8 5 9 8 9 2 5 9 9 9 7 7 7 3 9 8 8 8 9 7 0           Wheat 8 8 9 4 7 7 4 4 8 7 3 2 0 8 9 8 9 8 9 3 5 8 8 7 9 6 0                    Wild buckwheat -- -- 9 9 -- -- -- 5 -- 9 9 9 7 9 9 8 7 8 8 9 4 8 5 8 9         9 9                                                                              Wild oat 9 9 9 5 8 7 6 5 5 5 7 7 2 9 9 9 9 9 9 7 6 7 7 8 9 9 3                  COMPOUND                                                                         270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286           287 288 289 290 291 292 293 294 295 296                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 9 9 9 3 4 9 6 4 0 0 8 0 3 9 9 9 9 9 8 9 7 9 4 8 2 2 6                    Barnyardgrass 8 9 9 1 2 9 3 3 2 4 6 0 7 9 9 9 9 9 9 9 6 9 5 9 2 2 4                 Bedstraw 4 9 7 1 2 8 0 0 3 4 2 3 5 8 7 6 8 7 8 7 3 5 3 4 3 2 3                   Blackgrass 9 9 9 9 9 9 7 2 3 5 7 5 5 9 9 9 9 9 8 9 9 9 6 8 4 7 4             Cheatgrass 9 9 9 9 8 9 8 2 0 2 7 2 5 9 9 9 9 9 9 9 8 9 4 7 2 5 2                   Chickweed 4 7 9 2 2 8 0 0 0 0 0 0 0 0 9 10 9 9 8 9 2 7 7 3 3 3 3             Cocklebur 5 1 4 0 0 7 2 2 0 2 0 0 5 -- -- -- -- -- -- -- -- -- -- --         -- -- --                                                                         Corn 9 10 9 7 5 9 3 0 0 0 4 0 2 9 9 9 9 7 9 9 6 9 6 9 2 1 2                     Cotton 9 7 8 0 2 9 2 0 0 0 0 0 5 9 9 9 9 10 10 8 7 8 6 7 1 7 3                  Crabgrass 7 8 9 2 0 8 2 2 0 0 2 0 0 6 7 6 6 6 2 7 2 9 2 5 1 1 1                         Giant foxtail 7 9 9 2 0 9 2 3 0 0 4 0 3 10 9 9 10 10 8 9 6 9 6         8 3 3 4                                                                          Lambsquarters -- 9 10 2 0 10 5 5 2 6 7 3 9 10 10 10 10 10 10 9 7 10 7 8        5 8 7                                                                            Morningglory 9 9 9 0 1 9 6 5 2 2 1 2 6 2 9 9 9 9 9 9 6 9 6 5 6 3 2                   Nutsedge 8 8 -- -- -- -- 0 0 0 0 0 0 0 6 9 -- 3 -- -- 4 0 -- 0 0 0        0 0                                                                              Rape 9 9 9 0 1 9 0 0 0 0 0 0 5 9 9 9 9 10 9 0 8 9 9 7 0 3 5                     Rice 10 9 9 9 9 9 9 9 6 5 9 8 7 9 9 9 10 10 9 9 8 9 8 7 2 8 6                   Sorghum 9 9 9 9 9 9 9 9 0 0 7 2 8 9 9 9 10 9 9 9 7 9 8 9 2 2 3                  Soybean 9 9 9 3 2 7 0 1 2 4 0 3 6 8 9 9 9 9 9 9 2 6 1 6 1 4 2                   Sugar beet 7 8 9 0 0 3 0 2 0 0 0 0 4 9 9 10 9 7 9 8 7 9 9 5 3 2 7                     Velvetleaf 9 9 9 8 8 9 5 2 0 0 5 0 0 9 9 8 9 9 8 6 6 9 7 5 3 6 1           Wheat 8 8 9 2 2 9 0 0 0 0 0 0 0 9 9 9 9 9 9 9 7 9 5 3 0 1 3                    Wild buckwheat 9 9 9 8 8 9 8 5 0 0 7 0 4 9 9 9 9 9 9 8 6 9 7 8 3 0 3               Wild oat 9 9 9 8 8 9 8 5 0 0 7 0 4 9 9 9 9 9 9 9 8 9 5 7 2 2                5                                                                                COMPOUND                                                                         297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313           314 315 316 317 318 319 320 321 322 323                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 3 2 4 9 8 9 7 5 8 6 8 7 5 7 7 6 5 0 0 0 0 0 0 0 0 9 9                    Barnyardgrass 3 1 0 9 9 9 8 3 9 2 8 2 8 9 9 9 2 2 0 0 0 0 0 0 0 3 6                 Bedstraw 5 0 0 7 5 3 5 6 6 6 6 6 6 6 6 7 3 5 0 0 2 0 0 0 0 6 7                   Blackgrass 7 4 4 9 9 7 5 3 9 8 9 7 7 7 9 8 2 2 0 0 0 0 0 0 0 7 9             Cheatgrass 2 0 0 9 8 9 8 0 7 3 7 5 7 6 8 8 3 0 0 0 0 0 0 0 0 9 9                   Chickweed 7 2 0 7 7 9 9 6 6 7 2 2 0 2 0 0 0 0 0 0 0 0 0 0 0 8 9               Cocklebur -- -- -- -- -- -- -- -- -- -- 5 1 8 9 9 7 0 0 0 0 0 7 1 2         0 9 8                                                                            Corn 2 2 0 5 9 9 1 0 8 6 7 6 8 9 7 7 0 0 0 0 0 0 0 0 0 9 9                      Cotton 7 4 0 9 9 9 9 6 9 8 6 9 9 9 9 7 2 0 0 0 0 0 0 0 0 9 9                    Crabgrass 0 0 0 5 7 8 5 4 7 2 4 2 6 0 3 0 0 0 0 0 0 0 0 0 0 7 8                         Giant foxtail 3 3 2 8 9 9 3 2 9 3 7 3 7 6 6 5 2 0 0 0 0 0 0 0 0        8 9                                                                              Lambsquarters 9 5 5 9 9 -- -- -- -- 4 -- 8 8 9 10 -- 3 0 0 5 0 0 0 0 0         10 --                                                                            Morningglory 2 2 1 5 9 9 8 3 9 3 6 3 9 10 9 9 1 7 0 0 0 4 1 2 0 5 10               Nutsedge 0 -- 0 -- 5 7 0 0 0 -- 4 3 3 7 2 4 0 0 0 0 -- 0 0 -- 0 5 8           Rape 5 0 0 8 9 9 9 7 7 0 7 6 7 9 7 7 3 2 0 0 2 4 2 0 0 9 9                     Rice 7 3 0 9 9 9 3 0 9 8 9 6 9 9 9 7 7 4 0 2 2 4 0 0 0 9 9                      Sorghum 6 3 0 9 9 9 8 3 9 8 8 4 6 8 9 8 3 3 0 0 0 0 0 0 0 9 9                   Soybean 4 2 0 7 8 7 1 0 8 2 8 8 8 9 9 5 2 0 0 0 0 0 0 0 0 8 9                   Sugar beet 8 2 3 8 8 9 8 5 8 2 5 6 7 8 8 -- 5 3 0 0 2 3 2 0 0 9 9                     Velvetleaf 0 0 0 7 8 8 7 1 6 3 7 5 6 9 2 8 0 0 0 0 0 0 0 0 0 9 10         Wheat 2 0 2 9 9 9 3 1 7 0 5 3 7 4 4 3 3 0 0 0 0 1 0 0 0 9 9                     Wild buckwheat 6 0 2 8 7 7 8 7 7 6 7 2 5 7 9 -- 0 2 -- -- -- -- -- --          -- -- --                                                                         Wild oat 3 3 1 8 8 8 5 2 7 5 8 2 6 9 8 5 3 0 0 0 0 1 0 0 0 9 9                  Compound                                                                         324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340           341 342                                                                          POSTEMERGENCE  Rate (10 g/ha)                                                   Barley 9 5 3 7 2 4 0 0 0 0 0 0 0 0 9 9 9 9 8                                    Barnyardgrass 9 4 0 8 0 1 0 0 0 0 0 0 0 0 9 9 6 3 8                             Bedstraw 9 6 6 9 5 5 0 0 0 0 0 0 0 0 7 9 2 4 8                                  Blackgrass 8 5 4 3 0 3 0 0 0 0 0 0 0 0 9 9 9 9 7                                Cheatgrass 9 7 5 8 7 8 0 0 0 0 0 0 0 0 9 9 9 7 8                                Chickweed 9 7 6 9 0 2 0 0 0 0 0 0 0 0 9 10 5 0 8                                Cocklebur 9 0 0 8 0 1 0 0 0 0 0 0 0 0 10 10 1 0 9                               Corn 9 9 1 9 4 9 0 0 0 0 0 0 0 0 9 9 9 6 9                                      Cotton 9 9 0 9 2 3 0 0 0 0 0 0 0 0 9 10 0 0 9                                   Crabgrass 5 2 0 3 0 2 0 0 0 0 0 0 0 0 7 7 1 2 7                                 Giant foxtail 9 7 0 9 5 7 0 0 0 0 0 0 0 0 9 10 7 3 8                            Lambsquarters 9 5 3 9 1 3 3 0 0 0 0 0 0 0 10 10 2 2 10                          Morningglory 10 8 1 9 1 1 0 0 0 0 0 0 0 0 9 9 2 3 9                             Nutsedge 8 -- 0 7 0 0 0 0 0 0 0 0 0 0 8 8 0 1 5                                 Rape 9 9 8 9 0 0 0 0 0 0 0 0 0 0 9 9 8 5 9                                      Rice 9 9 9 9 8 9 0 0 0 0 0 0 0 0 9 9 9 9 9                                      Sorghum 9 9 1 9 1 8 0 0 0 0 0 0 0 0 9 9 9 6 10                                  Soybean 9 8 2 8 2 9 0 0 0 0 0 0 0 0 9 9 2 1 6                                   Sugar beet 9 8 7 9 3 5 0 0 0 0 0 0 0 0 9 10 1 3 9                               Velvetleaf 9 0 0 8 0 0 0 0 0 0 0 0 0 0 9 10 1 0 8                               Wheat 9 9 8 1 0 7 0 0 0 0 0 0 0 0 9 9 9 9 8                                     Wild buckwheat -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         Wild oat 9 9 4 2 7 8 0 0 0 0 0 0 0 0 9 9 9 9 9                                  COMPOUND                                                                        165 166 167 168 169 170 171 93 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16          17 18 19                                                                         PREEMERGENCE Rate (200 g/ha) Rate (100 g/ha) Rate (50 g/ha)                     Barley 8 9 8 2 3 2 2 0 4 7 7 3 9 2 0 1 0 0 0 0 0 0 0 0 0 0 0                    Barnyardgrass 9 9 9 9 9 9 7  6 9 9 9 9 0 2 0 2 0 3 0 0 0 0 0 0 0 0                   Bedstraw 7 7 9 6 8 9 4 0 4 9 9 9 9 8 0 6 0 7 0 0 0 0 0 2 0 3 0                 Blackgrass 7 8 9 8 3 9 0 2 6 8 9 4 8 4 5 2 4 6 7 0 3 0 1 0 0 2 3               Cheatgrass 8 8 9 8 4 8 0 0 9 9 9 5 10 8 6 5 6 5 6 2 3 0 0 2 0 2 0               Chickweed 9 9 9 8 9 9 2 8 8 9 10 6 9 9 0 8 -- -- 9 0 8 5 2 0 5 8 --           Cocklebur -- 8 6 1 2 8 2  0 0 0 0 8 10 0 4 0 0 2 0 0 -- 0 0 0 4 0                   Corn 7 9 9 8 8 7 3  6 9 9 9 9 4 2 0 1 6 7 0 1 0 0 0 0 0 0                  Cotton 8 8 7 3 5 9 2  5 8 7 7 8 7 0 0 4 0 0 0 0 0 0 0 0 0 0                     Crabgrass 9 9 8 7 9 9 9  8 9 8 4 8 7 0 0 1 0 2 0 0 0 0 0 0 0 0                  Giant foxtail 9 9 9 7 9 9 9  1 9 6 3 3 2 2 2 2 2 3 0 0 2 0 0 0 2 0                   Lambsquarters 9 9 9 8 9 9 7 5 9 9 9 8 9 -- 0 6 6 6 9 6 6 -- 5 0 --        3 6                                                                              Morningglory 0 6 5 4 4 9 0  0 5 8 5 9 5 2 2 0 2 0 0 0 0 0 0 0 0 0                     Nutsedge 9 9 9 9 0 10 3  7 10 10 3 8 10 0 0 0 0 0 0 0 0 0 0 0 0 0         Rape 9 9 9 9 9 9 2 0 8 6 9 9 9 9 0 0 3 5 2 0 6 0 0 1 0 2 0                      Rice 9 9 9 9 10 9 9  9 9 8 9 10 9 2 0 3 0 3 0 6 0 0 0 0 0 2                     Sorghum 9 9 9 9 9 9 7  9 9 7 7 9 9 3 0 2 0 0 0 0 0 0 0 0 0 0                    Soybean 8 9 8 4 7 8 5  2 7 6 7 8 2 0 2 4 2 4 0 2 0 0 0 0 0 3                    Sugar beet 9 9 9 8 9 9 7 5 7 8 9 9 10 9 0 3 4 4 7 2 2 4 0 0 0 0 2                     Velvetleaf 3 8 8 8 1 7 2  4 8 5 6 9 0 2 1 0 0 0 0 0 2 0 0 0 0 0             Wheat 8 9 9 5 7 9 2 0 8 8 9 2 9 5 1 0 0 2 0 0 0 0 0 0 0 -- 0                  Wild buckwheat 7 7 8 3 7 9 0 0 2 7 9 9 9 7 0 4 0 0 0 0 0 2 0 2 0 0 0               Wild oat 8 8 9 3 4 6 0 0 7 7 8 2 9 7 2 2 0 2 0 0 0 2 0 0 0 0                 COMPOUND                                                                        20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 4      4 45 46 47                                                                       PREEMERGENCE Rate (50 g/ha)                                                     Barley 0 0 0 0 0 8 8 8 9 6 2 2 0 0 2 8 8 0 2 0 0 0 0 0 0 0 0 0                  Barnyardgrass 2 0 0 0 0 9 9 9 9 9 9 7 6 0 2 9 9 0 7 2 0 0 0 0 0 0 0 0             Bedstraw 9 2 2 0 0 9 9 9 9 8 8 6 6 7 0 7 8 2 3 0 0 0 0 0 0 0 -- 2                 Blackgrass 3 0 0 0 2 9 9 9 9 3 7 8 0 5 7 7 8 0 3 2 2 2 1 0 0 2 1 3           Cheatgrass 3 0 0 0 2 9 9 9 9 9 8 7 8 4 9 9 9 0 7 5 4 3 3 3 0 2 3 3                 Chickweed 8 7 2 2 5 9 9 9 8 8 9 7 6 8 8 9 9 0 8 6 6 7 9 2 0 3 0 7             Cocklebur 0 0 0 0 0 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --          -- -- -- -- -- -- --                                                             Corn 2 0 0 0 0 9 9 9 9 9 9 6 3 2 9 9 9 1 2 2 0 0 0 0 0 0 0 0                    Cotton 0 0 0 0 0 5 7 7 6 7 9 0 0 1 3 5 8 0 0 0 0 0 0 0 0 0 0 0                  Crabgrass 0 0 0 0 0 9 9 10 9 10 9 7 6 1 9 9 9 0 0 0 0 0 0 0 0 0 0 0                 Giant foxtail 0 2 0 0 0 9 9 9 9 9 9 9 5 2 9 9 9 0 5 0 0 0 0 0 0 0 0         Lambsquarters 3 0 0 0 0 9 10 10 10 9 8 9 9 7 10 10 10 4 8 9 0 10 3 0 0         0 0 0                                                                            Morningglory 1 0 0 0 0 6 9 8 9 9 9 2 0 0 1 9 9 0 0 0 0 0 0 0 0 0 0 0               Nutsedge 0 0 0 0 -- 9 8 8 9 10 9 5 0 0 0 8 2 0 0 0 0 0 0 -- 0 0 0 0           Rape 0 0 0 0 0 8 9 9 9 9 9 0 0 4 3 4 8 0 3 0 2 2 2 2 0 0 0 0                   Rice 2 0 0 0 4 10 9 9 10 10 10 8 7 4 7 9 10 0 8 5 4 8 3 0 0 0 0 2                     Sorghum 0 0 0 3 0 9 9 8 9 9 9 6 2 2 2 9 9 0 2 1 0 0 0 0 0 0 0 0             Soybean 1 0 0 0 0 8 8 8 8 9 9 2 1 1 1 8 9 1 1 3 0 0 2 0 0 0 0 0                     Sugar beet 0 0 0 0 2 8 9 9 9 9 9 4 7 6 8 9 9 2 9 2 1 2 3 2 0 2 0         2                                                                                Velvetleaf 0 0 0 0 0 3 5 6 9 8 9 1 1 0 1 2 9 0 0 0 0 0 0 0 0 0 0 0                   Wheat 0 0 0 0 0 9 9 8 3 7 8 7 2 0 0 8 9 0 2 0 0 2 0 0 0 0 0 0                   Wild buckwheat 2 0 0 2 0 9 9 3 8 3 8 2 0 0 0 3 2 0 2 0 2 0 3 0 0 0        0 0                                                                              Wild oat 0 0 0 0 0 9 8 9 8 8 9 8 2 3 8 9 9 0 2 2 0 0 2 0 0 0 0 2                COMPOUND                                                                        48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 7      2 73 74 75                                                                       PREEMERGENCE Rate (50 g/ha)                                                     Barley 0 0 3 7 2 8 2 2 4 4 2 4 2 0 2 6 6 0 0 3 2 1 5 0 0 2 2 0                  Barnyardgrass 0 0 9 9 8 9 8 9 9 9 9 5 6 4 9 9 9 6 0 8 7 7 1 0 0 0 6 0             Bedstraw 0 0 8 8 5 8 8 7 7 9 9 9 9 8 0 6 8 0 4 5 6 0 8 8 2 0 1 1                   Blackgrass 2 0 8 8 9 9 4 2 8 9 9 7 6 5 4 8 9 4 1 5 6 2 3 3 0 0 5 0         Cheatgrass 0 4 8 8 8 9 6 2 8 9 8 8 7 6 7 8 8 7 5 7 8 7 6 0 0 7 8 0                   Chickweed 2 3 -- 9 8 9 10 10 10 9 9 10 10 9 5 9 9 3 0 9 9 8 8 7 5         5 7 0                                                                            Cocklebur -- -- 9 9 8 9 9 0 6 9 8 9 9 0 1 8 8 0 -- 8 8 0 9 0 0 0 -- 2             Corn 0 0 8 8 0 9 9 3 7 9 9 9 7 2 0 7 9 8 2 1 9 3 8 2 0 0 2 2                  Cotton 0 1 8 9 1 9 9 2 9 8 8 9 9 5 0 7 8 1 0 4 8 0 8 7 0 1 2 0                  Crabgrass 0 0 6 9 6 9 5 2 1 7 2 4 3 0 6 9 9 6 2 7 5 2 2 0 0 1 2 1                     Giant foxtail 0 0 9 9 5 9 1 0 2 9 6 2 4 2 2 9 9 3 0 5 6 2 2 0 0 1        4 0                                                                              Lambsquarters 4 2 9 9 8 10 9 8 9 9 9 9 9 10 9 9 10 9 0 9 9 6 -- 8 7 6 9         Morningglory 0 0 7 9 2 9 9 8 0 2 6 9 9 3 0 2 8 3 0 0 7 2 9 0 0 0 5 1               Nutsedge 0 0 10 10 5 10 10 10 -- 8 -- -- 9 8 5 10 10 0 0 10 10 0 0 0        -- 0 0 0                                                                         Rape 0 0 9 9 9 9 9 8 9 9 9 9 9 9 5 9 9 1 0 9 8 3 7 9 2 2 2 0                    Rice 0 3 9 10 9 9 9 9 8 8 9 9 9 9 9 10 8 10 8 9 7 8 7 2 1 4 7 0                         Sorghum 0 0 7 6 3 9 3 1 7 9 4 5 3 2 6 8 9 4 2 9 7 0 2 2 0 2 1 0         Soybean 0 0 6 8 1 8 9 1 2 8 8 9 8 0 1 8 9 3 3 0 8 0 7 4 0 5 7 1                         Sugar beet 0 2 9 9 9 9 9 9 9 9 9 9 9 9 4 9 9 5 5 9 8 7 9 9 4 4         8 3                                                                              Velvetleaf 0 0 8 9 5 9 0 4 5 8 7 9 8 2 2 7 7 5 0 5 6 2 8 0 0 0 2 1                   Wheat 0 0 3 8 7 9 2 0 3 7 3 2 4 0 5 7 7 8 0 7 2 1 2 0 0 0 0 0                   Wild buckwheat 0 0 1 7 6 8 9 0 7 9 9 9 8 7 3 3 3 0 3 0 0 0 3 0 0 0        1 2                                                                              Wild oat 0 0 4 8 8 9 8 0 8 8 5 8 8 0 5 6 6 6 0 6 4 2 2 0 0 2 3 0                COMPOUND                                                                        76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 1      00 101 102 103                                                                   PREEMERGENCE Rate (50 g/ha)                                                     Barley 0 3 0 0 0 5 7 2 4 0 1 0 0 0 0 0 0 1 2 3 0 2 1 1 0 0 4 7                  Barnyardgrass 1 4 9 0 0 5 9 9 8 3 9 3 9 9 4 2 9 5 7 5 3 3 4 1 2 0 3 6             Bedstraw 0 2 1 0 0 1 8 9 5 3 7 1 3 8 0 0 0 0 0 0 2 3 5 2 5 0 2 7                   Blackgrass 2 5 7 3 0 9 9 9 7 2 9 3 6 7 7 2 8 2 6 2 3 6 8 7 4 2 6 8         Cheatgrass 2 8 9 1 0 9 9 9 7 2 9 8 9 8 7 5 8 7 0 0 5 6 6 4 0 0 8 8                   Chickweed 0 5 7 2 0 7 9 9 7 0 7 1 7 8 8 8 0 9 8 -- 9 9 9 9 9 0 5 8         Cocklebur 1 2 5 0 0 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- --                                                                Corn 0 5 9 0 0 0 7 9 9 9 5 0 6 9 9 9 0 4 7 8 7 6 7 8 7 0 0 0                    Cotton 2 0 1 0 0 7 5 8 3 0 5 0 5 5 2 0 0 6 5 3 7 9 3 7 5 0 -- 9                         Crabgrass 0 4 7 0 0 6 4 7 3 4 0 0 2 3 0 0 0 7 5 2 2 6 5 0 0 0 1        3                                                                                Giant foxtail 0 5 8 0 0 3 9 8 3 3 5 2 5 3 0 0 0 5 7 0 1 2 7 0 0 0 3 3             Lambsquarters 0 8 7 0 0 9 10 10 10 9 10 8 9 9 9 9 9 9 6 9 9 -- 9 7 9         0 9 9                                                                            Morningglory 2 3 5 0 0 7 7 9 7 3 9 1 2 8 6 7 2 1 1 9 4 0 1 2 3 0 7 8               Nutsedge 0 4 10 -- -- 9 10 10 5 6 10 0 8 10 10 0 0 0 6 0 4 5 0 0 3 0        0 0                                                                              Rape 0 3 7 1 0 9 9 9 4 0 9 1 9 9 3 3 4 2 3 7 7 6 2 7 9 0 3 6                    Rice 0 7 8 0 0 8 8 9 9 8 9 0 7 8 9 8 9 4 9 8 9 3 8 3 4 0 5 8                    Sorghum 0 4 5 0 0 8 9 9 9 5 9 3 9 8 7 6 6 7 8 9 4 8 9 5 3 0 3 8                         Soybean 3 7 6 0 0 2 6 9 7 4 9 1 5 7 5 3 0 2 5 7 7 1 3 4 7 0 0 1         Sugar beet 2 9 8 1 0 8 9 9 9 8 9 8 8 6 5 8 2 8 5 8 9 5 6 9 9 0 8 9                   Velvetleaf 0 0 3 0 0 5 9 9 4 0 1 1 4 6 0 0 0 0 1 1 0 1 0 6 1 0 0 3         Wheat 0 4 2 0 0 8 7 7 8 5 1 0 0 0 2 3 0 3 6 0 0 3 6 0 0 0 8 8                   Wild buckwheat 0 1 4 0 0 6 9 9 9 -- 7 -- 9 10 0 -- -- 0 5 8 0 3 5 3 5 0        2 7                                                                              Wild oat 0 3 3 0 0 7 6 3 7 1 2 0 0 2 5 0 0 1 2 1 2 3 5 6 0 0 4 3                COMPOUND                                                                        104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 1      22 123 124 125 126 127 128 129 130 131                                           PREEMERGENCE Rate (50 g/ha)                                                     Barley 2 1 0 5 6 8 8 7 0 5 7 0 2 0 0 8 7 7 7 1 2 2 1 1 1 0 0 0                  Barnyardgrass 2 0 0 9 7 9 9 8 8 9 9 9 9 7 7 10 9 9 9 1 4 0 5 0 0 2 6 3           Bedstraw 2 2 0 8 8 7 8 5 2 7 8 8 9 9 7 7 3 8 7 2 5 3 8 6 1 2 0 0                     Blackgrass 5 2 2 7 9 9 9 7 7 7 7 8 5 3 3 8 7 9 6 5 6 5 7 4 3 0 5         2                                                                                Cheatgrass 2 3 3 9 9 9 9 8 7 8 9 8 8 7 6 9 8 9 9 7 7 7 6 3 2 2 7 7                   Chickweed 0 0 0 10 9 9 9 8 9 4 8 7 7 8 3 10 9 10 9 8 9 -- 10 7 10         3 9 9                                                                            Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 3 3         2 5 3 0 2 5 7                                                                    Corn 0 0 0 9 8 9 9 8 7 9 9 9 9 6 5 9 9 10 9 0 5 0 0 0 0 0 2 5                   Cotton 0 0 0 9 9 9 9 7 7 5 8 9 9 9 0 9 9 10 10 5 7 1 -- 4 3 2 6 0                     Crabgrass 1 0 0 8 8 9 9 7 8 4 5 3 7 3 2 9 6 9 9 2 1 1 2 2 0 3 2 2         Giant foxtail 0 0 0 8 3 8 9 6 2 3 9 5 8 1 3 9 9 8 7 2 3 1 2 1 0 3 0 2             Lambsquarters 0 2 3 9 10 9 9 9 9 6 9 9 9 10 9 10 10 10 10 7 9 9 10 9         -- 9 9 7                                                                         Morningglory 0 0 0 10 9 9 8 9 6 5 9 9 9 9 6 9 9 9 10 2 2 2 8 3 0 1 2 3           Nutsedge 10 0 -- 10 10 10 10 4 9 9 10 9 9 8 4 10 10 9 10 2 0 0 2 -- 0         0 9 9                                                                            Rape 0 0 0 9 9 9 9 9 7 7 8 9 9 9 7 9 9 9 9 9 9 9 9 6 9 5 8 8                    Rice 4 0 0 9 9 10 9 9 9 8 9 9 9 9 8 10 9 10 10 7 5 2 8 5 3 2 2 0                       Sorghum 0 0 0 8 8 9 9 9 9 8 9 9 8 6 6 9 9 9 9 0 0 0 6 3 0 0 5 2           Soybean 0 0 0 9 8 8 8 8 5 1 8 7 9 9 1 9 9 9 9 1 2 0 1 0 0 0 2 3                       Sugar beet 1 1 0 9 9 9 9 9 8 5 8 7 9 9 8 9 9 9 9 8 8 9 9 9 6 7 7        7                                                                                Velvetleaf 1 0 0 9 8 8 9 9 9 2 9 9 9 9 1 9 9 9 8 6 8 5 8 0 0 4 8 7                   Wheat 2 2 0 6 6 9 7 5 0 2 6 2 2 2 0 8 7 8 8 2 2 2 2 2 0 0 0 0                   Wild buckwheat 5 2 1 5 8 3 3 2 5 0 3 5 7 5 2 7 4 7 5 2 7 6 8 3 0 2        5 7                                                                              Wild oat 0 0 0 7 7 7 7 2 5 5 7 4 7 5 2 7 6 7 7 7 4 4 5 2 0 2 3 3                COMPOUND                                                                        132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 1      50 151 152 165 166 167 168 169 170 171                                           PREEMERGENCE Rate (50 g/ha)                                                     Barley 2 0 0 4 0 4 8 2 3 7 8 7 6 1 2 5 7 9 0 0 0 4 8 8 2 0 0 0                  Barnyardgrass 2 0 0 8 5 7 9 3 8 3 9 9 2 1 8 5 6 7 0 0 7 7 7 7 8 3 9 5             Bedstraw 8 7 2 7 7 9 7 5 5 4 7 8 8 5 9 6 8 9 8 5 9 2 8 6 0 6 6 0                   Blackgrass 3 6 3 7 6 8 9 8 8 6 10 8 7 7 7 9 8 9 5 5 8 5 8 8 3 2 9         --                                                                               Cheatgrass 4 3 2 8 8 9 9 9 8 8 10 10 8 8 9 9 9 9 9 9 8 7 8 9 6 0 8 --             Chickweed 9 5 0 8 8 9 9 5 9 5 9 7 10 0 8 9 9 -- 7 7 7 8 9 9 5 7 8 0             Cocklebur 8 6 0 0 0 2 5 2 1 7 9 9 5 2 9 5 9 7 2 2 0 3 3 2 -- -- 5 --           Corn 8 2 0 6 3 6 7 0 4 3 9 9 9 8 9 0 5 5 8 6 3 3 8 7 2 0 5 1                   Cotton 5 3 3 4 0 -- 8 0 2 5 7 8 8 2 4 2 6 6 2 1 3 0 8 2 0 4 2 0                         Crabgrass 2 6 0 0 0 0 2 2 3 2 7 9 3 0 5 7 2 5 0 1 0 7 8 6 5 5 5        7                                                                                Giant foxtail 2 2 0 3 0 2 6 2 5 9 9 9 4 0 3 2 3 3 0 0 0 9 8 7 2 7 8 8             Lambsquarters 9 9 5 9 8 9 9 9 8 7 9 9 5 7 9 8 9 9 9 5 9 8 9 8 8 7 9 7         Morningglory 7 6 0 6 3 6 8 3 6 2 6 9 8 6 9 8 8 8 5 4 3 0 4 3 0 2 5 0               Nutsedge 9 0 0 0 0 0 0 0 2 9 9 10 2 0 10 5 9 10 0 0 8 7 10 0 0 0 4 0         Rape 7 5 5 0 5 4 0 1 2 7 9 9 9 3 9 8 9 9 3 0 7 8 9 8 8 9 9 0                    Rice 7 8 0 7 1 7 9 5 6 9 9 10 10 8 9 10 8 10 9 9 10 9 8 9 9 9 10 3                   Sorghum 4 6 2 9 5 6 9 2 6 8 8 9 8 3 7 5 6 6 3 2 5 9 9 9 5 0 7 1               Soybean 2 1 0 2 0 2 3 2 0 7 9 9 8 4 9 7 9 9 8 6 6 2 7 4 0 3 4 0                   Sugar beet 9 8 4 9 8 8 9 8 8 7 9 9 9 3 9 7 9 9 8 7 7 7 9 8 3 9 9 6         Velvetleaf 8 0 3 0 6 3 2 4 3 7 9 9 6 0 9 5 7 9 2 0 0 1 6 2 1 3 9 0                   Wheat 0 0 2 7 3 7 8 5 7 7 8 8 9 6 5 6 7 9 4 4 3 2 8 8 2 2 4 0                   Wild buckwheat 4 7 3 -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- 4 3 5 3 3 2 0                                                           Wild oat 3 2 3 8 5 7 8 4 6 7 7 5 8 3 5 7 4 5 3 2 2 3 8 8 2 2 3 0                COMPOUND                                                                        172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 1      90 191 192 203 204 205 206 207 208 209                                           PREEMERGENCE Rate (50 g/ha)                                                     Barley 2 3 0 0 0 0 0 0 0 0 8 6 5 3 7 2 0 0 0 0 0 8 9 8 9 7 8 2                  Barnyardgrass 3 6 7 9 0 0 0 0 9 9 8 9 3 9 9 6 1 1 2 1 2 5 9 9 9 9 9 0             Bedstraw 2 5 1 0 0 0 2 0 2 2 9 8 2 7 8 6 0 2 5 5 0 0 8 9 9 8 9 4                   Blackgrass 7 8 2 7 0 3 3 2 4 5 9 9 9 9 9 9 6 5 7 7 7 8 8 9 8 9 8 2         Cheatgrass 8 8 7 8 5 2 2 0 7 7 9 10 9 9 10 10 7 7 7 7 7 9 9 9 9 8 9 8             Chickweed 7 8 2 4 0 3 4 0 4 9 9 9 -- 8 9 8 0 -- 3 2 6 9 9 9 9 10 9 0           Cocklebur 0 2 0 2 0 0 0 0 0 0 7 8 7 8 8 8 2 0 0 0 0 -- 8 10 10 9 9 8             Corn 5 8 6 6 0 0 0 0 7 8 9 9 9 9 9 9 3 9 4 3 7 9 9 9 9 9 9 0                  Cotton 5 8 2 0 0 0 0 0 0 0 8 3 8 9 9 6 0 0 3 0 0 7 4 8 7 8 7 0                  Crabgrass 9 8 6 9 2 0 0 0 9 9 9 10 9 9 10 9 8 5 6 6 9 9 9 9 9 9 9 3                 Giant foxtail 9 8 5 7 6 0 4 0 9 9 9 10 9 9 9 9 8 7 6 6 9 8 9 9 9 9         9 3                                                                              Lambsquarters 9 9 5 9 -- 0 3 2 3 5 8 9 9 9 9 5 4 3 5 0 5 9 9 10 9 8 9 5         Morningglory 6 3 6 4 0 0 1 0 0 2 6 6 6 9 7 4 0 4 3 3 3 7 9 9 9 4 9 2               Nutsedge 0 8 0 0 0 0 0 0 0 9 7 10 8 10 7 5 7 0 0 0 0 6 10 10 9 5 10          Rape 4 8 3 0 0 0 0 0 0 2 7 8 5 9 9 6 0 0 0 2 0 8 8 9 7 4 9 0                    Rice 7 9 7 9 0 0 0 0 7 9 9 9 8 10 10 9 8 9 9 0 7 9 9 9 9 10 10 5                       Sorghum 7 8 7 9 0 0 0 0 9 9 8 9 9 9 9 8 0 1 1 0 4 9 8 9 8 8 9 0           Soybean 5 8 4 3 0 0 0 0 0 1 9 9 9 8 9 9 2 6 2 2 8 9 8 8 8 8 8 0                       Sugar beet 9 8 5 6 2 0 2 2 3 7 9 7 7 7 8 7 3 3 7 4 5 8 9 9 9 9 9        1                                                                                Velvetleaf 5 7 2 0 0 0 0 0 0 0 7 8 7 6 7 5 0 2 2 2 2 7 6 9 8 5 8 0                   Wheat 7 7 0 6 0 0 2 0 7 6 7 7 6 0 8 8 0 2 6 0 2 7 9 9 9 8 8 0                   Wild buckwheat -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- 5 8 8 8 3 8 0                                                        Wild oat 4 3 0 4 0 0 0 3 1 2 8 7 7 2 7 7 4 6 5 2 7 8 9 8 8 7 8 2                COMPOUND                                                                        210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 2      28 229 230 231 232 233 234 235 236 237                                           PREEMERGENCE Rate (50 g/ha)                                                     Barley 0 2 7 5 3 1 2 3 1 0 0 0 0 1 1 0 0 0 5 5 2 4 5 0 0 0 0 0                  Barnyardgrass 6 9 8 8 6 9 4 3 7 3 0 0 0 7 0 0 0 0 2 5 1 5 1 3 0 0 2 0             Bedstraw 5 8 8 8 9 6 0 1 8 2 0 0 1 7 6 0 0 0 3 2 3 3 0 3 2 0 0 0                   Blackgrass 2 8 8 7 6 5 6 6 7 6 0 3 0 2 5 3 0 0 3 8 7 4 3 4 3 0 0 0         Cheatgrass 8 9 9 9 9 8 6 8 9 8 4 0 2 7 8 7 0 2 7 10 8 9 8 8 0 0 0 0                 Chickweed 7 9 10 10 9 9 8 7 9 9 2 2 5 9 8 5 4 9 0 9 2 2 0 0 0 0 0 0         Cocklebur -- 8 -- -- -- 0 0 0 0 0 -- 0 -- -- 0 0 0 -- -- -- -- -- -- --        -- -- -- --                                                                      Corn 8 9 9 9 9 7 8 3 2 0 5 0 0 2 8 0 0 0 2 8 8 4 3 1 0 2 2 0                    Cotton 0 8 8 8 9 5 0 0 -- 0 0 0 0 0 2 0 0 0 2 4 5 2 2 2 0 0 2 0                         Crabgrass 8 9 7 9 4 5 3 6 3 2 0 2 3 0 3 0 0 0 2 5 3 6 6 2 0 0 2         Giant foxtail 6 9 9 8 2 3 5 5 2 0 0 2 0 5 7 0 0 0 3 7 1 5 2 0 0 0 2 0             Lambsquarters 8 9 9 9 9 8 7 9 9 9 6 -- 9 -- 8 -- -- 7 9 9 7 4 5 0 7 0        0 0                                                                              Morningglory 1 3 2 3 9 2 0 3 2 1 0 1 0 3 2 0 0 0 5 6 6 7 5 -- 0 0 1 0             Nutsedge 0 3 8 8 9 2 0 9 0 0 0 0 0 0 0 0 0 0 2 5 6 5 0 6 0 0 4 0                   Rape 3 9 9 8 8 8 1 9 7 1 0 1 0 7 8 2 0 0 0 3 3 0 3 2 0 0 0 0                     Rice 6 9 9 9 9 6 6 9 7 6 0 3 6 5 4 5 4 0 1 8 7 8 8 9 0 0 1 0                   Sorghum 5 9 9 9 8 8 3 3 2 0 0 0 0 6 1 2 2 0 3 7 7 8 6 2 0 0 2 0               Soybean 3 7 7 9 8 2 2 4 4 0 1 0 0 3 5 3 2 0 4 7 2 5 4 2 0 0 0 0                   Sugar beet 8 6 7 9 9 7 4 2 4 3 1 1 1 6 7 0 1 2 2 4 2 3 2 2 2 0 0 0         Velvetleaf 4 7 4 9 0 6 0 6 7 2 0 0 0 2 8 0 0 0 4 6 6 6 0 0 0 0 0 0                   Wheat 7 9 8 6 1 3 6 8 8 0 0 0 0 0 2 0 0 0 3 6 6 7 7 3 0 0 0 0                   Wild buckwheat 3 1 7 8 8 3 1 5 2 0 3 3 0 3 6 0 3 0 0 0 2 2 0 2 2          -- 0 3                                                                           Wild oat 7 9 8 8 8 3 6 7 3 2 0 0 1 0 2 3 0 0 4 7 7 5 6 1 0 0 0 0                COMPOUND                                                                        238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 2      56 257 258 259 260 261 262 263 264 265                                           PREEMERGENCE Rate (50 g/ha)                                                     Barley 0 0 8 8 8 8 8 8 3 2 0 0 0 5 1 5 0 0 8 5 8 5 0 8 0 0 0 2                  Barnyardgrass 0 0 9 9 9 9 9 9 4 6 1 0 1 8 3 6 2 3 4 8 9 9 8 9 1 0 2 2             Bedstraw 4 3 7 7 7 8 8 8 2 3 5 2 0 8 5 8 7 7 7 7 7 3 2 9 3 2 3 3                   Blackgrass 3 0 7 9 9 9 7 9 8 7 3 4 3 8 7 6 5 2 8 8 8 6 8 8 3 0 2 8         Cheatgrass 0 0 8 9 9 9 8 9 5 8 4 2 7 8 7 8 8 6 8 8 9 8 8 8 5 0 8 8                   Chickweed 0 0 9 9 9 9 9 9 9 9 7 9 9 9 6 9 9 5 5 8 9 7 3 9 5 3 2 0           Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- 0 2 -- 6 5 0 1 0 2 1 5 7        0 0 2 0                                                                          Corn 0 2 9 9 9 9 9 9 4 8 5 3 2 8 9 9 8 5 9 9 9 9 9 9 2 0 4 8                    Cotton 0 0 8 7 7 9 10 8 0 0 3 0 1 5 4 9 8 2 7 6 8 9 2 8 0 2 0 6                         Crabgrass 0 0 9 9 9 9 9 9 7 9 7 2 2 8 4 3 4 0 9 7 8 8 7 8 0 0 2        4                                                                                Giant foxtail 0 0 9 9 9 9 9 9 4 9 4 3 1 8 7 3 2 0 6 8 9 7 8 8 1 0 2 5             Lambsquarters 2 2 9 9 9 9 9 9 9 7 9 9 8 9 7 10 9 6 9 9 9 9 -- 8 7 3 5        9                                                                                Morningglory 0 0 7 6 8 8 8 8 0 3 2 2 1 1 3 9 8 1 8 8 8 3 1 8 0 0 5 3               Nutsedge 0 -- 10 9 9 10 10 10 8 6 -- -- 0 0 2 8 0 0 9 7 8 0 0 8 0 0         0 0                                                                              Rape 0 0 9 9 9 9 9 9 2 5 7 8 3 8 7 8 8 6 9 7 8 6 4 9 0 0 5 7                    Rice 2 2 9 9 9 10 9 10 4 8 2 0 1 7 8 8 8 0 9 9 9 -- 9 9 0 2 0 6                         Sorghum 0 0 9 9 9 9 8 9 2 4 3 0 3 8 8 9 7 5 8 8 8 8 7 8 1 2 5 7         Soybean 0 0 9 9 9 8 9 8 0 2 5 0 1 5 7 7 8 1 7 7 8 8 5 4 0 2 2 7                         Sugar beet 0 0 9 9 9 9 9 9 7 7 8 9 1 8 3 8 7 5 6 8 7 6 2 5 2 0         2 3                                                                              Velvetleaf 0 0 8 9 9 9 7 6 3 3 2 2 2 8 6 9 0 2 7 5 8 1 1 2 0 0 7 7                   Wheat 0 0 8 7 7 8 8 7 5 5 0 0 0 6 6 0 2 0 7 7 8 7 6 7 0 0 5 2                   Wild buckwheat 2 3 7 9 7 5 7 7 7 5 5 5 0 -- 3 3 3 2 3 3 3 2 2 4 0         2 3 3                                                                            Wild oat 0 0 7 7 7 7 7 7 2 6 0 0 1 5 3 4 5 2 7 8 8 7 6 7 2 3 7 4                COMPOUND                                                                        266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 2      84 285 286 287 288 289 290 291 292 293                                           PREEMERGENCE Rate (50 g/ha)                                                     Barley 0 4 2 0 9 7 8 0 2 9 0 0 0 0 0 0 1 9 8 2 4 9 8 2 2 4 0 1                  Barnyardgrass 5 4 1 0 1 4 8 2 1 9 0 0 0 0 1 2 2 9 9 9 9 9 9 6 2 9 0 5             Bedstraw 3 3 6 2 3 3 3 0 0 0 0 0 0 2 0 0 2 8 7 9 9 7 8 9 1 4 0 2                   Blackgrass 7 8 8 4 9 9 7 7 2 9 6 1 2 1 0 2 5 8 8 6 8 5 8 8 6 8 2 6         Cheatgrass 7 9 9 8 9 9 9 8 8 9 8 1 0 0 3 2 4 9 9 9 9 9 9 9 6 9 0 7                   Chickweed 3 -- 4 3 6 9 9 3 0 9 0 0 0 0 0 0 7 8 9 9 10 10 9 9 7 8 1        5                                                                                Cocklebur 2 6 1 0 1 1 2 2 0 7 0 0 0 4 0 0 0 8 7 8 7 7 7 7 -- 0 0 0                   Corn 6 7 6 1 9 8 8 2 2 9 0 0 0 0 2 7 2 9 9 6 6 9 9 9 2 8 0 2                     Cotton 7 8 6 0 8 8 5 2 4 9 0 -- 0 0 0 0 0 9 9 9 9 9 8 2 0 2 0 1             Crabgrass 0 2 2 0 9 9 9 4 0 9 2 0 0 0 0 0 0 9 9 9 9 9 9 9 7 9 2 2                 Giant foxtail 5 3 2 0 2 8 9 2 0 9 1 0 0 2 1 0 0 9 9 10 9 9 8 8 4 9         2 7                                                                              Lambsquarters 5 9 8 -- 9 9 10 0 0 9 0 0 0 0 5 -- 9 -- 9 9 -- 9 9 9 8 9         3 8                                                                              Morningglory 4 8 9 0 5 7 2 2 0 8 0 0 0 0 2 3 0 9 7 7 9 9 9 2 0 2 0 0               Nutsedge 0 5 0 0 10 9 6 0 0 9 0 0 0 0 0 0 0 9 6 4 5 9 9 10 3 8 0 0             Rape 7 5 8 3 8 8 5 1 1 8 1 0 0 2 0 0 4 9 9 9 9 9 9 2 6 9 2 2                  Rice 8 8 8 6 9 9 9 9 8 9 0 0 0 0 0 0 1 9 7 7 8 9 8 7 0 7 0 4                    Sorghum 9 8 8 4 9 8 8 4 3 9 0 0 0 0 2 0 0 9 8 9 8 8 9 9 0 8 0 3                         Soybean 3 7 6 0 6 7 5 0 1 6 0 0 0 0 1 0 2 9 8 6 7 7 4 3 1 6 0 1         Sugar beet 2 7 8 1 9 9 7 1 1 9 2 0 0 2 0 0 5 9 9 9 9 9 9 9 2 8 3 4                   Velvetleaf 4 7 0 0 1 1 0 1 0 1 0 0 0 0 0 0 0 8 8 9 9 5 9 0 0 1 0 0         Wheat 2 5 2 0 7 8 8 4 2 8 2 0 0 0 0 0 0 8 8 3 7 8 6 5 4 6 0 2                   Wild buckwheat 0 5 5 2 -- 8 5 2 0 9 -- -- -- -- -- -- -- 5 5 7 3 2 6 3         5 8 0 2                                                                          Wild oat 3 7 8 2 8 8 8 3 2 8 2 0 0 0 0 0 2 8 7 3 8 6 6 2 4 5 0 1                COMPOUND                                                                        294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 3      12 313 314 315 316 317 318 319 320 321                                           PREEMERGENCE Rate (50 g/ha)                                                     Barley 0 0 0 0 0 0 2 3 7 0 0 7 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0                  Barnyardgrass 0 0 0 0 0 0 9 6 9 2 0 8 6 1 1 0 0 4 0 0 0 0 0 0 0 0 0 0             Bedstraw 2 0 2 0 3 0 0 0 2 0 3 0 0 2 2 0 2 0 3 2 0 0 2 4 0 1 0 0                   Blackgrass 0 7 3 3 3 4 8 7 7 5 0 7 4 7 5 5 1 3 7 1 2 0 0 0 0 0 0 0         Cheatgrass 0 2 5 0 2 2 8 8 8 2 0 9 7 7 2 3 0 0 5 0 2 0 0 0 0 0 0 0                   Chickweed 8 8 8 7 2 0 7 7 9 0 3 9 3 0 1 3 3 -- 0 0 0 0 5 0 0 0 0 0         Cocklebur 0 0 0 0 0 0 -- -- -- -- -- -- -- 0 3 3 6 3 5 3 0 0 0 0 2 2 0          Corn 0 0 0 0 0 0 9 8 9 1 2 9 8 5 4 0 0 0 4 0 2 0 0 0 0 0 0 0                    Cotton 0 0 0 0 0 0 5 6 9 0 0 5 1 0 2 0 3 6 5 4 6 0 0 0 0 0 0 0                  Crabgrass 0 6 0 0 0 0 7 9 9 7 0 9 6 2 4 0 1 2 2 4 0 0 0 0 0 0 0 0                     Giant foxtail 0 1 0 0 0 0 9 8 9 4 2 9 3 6 2 0 2 4 5 4 0 0 0 0 0 0        0 0                                                                              Lambsquarters 2 7 9 10 5 4 9 10 9 5 0 10 8 7 5 9 3 9 9 5 10 0 3 2 3 0 0         Morningglory 0 0 0 0 0 0 0 7 8 2 1 8 1 2 2 1 4 5 3 0 0 0 0 0 2 0 0 0               Nutsedge 0 0 0 0 0 0 0 8 9 0 0 9 0 9 0 8 0 2 3 0 0 0 0 0 0 0 0 0                 Rape 0 3 3 2 2 0 3 8 7 0 0 2 0 7 8 5 7 5 7 0 0 0 0 0 0 0 0 0                       Rice 0 0 0 0 0 0 8 8 9 0 0 9 7 9 0 2 0 2 0 0 0 0 0 0 0 0 0 0                 Sorghum 0 0 0 0 0 0 8 8 9 0 2 9 5 8 0 0 0 2 0 0 0 0 0 0 0 0 0 0                 Soybean 0 3 0 0 0 0 2 7 8 2 0 5 1 2 3 2 7 4 3 0 0 0 0 0 0 0 0 0                 Sugar beet 2 2 2 1 1 2 9 9 9 0 0 6 3 3 5 5 7 7 6 0 0 0 0 0 0 0 0 0           Velvetleaf 0 0 0 0 0 0 0 3 7 2 1 2 0 6 7 6 6 3 6 0 0 0 0 0 0 1 0 0                 Wheat 0 0 0 0 0 0 6 7 8 2 0 7 2 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0                     Wild buckwheat 0 3 0 0 0 3 0 0 4 2 0 0 0 -- -- -- -- -- -- -- --         -- -- -- 0 -- -- 0                                                               Wild oat 3 2 2 0 0 0 6 6 8 0 0 7 4 3 2 0 0 3 2 0 0 0 0 0 0 0 0 0                COMPOUND                                                                        322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 3      40 341 342 1 2 3 4 5 6 7                                                         PREEMERGENCE Rate (50 g/ha) Rate (10 g/ha)                                      Barley 8 9 8 2 0 5 0 2 0 0 0 0 0 0 0 0 8 9 2 2 7 2 2 4 2 3 0 0                  Barnyardgrass 2 4 7 2 0 9 2 2 0 0 0 0 0 0 0 0 7 8 1 1 7 0 5 3 3 2 0 0             Bedstraw 9 9 9 1 5 8 0 3 0 0 0 0 2 0 0 0 5 1 0 0 2 4 6 0 3 7 9 0                   Blackgrass 8 9 9 7 6 9 3 7 0 0 0 0 0 0 0 0 7 7 7 4 6 2 4 4 3 5 2 0         Cheatgrass 9 9 9 8 7 9 7 9 0 0 0 0 0 0 0 0 9 9 9 6 8 3 5 5 2 9 4 1                   Chickweed 9 9 9 8 7 9 5 7 -- -- 0 0 0 -- 0 0 9 9 -- 0 10 2 9 9 0 5        5 0                                                                              Cocklebur 5 2 7 0 2 2 0 1 0 0 0 0 0 0 0 0 6 7 2 0 6 0 0 0 0 2 7 --                   Corn 9 9 9 9 2 9 2 8 0 0 0 0 0 0 0 0 9 9 3 6 9 2 4 1 2 8 4 0                     Cotton 8 9 9 5 0 8 4 3 0 0 0 0 0 0 0 0 7 8 1 0 5 0 0 2 2 3 0 0               Crabgrass 8 9 9 5 0 9 5 4 0 0 0 0 0 0 0 0 9 9 3 4 9 3 3 2 2 0 2 0               Giant foxtail 8 9 9 2 0 9 2 2 0 0 0 0 0 0 0 0 9 9 5 3 9 2 3 1 0 0 --         Lambsquarters 9 9 9 8 -- 9 5 7 0 0 0 2 2 0 0 0 10 9 0 0 10 6 8 7 0 6 0          Morningglory 3 8 8 3 1 9 1 3 0 0 0 0 0 0 0 0 7 6 3 0 9 0 2 6 4 8 0 0               Nutsedge 8 9 9 3 0 8 0 0 0 0 0 0 0 0 0 0 7 10 0 4 9 3 2 0 2 0 7 0               Rape 9 9 9 2 2 9 0 0 0 0 0 0 0 0 0 0 9 9 2 2 9 1 2 8 7 8 0 0                         Rice 9 9 9 10 8 9 5 7 0 0 0 0 0 0 0 0 9 10 9 7 10 2 2 8 8 8 7 0         Sorghum 9 9 9 7 0 9 3 4 0 0 0 0 0 0 0 0 8 9 2 0 9 2 2 0 4 3 2 0                         Soybean 9 9 9 5 2 8 1 7 0 0 0 0 0 0 0 0 9 9 2 0 6 0 3 4 2 4 2 0         Sugar beet 9 9 9 7 8 9 2 2 0 0 0 0 0 0 0 0 9 9 1 3 10 5 7 4 6 3 1 0                 Velvetleaf 7 8 9 1 0 8 0 0 0 0 0 0 0 0 0 0 5 7 0 0 6 3 4 3 2 3 0 0           Wheat 8 9 9 8 0 6 0 2 0 0 0 0 0 0 0 0 8 9 8 3 7 2 7 3 2 2 0 0                  Wild buckwheat -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- 2 5 3 2 3 2 0                                                              Wild oat 8 9 9 8 4 6 2 8 0 0 0 0 0 0 0 0 8 7 8 2 5 3 4 5 0 3 2 1                COMPOUND                                                                        8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31          32 33 34 35                                                                      PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 3 0 0 4 0 0 0 0 0 2                  Barnyardgrass 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 8 7 3 9 8 4 2 0 0 0 1           Bedstraw 0 0 0 0 0 0 0 0 2 0 0 2 8 -- 0 -- -- 5 9 2 0 5 4 0 2 0 0 0               Blackgrass 1 0 2 3 0 2 2 1 0 0 0 0 2 0 0 0 0 8 8 8 9 5 2 3 0 0 0 4             Cheatgrass 1 0 0 2 2 0 0 0 0 0 0 0 2 0 0 0 0 9 9 8 8 9 7 3 0 0 3 9               Chickweed 8 0 0 9 -- 0 5 9 -- -- 0 5 4 5 0 2 0 9 9 8 7 8 9 0 0 0 2 6         Cocklebur 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 0 -- 0 -- -- -- -- -- -- -- --          -- -- --                                                                         Corn 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 8 9 7 8 9 8 2 1 0 2 8                   Cotton 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 2 7 5 0 2 3 0 0 0 0 0                         Crabgrass 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 6 7 7 7 8 9 5 0 0         0 2                                                                              Giant foxtail 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 7 6 5 7 7 9 4 0 0 0 2           Lambsquarters 0 0 0 5 5 5 0 0 0 2 0 5 0 0 0 0 0 7 6 9 9 8 8 9 2 0 0 7           Morningglory 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 3 2 0 3 6 0 1 0 0 0 0           Nutsedge 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- -- 3 0 0 0 0 3 7 0 -- 0 0 0               Rape 0 0 0 0 0 1 0 0 0 2 0 0 0 0 0 0 0 3 9 4 8 5 0 0 0 0 2 0                         Rice 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 9 7 3 9 9 9 4 0 0 3 8             Sorghum 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 6 6 3 8 4 2 2 0 0 0 5                   Soybean 0 2 0 3 0 0 0 0 0 0 0 0 0 0 0 -- 0 3 6 5 5 8 7 2 0 0 1 2             Sugar beet 0 2 2 0 0 1 3 0 0 2 0 0 0 0 0 0 0 8 8 8 6 8 8 2 3 2 4 8               Velvetleaf 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0 1 1 2 1 3 2 0 0 0 0 0           Wheat 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 2 2 0 2 0 0 0 0 0 0                  Wild buckwheat 0 0 0 0 0 0 0 0 0 0 0 2 2 0 0 0 0 3 2 2 0 2 0 0 0 3 0 2           Wild oat 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7 8 3 2 3 0 0 0 0 0                2                                                                                COMPOUND                                                                        36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 6      0 61 62 63                                                                       PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 2 0 3 0 0 3 0 2 2 2 0 0 1                  Barnyardgrass 3 0 1 0 0 0 0 0 0 0 0 0 0 0 9 9 5 9 2 7 3 9 8 1 2 2 0 9             Bedstraw 0 0 2 0 0 0 0 0 0 0 0 0 0 0 1 8 0 5 8 2 4 7 2 9 8 0 -- 0                 Blackgrass 0 0 0 0 2 0 1 2 0 2 1 2 0 1 7 6 0 8 2 0 3 8 4 6 3 2 2 4           Cheatgrass 6 0 0 2 3 2 2 0 0 3 2 2 0 2 7 7 0 6 0 0 4 8 6 5 2 2 7 7                 Chickweed 6 0 3 0 0 -- 0 0 0 5 0 0 0 -- -- 9 3 9 10 10 0 9 8 9 10 7        0 2                                                                              Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- 4 9 7 5 9 4 0 2 1 8        7 0 -- 0                                                                         Corn 6 0 0 0 0 0 0 0 0 0 0 0 0 0 5 7 0 8 5 0 1 9 7 8 0 0 0 1                    Cotton 3 0 0 0 0 0 0 0 0 0 0 0 0 0 6 9 0 8 3 0 0 6 2 7 7 0 0 0                  Crabgrass 7 0 0 0 0 0 0 0 0 0 0 0 0 0 4 9 3 5 2 0 0 1 0 4 1 0 0 2                     Giant foxtail 6 0 0 0 0 0 0 0 0 0 0 0 0 0 6 7 2 7 0 0 0 7 2 0 2 0        0 6                                                                              Lambsquarters 9 0 0 9 -- 3 0 0 0 0 0 0 0 0 7 9 7 9 8 -- 6 8 5 9 9 8 5 8         Morningglory 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 9 2 3 9 3 0 0 0 8 7 0 0 0               Nutsedge 0 0 0 -- 0 0 0 0 0 0 0 0 0 0 9 9 -- 5 0 0 0 -- 5 -- 10 0 0         9                                                                                Rape 2 0 2 0 0 0 0 0 0 0 0 0 0 0 7 9 2 8 8 8 5 9 8 8 8 7 0 5                    Rice 8 2 2 0 0 2 0 0 0 0 0 0 0 0 9 10 8 9 9 7 5 8 8 8 8 7 5 7                   Sorghum 7 0 0 0 0 0 0 0 0 0 0 0 0 0 5 5 2 2 2 1 1 6 1 2 3 1 2 6                         Soybean 1 0 0 0 0 0 0 0 0 0 0 0 0 0 1 8 1 7 7 0 0 5 3 8 7 0 0 2         Sugar beet 9 0 2 2 0 0 2 0 0 0 0 0 0 0 7 9 5 8 9 7 6 7 7 9 8 5 4 6                   Velvetleaf 1 0 0 0 0 0 0 0 0 0 0 0 0 0 2 8 2 6 0 0 0 5 1 8 3 0 0 3         Wheat 2 0 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 4 0 0 2 2 0 2 2 0 0 3                   Wild buckwheat 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7 0 3 7 0 2 4 2 8 8 3 0 0           Wild oat 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 5 0 5 2 0 2 3 3 4 4 0 0                1                                                                                COMPOUND                                                                        64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 8      8 89 90 91                                                                       PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 2 0 1 0 0 0 0 0 0 0                  Barnyardgrass 9 0 0 5 2 0 0 0 0 0 0 0 0 0 2 0 0 2 6 7 2 3 3 2 7 9 0 0             Bedstraw 0 0 0 0 2 0 6 2 0 0 0 0 0 0 2 0 0 0 4 7 2 0 1 0 3 3 0 0                   Blackgrass 5 3 0 2 2 0 0 0 0 0 0 0 0 0 0 0 0 5 7 8 3 0 5 2 4 5 2 0         Cheatgrass 7 5 2 6 5 4 2 0 0 0 4 0 0 8 7 0 0 9 9 9 0 0 9 1 8 7 2 0                   Chickweed 8 0 0 0 8 7 7 6 0 0 2 0 0 0 0 0 0 2 9 7 3 0 7 0 5 3 9 0           Cocklebur -- 0 0 0 0 -- 0 0 0 0 1 -- 0 -- -- 0 0 -- -- -- -- -- -- --         -- -- -- --                                                                      Corn 7 0 0 0 3 0 0 0 0 0 0 0 0 0 3 0 0 0 0 6 9 5 2 0 2 3 6 6                    Cotton 4 0 0 0 6 0 1 0 0 0 0 0 0 0 0 0 0 4 2 3 2 0 3 0 2 0 -- 0                         Crabgrass 3 0 0 0 2 0 0 0 0 0 0 0 0 0 2 0 0 3 3 3 3 1 0 0 2 0 0         Giant foxtail 8 0 0 0 3 0 0 0 0 0 0 0 0 0 4 0 0 3 6 5 1 2 2 0 2 2 0 0             Lambsquarters 8 5 2 5 -- 3 9 -- -- 2 5 0 0 0 8 0 0 10 10 9 4 8 9 8 4         9 9 9                                                                            Morningglory 3 0 0 0 0 0 3 0 0 0 2 0 0 0 2 0 0 3 2 7 2 0 4 0 1 2 1 0               Nutsedge 9 0 -- 0 0 -- 0 0 -- 0 -- 0 -- -- 7 -- 0 0 5 10 0 0 5 0 6 9        10 0                                                                             Rape 8 0 0 0 6 0 1 2 0 0 0 0 0 0 1 0 0 1 8 8 1 0 5 0 6 6 0 0                    Rice 8 8 4 8 7 5 2 0 0 0 1 0 0 2 0 0 0 5 7 7 7 5 5 0 5 8 2 2                    Sorghum 6 0 0 3 2 0 0 0 0 0 0 0 0 1 0 0 0 7 9 9 6 2 8 0 7 7 6 3                         Soybean 5 0 0 0 2 0 5 3 0 2 1 0 0 4 1 0 0 2 6 5 3 3 4 0 1 2 1 1         Sugar beet 9 1 0 5 7 7 9 7 0 2 0 0 0 3 2 0 0 7 9 9 3 6 7 3 5 5 3 3                   Velvetleaf 4 0 0 0 2 0 0 0 0 0 1 0 0 0 0 0 0 2 2 8 2 0 2 0 2 4 0 0         Wheat 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 4 2 5 0 0 0 0 0 0 0                   Wild buckwheat 0 2 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 9 -- 8 -- -- -- 10 3        -- 2                                                                             Wild oat 0 0 0 0 1 0 0 0 0 0 0 0 0 0 2 0 0 4 3 2 3 0 0 0 0 0 0 0                COMPOUND                                                                        92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 1      12 113 114 115 116 117 118 119                                                   PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 -- 0 0 0 0 0 0 0 0 1 3 0 0 0 3 0 8 6 2 0 0 0 0 0 0 0 4                         Barnyardgrass 2 0 1 0 0 0 1 0 0 0 1 5 1 0 0 7 6 8 8 7 4 2 8 1 3        2 0 9                                                                            Bedstraw 0 -- 0 0 0 0 0 0 0 0 0 0 0 0 0 7 8 4 4 0 1 5 7 2 7 5 0 2                     Blackgrass 2 -- 2 0 0 4 3 0 0 0 1 4 0 0 0 2 3 7 8 4 2 4 6 5 3 2 0        7                                                                                Cheatgrass 3 -- 2 0 0 0 0 0 0 0 3 6 0 0 0 7 8 9 8 7 8 6 7 7 7 3 2 7                 Chickweed 0 -- 8 9 5 9 7 6 8 0 2 4 0 0 0 9 9 9 7 5 9 0 5 3 5 9 2 9           Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- 9 -- --                                                           Corn 0 0 0 0 1 0 1 0 2 0 0 0 0 0 0 5 6 5 7 3 3 1 8 5 5 0 0 8                    Cotton 0 0 0 2 2 0 2 0 2 0 0 1 0 0 0 8 7 7 8 5 5 0 3 0 8 8 0 8                  Crabgrass 0 0 2 0 0 0 0 0 0 0 1 1 0 0 0 7 4 7 8 3 4 0 0 0 5 2 0 9                     Giant foxtail 0 0 0 0 0 0 0 0 0 0 1 2 0 0 0 0 3 7 7 2 0 0 2 0 0 0        0 8                                                                              Lambsquarters 5 -- 1 9 0 3 7 5 5 0 7 6 0 0 0 9 10 9 9 9 8 -- 9 10 9 10         7 10                                                                             Morningglory 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 8 8 3 6 8 5 0 1 0 9 9 1 8               Nutsedge 0 -- 0 0 0 0 0 0 0 0 0 0 8 0 0 5 10 9 10 -- 10 0 0 3 6 8 0         2                                                                                Rape 0 -- 0 1 -- 0 0 3 1 0 2 0 0 0 0 9 8 9 8 8 7 3 7 0 7 6 0 9                  Rice 0 0 0 0 1 0 0 0 2 0 2 5 0 0 0 8 8 10 8 5 7 1 7 3 7 5 0 9                   Sorghum 2 0 0 0 1 0 0 0 1 0 1 2 0 0 0 7 2 9 8 3 3 0 4 6 4 1 0 8                         Soybean 0 0 0 0 2 0 1 0 0 0 0 0 0 0 0 7 6 3 7 1 1 0 2 2 4 3 0 8         Sugar beet 0 -- 0 7 2 2 3 7 5 0 5 7 0 0 0 9 8 8 9 7 8 2 5 5 8 8 2 9                 Velvetleaf 0 0 0 0 0 0 0 0 0 0 0 1 1 0 0 8 5 7 8 3 6 0 3 2 7 2 0 7           Wheat 0 -- 2 0 0 0 0 0 0 0 0 6 0 0 0 5 2 7 7 2 0 0 0 0 0 0 0 7                         Wild buckwheat -- -- 0 0 0 0 0 3 0 0 5 1 0 0 0 3 5 2 4 0 2 0 1         0 3 3 0 3                                                                        Wild oat 0 -- 2 0 0 0 2 0 0 0 1 2 0 0 0 6 5 6 5 2 2 0 2 2 0 0 0                5                                                                                COMPOUND                                                                        120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 1      38 139 140 141 142 143 144 145 146 147                                           PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 2 2 0 1 1 2 0 0 0 0 0 0 0 0 0 0 2 2 0 0 2 4 3 2 0 0 1                  Barnyardgrass 4 5 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 4 7 1 0 4 2             Bedstraw 1 7 2 0 0 2 0 0 0 0 0 0 5 2 3 4 0 3 2 2 0 0 7 5 7 5 7 2                   Blackgrass 5 4 2 5 6 -- 4 0 2 0 2 2 2 3 2 3 3 2 6 2 5 2 6 7 7 2 5         3                                                                                Cheatgrass 7 7 7 4 7 4 2 0 0 0 2 3 2 0 0 7 7 7 8 8 7 7 9 8 2 0 8 8                   Chickweed 8 8 9 4 8 8 8 0 0 0 3 8 5 3 0 4 -- 6 5 0 7 0 7 7 7 -- 7         --                                                                               Cocklebur -- -- -- 0 3 1 3 2 0 0 0 0 0 3 0 0 0 0 2 0 0 2 5 7 2 1 1 1               Corn 7 7 9 0 0 0 2 0 0 0 0 0 3 0 0 1 0 0 0 0 0 0 6 8 6 2 1 0                         Cotton 3 8 6 2 3 0 1 0 0 0 0 0 0 0 0 0 0 0 2 0 0 2 5 6 2 -- 2 0         Crabgrass 6 8 2 0 0 0 3 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 5 6 5 0 0 0                     Giant foxtail 2 2 1 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6 8 3 0        2 0                                                                              Lambsquarters 9 9 9 5 -- 5 2 -- 0 5 9 7 9 5 0 5 5 5 6 8 7 5 8 8 0 0 7 7         Morningglory 9 9 8 0 0 0 2 0 0 0 0 0 0 0 0 0 1 0 1 2 0 0 3 6 2 0 2 0               Nutsedge 8 8 3 0 0 0 0 0 0 0 0 2 4 0 0 0 0 0 0 0 0 4 8 9 6 0 0 4                 Rape 8 8 3 1 7 3 5 0 2 0 7 4 4 2 3 0 0 0 0 0 0 2 7 9 5 0 7 1                       Rice 9 8 9 2 2 0 4 0 0 0 0 0 0 0 0 3 0 2 7 0 0 7 9 9 9 8 10 9               Sorghum 5 7 9 0 0 0 2 0 0 0 0 0 0 0 0 4 0 1 0 0 0 2 6 5 5 2 4 0                   Soybean 3 7 7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 2 8 9 6 3 5 5               Sugar beet 8 8 8 8 5 7 8 7 4 2 5 4 8 7 2 7 7 7 7 7 7 3 9 8 3 0 8 6             Velvetleaf 6 5 2 0 0 0 0 0 0 0 0 5 0 0 0 0 2 0 0 0 2 0 3 6 2 0 2 0               Wheat 0 3 0 0 3 0 0 0 0 0 0 0 0 0 0 2 2 3 2 0 2 4 7 5 3 0 2 2                       Wild buckwheat 1 5 3 0 5 2 0 2 0 3 2 4 3 5 3 -- -- 0 -- -- -- --        -- -- -- -- -- --                                                                Wild oat 2 5 3 5 4 2 2 0 0 0 0 2 2 0 2 3 4 2 5 0 2 6 5 2 5 0 0 5                COMPOUND                                                                        148 149 150 151 152 165 166 167 168 169 170 171 172 173 174 175 176 177 1      78 179 180 181 182 183 184 185 186 187                                           PREEMERGENCE Rate (10 g/ha)                                                     Barley 1 5 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 1 0                  Barnyardgrass 4 5 0 0 0 0 0 5 0 0 0 0 1 0 3 0 0 0 0 0 0 2 9 5 2 5 4 1             Bedstraw 7 8 5 -- 7 9 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 7 2 0 8 2 0                 Blackgrass 4 5 0 2 7 9 4 5 3 0 0 3 5 5 0 2 0 1 1 0 2 0 7 8 2 7 7 3           Cheatgrass 8 10 8 2 8 10 7 7 5 2 3 2 0 2 2 3 2 0 0 0 3 0 8 7 7 8 10 7           Chickweed 8 8 7 4 7 10 9 9 10 8 7 0 2 3 0 1 2 0 0 0 4 0 5 5 5 5 -- 2             Cocklebur 0 1 1 1 0 -- 0 0 8 0 2 -- 0 0 0 0 0 0 0 0 0 0 2 7 0 6 6 0             Corn 4 5 2 2 1 0 4 0 0 0 0 0 3 2 2 2 0 0 0 0 0 3 9 9 1 8 6 8                  Cotton 0 7 0 0 0 0 0 0 0 0 0 0 2 2 1 0 0 0 0 0 0 0 -- 0 0 2 2 3                         Crabgrass 0 0 0 0 0 0 0 0 0 0 2 0 1 6 0 2 0 0 0 0 1 1 8 6 2 6 3        7                                                                                Giant foxtail 2 0 0 0 0 3 0 5 0 0 3 0 1 3 0 4 0 0 0 0 2 1 8 6 3 9 6 7             Lambsquarters 9 8 7 0 5 10 9 9 8 7 9 2 9 8 2 0 0 0 0 0 0 0 5 5 7 5 7          Morningglory 0 3 5 4 1 2 2 2 3 0 0 0 3 2 2 0 0 0 0 0 0 0 5 2 2 3 4 2               Nutsedge 9 7 0 0 0 0 0 0 10 0 -- 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0             Rape 7 8 1 0 5 9 0 0 0 0 0 0 0 2 1 0 0 0 0 0 0 0 3 3 4 3 5 0                  Rice 8 9 7 5 9 6 5 8 6 6 6 0 2 7 2 0 0 0 0 0 0 0 9 8 7 9 9 9                    Sorghum 2 3 0 0 2 0 0 0 0 0 0 0 2 4 3 2 0 0 0 0 1 0 7 3 0 2 1 2                         Soybean 8 6 4 5 2 0 2 1 0 0 0 0 3 4 2 2 0 0 0 0 0 0 6 7 3 5 8 8         Sugar beet 8 8 7 2 5 9 2 3 0 2 6 1 7 7 2 3 0 0 0 0 0 0 2 2 3 2 3 3                   Velvetleaf 0 3 0 0 0 0 3 0 1 0 1 0 0 0 1 0 0 0 0 0 0 0 5 0 2 3 2 3         Wheat 6 4 3 0 0 5 2 0 0 0 0 0 0 4 0 3 0 0 0 0 0 0 7 3 0 0 2 6                   Wild buckwheat -- -- -- -- -- 10 2 2 0 0 0 0 -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- --                                                             Wild oat 2 2 0 0 0 9 0 0 0 0 0 0 2 2 0 2 0 0 0 0 0 0 6 1 2 0 6 6                COMPOUND                                                                        188 189 190 191 192 203 204 205 206 207 208 209 210 211 212 213 214 215 2      16 217 218 219 220 221 222 223 224 226                                           PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 0 0 0 2 4 9 2 1 6 0 0 0 1 1 1 0 0 1 1 0 0 0 0 0 0 0 0                  Barnyardgrass 0 0 0 0 0 2 2 9 4 1 7 0 2 6 3 4 0 3 0 1 2 0 0 0 0 0 0 0             Bedstraw 0 2 2 0 0 0 0 7 7 7 3 0 1 2 3 5 2 2 0 2 1 2 0 0 0 0 1 0                   Blackgrass 2 3 6 0 5 5 3 7 7 7 7 0 3 5 8 2 3 2 0 4 2 0 0 0 0 0 0 0         Cheatgrass 5 5 2 0 0 8 7 9 8 7 8 0 6 8 8 9 8 5 2 5 7 7 2 0 0 0 0 0                   Chickweed 0 3 0 0 5 5 7 9 8 7 5 0 7 9 -- 9 9 9 4 5 9 7 0 0 0 7 5 0         Cocklebur 0 0 0 0 0 -- -- 10 10 8 2 0 0 -- 0 0 -- -- -- -- -- 0 0 -- --        -- 0 0                                                                           Corn 2 0 0 0 6 5 9 7 8 3 8 0 0 8 6 9 2 0 0 0 0 0 0 0 0 0 0 0                    Cotton 0 0 2 0 0 0 1 5 3 2 4 0 0 3 2 0 7 0 0 0 0 0 0 0 0 0 0 0                  Crabgrass 2 3 6 0 4 5 9 9 8 4 6 0 2 6 2 6 1 0 0 2 2 0 0 0 0 0 2 0                     Giant foxtail 2 2 6 0 6 0 8 9 7 2 8 0 2 8 4 2 1 0 0 2 2 0 0 0 0 0        2 0                                                                              Lambsquarters 2 0 5 0 2 5 9 -- 9 5 5 0 3 9 8 9 9 9 6 3 9 2 0 -- 0 7 3          --                                                                               Morningglory 0 0 0 0 0 2 4 7 7 2 6 0 0 0 2 3 2 0 0 0 0 0 0 0 0 0 0 0               Nutsedge 0 0 0 0 0 5 7 10 -- 0 8 0 0 0 0 0 3 0 0 2 0 0 0 0 0 0 0 0             Rape 0 0 0 0 0 0 3 8 1 1 9 0 0 7 5 3 6 1 0 2 1 0 0 0 0 2 1 0                  Rice 5 2 4 0 4 8 9 8 9 8 9 0 0 6 5 9 3 2 0 0 0 0 0 0 0 0 0 3                    Sorghum 0 0 0 0 0 2 2 8 6 3 9 0 2 2 8 2 0 0 0 0 0 0 0 0 0 0 0 0                         Soybean 0 1 0 0 3 4 4 5 7 5 4 0 2 6 2 7 7 0 0 0 0 0 0 0 0 0 2 2         Sugar beet 0 2 2 0 0 2 5 8 6 1 7 0 2 3 2 9 8 5 2 2 2 0 0 0 0 0 3 0                   Velvetleaf 0 0 0 0 0 0 4 6 5 2 2 0 0 5 1 7 0 3 0 1 0 0 0 0 0 0 2 0         Wheat 0 0 0 0 0 4 8 8 7 6 6 0 2 8 6 1 1 0 0 0 1 0 0 0 0 0 0 0                   Wild buckwheat -- -- -- -- -- 3 0 5 0 3 2 0 2 1 3 2 4 2 0 7 1 1 0 0 0 3        0 0                                                                              Wild oat 0 1 1 0 3 5 5 8 7 7 5 0 2 6 3 2 2 2 2 3 2 2 0 0 0 0 0 0                COMPOUND                                                                        226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 2      44 245 246 247 248 249 250 251 252 253                                           PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 0 0 -- 0 0 0 0 0 0 0 0 0 0 5 5 6 2 2 7 0 0 0 0 0 0 0 1                         Barnyardgrass 0 0 0 1 0 1 0 0 0 0 0 0 0 0 7 8 6 6 5 9 2 2 0 0 0        3 0 2                                                                            Bedstraw 0 0 0 -- 0 0 0 2 2 0 0 0 2 0 2 3 4 7 5 8 5 0 2 0 0 7 4 2                     Blackgrass 0 0 3 -- 2 0 0 2 0 0 0 0 2 3 7 7 5 9 5 7 0 0 2 0 1 7 5        5                                                                                Cheatgrass 0 0 7 -- 7 7 7 4 0 0 0 0 0 0 8 8 7 7 6 8 0 2 0 0 2 5 6 6                 Chickweed 4 0 0 -- 2 3 0 0 0 0 0 0 0 0 5 9 9 9 9 8 2 5 8 3 3 9 4 9           Cocklebur -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- 0 2 0 0                                                              Corn 0 0 0 2 1 6 2 0 0 0 0 0 0 0 9 9 6 9 8 9 0 0 2 0 0 3 5 7                    Cotton 0 0 0 0 -- 2 0 -- 0 0 0 0 0 0 4 2 5 2 6 8 0 0 2 0 0 3 4 0                       Crabgrass 0 0 2 0 0 4 0 0 0 0 0 0 0 0 9 9 9 9 9 9 7 6 2 2 0 5 0          Giant foxtail 0 0 1 1 0 2 0 0 0 0 0 0 0 0 7 9 8 6 6 9 2 6 2 2 0 5 2 0             Lambsquarters -- -- 4 -- 3 3 2 0 0 0 0 0 0 0 5 9 9 9 9 9 0 5 7 0 -- 9        5 9                                                                              Morningglory 0 0 0 2 1 0 1 1 0 0 1 0 0 0 6 4 5 5 3 6 0 0 2 0 0 0 0 2               Nutsedge 0 0 -- 0 0 5 0 1 0 0 -- 0 -- 0 5 9 7 8 2 9 6 -- 0 -- 0 0 0          Rape 0 0 0 -- 0 0 0 0 0 0 0 0 0 0 4 5 6 7 6 7 0 0 2 0 0 7 4 5                   Rice 0 0 0 1 3 4 3 0 0 0 0 0 0 0 9 9 8 9 7 9 2 2 2 0 0 3 2 5                    Sorghum 0 0 2 2 1 4 2 0 0 0 0 0 0 0 9 8 3 8 7 9 0 0 0 0 0 4 0 4                         Soybean 0 0 0 3 2 6 2 0 0 0 0 0 0 0 7 5 4 5 3 3 0 2 2 0 0 2 2 3         Sugar beet 0 0 0 -- 0 0 0 0 1 0 0 0 0 0 4 5 8 7 8 7 0 5 8 7 0 7 3 5                 Velvetleaf 0 0 0 1 1 1 0 0 0 0 0 0 0 0 4 2 6 7 6 5 2 2 0 0 0 3 0 4           Wheat 0 0 0 -- 0 4 2 3 0 0 0 0 0 0 8 6 5 4 6 7 0 0 0 0 0 0 3 0                         Wild buckwheat 0 0 0 -- 0 2 0 0 2 0 0 0 0 0 3 2 7 3 3 7 3 -- 5         -- 0 -- 0 3                                                                      Wild oat 0 0 2 -- 2 2 4 2 0 0 0 0 0 0 6 6 6 3 6 6 0 0 0 0 0 2 2                1                                                                                COMPOUND                                                                        254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 2      72 273 274 275 276 277 278 279 280 281                                           PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 0 4 5 0 0 0 7 0 0 0 0 0 0 0 0 0 0 1 0 0 7 0 0 0 0 0 0                  Barnyardgrass 1 0 2 2 4 4 1 5 0 0 2 0 1 2 0 0 0 1 2 0 0 8 0 0 0 0 0 0             Bedstraw 0 3 7 6 5 2 0 3 0 0 2 0 0 0 0 0 0 1 2 0 0 2 0 0 0 0 0 0                   Blackgrass 5 2 5 3 7 5 1 7 0 0 0 0 6 3 3 0 7 5 5 2 2 8 0 0 0 0 0 1         Cheatgrass 6 0 8 8 8 7 7 8 0 0 5 6 7 8 9 5 9 8 8 7 5 8 0 0 0 0 0 0                   Chickweed 7 0 2 8 5 7 2 7 0 0 0 0 2 0 2 0 0 6 8 0 0 8 0 0 0 -- 0 0         Cocklebur 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -- 0                   Corn 2 0 7 5 8 7 2 8 2 0 2 2 0 5 1 0 1 0 2 1 2 8 0 0 0 0 0 0                     Cotton 1 0 0 2 5 0 -- 2 0 0 0 0 0 2 3 0 2 2 3 0 2 6 0 0 0 0 0 0             Crabgrass 0 0 7 6 5 6 0 5 0 0 0 0 0 0 0 0 5 4 8 2 0 9 0 0 0 0 0 0                 Giant foxtail 0 0 5 6 9 5 1 8 0 0 0 0 0 0 0 0 0 0 9 1 0 9 0 0 0 0 0         Lambsquarters -- 2 4 7 9 9 2 3 2 0 0 7 2 -- 5 3 -- 5 9 0 0 4 -- 0 -- 0         0 0                                                                              Morningglory 2 0 3 3 3 1 0 0 0 0 1 0 1 0 3 0 0 3 2 0 0 3 0 0 0 0 0 0               Nutsedge 0 0 9 0 3 0 0 8 0 0 0 0 0 0 0 0 8 0 0 0 0 10 0 0 0 0 0 0               Rape 3 2 5 5 7 3 0 3 0 0 0 0 0 1 1 0 0 0 0 0 0 2 0 0 0 0 0 0                         Rice 7 0 8 5 7 8 5 9 0 0 0 0 3 5 3 0 5 5 9 5 3 9 0 0 0 0 0 0               Sorghum 2 0 8 5 7 8 3 9 0 0 2 2 2 5 3 0 2 2 1 1 2 9 0 0 0 0 0 0                   Soybean 4 0 4 2 3 2 0 2 0 0 2 2 0 5 2 0 2 0 1 1 0 5 0 0 0 0 0 0               Sugar beet -- 0 2 5 3 2 0 3 0 0 0 0 0 3 1 0 0 -- 3 0 0 2 0 0 0 1 0 0         Velvetleaf 0 0 4 0 4 0 0 1 0 0 0 0 2 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0                   Wheat 0 0 6 7 6 4 2 5 0 0 0 0 0 3 0 0 4 3 0 2 0 7 0 0 0 0 0 0                   Wild buckwheat 2 2 2 0 0 2 0 3 0 0 0 0 0 0 0 0 5 6 0 0 0 0 -- --          -- -- -- --                                                                      Wild oat 2 0 7 4 6 4 3 5 0 0 3 0 0 3 5 0 5 3 3 2 2 6 0 0 0 0 0 0                COMPOUND                                                                        282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 3      00 301 302 303 304 305 306 307 308 309                                           PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 3 1 0 1 1 2 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0                  Barnyardgrass 0 0 2 0 3 2 0 0 0 0 0 0 0 0 0 0 0 0 1 3 3 0 0 3 2 0 0 0             Bedstraw 0 0 2 1 4 0 4 1 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 2                   Blackgrass 0 6 5 1 4 0 2 3 0 4 0 0 0 3 3 2 2 2 2 0 4 0 0 0 0 3 3 0         Cheatgrass 0 8 8 5 7 2 8 6 2 6 0 0 0 0 1 0 0 0 4 6 6 0 0 7 3 2 0 0                   Chickweed 0 8 9 8 8 9 8 7 0 4 0 0 2 2 2 2 -- 0 0 2 9 0 0 3 2 0 0 0         Cocklebur 0 4 5 4 6 6 5 0 0 0 0 0 0 0 0 0 0 0 -- -- -- -- -- -- -- 0 0          Corn 0 5 3 0 3 2 2 2 0 2 0 0 0 0 0 0 0 0 2 1 5 0 0 4 1 4 2 0                    Cotton 0 2 1 0 2 2 6 0 0 0 0 0 0 0 0 0 0 0 2 2 2 0 0 2 0 -- 0 0                         Crabgrass 0 5 4 5 8 8 5 3 0 4 0 0 0 2 0 0 0 0 5 2 5 0 0 7 3 0 0         Giant foxtail 0 2 3 3 3 3 5 3 0 5 0 0 0 0 0 0 0 0 6 2 8 1 0 8 2 0 0 0             Lambsquarters -- -- 9 9 3 9 8 7 5 6 0 0 0 2 4 10 4 3 3 9 9 0 0 5 5 2         3 3                                                                              Morningglory 0 3 3 1 5 3 5 -- 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 2 0 0 0 0             Nutsedge 0 2 0 -- 0 -- 8 0 0 8 0 0 0 0 0 0 0 0 0 0 8 0 0 0 0 0 0 0               Rape 0 8 8 6 8 9 6 0 1 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 2 0                         Rice 0 5 3 0 2 2 3 0 0 0 0 0 0 0 0 0 0 0 0 3 7 0 0 8 2 0 0 0               Sorghum 0 3 3 0 5 0 7 2 0 2 0 0 0 0 0 0 0 0 3 1 3 0 0 5 1 0 0 0                   Soybean 0 4 1 0 0 3 2 0 0 -- 0 0 0 0 0 0 0 0 1 3 2 0 0 2 0 0 1 0             Sugar beet 3 7 8 4 5 8 7 6 0 5 0 0 0 0 0 0 0 0 0 0 2 0 0 6 0 0 2 0               Velvetleaf 0 4 4 3 3 2 6 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 4 0 3             Wheat 0 3 2 0 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 2 5 0 0 0 0 0 0 0                         Wild buckwheat -- 4 5 1 0 0 2 2 2 2 0 0 0 2 0 0 2 0 0 0 0 0 0 0        2 -- 2 --                                                                        Wild oat 0 2 2 0 2 2 2 2 2 3 0 0 0 2 0 0 0 0 2 6 2 0 0 0 0 0 0 0                COMPOUND                                                                        310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 3      28 329 330 331 332 333 334 335 336 337                                           PREEMERGENCE Rate (10 g/ha)                                                     Barley 0 0 0 0 0 0 0 0 0 0 0 0 2 8 3 0 0 2 0 0 0 0 0 0 0 0 0 0                  Barnyardgrass 0 0 0 0 0 0 0 0 0 0 0 0 1 1 3 0 0 3 1 1 0 0 0 0 0 0 0 0             Bedstraw 0 0 0 0 0 0 0 2 0 0 0 0 1 8 5 0 0 5 0 0 0 0 0 0 0 0 0 0                   Blackgrass 0 0 1 1 1 0 0 0 0 0 0 0 7 8 7 5 0 5 0 0 0 0 0 0 0 0 0 0         Cheatgrass 0 0 3 0 0 0 0 0 0 0 0 0 9 9 9 7 0 7 0 3 0 0 0 0 0 0 0 0                   Chickweed 0 0 0 0 0 0 0 0 0 0 0 0 9 9 9 8 2 9 0 2 0 -- -- -- -- 0         0 0                                                                              Cocklebur -- 3 2 -- 0 0 0 0 0 0 0 0 0 0 1 0 0 1 0 0 0 0 0 0 0 0 0 0                 Corn 0 0 0 0 0 0 0 0 0 0 0 0 9 8 9 7 0 9 2 2 0 0 0 0 0 0 0 0                       Cotton 2 2 -- 0 0 0 0 0 0 0 0 0 2 5 8 1 0 5 2 2 0 0 0 0 0 0 0 0           Crabgrass 0 0 0 0 0 0 0 0 0 0 0 0 5 7 6 0 0 5 2 0 0 0 0 0 0 0 0 0                   Giant foxtail 0 2 2 0 0 0 0 0 0 0 0 0 3 8 8 0 0 6 0 0 0 0 0 0 0 0         0 0                                                                              Lambsquarters 5 0 5 -- 10 0 0 0 0 0 0 0 9 9 9 3 2 9 0 3 0 0 0 0 0 0 0 0         Morningglory 3 5 3 0 0 0 0 0 0 0 0 0 2 5 3 1 1 2 0 0 0 0 0 0 0 0 0 0               Nutsedge 0 0 0 0 0 0 0 0 0 0 0 0 5 3 9 -- 0 7 0 0 0 0 0 0 0 0 0 0               Rape 0 0 0 0 0 0 0 0 0 0 0 0 7 9 9 0 0 9 0 0 0 0 0 0 0 0 0 0                         Rice 0 0 0 0 0 0 0 0 0 0 0 0 9 9 9 8 3 9 0 3 0 0 0 0 0 0 0 0               Sorghum 0 0 0 0 0 0 0 0 0 0 0 0 8 8 8 3 0 8 0 2 0 0 0 0 0 0 0 0                   Soybean 2 3 2 0 0 0 0 0 0 0 0 0 7 9 9 2 0 4 0 2 0 0 0 0 0 0 0 0               Sugar beet 2 0 3 0 0 0 0 0 0 0 0 0 9 8 8 5 3 9 0 0 0 0 0 0 0 0 0 0             Velvetleaf 3 2 3 0 0 0 0 0 0 0 0 0 5 3 8 0 0 1 0 0 0 0 0 0 0 0 0 0               Wheat 0 0 0 0 0 0 0 0 0 0 0 0 5 8 6 2 0 0 0 0 0 0 0 0 0 0 0 0                       Wild buckwheat -- -- -- -- -- -- 0 -- -- -- -- 0 -- -- -- -- --         -- -- -- -- -- -- -- -- -- -- --                                                 Wild oat 0 0 0 0 0 0 0 0 0 0 0 0 7 8 6 5 2 2 0 2 0 0 0 0 0 0 0 0                COMPOUND                                                                        338 339 340 341 342                                                             PREEMERGENCE Rate (10 g/ha)                                                     Barley 5 3 0 0 2                                                                Barnyardgrass 2 4 0 0 0                                                         Bedstraw 2 0 0 0 0                                                              Blackgrass 0 5 5 2 0                                                            Cheatgrass 9 9 7 3 8                                                            Chickweed 9 9 0 0 7                                                             Cocklebur 2 6 0 0 2                                                             Corn 8 7 0 0 4                                                                  Cotton 4 6 0 -- 2                                                               Crabgrass 2 9 0 0 3                                                             Giant foxtail 5 9 0 0 3                                                         Lambsquarters 8 9 0 0 9                                                         Morningglory 5 2 0 0 4                                                          Nutsedge 6 4 0 0 0                                                              Rape 5 9 0 0 5                                                                  Rice 7 9 3 0 8                                                                  Sorghum 1 9 0 0 9                                                               Soybean 6 5 0 0 3                                                               Sugar beet 2 9 0 0 7                                                            Velvetleaf 2 5 0 0 2                                                            Wheat 8 8 2 0 5                                                                 Wild buckwheat -- -- -- -- --                                                   Wild oat 2 2 2 0 4                                                       

TEST B

The compounds evaluated in this test were formulated in a non-phytoxic solvent and applied to the soil surface before plant seedlings emerged (preemergence application), to water that covered the soil surface (paddy application), and to plants that were in the one-to-four leaf stage (postemergence application). A sandy loam soft was used for the preemergence and postemergence tests, while a silt loam soil was used in the paddy test. Water depth was approximately 2.5 cm for the paddy test and was maintained at this level for the duration of the test.

Plant species in the preemergence and postemergence tests consisted of barley (Hordeum vulgare), bedstraw (Galium aparine), blackgrass (Alopecurus myosuroides), chickweed (Stellaria media), corn (Zea mays), cotton (Gossypium hirsutum), crabgrass (Digitaria sanguinalis), downy brome (Bromus tectorum), duck salad (Heteranthera limosa), giant foxtail (Setaria faberii), lambsquarters (Chenopodium album), morningglory (Ipomoea hederacea), pigweed (Amaranthus retroflexus), rape (Brassica napus), ryegrass (Lolium multiflorum), sorghum (Sorghum bicolor), soybean (Glycine max), speedwell (Veronica persica), sugar beet (Beta vulgaris), velvetleg (Abutilon theophrasti), wheat (Triticum aestivum), wild buckwheat (Polygonum convolvulus), and wild oat (Avena fatua). All plant species were planted one day before application of the compound for the preemergence portion of this test. Plantings of these species were adjusted to produce plants of appropriate size for the postemergence portion of the test. Plant species in the paddy test consisted of barnyardgrass (Echinochloa crus-galli), rice (Oryza sativa), and umbrella sedge (Cyperus difformis).

All plant species were grown using normal greenhouse practices. Visual evaluations of injury expressed on treated plants, when compared to untreated controls, were recorded approximately fourteen to twenty-one days after application of test compounds. Plant response ratings, summarized in Table B, are recorded on a o to 10 scale where 0 is no injury and 10 is complete control. A dash (-) response means no test result.

    TABLE B                                                                           - COMPOUND                                                                       2 7 125 209 254 269 292 1 2 3 5 7 11 13 14 35 50 51 53 58 59 60 63 64         71 77 78 81                                                                      POSTEMERGENCE Rate (125 g/ha) Rate (62 g/ha)                                    Barley Igri 10 8 0 0 8 9 8 10 10 9 10 8 9 9 9 5 9 9 9 6 8 7 9 9 3 5 4 8         Bedstraw 10 5 8 0 10 10 10 10 10 10 10 5 9 10 8 10 10 10 10 10 10 10 9         9 9 7 9 8                                                                        Blackgrass 10 9 8 6 9 10 10 9 10 10 10 8 9 9 7 10 10 9 9 9 9 9 10 10 7         7 8 10                                                                           Chickweed 10 3 10 0 10 6 9 9 10 10 10 0 10 9 9 10 9 10 9 9 10 10 10 10         9 7 9 9                                                                          Corn 10 7 8 7 10 9 10 7 10 10 10 7 10 10 10 10 8 10 7 10 10 9 10 10 7 7        8 4                                                                              Cotton 7 6 10 0 9 7 9 6 7 9 7 5 9 8 9 8 10 10 10 9 10 10 9 10 10 7 8 8           Crabgrass 8 6 0 0 0 0 10 8 7 8 10 5 7 10 7 4 5 8 8 4 0 3 7 10 6 7 5 7           Downy brome 10 9 0 2 9 9 6 9 10 10 10 8 9 9 7 10 8 8 9 6 8 7 9 8 4 6 3        7                                                                                Duck salad -- -- 4 0 3 7 8 -- -- -- -- -- -- -- -- -- 10 10 10 8 10 10         9 10 10 7 9 4                                                                    Giant foxtail 10 8 3 5 7 5 10 8 10 10 10 7 10 10 10 9 10 10 10 7 6 4 10        10 5 7 8 9                                                                       Lambsquarters 10 10 10 0 8 2 9 10 10 10 10 9 10 10 8 10 10 10 10 9 10          10 10 10 10 10 10 9                                                              Morningglory 10 7 10 5 10 8 10 7 10 10 10 6 9 10 10 10 10 10 10 10 10          10 10 10 10 10 10 10                                                             Pigweed 8 6 9 0 9 7 7 8 7 7 10 4 9 10 6 10 10 10 10 10 10 10 10 10 10          10 10 9                                                                          Rape 10 0 10 0 10 10 10 7 10 10 10 0 10 10 10 4 10 10 10 10 10 10 10 10        8 10 10 9                                                                        Ryegrass 10 5 0 2 9 9 7 10 10 5 10 4 9 10 9 9 9 10 10 6 9 9 10 10 6 8 6        6                                                                                Sorghum 10 7 5 7 9 8 10 7 10 10 10 7 10 10 10 10 8 10 7 7 8 7 10 10 7          10 10 10                                                                         Soybean 10 6 9 0 10 8 3 8 10 10 10 4 10 10 10 10 10 10 10 10 10 10 10          10 9 9 9 9                                                                       Speedwell 8 0 6 0 4 5 9 7 6 4 10 0 0 8 0 5 6 10 9 9 10 8 8 8 4 6 6 3               Sugar beet 10 7 10 0 9 4 9 10 10 10 10 7 10 10 9 10 10 10 10 10 10          10 10 10 9 10 10 9                                                               Velvetleaf 10 6 10 0 7 4 8 8 10 10 10 4 8 10 7 10 10 10 10 10 10 8 10          10 10 8 10 9                                                                     Wheat 9 6 0 0 5 6 8 9 9 9 10 6 9 9 9 7 9 9 9 5 6 4 9 9 2 3 2 8                  Wild buckwheat 10 4 9 0 10 10 -- -- 10 10 10 2 9 10 9 0 8 10 9 8 10 10         9 9 3 6 9 9                                                                      Wild oat 10 8 0 0 9 8 9 10 10 10 10 8 9 10 8 9 7 9 8 5 8 7 8 8 2 2 4 9           Barnyardgrass 9 2 7 0 8 9 7 8 8 7 9 0 8 8 8 9 9 9 9 8 8 7 9 10 8 9 9 9         Rice Japonica 9 8 7 6 8 9 6 8 8 8 9 2 8 8 7 8 9 9 9 8 9 9 8 9 9 9 9 9             Umbrella sedge 9 5 9 0 8 8 4 9 9 9 9 4 9 6 3 5 9 10 9 8 9 9 9 9 3 9 9        9                                                                                COMPOUND                                                                        82 83 84 86 88 89 102 103 108 109 110 111 112 114 115 116 117 118 119          120 121 122 125 166 167 170 172 173                                              POSTEMERGENCE Rate (62 g/ha)                                                    Barley Igri 8 9 9 8 8 8 9 9 8 10 10 9 8 9 4 6 4 5 10 9 10 10 0 9 9 9 9         9                                                                                Bedstraw 9 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 -- 10 10 10         10 6 10 10 -- 9 10                                                               Blackgrass 10 10 9 9 9 10 9 9 10 10 10 10 10 9 9 9 9 9 10 10 10 10 8 9         9 9 10 10                                                                        Chickweed 10 10 10 9 9 10 9 9 10 10 10 10 9 9 9 10 10 3 10 10 10 10 9          10 10 10 9 9                                                                     Corn 9 9 10 4 8 9 6 0 10 9 10 10 8 9 9 8 5 5 10 10 10 10 5 10 10 10 9 9         Cotton 9 10 9 9 9 9 7 8 10 9 10 10 9 9 9 9 10 3 10 10 10 10 9 8 10 10 6        9                                                                                Crabgrass 4 5 6 3 3 4 1 2 7 9 9 6 6 2 2 2 0 0 8 7 9 7 0 8 8 10 8 9                   Downy brome 7 6 9 6 8 5 9 9 9 9 10 9 7 6 0 8 0 0 10 9 9 9 0 9 9 9         9 9                                                                              Duck salad 9 9 3 9 9 9 6 9 10 9 10 8 10 4 4 7 6 5 9 9 9 9 4 9 9 9 7 5             Giant foxtail 9 10 9 6 6 7 7 7 6 9 10 9 6 8 7 9 3 0 10 10 10 7 2 9 9         10 9 9                                                                           Lambsquarters 9 10 10 10 9 10 10 10 10 10 10 10 10 9 10 9 5 3 10 10 10         10 10 10 10 10 9 9                                                               Morningglory 10 10 9 9 10 10 10 9 10 8 10 10 10 8 10 10 10 9 10 10 10          10 10 10 10 10 9 10                                                              Pigweed 10 10 9 9 8 10 9 10 10 10 10 10 10 7 6 9 8 7 10 10 10 10 8 10          10 10 9 9                                                                        Rape 10 10 10 10 10 10 9 10 10 10 10 10 10 9 9 10 10 10 10 10 10 10 9          10 10 10 6 9                                                                     Ryegrass 6 6 10 5 6 5 6 4 10 10 10 9 7 9 5 9 6 6 10 6 10 10 0 9 9 10 9         9                                                                                Sorghum 10 10 10 9 8 9 10 10 10 9 10 10 10 8 9 9 9 0 10 10 10 10 5 10          10 10 6 9                                                                        Soybean 10 10 9 9 9 9 8 9 10 9 10 10 9 8 9 10 9 1 10 10 10 10 9 9 10 10        9 9                                                                              Speedwell 9 0 10 9 9 10 -- -- -- 10 10 9 10 9 8 10 10 9 10 8 10 0 -- 9         5 9 10 8                                                                         Sugar beet 9 10 10 10 9 10 10 10 10 9 10 10 10 9 9 9 9 5 10 10 10 10 10        10 10 10 9 9                                                                     Velvetleaf 9 10 7 9 9 9 7 9 10 10 10 10 10 8 9 9 9 4 10 10 10 9 9 9 10         10 9 8                                                                           Wheat 8 5 9 6 6 7 9 9 5 9 9 8 5 6 4 4 0 0 9 9 9 9 0 9 9 9 9 9                   Wild buckwheat 9 9 10 8 9 9 9 9 10 9 9 10 9 9 9 10 9 9 10 10 8 10 9 9 9        9 9 10                                                                           Wild oat 4 3 9 5 5 4 8 8 9 9 10 7 6 9 4 8 5 3 9 6 9 9 0 9 9 9 9 9                     Barnyardgrass 9 9 8 9 9 9 4 7 9 9 9 8 8 8 9 8 6 8 9 9 9 9 4 9 0          10 7 6                                                                           Rice Japonica 9 9 9 9 8 8 6 6 9 9 9 9 8 8 7 7 8 7 8 8 9 9 6 9 8 9 7 9             Umbrella sedge 9 9 6 9 8 8 6 9 9 8 9 8 8 9 9 9 9 8 9 9 9 9 9 10 9 9 8        8                                                                                COMPOUND                                                                        203 208 209 211 212 213 214 217 218 219 225 229 230 231 232 252 254 256 2      58 259 261 266 267 268 269 270 271 274                                           POSTEMERGENCE Rate (62 g/ha)                                                    Barley Igri 9 9 0 10 9 7 8 9 8 7 9 9 9 9 9 9 8 9 10 9 10 9 9 9 9 10 10         9                                                                                Bedstraw 10 10 0 10 10 10 10 8 8 10 9 10 10 10 10 10 10 10 9 9 10 10 10        10 10 10 10 9                                                                    Blackgrass 9 10 5 10 9 8 9 9 8 8 8 10 9 9 10 10 9 9 9 9 10 10 10 10 10         10 10 9                                                                          Chickweed 10 9 0 10 8 10 10 9 10 10 10 10 10 10 10 7 10 10 10 9 9 6 10         10 2 8 10 0                                                                      Corn 10 10 4 10 10 10 10 10 10 10 10 9 9 10 10 10 9 10 10 10 10 10 10          10 9 10 10 10                                                                    Cotton 9 10 0 10 10 10 10 10 9 7 10 2 -- 8 7 8 9 0 5 8 4 5 9 9 5 9 9 2           Crabgrass 10 10 0 7 7 8 5 8 6 4 9 6 4 9 9 7 0 9 10 7 10 0 4 3 0 10 10         5                                                                                Downy brome 10 9 0 10 9 8 8 9 8 7 10 9 9 9 10 10 8 9 9 10 9 9 10 10 9          10 10 9                                                                          Duck salad 9 10 0 10 9 9 10 9 8 6 8 8 8 0 0 6 3 6 9 5 7 9 3 4 0 0 3 0             Giant foxtail 7 10 5 10 10 10 7 9 8 6 10 8 7 9 9 9 6 10 10 10 10 10 6        7 3 10 10 6                                                                      Lambsquarters 10 10 0 10 10 10 10 10 10 10 10 10 10 10 10 9 8 10 10 10         10 8 10 10 0 10 10 0                                                             Morningglory 10 10 4 10 10 10 10 10 10 10 9 9 10 9 10 10 10 10 10 9 10         10 10 10 7 10 10 0                                                               Pigweed 10 10 0 10 7 10 10 10 10 10 10 10 9 10 10 8 9 10 10 10 10 5 10         10 7 10 10 4                                                                     Rape 10 10 0 9 10 10 10 10 9 9 10 8 9 10 9 10 10 10 10 9 10 9 10 10 10         9 9 6                                                                            Ryegrass 10 10 0 -- 8 10 8 9 9 8 10 5 2 9 9 5 9 10 9 10 10 2 10 10 5 9         10 9                                                                             Sorghum 10 10 7 10 10 10 10 10 9 8 10 8 9 10 10 10 9 10 10 10 10 10 10         10 8 10 10 9                                                                     Soybean 10 9 0 10 10 10 10 9 10 10 10 9 9 10 9 8 10 10 10 9 9 10 10 10         7 8 9 3                                                                          Speedwell 7 8 0 9 3 10 9 7 3 5 7 9 0 -- 10 8 4 3 0 3 3 3 10 0 3 6 3 0             Sugar beet 10 10 0 10 8 10 10 9 10 10 10 8 8 10 10 8 9 9 9 10 10 6 10        10 -- 9 9 7                                                                      Velvetleaf 10 10 0 10 10 10 7 10 10 9 10 9 10 9 8 8 5 10 10 8 9 10 9 7         4 9 10 3                                                                         Wheat 9 9 0 9 8 7 6 9 9 7 9 8 8 9 9 9 4 9 9 9 9 8 9 9 5 10 9 9                  Wild buckwheat 9 10 0 9 9 10 10 9 9 9 10 9 9 9 9 10 10 9 9 9 10 9 10 9         10 10 10 --                                                                      Wild oat 9 9 0 9 8 7 7 9 9 7 8 9 9 9 9 9 9 9 9 9 9 9 9 10 5 10 9 9                   Barnyardgrass 9 10 0 9 8 9 9 8 9 9 8 0 0 9 0 8 8 9 9 9 9 3 8 0 7 4        9 0                                                                              Rice Japonica 9 9 4 9 8 9 9 9 8 9 9 0 0 9 9 9 8 9 9 9 9 9 8 8 8 9 9 6             Umbrella sedge 9 9 0 10 9 9 9 9 9 9 9 0 6 6 5 8 8 9 9 5 9 4 5 5 7 10         9 3                                                                              COMPOUND                                                                        275 276 289 292 300 301 302 305 310 1 2 3 5 7 11 13 14 25 26 27 28 29          30 31 34 35 36 50                                                                POSTEMERGENCE Rate (62 g/ha) Rate (31 g/ha)                                     Barley Igri 9 -- 10 7 10 10 10 9 9 10 9 9 10 7 9 9 9 9 8 10 9 10 10 9 7 5       5 8                                                                             Bedstraw 10 6 10 10 10 10 10 10 10 10 10 10 10 3 8 9 8 10 10 10 10 10          10 7 8 10 10 8                                                                   Blackgrass 10 9 10 10 10 10 10 10 10 9 9 9 10 7 9 8 7 10 10 10 10 10 10        9 8 9 10 9                                                                       Chickweed 10 1 10 9 10 10 10 10 7 6 8 9 10 0 10 9 9 10 10 10 10 10 10 4        10 10 10 9                                                                       Corn 10 8 10 10 9 10 10 10 9 7 10 10 10 6 10 10 10 10 10 10 10 10 10 10        10 10 10 7                                                                       Cotton 8 0 10 8 10 8 9 9 8 6 7 8 7 4 8 7 9 5 7 10 10 10 10 6 6 7 8 10             Crabgrass 10 3 8 9 9 9 10 10 4 7 6 7 8 5 6 10 7 7 6 10 6 10 10 6 7 4         7 4                                                                              Downy brome 9 -- 9 4 10 9 10 9 9 9 8 8 10 6 9 5 5 10 9 10 10 10 10 5 7         9 10 8                                                                           Duck salad 8 0 8 8 6 5 9 9 0 -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- 10                                                                   Giant foxtail 10 6 10 10 10 10 10 10 9 7 8 9 10 6 10 10 10 10 10 10 9          10 10 9 8 8 10 10                                                                Lambsquarters 10 3 10 8 10 10 10 10 9 10 10 10 10 -- 10 10 8 10 10 10          10 10 10 10 10 10 10 10                                                          Morningglory 8 7 10 6 8 10 10 10 10 7 10 10 8 6 8 8 9 10 10 10 10 10 10        8 8 10 10 10                                                                     Pigweed 10 8 9 7 9 9 10 9 8 6 6 6 10 3 8 9 3 10 10 10 10 10 10 7 8 8 10        10                                                                               Rape 10 0 5 9 9 9 9 9 9 6 8 10 10 0 10 10 10 9 10 10 10 10 10 0 5 4 10         10                                                                               Ryegrass 10 2 8 7 10 9 10 9 9 10 9 4 10 4 9 8 5 10 10 10 10 10 10 9 9 9        10 9                                                                             Sorghum 10 8 10 10 9 10 10 10 9 7 10 10 10 7 10 10 10 10 10 10 10 10 10        10 7 10 10 7                                                                     Soybean 8 4 8 2 9 9 10 10 9 7 10 10 10 3 8 10 10 10 10 10 10 10 10 10          10 10 10 10                                                                      Speedwell 7 0 8 9 10 10 8 10 10 5 6 4 9 0 0 6 0 8 6 6 9 9 0 0 0 5 8 6             Sugar beet 9 5 10 9 9 10 10 10 10 10 10 10 10 6 10 10 9 10 10 10 10          10 10 10 10 10 10 10                                                             Velvetleaf 7 4 7 7 8 7 10 8 9 7 8 10 9 4 8 9 6 7 9 10 10 10 10 7 6 7 10        10                                                                               Wheat 9 -- 9 8 9 9 9 9 6 7 8 8 10 5 9 9 9 9 9 10 9 10 10 8 6 7 8 9                   Wild buckwheat 10 0 9 -- 9 9 9 8 9 10 7 9 10 0 9 5 7 10 7 10 10 10        10 6 0 0 5 7                                                                     Wild oat 9 -- 9 8 10 10 10 9 9 10 10 9 9 5 9 7 6 10 9 9 9 9 -- 9 8 9 9         7                                                                                Barnyardgrass 9 0 7 5 6 9 10 10 7 2 6 5 8 0 7 8 7 8 8 8 9 10 8 3 2 8 9         8                                                                                Rice Japonica 9 7 8 2 7 7 8 8 4 8 8 8 9 0 8 8 7 7 8 8 8 9 8 6 8 8 8 0             Umbrella sedge 9 0 8 3 9 9 9 8 3 8 9 9 8 4 8 4 2 9 9 9 10 9 8 8 2 3 8        9                                                                                COMPOUND                                                                        51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103 107 108 109         110 111 112 114 115 116                                                          POSTEMERGENCE Rate (31 g/ha)                                                    Barley Igri 9 9 5 7 5 9 9 2 2 1 7 7 8 7 6 6 7 9 9 9 7 10 10 9 8 6 4 6             Bedstraw 10 9 10 10 10 7 9 7 5 7 6 9 10 9 10 10 10 9 9 10 10 9 10 10         10 10 10 10                                                                      Blackgrass 9 9 9 8 8 9 9 4 7 7 10 10 10 9 9 9 10 9 9 10 9 10 10 10 10 9        9 9                                                                              Chickweed 10 9 9 10 10 10 10 9 4 9 9 10 10 10 6 9 10 9 9 10 10 10 10 10        9 9 5 10                                                                         Corn 10 7 10 10 8 10 10 6 6 7 0 7 9 10 1 7 9 3 0 10 10 9 10 10 8 9 9 8           Cotton 10 10 9 10 10 9 9 10 6 7 7 9 9 9 8 8 9 7 8 10 10 9 9 10 8 8 9 9         Crabgrass 7 7 3 0 0 5 8 6 5 4 4 4 5 4 2 0 2 0 2 7 5 6 9 0 2 0 0 2                     Downy brome 8 9 5 7 6 9 8 1 5 2 6 6 3 8 4 6 4 8 8 9 9 9 10 9 6 6         0 7                                                                              Duck salad 9 10 7 10 10 9 9 9 7 6 3 9 9 1 9 6 9 3 7 10 10 9 10 8 9 4 4         7                                                                                Giant foxtail 10 8 7 5 3 10 10 5 7 7 8 8 9 8 5 5 5 6 6 9 5 9 9 8 4 8 5         6                                                                                Lambsquarters 10 10 9 10 10 10 10 8 9 10 8 9 10 10 9 9 10 9 10 10 10 10        10 10 10 8 5 7                                                                   Morningglory 10 10 10 10 10 10 10 10 9 10 9 10 10 8 9 10 10 9 9 10 10 7        10 10 10 8 10 10                                                                 Pigweed 10 10 10 10 10 10 10 10 9 10 9 10 10 9 8 7 5 8 10 10 10 10 10          10 10 7 6 9                                                                      Rape 10 10 10 10 10 10 10 7 8 9 9 10 10 10 10 10 10 9 9 10 10 10 10 10         10 9 9 10                                                                        Ryegrass 10 9 5 9 8 8 9 3 4 4 5 5 5 8 4 6 4 5 3 10 10 10 10 9 7 8 5 9             Sorghum 10 6 7 7 7 10 10 6 8 10 10 10 10 10 9 8 9 9 10 10 10 9 10 10         9 8 9 9                                                                          Soybean 10 10 10 10 10 10 10 9 9 9 8 9 9 9 8 9 9 7 9 10 10 8 10 10 9 8         9 9                                                                              Speedwell 10 8 9 10 8 -- 4 1 4 6 3 6 0 10 7 9 9 -- -- -- -- 10 10 -- 10        9 5 10                                                                           Sugar beet 10 10 9 10 10 10 10 9 10 10 9 9 10 10 9 9 9 9 10 10 10 9 10         10 10 6 8 9                                                                      Velvetleaf 10 10 10 10 7 10 10 9 8 10 8 9 10 7 8 7 8 4 9 10 8 10 10 10         10 8 9 9                                                                         Wheat 9 9 4 5 2 9 9 0 2 1 4 4 3 9 4 5 6 9 9 9 4 9 9 8 5 5 4 2                   Wild buckwheat 10 8 8 10 10 9 9 0 4 8 9 8 9 9 8 9 9 9 9 10 10 -- 9 9 9         9 -- 9                                                                           Wild oat 9 7 4 7 5 7 7 0 0 2 7 4 2 9 3 4 2 8 8 9 9 9 10 7 6 6 4 8                     Barnyardgrass 9 9 8 8 7 9 9 8 6 8 8 9 9 3 9 8 8 2 6 8 9 9 9 8 8 8        9 8                                                                              Rice Japonica 9 9 8 9 9 8 9 8 7 9 8 9 9 8 8 7 6 3 3 9 9 9 9 8 8 8 7 7             Umbrella sedge 10 9 8 9 9 9 9 3 9 9 8 8 9 4 8 6 7 3 9 9 8 8 9 8 8 8 9        9                                                                                COMPOUND                                                                        117 118 119 120 121 122 125 166 167 170 172 173 203 204 205 206 207 208 2      09 211 212 213 214 217 218 219 225 229                                           POSTEMERGENCE Rate (31 g/ha)                                                    Barley Igri 3 3 10 8 10 10 0 9 9 8 9 9 9 10 10 10 9 9 0 10 9 6 6 9 8 6         9 9                                                                              Bedstraw 10 9 9 10 10 10 3 9 10 10 9 10 9 9 10 10 10 10 0 9 10 10 10 7         8 10 8 10                                                                        Blackgrass 8 9 10 10 9 10 6 9 9 9 10 10 9 10 10 10 10 10 5 10 9 8 8 9 7        7 7 10                                                                           Chickweed 10 3 10 10 10 10 7 10 10 10 8 8 9 10 10 10 10 9 0 9 7 10 10 8        10 10 10 9                                                                       Corn 4 3 10 10 10 10 4 10 10 10 9 9 10 10 10 10 10 10 3 10 10 10 10 10         9 10 10 9                                                                        Cotton 9 3 10 10 10 10 8 8 8 10 5 9 9 5 8 8 6 9 0 9 9 10 10 6 7 7 8 0             Crabgrass 0 0 7 4 7 5 0 7 4 10 8 9 10 10 10 10 10 10 0 6 6 6 4 7 4 3         8 4                                                                              Downy brome 0 0 10 9 9 9 0 8 9 8 9 9 10 10 10 10 10 9 0 10 9 8 7 9 7 6         9 9                                                                              Duck salad 5 4 9 9 9 9 3 9 7 9 5 4 9 9 10 9 10 10 0 10 9 9 9 6 4 0 2 4           Giant foxtail 2 0 9 9 10 4 0 9 7 10 9 9 6 10 10 10 10 10 5 10 9 8 6 8         6 3 10 8                                                                         Lambsquarters 5 0 10 10 10 10 10 10 10 10 9 9 10 10 10 10 10 10 0 10 10        10 10 10 10 10 10 10                                                             Morningglory 10 9 10 10 10 10 10 9 10 10 9 10 10 10 10 9 8 10 3 10 10          10 10 10 10 10 9 9                                                               Pigweed 8 0 10 10 10 10 8 10 8 10 9 9 10 10 10 10 9 10 0 10 7 10 10 10         7 9 10 8                                                                         Rape 9 10 10 10 10 10 9 10 10 10 5 9 10 10 10 10 9 10 0 9 9 10 10 9 9 9        10 8                                                                             Ryegrass 6 5 10 5 10 10 0 9 9 9 9 9 10 10 10 10 -- 10 0 9 7 10 7 9 7 8         9 5                                                                              Sorghum 9 0 10 10 10 9 4 10 10 10 6 9 10 10 10 10 10 10 6 9 10 10 10 10        8 7 10 8                                                                         Soybean 9 0 10 10 10 10 8 9 10 10 9 9 8 10 10 10 10 8 0 10 9 10 10 8 10        10 10 9                                                                          Speedwell 9 -- 9 0 10 -- 0 8 5 9 9 6 7 8 4 9 0 7 0 8 1 10 7 3 0 3 6 6             Sugar beet 9 5 10 10 10 10 10 10 10 10 9 9 10 10 10 10 10 10 0 8 8 10        10 9 9 10 10 8                                                                   Velvetleaf 9 4 10 10 10 8 9 9 9 10 8 8 10 10 10 9 8 10 0 10 10 9 6 10 8        8 10 9                                                                           Wheat 0 0 9 8 9 9 0 9 9 9 9 9 9 9 9 9 9 9 0 9 8 6 4 9 9 6 7 8                   Wild buckwheat 9 -- 10 10 8 9 8 8 9 9 9 9 9 9 10 10 9 9 0 8 9 10 10 8 8        8 10 9                                                                           Wild oat 5 3 9 6 9 9 0 9 9 9 9 9 9 10 10 9 9 8 0 8 7 7 6 9 7 6 7 9                   Barnyardgrass 5 7 9 8 9 8 3 8 0 9 3 4 5 9 9 9 9 10 0 9 8 9 8 8 8 8        5 0                                                                              Rice Japonica 8 6 8 8 9 8 3 8 6 9 3 9 9 9 9 9 9 9 3 9 8 9 9 8 8 8 8 0             Umbrella sedge 9 8 9 8 9 9 9 10 9 8 7 8 9 9 9 9 9 9 0 9 9 9 9 9 9 9 9         COMPOUND                                                                        230 231 232 240 241 242 243 244 245 252 254 256 258 259 261 266 267 268 2      69 270 271 272 274 275 276 283 284 285                                           POSTEMERGENCE Rate (31 g/ha)                                                    Barley Igri 9 9 8 10 10 10 10 10 10 9 7 9 9 9 10 9 9 9 8 -- 10 9 3 9 7         10 10 10                                                                         Bedstraw 9 10 10 10 10 10 10 10 10 10 10 10 9 9 10 10 10 10 9 10 10 10         2 10 6 10 10 10                                                                  Blackgrass 9 9 10 10 10 10 10 10 10 10 9 9 9 9 9 10 10 10 9 10 10 10 9         10 9 10 10 10                                                                    Chickweed 9 10 10 10 10 10 10 10 5 5 10 8 10 8 9 3 9 10 0 7 10 10 0 10         1 10 10 10                                                                       Corn 9 10 10 10 10 10 10 10 10 10 9 10 10 10 10 10 10 10 9 10 10 10 9          10 8 10 10 10                                                                    Cotton 1 8 6 9 9 10 10 10 8 7 8 0 3 7 4 4 8 8 5 9 8 6 0 7 0 10 10 10               Crabgrass 1 7 7 9 9 10 10 10 9 7 0 9 10 4 7 0 3 2 0 10 10 9 5 10 2 9        8 8                                                                              Downy brome 8 9 10 10 10 10 10 10 9 10 8 9 9 10 9 9 10 10 8 8 10 9 6 9         -- 10 10 10                                                                      Duck salad 6 0 0 7 8 9 8 8 9 0 3 3 6 4 4 8 3 3 0 0 0 0 0 7 0 9 9 8                   Giant foxtail 7 7 7 9 10 10 10 10 10 9 5 10 10 10 10 10 5 5 2 10          10 10 5 10 5 10 10 10                                                            Lambsquarters 10 10 10 10 10 10 10 9 9 4 2 10 10 10 10 8 10 0 0 -- 10          10 0 9 0 10 10 10                                                                Morningglory 10 9 8 10 10 10 10 10 10 10 10 10 10 8 10 10 10 10 5 9 10         10 0 7 7 9 10 10                                                                 Pigweed 9 10 8 10 10 10 10 10 10 8 9 10 10 10 9 3 10 9 7 10 10 10 4 10         7 10 10 10                                                                       Rape 9 9 7 10 10 10 10 10 10 9 10 10 10 9 10 9 10 9 9 9 9 9 0 9 0 10 10        10                                                                               Ryegrass 0 9 9 10 10 10 10 10 10 5 7 10 9 10 10 0 10 10 5 8 10 10 0 10         2 10 8 4                                                                         Sorghum 8 10 10 10 10 10 10 10 10 10 8 10 10 10 10 10 10 10 8 10 10 10         9 10 8 10 10 10                                                                  Soybean 8 9 9 9 10 9 9 9 10 8 10 7 10 9 8 10 10 10 5 7 8 7 2 7 3 9 10          10                                                                               Speedwell 0 -- 10 4 4 9 10 0 8 5 3 2 0 2 2 2 10 0 0 5 0 0 0 6 0 8 8 0             Sugar beet 8 9 9 10 10 10 10 10 10 8 9 8 9 9 9 6 10 10 2 9 9 9 5 9 2         9 9 9                                                                            Velvetleaf 10 9 7 8 8 10 10 10 9 7 4 9 10 7 5 10 8 6 2 9 7 9 0 6 4 9 10        10                                                                               Wheat 6 9 9 9 9 10 10 9 9 9 3 8 9 9 8 8 9 8 4 9 9 9 6 9 5 9 9 9                         Wild buckwheat 9 9 9 10 10 -- 9 -- 10 10 10 9 9 8 10 9 9 9 10          10 10 -- 6 10 -- 10 10 10                                                        Wild oat 9 9 9 10 10 10 10 10 9 7 9 9 9 9 8 9 9 9 5 9 9 9 4 9 -- 10 9 9         Barnyardgrass 0 6 0 7 7 9 9 9 9 3 7 6 9 9 9 0 3 0 6 0 3 5 0 9 0 9 7 5             Rice Japonica 0 8 8 9 9 9 9 9 8 8 8 9 9 8 9 1 8 8 6 9 8 8 3 9 3 9 8 7         Umbrella sedge 3 4 0 9 9 9 8 9 9 8 7 9 9 5 9 3 5 4 2 9 9 9 0 9 0 9 9           9                                                                                COMPOUND                                                                        286 287 288 289 291 292 300 301 302 305 310 1 2 3 5 7 11 13 14 25 26 27 2      8 29 30 31 34 35                                                                 POSTEMERGENCE Rate (31 g/ha) Rate (16 g/ha)                                     Barley Igri 10 10 10 9 10 5 10 10 10 9 9 6 9 7 10 6 9 9 9 9 8 9 8 10 10 8       7 3                                                                             Bedstraw 10 10 10 10 10 8 10 10 10 10 10 9 8 9 10 0 5 8 4 10 10 10 10          10 10 7 5 10                                                                     Blackgrass 10 10 10 10 10 9 10 10 10 10 9 8 8 9 10 5 8 8 5 10 10 10 9          10 10 7 4 8                                                                      Chickweed 10 10 10 10 10 8 10 10 10 10 6 6 5 7 10 0 9 9 9 10 10 10 5 10        10 -- 10 10                                                                      Corn 10 10 10 10 10 10 9 10 10 10 9 7 8 10 10 6 10 10 10 10 10 10 10 10        10 9 10 10                                                                       Cotton 10 10 7 8 8 7 7 7 9 8 7 5 6 7 6 3 6 6 8 4 7 9 8 10 10 4 5 6                   Crabgrass 10 10 7 8 10 5 9 8 10 10 4 7 5 6 7 4 5 7 6 6 5 7 4 10 10        4 6 3                                                                            Downy brome 10 10 9 9 10 3 10 9 10 9 9 8 7 6 10 6 8 5 4 10 9 10 10 10          10 5 7 7                                                                         Duck salad 9 9 9 7 8 2 5 4 8 7 0 -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- --                                                                      Giant foxtail 10 10 10 9 10 7 10 10 10 10 9 6 8 8 8 6 9 10 10 10 10 10         7 10 10 8 7 8                                                                    Lambsquarters 10 10 10 9 10 8 10 10 10 10 9 10 10 10 10 9 10 10 5 10 10        10 10 10 10 9 10 10                                                              Morningglory 10 10 10 9 9 5 7 9 10 10 10 6 10 10 7 6 7 6 7 10 10 10 10         10 10 7 7 10                                                                     Pigweed 10 10 9 9 10 7 8 9 10 8 7 5 5 4 10 2 8 9 0 7 7 10 10 10 10 6 8         7                                                                                Rape 10 10 10 3 10 9 9 9 9 9 9 5 6 8 10 0 8 10 10 9 10 10 10 10 10 0 4         2                                                                                Ryegrass 10 10 7 6 10 5 10 9 10 9 7 9 5 3 10 4 9 4 3 10 10 10 10 10 10         7 9 7                                                                            Sorghum 10 10 10 10 10 10 9 10 10 10 9 7 8 10 10 7 8 10 8 10 10 10 10          10 10 8 7 10                                                                     Soybean 10 10 10 8 9 1 9 9 10 9 9 7 9 8 10 2 8 10 8 10 10 10 10 10 10 7        10 10                                                                            Speedwell 10 2 10 6 0 8 10 10 6 10 10 4 5 0 9 0 0 5 0 6 6 5 8 8 0 0 0 3         Sugar beet 10 10 10 9 9 9 9 10 10 10 10 9 10 10 10 5 9 9 8 8 9 10 10 10        10 8 9 10                                                                        Velvetleaf 10 7 10 6 8 5 6 7 9 7 9 6 7 6 8 3 6 8 3 7 9 10 9 9 10 5 6 7           Wheat 10 9 9 9 9 6 9 9 9 9 5 7 8 6 10 5 9 9 9 9 7 10 5 10 10 7 6 6                 Wild buckwheat 10 10 10 -- -- -- 9 8 9 -- 8 10 6 9 10 0 9 5 3 10 6         10 10 10 10 6 0 0                                                                Wild oat 9 10 9 8 9 5 10 10 10 8 9 9 10 8 9 5 8 4 3 9 9 9 6 9 9 8 7 8             Barnyardgrass 9 9 9 3 8 3 5 9 10 9 3 0 0 0 7 0 4 5 2 7 8 8 8 9 7 0 1         6                                                                                Rice Japonica 9 9 8 0 8 2 6 6 8 8 2 6 6 7 8 0 5 7 6 5 6 2 8 8 8 0 8 4             Umbrella sedge 9 9 9 8 9 0 9 7 9 7 2 6 9 9 8 0 7 0 1 9 9 9 9 8 7 0 2          COMPOUND                                                                        36 50 51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103 107           108 109 110 111 112 114                                                          POSTEMERGENCE Rate (16 g/ha)                                                    Barley Igri 4 8 8 9 4 7 4 7 8 0 1 0 7 6 6 5 5 6 6 8 8 9 7 10 10 9 7 6             Bedstraw 10 8 10 8 10 10 10 7 7 7 4 6 5 8 9 8 9 9 10 8 9 10 10 -- 10         10 9 10                                                                          Blackgrass 9 9 9 9 9 8 7 9 9 4 6 7 10 9 10 9 9 8 9 9 9 10 9 10 10 10 10        9                                                                                Chickweed 10 8 10 9 7 10 10 10 10 9 3 5 7 10 10 9 -- 9 8 9 9 10 10 9 10        9 8 8                                                                            Corn 10 7 10 6 10 9 7 10 10 5 4 7 0 5 9 8 0 4 8 2 0 10 10 7 9 10 8 9               Cotton 8 10 10 10 8 10 10 8 9 9 4 7 5 5 9 8 4 8 4 3 7 10 10 9 9 10 8        8                                                                                Crabgrass 6 3 6 6 3 0 0 3 7 5 4 3 2 4 5 3 2 0 0 0 0 5 2 6 7 0 0 0                     Downy brome 9 6 8 9 4 7 4 8 7 0 3 0 6 5 3 3 3 5 3 7 7 8 4 9 10 9         6 5                                                                              Duck salad -- 10 9 9 7 10 10 8 9 9 5 5 0 9 9 0 7 4 8 2 4 10 10 9 -- 7 9        4                                                                                Giant foxtail 10 7 7 8 4 4 0 8 10 3 6 6 6 8 8 7 5 4 2 5 4 9 3 7 8 7 2 7         Lambsquarters 10 10 10 10 9 10 10 10 10 7 8 10 6 9 10 10 9 8 10 9 10 10        10 10 10 10 10 6                                                                 Morningglory 10 10 10 8 10 10 10 10 10 10 7 10 9 10 10 7 9 10 10 7 9 10        10 7 10 10 10 8                                                                  Pigweed 10 10 10 10 7 10 8 10 10 10 8 10 7 10 10 8 6 4 3 8 9 10 10 10          10 10 10 6                                                                       Rape 10 10 10 10 10 10 10 10 10 5 7 9 9 10 8 9 10 9 10 9 8 10 10 10 10         10 10 9                                                                          Ryegrass 10 7 9 9 2 9 4 7 9 2 3 2 5 5 3 4 0 4 4 3 2 10 9 10 10 9 7 8               Sorghum 10 7 10 6 6 6 6 10 10 5 7 8 10 10 10 10 9 7 8 9 10 10 9 9 9         10 9 8                                                                           Soybean 10 10 10 10 10 10 10 10 10 9 8 9 8 8 9 9 8 8 9 6 8 10 10 8 10          10 9 8                                                                           Speedwell 4 5 9 7 9 10 8 4 0 1 3 3 -- -- -- 8 7 9 7 -- -- -- -- 6 9 5 9        9                                                                                Sugar beet 10 9 10 10 9 10 10 10 10 7 10 10 6 9 10 9 9 9 9 9 9 10 10 --        10 10 9 6                                                                        Velvetleaf 6 10 10 10 10 8 6 10 10 8 6 8 6 9 9 5 7 7 7 2 8 10 7 8 10 10        8 8                                                                              Wheat 6 6 8 9 0 2 1 7 8 0 0 0 4 3 2 4 3 5 5 9 8 8 4 9 9 8 5 5                   Wild buckwheat 4 7 10 8 6 10 10 6 8 0 4 7 9 7 8 9 8 8 9 8 7 9 10 9 9 8         9 8                                                                              Wild oat 9 5 9 7 2 7 4 5 6 0 0 0 7 0 0 7 2 4 2 6 5 9 8 9 10 6 5 6                     Barnyardgrass 8 8 9 9 8 7 6 9 9 0 0 7 4 8 8 3 8 8 8 1 2 8 8 9 9 8        7 8                                                                              Rice Japonica 5 0 9 9 8 9 9 8 8 8 3 8 6 8 8 5 8 3 6 2 2 9 8 8 8 8 8 8             Umbrella sedge 4 9 9 9 8 9 9 8 9 0 5 9 4 7 8 2 5 0 6 0 7 9 8 8 8 8 8         7                                                                                COMPOUND                                                                        115 116 117 118 119 120 121 122 125 166 167 170 172 173 203 204 205 206 2      07 208 209 211 212 213 214 217 218 219                                           POSTEMERGENCE Rate (16 g/ha)                                                    Barley Igri 3 5 2 0 10 5 9 8 0 8 9 5 9 9 8 10 10 9 9 9 0 9 8 5 6 9 7 6           Bedstraw -- 10 10 9 9 9 10 10 0 9 10 10 9 9 8 9 10 9 10 10 0 9 10 10          10 6 8 10                                                                        Blackgrass -- 9 8 7 10 10 9 9 4 9 9 9 10 10 9 10 10 10 10 10 5 10 8 8 7        8 7 7                                                                            Chickweed -- 10 10 3 10 10 10 10 4 10 10 10 6 6 8 10 10 10 9 8 0 8 6 10        10 6 9 10                                                                        Corn 9 5 3 0 10 10 10 10 3 10 10 10 8 9 10 10 10 10 10 9 0 9 10 10 9 10        9 7                                                                              Cotton 9 9 9 3 10 10 10 10 8 7 7 10 5 8 7 5 8 7 6 9 0 6 7 9 10 6 4 6               Crabgrass 0 0 0 0 -- 0 5 4 0 5 3 10 6 9 9 10 10 10 10 9 0 5 5 4 3 6         3 0                                                                              Downy brome 0 2 0 0 10 8 9 7 0 7 9 6 9 9 10 10 10 10 10 9 0 9 9 7 7 8 7        6                                                                                Duck salad 3 6 5 4 8 7 9 8 1 8 7 9 2 3 8 9 10 9 9 10 0 10 8 9 9 0 0 0             Giant foxtail 4 5 0 0 -- 9 9 4 0 7 7 10 8 9 6 9 10 10 10 10 5 8 8 6 5        7 5 0                                                                            Lambsquarters -- 7 -- 0 10 10 10 8 8 10 10 10 9 9 10 10 10 10 10 10 0          10 10 10 10 10 10 10                                                             Morningglory 10 10 10 9 10 10 10 10 10 8 9 9 9 9 10 10 10 7 7 10 0 10          10 10 10 10 10 7                                                                 Pigweed 5 8 8 0 -- 10 10 10 8 8 5 10 9 9 10 10 10 10 9 10 0 10 5 10 10         7 7 8                                                                            Rape 9 9 9 9 10 10 10 10 9 10 10 10 0 7 10 10 10 10 9 10 0 8 9 10 10 9         7 8                                                                              Ryegrass 3 9 5 4 10 4 10 9 0 8 9 8 9 9 10 10 10 10 6 10 0 4 3 8 6 9 6 7         Sorghum 8 9 8 0 -- 10 10 9 3 10 10 10 6 9 10 10 10 10 10 10 5 7 10 10          10 10 7 4                                                                        Soybean 9 9 9 0 10 10 10 10 8 9 8 10 9 9 8 10 10 10 10 7 0 10 9 10 10 7        9 7                                                                              Speedwell -- 10 0 7 -- 0 10 0 0 8 4 9 9 6 5 8 3 8 0 5 0 8 0 10 7 3 0 3           Sugar beet -- 9 9 4 10 10 10 10 9 10 10 10 8 9 10 10 10 10 9 10 0 8 7         10 10 9 9 10                                                                     Velvetleaf 9 9 9 2 -- 10 10 8 8 9 9 9 7 7 10 10 10 8 7 9 0 10 8 9 4 8 8        8                                                                                Wheat 4 0 0 0 9 7 9 8 0 8 8 9 9 9 7 9 9 9 8 8 0 8 7 6 3 9 5 5                   Wild buckwheat -- 9 9 8 10 10 8 9 -- 7 8 9 -- 9 9 9 10 9 7 9 0 7 9 10          10 7 8 8                                                                         Wild oat 3 5 4 0 8 4 9 8 0 8 9 5 9 9 8 10 9 9 9 6 0 6 6 6 6 9 5 5                     Barnyardgrass 9 7 4 5 8 5 8 8 0 2 0 9 0 0 1 9 9 9 8 9 0 9 6 9 5 3        6 5                                                                              Rice Japonica 7 7 7 5 7 6 8 8 0 6 5 9 0 4 9 9 9 9 9 9 0 9 8 8 8 8 8 8             Umbrella sedge 9 9 8 8 9 8 9 8 9 10 9 7 5 7 9 9 9 9 9 9 0 9 9 9 9 8 8        8                                                                                COMPOUND                                                                        225 229 230 231 232 240 241 242 243 244 245 252 254 256 258 259 261 266 2      67 268 269 270 271 272 274 275 276 283                                           POSTEMERGENCE Rate (16 g/ha)                                                    Barley Igri 9 8 8 8 8 9 9 10 10 9 9 9 5 9 9 8 10 8 9 8 6 9 9 9 3 8 7 10         Bedstraw 8 9 9 9 9 10 10 10 10 10 10 10 9 10 9 8 10 9 10 10 8 10 10 10         0 10 5 10                                                                        Blackgrass 6 9 9 9 10 10 10 10 10 10 10 10 9 9 9 9 9 10 10 9 9 10 10 10        9 10 9 10                                                                        Chickweed 9 8 3 6 10 10 10 10 -- 10 4 4 10 8 10 8 9 3 9 9 0 6 10 10 0 8        0 10                                                                             Corn 10 9 9 10 9 10 10 10 10 10 10 10 8 10 10 10 10 10 10 10 6 10 10 10        3 10 8 10                                                                        Cotton 7 0 0 5 4 6 9 8 8 9 7 6 8 0 2 3 2 1 7 7 1 8 8 5 0 5 0 10                         Crabgrass 7 3 0 7 6 6 8 10 10 9 8 2 0 8 9 3 6 0 0 0 0 9 9 9 2          10 0 9                                                                           Downy brome 9 7 5 9 9 9 10 10 10 10 9 10 7 9 9 9 9 8 10 8 6 8 10 9 6 9         6 10                                                                             Duck salad 0 0 2 0 0 6 7 8 8 5 9 0 3 2 3 0 0 0 1 2 0 0 0 0 0 5 0 8                   Giant foxtail 8 7 6 6 5 8 10 10 10 10 9 8 2 9 10 9 10 7 4 5 0 8 9         10 2 10 3 10                                                                     Lambsquarters 10 8 10 9 10 10 9 10 10 7 9 0 0 10 10 10 9 4 7 0 0 10 10         9 0 9 0 10                                                                       Morningglory 9 9 9 8 7 10 10 10 10 10 10 10 9 10 10 7 10 10 9 10 5 8 9         9 0 7 6 8                                                                        Pigweed 10 8 9 10 4 10 10 10 10 10 10 5 8 9 10 10 9 2 10 9 5 10 9 10 2         9 5 10                                                                           Rape 10 6 7 9 6 10 10 10 10 10 10 9 9 10 10 8 10 7 9 9 8 9 9 9 0 9 0 10         Ryegrass 5 4 0 9 8 10 10 10 10 10 10 4 4 10 9 10 9 0 10 9 4 8 9 10 0 10        0 10                                                                             Sorghum 9 8 8 10 10 10 10 10 10 10 10 9 8 10 10 10 10 9 10 10 7 10 10          10 3 10 8 10                                                                     Soybean 10 8 8 9 9 9 10 9 9 9 9 8 9 7 10 8 8 10 9 10 3 5 7 6 0 6 0 9               Speedwell 5 2 -- -- -- 4 4 -- 10 0 6 3 0 0 0 0 0 -- 8 0 0 -- 0 0 0 3        0 7                                                                              Sugar beet 10 6 3 9 8 10 9 10 10 10 10 7 9 8 9 9 8 2 10 10 0 9 9 9 0 9         2 8                                                                              Velvetleaf 8 8 6 8 6 6 8 10 10 9 8 4 3 9 9 5 3 7 8 4 0 6 7 8 0 5 1 8               Wheat 6 7 5 9 8 9 9 10 10 9 9 8 0 8 8 7 7 3 9 7 3 9 9 9 6 9 4 9                   Wild buckwheat 8 6 9 9 9 10 10 10 9 -- 10 7 9 9 9 3 10 8 9 9 -- 10        10 10 6 -- -- 10                                                                 Wild oat 5 8 8 8 8 10 10 10 10 9 9 7 6 9 9 8 8 7 9 7 4 9 9 9 4 9 6 10             Barnyardgrass 3 0 0 2 0 0 6 9 9 7 9 2 1 6 7 8 9 0 0 0 0 0 0 3 0 7 0 8         Rice Japonica 8 0 0 7 6 6 7 8 9 9 8 5 7 9 8 8 9 0 8 6 5 5 3 8 0 8 1 8             Umbrella sedge 7 0 0 2 0 7 8 9 8 8 9 8 7 8 9 3 9 2 4 2 0 9 8 9 0 6 0         9                                                                                COMPOUND                                                                        284 285 286 287 288 289 291 292 300 301 302 305 310 1 2 3 5 7 11 13 14         25 26 27 28 29 30 31                                                             POSTEMERGENCE Rate (16 g/ha) Rate (8 g/ha)                                      Barley Igri 10 10 10 10 10 9 9 3 9 9 10 9 9 5 6 5 8 5 9 8 7 7 8 9 8 10         9 7                                                                              Bedstraw 10 10 10 10 10 10 10 7 9 10 10 10 10 8 8 -- 10 0 3 3 3 9 10 10        10 10 10 5                                                                       Blackgrass 9 10 10 10 10 10 10 9 10 10 10 10 8 5 8 7 9 5 7 6 3 8 10 10         9 9 10 6                                                                         Chickweed 10 10 10 10 10 10 10 8 10 9 10 9 6 5 5 6 9 0 9 8 8 9 10 10 3         10 10 --                                                                         Corn 10 10 10 10 10 10 10 10 9 9 10 9 9 6 8 10 10 6 9 10 9 9 10 10 10          10 10 8                                                                          Cotton 10 10 10 10 7 8 7 5 5 7 8 5 6 4 4 6 6 2 5 4 6 3 4 7 6 9 9 3                   Crabgrass 8 8 10 9 7 7 9 5 8 8 10 8 2 6 5 5 7 3 4 6 6 5 4 6 3 7 8         4                                                                                Downy brome 10 10 10 10 9 9 9 3 9 9 9 8 8 6 5 4 10 5 6 2 2 10 8 9 7 10         10 2                                                                             Duck salad 6 2 6 8 9 0 6 0 4 0 7 5 0 -- -- -- -- -- -- -- -- -- -- --          -- -- -- --                                                                      Giant foxtail 10 10 10 10 10 9 10 6 9 9 10 10 8 6 6 8 7 6 8 6 9 10 10          10 6 10 10 7                                                                     Lambsquarters 10 10 -- 10 10 8 9 5 10 10 10 9 8 9 10 10 10 8 9 8 5 10          10 10 9 10 10 9                                                                  Morningglory 10 10 10 10 10 8 8 1 6 8 9 8 10 6 10 7 6 6 6 4 6 10 10 10         10 10 10 6                                                                       Pigweed 10 10 10 10 8 7 9 7 7 9 9 8 6 3 4 3 10 0 7 8 0 7 6 10 8 10 9 6           Rape 10 10 10 10 10 0 9 9 9 9 9 9 9 2 5 7 10 0 6 10 10 3 6 9 9 10 10 0         Ryegrass 7 3 10 9 6 5 9 4 9 9 10 9 4 6 3 0 9 4 5 3 2 10 10 9 8 10 9 0             Sorghum 10 10 10 10 10 10 10 9 8 9 10 10 8 6 7 8 10 7 7 10 7 10 10 10        10 10 10 8                                                                       Soybean 9 9 10 10 10 8 8 0 8 9 10 8 9 6 7 7 10 0 7 10 8 8 10 10 10 10          10 6                                                                             Speedwell 7 0 10 0 10 4 0 8 9 10 5 10 9 4 4 0 8 0 0 2 0 5 2 0 5 8 0 0             Sugar beet 8 9 10 10 10 9 9 9 9 10 10 9 10 9 10 9 10 3 9 9 6 6 8 10 9        10 10 6                                                                          Velvetleaf 10 10 10 5 10 4 6 4 5 5 8 7 9 5 5 5 7 0 4 6 0 6 8 8 8 7 10 4         Wheat 9 9 10 9 9 9 9 2 9 9 9 9 4 5 4 0 9 4 9 8 8 8 4 9 5 10 9 4                         Wild buckwheat 10 10 10 10 10 -- 9 9 9 8 9 7 8 9 6 6 -- 0 8 2 3        8 6 9 9 10 10 0                                                                  Wild oat 9 9 9 9 9 8 9 4 9 10 10 8 9 8 7 7 7 4 8 2 2 8 8 8 6 7 9 6                   Barnyardgrass 3 0 9 9 9 0 2 0 4 6 9 9 0 0 0 0 5 0 3 3 0 3 7 4 8 6         5 0                                                                              Rice Japonica 3 3 9 9 8 0 3 2 6 5 4 7 0 3 2 0 8 0 0 4 4 3 3 0 8 8 8 0             Umbrella sedge 9 9 8 8 9 8 7 0 0 5 8 5 0 5 8 9 6 0 3 0 0 9 8 9 7 2 4          COMPOUND                                                                        34 35 36 50 51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103         107 108 109 110 111                                                              POSTEMERGENCE Rate (8 g/ha)                                                     Barley Igri 5 2 3 7 7 8 2 5 2 7 6 0 0 0 2 4 5 4 5 3 5 8 8 8 6 10 10 8             Bedstraw 3 7 10 8 9 7 9 10 10 6 7 5 2 5 5 7 9 7 6 8 10 8 8 10 10 8 9         9                                                                                Blackgrass 3 7 5 9 8 8 8 7 6 9 9 2 5 6 9 9 9 9 8 8 9 9 8 10 8 10 10 10           Chickweed 8 3 9 8 10 8 4 10 10 6 9 9 1 3 5 10 9 7 2 8 5 5 8 10 10 9 9         6                                                                                Corn 10 10 10 6 9 6 7 9 4 7 10 3 3 7 0 4 6 6 0 1 7 0 0 10 10 4 9 9                   Cotton 0 4 7 9 10 10 7 9 10 6 8 8 3 6 5 -- 9 8 4 7 4 2 7 10 10 8 8        10                                                                               Crabgrass 6 3 5 3 5 5 0 0 0 3 6 3 3 0 2 2 5 2 0 0 0 0 0 5 0 4 4 0                     Downy brome 5 3 7 6 7 9 2 6 2 8 7 0 1 0 3 2 2 0 3 5 0 7 6 8 3 9 9        8                                                                                Duck salad -- -- -- 9 9 9 7 10 10 8 8 9 0 4 0 6 7 0 7 0 7 0 0 10 9 9 9          Giant foxtail 7 7 8 6 6 8 3 3 0 7 9 0 5 6 5 6 7 4 4 2 0 4 2 6 2 6 7 4             Lambsquarters 5 10 10 10 10 10 7 10 10 10 10 5 8 8 5 8 10 9 9 8 9 9 9        10 10 10 10 10                                                                   Morningglory 7 9 10 10 10 8 10 8 9 9 10 9 7 8 8 10 10 7 8 9 10 7 8 10          10 5 10 10                                                                       Pigweed 7 7 8 9 10 8 3 10 8 10 10 10 7 9 7 8 10 8 4 2 2 7 9 10 8 8 8 10         Rape 3 0 9 10 10 10 9 10 10 10 10 5 7 8 8 9 7 9 9 9 10 9 7 10 9 10 10          10                                                                               Ryegrass 5 4 7 5 9 8 0 9 4 7 8 0 2 2 0 4 0 0 0 3 0 3 2 10 7 10 10 7                 Sorghum 7 8 10 7 9 6 6 4 4 10 10 4 7 7 10 9 10 9 9 7 8 9 9 10 9 9 8        10                                                                               Soybean 7 10 10 10 10 10 10 10 10 9 10 9 7 8 7 8 9 8 6 8 9 5 8 10 10 8         10 10                                                                            Speedwell 0 0 0 4 9 7 9 10 6 -- -- 0 2 2 2 4 0 -- -- 8 4 -- -- -- -- 6         8 4                                                                              Sugar beet 8 9 10 9 10 9 7 10 10 10 10 3 9 8 6 9 10 9 8 9 9 9 9 10 10 9        10 10                                                                            Velvetleaf 5 6 6 10 10 10 10 7 5 9 10 7 3 7 5 9 9 4 6 2 6 1 7 10 6 8 9         10                                                                               Wheat 4 4 4 5 8 9 0 0 0 7 7 0 0 0 0 3 2 2 2 4 3 8 6 8 3 9 9 6                   Wild buckwheat 0 0 3 6 10 7 5 10 10 6 7 0 2 5 9 7 8 4 5 8 8 5 5 9 10 8         9 --                                                                             Wild oat 5 7 8 4 8 6 2 5 3 5 5 0 0 0 4 0 0 5 0 2 0 5 5 9 7 9 9 6                       Barnyardgrass 0 0 7 5 9 9 7 7 5 8 8 0 0 5 2 8 8 3 8 0 2 0 2 8 7         8 8 6                                                                            Rice Japonica 6 0 5 0 9 9 7 8 9 7 8 8 0 6 0 6 7 3 6 0 2 0 0 9 8 8 8 7             Umbrella sedge 2 0 0 9 9 9 8 9 9 8 9 0 4 9 0 7 8 0 3 0 4 0 3 9 8 8 8         8                                                                                COMPOUND                                                                        112 114 115 116 117 118 119 120 121 122 125 166 167 170 172 173 203 204 2      05 206 207 208 209 211 212 213 214 217                                           POSTEMERGENCE Rate (8 g/ha)                                                     Barley Igri 6 6 3 4 0 0 9 5 7 5 0 6 9 4 9 9 7 9 10 9 7 7 0 9 7 4 4 8               Bedstraw 9 9 10 10 10 9 8 9 10 10 0 9 9 9 6 9 7 9 10 9 8 10 0 8 9 10        10 5                                                                             Blackgrass 10 9 9 8 7 6 10 10 9 9 0 8 8 9 10 10 9 10 10 10 10 9 2 9 8 7        7 7                                                                              Chickweed 8 7 5 10 10 0 9 10 10 10 0 10 9 10 5 4 7 9 10 10 7 7 0 8 5 10        10 3                                                                             Corn 8 9 9 4 0 0 10 10 10 10 0 10 10 10 8 8 10 10 10 10 10 9 0 8 10 9 8        8                                                                                Cotton 8 7 8 9 9 3 9 10 10 8 7 5 7 9 5 5 6 4 8 4 6 7 0 4 6 8 10 6                     Crabgrass 0 0 0 0 0 0 0 0 3 3 0 5 3 10 5 8 8 10 10 10 9 8 0 3 4 3        2 5                                                                              Downy brome 5 4 0 2 0 0 9 7 8 6 0 7 9 4 8 9 9 9 10 10 10 5 0 9 6 7 6 7           Duck salad 6 4 0 6 5 2 8 6 8 7 0 8 6 8 0 0 7 9 9 9 9 9 0 9 8 7 8 0                 Giant foxtail 0 6 3 4 0 0 7 6 7 2 0 5 4 10 8 9 5 8 10 10 10 10 0 8         7 5 3 6                                                                          Lambsquarters 10 5 5 5 0 0 10 10 10 4 7 10 10 10 9 9 10 10 10 10 9 10 0        10 10 10 10 10                                                                   Morningglory 10 7 9 10 10 8 10 10 10 10 10 8 7 9 9 8 9 10 10 7 7 10 0 8        10 10 10 10                                                                      Pigweed 10 6 3 7 5 0 10 10 10 10 8 4 5 10 8 9 10 10 10 10 5 10 0 8 3 9         9 5                                                                              Rape 10 9 9 9 9 9 10 10 10 10 9 9 9 10 0 6 9 10 10 9 9 10 0 6 8 10 10 9         Ryegrass 6 7 3 9 5 4 9 3 9 8 0 8 8 8 3 9 8 10 10 10 6 7 0 3 2 8 6 5                 Sorghum 9 7 8 9 7 0 9 10 9 8 2 9 10 10 6 8 10 10 10 10 10 10 3 7 10        10 10 8                                                                          Soybean 8 8 8 8 9 0 10 10 10 10 5 8 8 8 8 9 7 10 10 10 8 6 0 9 6 10 10         6                                                                                Speedwell 9 9 2 10 0 4 9 0 10 0 0 7 0 9 9 2 5 4 3 8 0 3 0 7 0 10 7 2               Sugar beet 8 6 5 9 9 3 10 10 10 10 7 10 10 10 8 9 10 10 10 10 8 10 0        8 7 10 10 8                                                                      Velvetleaf 8 8 9 9 6 0 10 10 10 6 8 8 7 9 6 5 7 8 10 7 5 7 0 8 8 8 3 5           Wheat 5 4 4 0 0 0 9 5 9 5 0 8 8 8 9 9 5 8 9 7 7 6 0 7 4 5 0 8                  Wild buckwheat 7 7 8 9 9 8 10 10 8 9 -- 6 6 9 9 8 8 9 9 9 7 7 0 7 8 10         9 3                                                                              Wild oat 5 5 0 4 3 0 8 4 9 8 0 8 8 5 6 8 7 9 9 9 8 5 0 5 4 5 4 8                       Barnyardgrass 6 8 8 6 3 3 6 3 8 2 0 0 0 8 0 0 1 5 8 9 7 9 0 9 6         8 3 0                                                                            Rice Japonica 8 8 7 7 6 4 6 3 8 7 0 4 0 8 0 0 9 6 9 8 9 9 0 8 8 8 8 7             Umbrella sedge 7 7 9 9 8 7 9 8 8 8 9 9 9 6 2 4 7 9 9 9 9 9 0 9 8 9 9         2                                                                                COMPOUND                                                                        218 219 225 229 230 231 232 240 241 242 243 244 245 252 254 256 258 259 2      61 266 267 268 269 270 271 272 274 275                                           POSTEMERGENCE Rate (8 g/ha)                                                     Barley Igri 5 3 8 7 6 6 7 9 9 10 9 7 9 6 5 8 9 7 9 6 9 6 5 9 9 9 0 8               Bedstraw 7 9 7 9 6 9 9 9 10 10 10 10 10 10 9 9 9 5 9 9 10 9 6 9 10 9        0 6                                                                              Blackgrass 6 6 5 9 9 9 9 10 10 10 10 10 10 9 8 9 9 9 9 9 10 9 9 10 10          10 8 10                                                                          Chickweed 8 8 8 7 3 4 10 10 10 10 10 10 0 3 9 8 9 3 7 0 7 9 0 5 10 10 0        6                                                                                Corn 7 7 9 8 8 8 8 10 10 10 10 10 10 9 7 10 10 9 10 9 9 10 6 10 10 10 0        10                                                                               Cotton 4 4 6 0 0 5 4 4 8 8 8 8 7 3 8 0 0 0 0 0 7 6 0 7 7 5 0 4                  Crabgrass 2 0 6 2 0 5 4 6 8 8 9 8 8 2 0 7 8 0 4 0 0 0 0 8 7 7 0 8                     Downy brome 7 4 6 5 5 8 8 9 9 10 10 10 8 9 6 9 9 9 9 7 9 8 5 --          10 9 4 9                                                                         Duck salad 0 0 0 0 2 0 0 5 6 8 7 4 7 0 2 0 0 0 0 0 0 0 0 0 0 0 0 2                   Giant foxtail 5 0 6 6 5 5 3 8 10 9 9 10 8 6 0 9 10 9 10 6 3 2 0 6         9 10 0 10                                                                        Lambsquarters 10 10 10 8 9 9 10 9 9 10 10 5 8 -- 0 9 10 10 8 -- -- 0 0         10 10 9 0 9                                                                      Morningglory 9 4 8 8 9 8 7 9 10 10 10 10 10 8 9 9 10 6 10 10 8 9 4 8 8         8 0 6                                                                            Pigweed 6 7 8 7 8 10 4 10 9 10 10 10 10 5 8 8 9 9 9 2 9 8 5 10 9 8 0 8           Rape 7 7 9 3 6 9 5 9 10 10 10 10 10 9 9 9 10 8 10 6 9 9 6 8 9 9 0 9               Ryegrass 4 6 3 0 0 9 6 10 9 10 10 9 9 0 4 9 9 9 9 0 8 7 0 5 9 10 0 9         Sorghum 6 3 8 8 8 9 10 9 10 10 10 10 10 9 8 10 10 10 10 9 10 9 6 10 10         10 0 10                                                                          Soybean 8 7 7 8 8 9 9 8 10 9 9 9 9 8 9 5 9 7 7 8 9 9 0 5 7 6 0 5                       Speedwell 0 3 3 -- 0 -- -- 3 3 -- 10 0 4 2 0 0 0 0 0 0 0 0 0 2 0        -- 0 0                                                                           Sugar beet 9 9 9 2 2 9 7 9 9 10 10 10 9 5 9 6 9 9 7 0 9 9 0 9 9 9 0 9             Velvetleaf 5 7 6 7 6 8 5 5 7 9 8 8 8 4 0 7 8 3 2 2 7 3 0 4 4 3 0 1               Wheat 4 3 3 5 4 9 8 9 9 10 10 6 8 5 0 7 7 7 7 3 8 4 3 9 9 9 5 9                   Wild buckwheat 7 7 6 5 6 8 8 10 10 10 9 8 9 -- 9 9 9 0 10 7 9 9 6         10 10 10 -- 10                                                                   Wild oat 4 4 4 6 7 8 7 9 9 10 10 9 9 4 6 8 9 8 7 5 8 7 4 9 9 9 3 9                   Barnyardgrass 1 3 0 0 0 0 0 0 2 6 8 0 8 0 0 0 4 5 8 0 0 0 0 0 0 0         0 0                                                                              Rice Japonica 7 6 5 0 0 2 0 3 0 7 8 5 8 4 6 8 0 7 8 0 6 0 2 3 2 8 0 8             Umbrella sedge 4 3 0 0 0 0 0 7 8 8 7 8 8 6 3 8 9 0 8 0 2 0 0 8 4 8 0         4                                                                                COMPOUND                                                                        276 283 284 285 286 287 288 289 291 292 300 301 302 305 310 1 3 5 11 13 1      4 25 26 27 28 29 30 31                                                           POSTEMERGENCE Rate (8 g/ha) Rate (4 g/ha)                                       Barley Igri 6 9 10 9 10 10 9 8 9 2 9 9 10 9 7 5 5 5 8 2 4 5 6 8 5 8 8 5         Bedstraw 2 10 10 10 10 10 10 9 9 6 9 10 10 10 9 5 9 9 0 2 2 7 10 -- 5          10 10 5                                                                          Blackgrass 8 10 9 9 10 9 10 10 10 9 9 10 9 10 7 5 7 7 7 3 0 8 9 7 7 9 9        5                                                                                Chickweed 0 10 10 10 10 10 10 9 9 8 9 9 10 9 5 0 0 8 8 5 5 8 10 10 2 10        10 --                                                                            Corn 8 10 10 10 10 10 10 10 9 9 8 9 10 9 8 6 10 10 7 10 8 8 10 10 8 10         10 7                                                                             Cotton 0 10 8 10 9 9 6 7 7 4 4 4 7 2 4 3 3 5 3 3 0 0 2 6 4 8 8 0                       Crabgrass 0 8 5 6 9 8 4 7 8 4 6 6 9 7 2 5 4 6 3 3 5 4 3 5 0 6 6         3                                                                                Downy brome 5 10 9 10 10 10 9 9 9 2 9 9 9 8 5 4 4 9 4 0 0 6 4 7 6 10 9          Duck salad 0 8 5 0 3 3 9 0 2 0 3 0 3 2 0 -- -- -- -- -- -- -- -- -- --         -- -- --                                                                         Giant foxtail 0 10 9 10 10 10 9 9 10 4 9 8 9 9 6 6 6 6 8 6 7 7 8 8 6 10        10 7                                                                             Lambsquarters 0 9 10 10 10 9 10 8 9 5 10 10 10 9 7 8 10 10 9 5 5 8 10          10 9 10 10 5                                                                     Morningglory 5 6 10 10 10 10 10 7 8 0 3 7 9 7 9 6 6 6 5 4 6 7 10 10 10         10 10 5                                                                          Pigweed 5 10 8 8 10 10 8 7 9 7 5 8 8 7 5 3 2 10 7 7 0 6 5 10 7 8 8 6               Rape 0 10 10 10 10 10 10 0 9 9 9 9 9 9 9 0 3 10 4 9 9 3 5 6 8 10 10          Ryegrass 0 9 4 0 10 8 5 4 9 3 8 7 9 5 0 3 0 7 4 0 0 9 9 7 6 8 6 0                     Sorghum 8 10 10 10 10 10 10 9 10 9 7 9 10 10 8 6 7 10 6 8 7 10 10        10 10 10 10 8                                                                    Soybean 0 9 9 9 10 10 10 8 8 0 8 8 10 8 8 5 7 10 6 8 7 7 7 10 8 10 10 5         Speedwell 0 5 6 0 10 0 9 4 0 5 8 10 0 9 9 4 0 7 0 0 0 4 2 0 3 7 0 0                 Sugar beet 0 8 -- 9 10 10 10 9 8 9 9 9 10 9 10 6 6 10 8 8 5 6 6 10         6 10 10 5                                                                        Velvetleaf 0 7 10 10 9 1 9 2 6 2 2 2 6 4 8 4 4 6 3 0 0 5 5 7 7 7 8 4               Wheat 4 9 9 9 10 5 8 7 9 0 8 8 9 8 3 4 0 9 9 3 3 6 4 7 4 8 9 2                     Wild buckwheat 0 10 -- 10 10 10 10 -- 9 7 8 8 6 -- 8 7 5 9 8 0 0         6 4 9 6 10 10 0                                                                  Wild oat 4 10 9 5 9 9 9 6 9 4 9 9 9 7 5 7 6 6 6 0 0 7 5 7 3 6 8 5                     Barnyardgrass 0 6 0 0 6 7 8 0 0 0 4 3 7 6 0 0 0 0 1 0 0 0 6 2 8 4        0 0                                                                              Rice Japonica 0 7 3 2 3 7 8 0 2 0 0 3 3 6 0 2 0 6 0 0 0 1 0 0 6 5 0 0             Umbrella sedge 0 9 8 6 0 0 9 6 3 0 0 2 6 2 0 2 8 3 0 0 0 8 5 9 7 0 0          COMPOUND                                                                        34 35 36 50 51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103         107 108 109 110 111                                                              POSTEMERGENCE Rate (4 g/ha)                                                     Barley Igri 2 0 2 4 7 8 0 4 1 6 6 0 0 0 2 3 3 3 3 3 3 8 7 7 3 9 9 7                 Bedstraw 2 7 9 7 9 5 8 9 9 5 4 4 0 4 4 6 8 0 6 7 9 7 8 10 10 8 9 9           Blackgrass 2 7 5 8 7 8 6 6 4 8 9 2 4 3 8 9 8 9 8 8 8 8 8 9 6 10 10 10           Chickweed 5 0 9 8 9 6 4 10 10 5 7 7 0 0 4 8 8 6 0 4 4 5 7 10 10 5 8 5           Corn 8 10 10 5 8 6 7 6 3 4 10 2 2 6 0 2 5 4 0 0 5 0 0 10 10 3 8 9                   Cotton 0 3 6 8 10 8 6 9 9 5 8 7 0 4 4 3 9 2 2 7 2 0 6 10 9 8 6 8             Crabgrass 4 3 4 0 4 5 0 0 0 0 2 3 3 0 0 2 5 0 0 0 0 0 0 2 0 2 2 0                 Downy brome 2 0 5 4 5 8 0 4 0 6 6 0 0 0 3 2 0 0 0 4 0 4 5 6 0 9 9 7         Duck salad -- -- -- 9 9 9 6 10 9 0 8 5 0 0 0 1 2 0 0 0 4 0 0 9 8 8 9 0           Giant foxtail 6 6 7 4 5 7 3 0 0 7 8 0 3 5 2 6 7 2 3 2 0 2 0 4 0 4 5 4           Lambsquarters 2 9 10 10 10 10 -- 10 10 10 10 1 6 7 5 6 9 9 6 8 9 9 --         10 10 10 10 10                                                                   Morningglory 6 8 9 10 10 8 8 7 8 9 10 8 5 7 7 9 9 6 6 7 10 7 8 10 10 3         10 10                                                                            Pigweed 7 6 8 7 10 7 3 10 8 8 10 8 7 9 3 8 10 6 0 0 0 7 8 10 8 8 8 10             Rape 2 0 8 10 10 9 8 10 10 9 9 5 6 7 8 9 6 9 7 8 10 9 6 10 9 9 10 10           Ryegrass 2 2 5 5 8 7 0 8 2 6 6 0 0 0 0 3 0 0 0 2 0 0 0 10 5 9 10 5                 Sorghum 7 6 10 6 8 6 5 3 3 9 9 3 6 7 9 9 9 9 9 7 7 8 9 9 8 9 8 9               Soybean 6 7 10 10 8 9 9 9 10 8 10 8 6 6 6 7 8 4 5 8 9 4 7 10 10 6 10        9                                                                                Speedwell 0 0 0 4 9 5 7 10 2 4 0 0 0 0 -- 0 -- 2 0 8 0 -- -- -- -- 6 8         4                                                                                Sugar beet 5 9 10 9 10 7 6 10 10 10 10 3 6 7 6 9 9 8 8 8 8 9 9 10 10 8         9 9                                                                              Velvetleaf 2 5 6 10 10 10 9 7 0 8 9 6 0 6 4 7 8 3 4 2 3 0 4 10 5 7 8 8           Wheat 2 2 3 4 6 9 0 0 0 6 5 0 0 0 0 0 2 0 2 2 0 8 6 7 0 9 9 5                  Wild buckwheat 0 0 2 5 10 6 3 10 7 5 5 0 0 4 8 5 8 4 5 5 2 4 4 9 10 8          -- 7                                                                             Wild oat 3 4 6 3 6 6 0 5 2 4 5 0 0 0 0 0 0 3 0 0 0 3 5 8 6 9 9 6                       Barnyardgrass 0 0 0 2 7 8 6 7 2 6 8 0 0 0 0 5 6 2 7 0 0 0 0 6 5         8 8 6                                                                            Rice Japonica 0 0 5 0 8 0 6 8 9 5 7 7 0 0 0 3 6 2 0 0 2 0 0 8 8 8 7 7             Umbrella sedge 2 0 0 8 9 9 7 9 9 1 9 0 2 3 0 4 8 0 0 0 2 0 0 9 8 7 8         7                                                                                COMPOUND                                                                        112 114 115 116 117 118 119 120 121 122 166 167 170 172 173 203 204 205 2      06 207 208 211 212 213 214 217 218 219                                           POSTEMERGENCE Rate (4 g/ha)                                                     Barley Igri 5 5 2 3 0 0 9 4 5 5 5 7 3 8 9 5 9 10 9 6 5 8 7 3 3 7 4 0               Bedstraw 8 8 10 10 10 8 8 7 10 10 5 6 9 6 8 6 6 9 7 7 7 6 7 10 9 3 4        8                                                                                Blackgrass 9 9 9 8 5 5 9 10 8 9 8 8 7 10 9 7 10 10 10 9 8 8 8 7 7 6 5 5         Chickweed 6 3 4 9 10 0 9 9 10 10 8 7 9 4 3 6 9 10 8 5 7 5 5 10 10 0 7 7         Corn 7 8 7 4 0 0 9 10 10 10 9 10 10 7 8 9 9 10 10 9 9 8 9 9 7 7 6 6                 Cotton 6 5 8 8 9 2 8 10 8 6 3 5 8 5 4 3 3 6 3 4 6 3 6 8 7 4 4 3                 Crabgrass 0 0 0 0 0 0 0 0 0 0 4 0 9 5 8 7 9 10 8 8 6 2 3 3 0 4 0 0           Downy brome 5 3 0 0 0 0 8 3 5 5 2 8 0 7 9 5 8 9 9 8 3 8 5 6 5 7 6 3               Duck salad 0 3 0 6 5 0 6 0 3 2 8 0 8 0 0 3 5 9 1 9 9 8 7 6 8 0 0 0             Giant foxtail 0 6 3 2 0 0 6 6 4 0 5 3 10 7 9 5 7 10 8 10 8 6 6 4 0 5         4 0                                                                              Lambsquarters 9 5 2 5 0 0 10 8 9 2 10 10 10 9 9 9 10 10 10 8 10 10 10          10 10 9 10 8                                                                     Morningglory 10 7 9 9 10 7 10 10 10 10 7 4 8 8 7 8 7 10 7 6 10 6 10 8          10 7 7 0                                                                         Pigweed 10 3 0 6 4 0 9 10 10 10 2 4 10 8 8 8 10 10 10 4 10 5 3 9 7 3 5         6                                                                                Rape 10 9 9 9 9 8 9 10 10 10 7 9 10 0 0 8 10 10 9 9 8 6 8 10 10 8 5 6             Ryegrass 6 7 0 7 2 2 8 3 9 6 3 7 7 3 7 4 8 10 6 4 5 3 0 7 4 4 3 4                 Sorghum 9 7 8 8 7 0 9 10 9 8 9 9 10 5 8 10 10 10 10 10 10 7 8 10 8         7 6 3                                                                            Soybean 8 7 8 8 9 0 9 10 10 10 8 7 8 7 8 7 9 10 9 7 5 8 6 10 10 5 7 7             Speedwell 7 9 2 10 0 -- 9 0 10 0 6 0 9 9 0 5 4 0 6 0 0 4 0 9 6 0 0 0           Sugar beet 8 3 5 9 9 3 9 10 10 10 9 9 10 7 9 8 9 9 9 5 8 6 7 10 10 7 9        8                                                                                Velvetleaf 7 7 8 9 5 0 9 10 9 5 7 7 9 5 4 6 7 9 5 4 6 3 5 8 3 3 5 6                 Wheat 3 4 3 0 0 0 9 4 5 5 5 5 8 7 9 3 7 8 7 7 3 7 3 3 0 6 3 0                     Wild buckwheat 7 5 7 9 9 5 10 7 8 9 5 5 8 8 8 7 8 9 7 3 7 5 7 10         7 2 7 7                                                                          Wild oat 4 4 0 3 3 0 4 2 9 6 6 8 4 5 7 5 8 9 8 8 4 4 3 4 4 6 3 3                       Barnyardgrass 5 7 4 4 0 2 0 0 6 2 0 0 7 0 0 1 3 7 7 2 8 7 3 2 2         0 0 1                                                                            Rice Japonica 8 8 6 6 5 4 0 2 7 0 4 0 7 0 0 8 4 8 6 8 9 6 6 6 7 7 4 2             Umbrella sedge 3 6 8 8 8 0 9 8 7 3 9 9 4 0 2 6 9 9 7 2 8 9 8 8 8 0 0          COMPOUND                                                                        225 229 230 231 232 240 241 242 243 244 245 252 256 258 259 261 266 267 2      68 270 271 272 274 275 276 283 284 285                                           POSTEMERGENCE Rate (4 g/ha)                                                     Barley Igri 6 6 5 5 4 9 8 10 7 5 8 6 8 8 6 7 4 6 5 9 8 9 0 7 5 9 9 9               Bedstraw 4 9 6 8 7 8 9 10 9 10 10 9 8 9 5 9 7 9 9 6 9 7 0 6 0 9 10          10                                                                               Blackgrass 4 9 9 9 9 10 10 10 10 10 9 9 9 8 8 8 9 9 9 8 9 10 2 9 4 9 9         9                                                                                Chickweed 8 2 0 0 8 9 8 10 10 10 0 0 7 9 3 7 0 2 3 4 9 9 0 5 0 9 10 10           Corn 7 8 8 7 7 10 10 10 10 10 9 9 10 10 9 10 9 8 9 10 10 10 0 10 4 9          10 10                                                                            Cotton 3 0 0 5 2 4 7 7 7 8 5 0 0 0 0 0 0 5 1 3 3 2 0 0 0 5 8 8                  Crabgrass 5 0 0 2 1 6 5 8 9 7 6 0 7 7 0 0 0 0 0 7 7 7 0 7 0 7 5 3                     Downy brome 4 0 3 7 7 8 8 9 9 9 6 8 9 8 8 8 5 8 6 7 9 9 0 9 3 9 9        9                                                                                Duck salad 0 0 0 0 0 5 2 4 7 0 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 4 0                   Giant foxtail 5 4 4 4 0 8 10 9 8 7 7 5 7 10 5 10 4 0 0 5 7 10 0 9         0 8 8 9                                                                          Lambsquarters 10 7 8 -- 10 9 8 10 10 4 8 0 9 10 8 8 0 7 0 8 9 9 0 6 0 8        9 9                                                                              Morningglory 6 8 8 8 7 9 10 10 9 10 10 7 9 10 5 8 9 8 8 7 8 5 0 3 4 5          10 10                                                                            Pigweed 8 1 6 9 3 10 7 10 10 8 9 5 8 8 8 8 0 8 7 10 8 8 0 8 2 9 7 8                 Rape 9 0 2 8 5 9 9 10 10 9 9 8 8 9 7 9 4 8 9 8 9 8 0 9 0 10 9 9                 Ryegrass 0 0 0 4 3 10 7 10 10 4 8 0 9 9 8 8 0 8 3 4 4 8 0 9 0 8 0 0         Sorghum 7 8 8 9 9 9 10 10 10 10 10 9 10 10 10 9 9 9 9 10 9 9 0 9 8 10 9        10                                                                               Soybean 6 7 3 8 6 8 8 9 9 9 8 8 5 9 7 4 8 8 9 4 7 5 0 4 0 9 8 9                         Speedwell 3 0 0 -- -- 0 3 6 10 0 3 0 0 0 0 0 0 5 0 0 0 0 0 0 0         3 5 0                                                                            Sugar beet 8 2 2 8 5 9 8 10 10 10 8 0 6 8 9 7 0 9 8 9 9 9 0 5 0 8 8 9             Velvetleaf 5 5 4 7 4 5 6 9 8 7 7 0 6 7 0 0 0 5 0 0 0 3 0 0 0 7 8 10             Wheat 3 3 3 7 4 8 9 9 8 4 5 5 7 7 6 7 0 6 4 9 8 8 0 8 2 9 9 9                         Wild buckwheat 6 4 5 8 7 9 9 -- 9 -- 9 -- 9 8 0 9 7 5 7 9 9 9          -- 10 -- 9 -- 10                                                                 Wild oat 2 4 6 5 4 9 9 10 10 9 8 4 7 8 7 7 4 6 7 8 5 9 0 8 0 10 7 5                 Barnyardgrass 0 0 0 0 0 0 0 5 6 0 7 0 0 0 0 6 0 0 0 0 0 0 0 0 0 2 0         Rice Japonica 0 0 0 0 0 0 0 7 6 4 8 3 6 0 5 8 0 0 0 0 0 6 0 7 0 6 2 2             Umbrella sedge 0 0 0 0 0 7 7 7 6 3 7 0 6 8 0 1 0 0 0 7 3 3 0 3 0 8 7          COMPOUND                                                                        286 287 288 289 291 300 301 302 305 310 25 26 27 28 29 30 31 34 36 107         204 205 206 207 240 241 242 243                                                  POSTEMERGENCE Rate (4 g/ha) Rate (2 g/ha)                                       Barley Igri 10 9 8 7 9 9 9 9 8 4 3 5 6 5 6 7 4 0 2 4 7 10 7 4 8 6 9 6             Bedstraw 10 9 10 9 8 8 8 9 7 5 6 6 8 4 10 7 5 0 8 10 5 5 4 6 7 6 8 9           Blackgrass 9 9 9 10 10 9 9 9 9 6 7 9 7 7 6 5 4 0 4 9 10 10 10 9 9 9 9         10                                                                               Chickweed 10 10 10 9 7 8 9 9 9 -- 5 6 9 0 9 10 0 2 8 10 8 10 6 5 5 6 8         9                                                                                Corn 10 10 10 9 9 7 8 10 8 7 7 10 10 7 10 10 6 7 10 10 8 9 10 7 10 9 10        10                                                                               Cotton 9 8 3 5 3 2 0 5 0 0 0 2 4 2 7 6 0 0 3 10 0 4 2 0 1 3 2 5                         Crabgrass 8 8 0 5 8 5 4 8 5 0 3 2 4 0 5 5 0 3 3 0 8 10 7 7 5 4         7 8                                                                              Downy brome 9 5 8 8 9 7 8 9 7 0 4 2 4 6 9 5 0 0 4 3 8 9 9 7 5 5 9 9                 Duck salad 1 1 8 0 0 0 0 0 0 0 -- -- -- -- -- -- -- -- -- 7 0 9 0 3        0 0 0 5                                                                          Giant foxtail 9 10 8 7 8 8 7 9 7 5 6 7 7 6 10 9 6 5 7 2 6 9 7 7 5 8 9 8         Lambsquarters 10 9 10 8 9 9 9 9 9 4 6 10 10 8 10 10 5 0 8 10 10 10 9 8         8 7 10 10                                                                        Morningglory 10 10 10 7 7 2 6 9 4 9 7 8 9 10 8 10 4 5 7 10 7 10 6 5 8 8        8 8                                                                              Pigweed 8 10 8 7 8 5 7 8 7 2 5 4 9 6 7 7 5 6 7 10 10 10 9 3 9 7 10 10             Rape 10 10 10 0 9 7 9 9 9 9 3 2 6 7 7 8 0 0 6 9 5 9 9 7 7 9 10 8                   Ryegrass 9 4 4 0 8 6 4 4 0 0 4 6 3 5 7 0 0 0 2 8 6 10 6 -- 7 2 5          10                                                                               Sorghum 10 10 10 9 9 7 8 9 9 8 10 9 10 9 10 10 8 6 10 8 10 10 10 10 9          10 10 10                                                                         Soybean 10 10 9 8 7 7 8 10 6 8 6 6 10 7 10 10 3 3 8 10 8 10 7 6 5 8 9 9         Speedwell 10 0 8 0 0 -- 10 -- 6 8 2 0 0 2 5 0 0 0 0 -- -- 0 3 0 0 2 0 9         Sugar beet 10 10 9 8 7 9 9 10 9 9 5 4 6 6 10 10 4 3 9 10 8 7 9 4 9 8 9         10                                                                               Velvetleaf 8 0 8 0 4 0 0 6 0 6 4 4 5 5 7 7 3 0 5 9 7 8 3 2 5 6 6 7                   Wheat 9 4 8 7 6 7 5 9 5 0 5 4 3 4 6 8 0 0 2 3 4 7 6 4 7 5 7 5                   Wild buckwheat -- 10 10 5 9 8 3 6 -- 8 6 -- 7 5 9 9 0 0 2 9 6 8 0         3 9 -- 9 6                                                                       Wild oat 9 5 8 5 8 7 8 9 4 2 5 4 5 0 4 6 0 0 4 6 7 9 7 6 8 8 9 10                     Barnyardgrass 4 4 7 0 0 3 0 2 2 0 0 0 2 7 1 0 0 0 0 4 0 5 0 0 0 0        3 3                                                                              Rice Japonica 2 2 7 0 0 0 2 -- 4 0 0 0 0 5 0 0 0 0 0 7 3 3 3 6 0 0 6 2           Umbrella sedge 0 0 7 0 0 0 0 2 0 0 2 5 8 7 0 0 0 2 -- 8 7 9 3 0 0 3 7         3                                                                                COMPOUND                                                                        244 245 272 283 284 285 286 287 288 291                                         POSTEMERGENCE Rate (2 g/ha)                                                     Barley Igri 4 8 5 9 8 8 9 9 8 7                                                 Bedstraw 9 9 0 8 9 10 10 8 10 5                                                 Blackgrass 9 9 9 9 9 9 9 9 8 10                                                 Chickweed 10 0 9 9 10 10 9 10 9 5                                               Corn 10 9 9 9 10 10 10 9 9 9                                                    Cotton 8 4 0 3 7 6 5 5 3 0                                                      Crabgrass 4 4 6 5 3 0 7 7 0 5                                                   Downy brome 8 4 7 7 5 6 8 0 6 6                                                 Duck salad 0 2 0 2 0 0 0 0 2 0                                                  Giant foxtail 6 6 10 7 6 9 9 7 7 7                                              Lambsquarters 3 8 7 8 9 9 9 6 8 9                                               Morningglory 9 8 3 4 5 10 7 9 8 5                                               Pigweed 7 8 7 9 7 8 6 10 7 7                                                    Rape 8 9 3 9 7 6 9 10 9 7                                                       Ryegrass 0 4 2 3 0 0 2 0 2 5                                                    Sorghum 10 10 9 9 9 9 10 10 10 8                                                Soybean 8 6 4 6 8 9 10 9 8 5                                                    Speedwell 0 0 0 0 3 0 9 0 7 0                                                   Sugar beet 10 -- 6 6 8 9 10 10 9 7                                              Velvetleaf 6 5 0 7 8 10 6 0 8 2                                                 Wheat 3 4 4 9 8 5 9 3 7 6                                                       Wild buckwheat -- 9 9 8 8 -- 9 10 10 --                                         Wild oat 7 4 5 8 6 2 9 0 4 5                                                    Barnyardgrass 0 5 0 0 0 0 0 0 2 0                                               Rice Japonica 0 7 1 2 0 1 1 2 3 0                                               Umbrella sedge 0 0 2 8 5 0 0 0 0 0                                              COMPOUND                                                                        2 7 125 209 254 269 292 1 2 3 5 7 11 13 14 35 50 51 53 58 59 60 63 64          71 77 78 81                                                                      PREEMERGENCE Rate (125 g/ha) Rate (62 g/ha)                                     Barley Igri 10 4 0 0 9 0 2 8 9 6 7 2 0 3 0 3 8 9 9 7 7 4 9 9 2 6 5 9               Bedstraw 10 5 8 5 10 8 3 10 10 10 10 0 9 9 8 10 10 10 10 10 10 10 9         9 9 6 8 8                                                                        Blackgrass 10 7 9 0 10 10 0 9 10 9 9 6 8 8 6 8 9 9 10 8 8 8 10 10 7 8 8        9                                                                                Chickweed 10 4 9 5 10 3 9 7 10 10 10 0 10 10 10 10 10 10 10 10 10 10 9         10 8 7 8 8                                                                       Corn 9 0 2 0 10 0 0 4 9 10 7 0 4 9 3 6 2 10 7 8 8 7 10 10 5 2 8 --                   Cotton 5 0 3 0 9 2 0 4 4 7 8 0 4 9 3 7 8 10 9 5 9 9 9 9 9 4 8 --             Crabgrass 9 4 3 3 7 6 3 7 8 9 8 3 6 4 0 8 9 10 10 7 7 6 10 9 6 6 8 --         Downy brome 10 7 0 7 9 9 2 9 10 9 10 5 7 7 6 10 9 9 9 7 8 7 10 9 2 7 6         9                                                                                Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 10 5 0 0 8 6 0 5 9 9 7 4 8 3 2 9 8 9 10 6 4 3 9 9 0 6 9          --                                                                               Lambsquarters 10 8 10 0 9 10 0 10 10 10 10 5 10 10 10 10 10 10 10 10 10        10 10 10 8 8 9 10                                                                Morningglory 6 3 7 0 9 0 0 0 4 6 8 0 5 8 0 8 9 10 8 0 10 10 9 10 8 6 10        --                                                                               Pigweed 10 7 9 0 9 8 7 9 10 9 10 6 8 9 8 8 10 10 10 10 9 9 9 10 9 9 9          --                                                                               Rape 10 3 10 0 10 3 3 9 10 10 10 0 6 10 8 9 9 9 9 10 10 10 10 10 9 10 9        9                                                                                Ryegrass 10 5 4 4 9 0 3 9 6 3 10 3 8 7 4 10 9 9 10 8 10 8 10 10 6 5 8 9         Sorghum 9 7 4 3 9 3 4 9 9 9 9 6 9 9 6 9 9 10 9 10 10 8 9 10 7 8 10 --             Soybean 8 0 3 0 10 3 0 4 7 6 7 0 3 8 3 3 8 10 8 5 9 9 10 9 9 6 9 --             Speedwell 10 9 10 0 9 10 4 9 10 8 10 5 4 9 7 10 10 10 10 10 10 9 10 8        6 3 6 9                                                                          Sugar beet 10 7 10 4 10 -- 6 9 10 10 10 0 9 9 9 10 9 9 9 10 10 10 10 10        9 9 9 9                                                                          Velvetleaf 9 4 7 0 8 4 3 7 9 7 9 3 8 8 0 8 9 9 9 8 10 8 9 9 9 7 8 --               Wheat 10 7 0 0 3 0 0 9 10 8 9 2 0 0 2 4 8 9 9 0 6 4 9 9 3 5 4 8                   Wild buckwheat 10 2 9 5 9 9 7 10 10 10 10 0 7 8 8 9 9 9 9 8 9 8 9         8 6 8 8 9                                                                        Wild oat 9 3 2 0 9 2 0 4 7 5 4 2 0 0 0 5 7 9 9 4 6 7 7 8 0 2 3 8                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        82 83 84 86 88 89 102 103 108 109 110 111 112 114 115 116 117 118 119          120 121 122 125 166 167 170 172 173                                              PREEMERGENCE Rate (62 g/ha)                                                     Barley Igri 6 6 8 9 6 8 8 9 9 9 9 5 5 8 2 9 4 2 10 9 9 9 0 7 0 2 5 0               Bedstraw 9 9 7 9 9 9 9 9 10 10 10 10 10 9 9 9 9 9 9 9 10 10 8 9 9 10        8 8                                                                              Blackgrass 10 10 9 9 9 9 10 10 10 10 10 10 10 9 9 9 8 8 10 10 10 10 9 9        9 9 10 9                                                                         Chickweed 10 10 8 9 10 10 9 9 10 9 9 9 9 10 8 10 9 9 10 10 10 10 9 9 9         10 9 8                                                                           Corn -- -- 10 4 8 7 7 2 10 8 9 5 6 9 9 9 6 6 9 9 10 10 0 9 10 10 4 9               Cotton -- -- 9 9 9 7 4 9 10 9 10 8 9 6 5 9 10 5 10 8 10 10 3 7 3 9 6        8                                                                                Crabgrass -- -- 6 7 3 8 3 4 10 9 9 7 7 8 5 9 7 3 7 6 8 7 3 9 8 9 9 9               Downy brome 9 7 6 7 7 5 8 9 9 9 9 9 9 8 5 8 7 4 10 9 10 10 0 9 9 6 4        8                                                                                Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail -- -- 10 8 8 8 8 8 9 9 9 9 7 9 7 8 6 5 8 8 8 6 0 9 8 9 9         9                                                                                Lambsquarters 9 9 10 10 9 10 10 10 10 9 10 9 9 9 8 10 9 9 10 10 10 9 10        10 10 10 10 10                                                                   Morningglory -- -- 9 9 7 9 8 9 10 8 9 7 9 9 9 9 10 7 9 9 9 9 5 7 5 9 6         5                                                                                Pigweed -- -- 7 9 9 9 9 9 10 9 10 10 9 9 9 9 9 8 9 9 10 9 9 9 8 9 9 9             Rape 9 9 9 9 9 9 9 9 10 9 9 9 9 9 9 10 9 10 10 10 10 10 9 9 9 10 3 7           Ryegrass 6 9 9 7 6 8 1 2 10 10 9 8 9 9 5 9 8 8 10 9 10 10 2 9 9 9 5 9           Sorghum -- -- 9 10 9 9 9 9 10 9 9 10 10 9 9 9 9 5 9 9 10 10 0 9 9 9 6         9                                                                                Soybean -- -- 9 6 9 8 2 7 10 8 10 6 5 7 4 9 9 1 9 8 10 10 2 8 3 9 6 8             Speedwell 10 10 9 9 9 9 9 8 7 9 10 9 10 10 10 10 8 10 10 10 10 5 10          10 8 10 10 10                                                                    Sugar beet 9 9 9 9 9 9 9 9 10 10 9 9 9 9 9 9 9 9 10 10 10 10 9 10 10 10        10 9                                                                             Velvetleaf -- -- 8 8 7 9 7 9 9 9 10 9 10 9 8 9 9 7 9 9 10 9 7 8 7 9 6 7         Wheat 8 8 9 5 5 8 6 8 9 9 7 5 4 6 1 4 3 0 9 9 9 9 0 8 4 9 7 0                   Wild buckwheat 9 9 6 9 9 9 9 9 9 9 9 10 9 9 9 9 9 10 10 10 10 10 9 7 9         8 10 10                                                                          Wild oat 5 7 9 3 0 3 4 7 9 9 9 0 5 7 3 8 7 3 9 6 9 9 0 5 5 5 4 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        203 208 209 211 212 213 214 217 218 219 225 229 230 231 232 252 254 256 2      58 259 261 266 267 268 269 270 271 274                                           PREEMERGENCE Rate (62 g/ha)                                                     Barley Igri 9 9 0 6 3 8 9 9 8 2 7 9 5 9 9 2 7 9 8 6 9 3 9 9 0 9 9 2                 Bedstraw 8 10 3 10 10 10 10 9 9 10 9 9 9 10 10 9 10 10 10 9 10 9 10        10 6 9 9 0                                                                       Blackgrass 9 9 0 9 9 9 8 9 9 8 5 9 9 9 9 10 9 10 10 10 10 10 10 10 9 10        10 9                                                                             Chickweed 9 9 3 10 10 10 9 10 10 10 8 9 9 9 2 10 10 6 10 9 9 8 10 10 0         0 10 0                                                                           Corn 9 10 0 10 9 10 10 9 8 0 10 6 3 9 9 8 10 9 10 10 9 7 10 9 0 9 7 0             Cotton 8 8 0 8 6 10 10 7 7 10 9 3 -- 9 8 3 9 10 8 8 9 6 9 9 0 9 8 0             Crabgrass 8 10 0 10 8 9 7 6 8 0 3 4 7 7 7 4 6 8 9 8 9 5 7 6 1 9 9 3             Downy brome 10 9 5 9 8 9 9 9 9 8 -- 7 7 10 10 10 9 10 10 10 10 9 10          10 3 10 10 9                                                                     Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 4 9 0 10 8 9 4 5 7 0 5 10 6 7 6 6 6 8 9 9 9 4 6 6 0 9 9 5         Lambsquarters 9 10 0 9 9 10 10 10 10 8 -- 10 6 9 10 9 8 10 10 10 10 9          10 9 9 9 10 0                                                                    Morningglory 8 9 0 4 6 10 10 3 5 3 9 4 2 9 9 0 9 9 7 5 9 8 9 9 0 3 9 0           Pigweed 9 10 0 10 9 10 10 8 9 7 9 9 8 9 10 7 9 8 9 9 10 7 9 9 7 9 9 5           Rape 10 10 0 9 9 10 10 9 5 9 8 0 3 3 5 9 10 9 9 9 9 7 9 9 2 9 8 0                   Ryegrass 9 10 3 8 4 9 7 8 6 7 0 2 0 9 8 5 9 10 10 9 10 3 9 6 0 9 9         Sorghum 10 10 3 10 9 10 10 10 9 4 9 9 9 10 9 9 9 10 9 9 10 9 10 9 2 9 9        4                                                                                Soybean 7 8 0 7 6 10 10 5 6 4 9 6 6 9 8 6 9 8 7 6 7 6 8 8 0 3 4 0                     Speedwell 8 9 0 10 10 10 8 10 9 2 -- 9 9 9 0 10 9 9 7 8 9 9 10 8         9 9 9 0                                                                          Sugar beet 9 9 4 9 9 10 10 9 9 10 8 8 5 9 9 8 9 9 9 9 9 5 9 9 -- 10 10          Velvetleaf 9 10 0 8 5 10 7 8 8 5 9 9 4 9 5 5 7 9 9 7 7 8 8 3 1 5 4 3               Wheat 9 9 0 7 3 9 5 9 7 0 3 8 5 9 9 0 0 9 8 9 8 3 9 6 0 9 9 7                       Wild buckwheat 9 9 3 9 9 9 9 8 9 9 9 8 9 9 8 9 9 9 9 9 9 10 9 9         9 9 9 --                                                                         Wild oat 6 7 0 5 2 7 6 7 5 4 4 6 2 9 8 2 8 9 9 9 9 5 6 5 0 9 9 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        275 276 289 292 300 301 302 305 310 1 2 3 5 7 11 13 14 25 26 27 28 29          30 31 34 35 36 50                                                                PREEMERGENCE Rate (62 g/ha) Rate (31 g/ha)                                      Barley Igri 10 0 5 0 4 5 9 9 0 5 7 6 6 0 0 0 0 2 1 2 2 2 0 2 0 0 2 6               Bedstraw 10 0 9 0 4 8 10 9 8 9 10 10 10 0 5 8 8 8 8 8 9 9 10 8 9 9          10 9                                                                             Blackgrass 10 5 9 0 9 9 10 10 9 8 8 9 7 4 7 7 4 8 8 9 8 9 7 4 4 7 8 9             Chickweed 10 3 9 5 7 9 10 10 9 6 10 10 10 0 10 8 10 8 9 9 8 9 10 0 8         10 10 10                                                                         Corn 10 0 6 0 5 2 3 7 4 0 8 8 6 0 4 8 3 9 9 9 10 10 10 8 0 2 3 0                       Cotton 9 0 0 0 4 8 9 8 9 3 3 6 7 0 4 9 3 6 7 8 5 9 9 2 0 7 9 8             Crabgrass 10 0 2 2 5 7 9 7 0 3 8 7 7 0 2 2 0 8 10 9 8 9 9 7 7 4 8 8             Downy brome 10 0 7 0 8 9 10 9 0 8 9 6 10 4 3 6 3 4 3 4 7 7 9 1 0 8 8         8                                                                                Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 9 3 7 0 8 7 9 9 0 3 8 8 4 3 5 3 2 7 9 9 7 9 9 8 6 7 9 8             Lambsquarters 10 0 0 0 9 10 10 10 10 9 10 10 10 5 10 9 10 3 7 10 5 9         8 5 6 10 10 10                                                                   Morningglory 5 0 0 0 7 7 9 7 7 0 3 5 8 0 2 6 0 6 7 2 7 9 9 5 2 3 8 9               Pigweed 9 3 9 0 9 9 9 9 8 7 10 7 10 6 7 9 8 9 9 8 8 9 10 7 8 8 9 10           Rape 9 0 1 0 6 6 10 4 3 6 10 9 10 0 4 9 8 6 4 8 9 8 8 3 0 6 8 9                       Ryegrass 10 0 6 0 4 5 10 7 2 6 4 2 8 0 5 7 3 5 8 5 9 4 8 3 0 6 7        9                                                                                Sorghum 10 8 9 1 6 5 9 9 0 7 8 9 9 4 8 9 5 10 10 9 9 10 10 7 5 9 9 8               Soybean 6 0 0 0 3 3 6 5 5 4 5 4 7 0 2 3 2 3 5 4 4 9 8 2 2 2 6 7                   Speedwell 10 6 10 -- 8 10 10 10 10 7 10 5 10 0 4 8 7 8 8 2 8 9 3 0        6 10 8 9                                                                         Sugar beet 10 0 9 4 9 9 10 10 10 8 10 10 10 0 9 8 8 9 9 8 8 9 10 2 9 10        10 9                                                                             Velvetleaf 3 5 4 0 6 6 9 6 8 6 7 5 8 0 4 8 0 7 7 8 7 9 8 3 0 5 8 8                   Wheat 10 0 1 0 6 6 9 5 0 6 8 7 8 0 0 0 2 4 4 0 2 3 1 2 0 3 0 5                 Wild buckwheat 10 3 8 5 4 8 10 9 9 9 10 10 10 0 6 8 7 7 7 7 8 9 8 0        0 9 10 --                                                                        Wild oat 9 0 5 0 4 5 9 6 0 3 5 3 3 0 0 0 0 5 4 0 3 4 3 2 3 4 3 5                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103 107 108 109         110 111 112 114 115 116                                                          PREEMERGENCE Rate (31 g/ha)                                                     Barley Igri 9 9 3 7 3 9 9 0 4 5 8 6 4 3 6 6 6 7 8 9 9 9 9 3 4 6 0 8                 Bedstraw 10 10 10 10 10 9 9 9 2 8 7 9 9 0 9 9 9 9 9 10 10 10 10 9          10 9 9 9                                                                         Blackgrass 9 10 8 8 7 9 9 6 8 7 9 9 10 8 9 9 9 9 9 10 10 10 10 10 9 9 9        9                                                                                Chickweed 10 10 9 10 10 9 9 8 5 7 7 10 10 7 9 9 9 9 9 10 9 9 9 9 9 9 8         9                                                                                Corn 10 6 7 7 4 9 10 0 0 6 -- -- -- 10 4 6 7 7 0 10 10 7 8 3 5 9 6 8               Cotton 10 8 4 9 9 8 9 7 0 7 -- -- -- 8 9 9 7 4 9 10 10 9 10 6 8 4 2         9                                                                                Crabgrass 10 9 6 7 3 9 9 3 3 6 -- -- -- 6 7 2 5 0 3 9 9 8 9 4 4 7 3 8             Downy brome 9 9 6 7 7 10 8 2 6 4 8 7 5 -- 6 6 5 5 8 9 8 9 9 6 6 7 3 7         Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 8 9 6 3 0 9 9 0 5 7 -- -- -- 6 8 5 7 7 7 9 8 8 9 7 5 9 5         8                                                                                Lambsquarters 10 10 9 10 10 10 10 8 6 7 9 9 9 9 10 8 10 10 10 10 10 9          10 9 9 9 8 9                                                                     Morningglory 10 5 0 10 10 9 10 8 2 9 -- -- -- 7 8 5 9 8 9 10 10 7 8 7 9        8 7 9                                                                            Pigweed 10 10 9 9 9 9 10 9 9 9 -- -- -- 7 8 8 9 9 9 10 10 9 10 10 9 9 9        9                                                                                Rape 9 9 10 10 10 10 10 9 9 9 9 9 9 3 9 9 9 9 9 10 10 9 9 9 9 9 9 9                 Ryegrass 9 10 7 10 8 10 9 6 5 8 6 5 5 4 5 6 8 1 2 10 10 10 9 7 9 8         5 9                                                                              Sorghum 10 9 10 10 8 9 10 7 7 10 -- -- -- 9 9 9 9 9 9 9 10 9 9 4 10 9 9        9                                                                                Soybean 10 7 4 8 8 9 9 8 4 7 -- -- -- 8 6 7 8 0 6 10 9 8 9 6 5 6 2 8               Speedwell 10 10 10 10 9 9 8 5 0 2 9 10 10 9 9 9 9 9 8 10 7 9 10 8 10        9 8 10                                                                           Sugar beet 9 9 10 10 10 10 10 9 9 9 9 9 9 4 9 9 9 9 9 10 10 9 9 9 9 9 7        9                                                                                Velvetleaf 9 8 8 10 8 9 9 9 4 7 -- -- -- 7 8 6 8 7 8 10 9 9 9 7 9 7 7 9         Wheat 9 9 0 5 3 9 9 2 3 4 7 5 3 4 3 4 4 4 7 9 6 9 7 5 4 3 0 1                   Wild buckwheat 9 9 8 9 8 9 8 5 6 7 9 9 8 5 9 9 8 9 9 9 9 -- 7 10 -- 9 9        9                                                                                Wild oat 9 8 3 6 6 6 5 0 0 1 7 4 2 6 2 0 3 4 5 9 9 9 8 0 0 5 0 8                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        117 118 119 120 121 122 125 166 167 170 172 173 203 204 205 206 207 208 2      09 211 212 213 214 217 218 219 225 229                                           PREEMERGENCE Rate (31 g/ha)                                                     Barley Igri 4 0 9 6 9 9 0 6 0 0 2 0 8 8 9 9 7 9 0 4 0 7 6 6 6 0 5 9                 Bedstraw 9 9 9 7 10 10 5 9 9 9 4 6 7 10 10 10 9 9 0 9 8 10 10 8 8 9        9 8                                                                              Blackgrass 8 7 10 10 10 10 5 8 9 7 9 9 8 9 9 9 9 9 0 8 9 9 8 9 9 6 5 9           Chickweed 9 8 10 10 10 10 8 9 9 9 6 -- 9 9 9 9 9 9 0 9 10 10 9 9 10 9         7 7                                                                              Corn 5 4 9 8 10 9 0 9 9 10 3 5 4 8 10 10 10 9 0 8 5 10 10 4 5 0 7 4                 Cotton 9 5 9 8 10 10 0 7 0 9 4 6 7 8 9 9 8 -- 0 6 5 10 10 5 7 7 9 2         Crabgrass 6 2 7 6 5 7 2 9 8 9 7 8 8 10 10 9 9 10 0 9 7 8 6 5 5 0 2 3               Downy brome 5 3 10 7 10 10 0 8 5 6 4 5 9 9 9 10 9 9 3 8 6 9 8 9 9 7         5 7                                                                              Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 5 1 8 7 5 5 0 9 4 9 7 9 3 10 9 9 9 9 0 9 7 8 3 4 4 0 3 7           Lambsquarters 9 9 10 10 10 9 9 8 10 10 10 9 9 9 10 10 9 9 0 9 -- 10 10        -- 10 8 -- 9                                                                     Morningglory 10 6 9 9 9 9 3 5 5 8 5 2 6 7 9 8 8 9 0 3 5 10 9 3 4 2 9 2           Pigweed 9 7 9 9 9 9 8 9 8 9 9 9 9 10 10 10 9 10 0 10 6 10 9 7 8 6 7 9           Rape 9 6 10 10 10 10 8 9 7 10 3 2 10 10 9 9 9 10 0 9 6 10 10 8 4 6 5 0         Ryegrass 7 6 10 5 10 10 0 9 5 9 5 6 8 8 9 9 9 9 0 5 0 9 7 6 6 5 0 2                 Sorghum 9 3 9 9 10 10 0 9 9 9 5 6 9 10 10 10 10 10 2 10 6 10 8 9 6         2 9 8                                                                            Soybean 8 0 8 7 10 10 0 5 2 8 3 5 6 7 7 7 8 7 0 6 4 10 9 3 6 2 7 4                   Speedwell 8 10 10 10 10 5 9 10 -- 10 9 9 7 8 8 9 3 9 0 9 10 10 8 9        -- 0 9 8                                                                         Sugar beet 9 8 10 10 10 10 9 10 9 10 9 9 9 10 10 9 9 9 4 9 6 10 10 9 9         9 -- 5                                                                           Velvetleaf 9 2 9 9 9 9 5 7 6 9 6 4 9 8 9 9 9 9 0 7 3 10 7 7 5 2 9 7                 Wheat 0 0 9 6 9 9 0 7 0 9 4 0 9 8 9 9 9 9 0 7 0 9 4 5 6 0 -- 7                   Wild buckwheat 9 9 10 10 9 10 9 -- 7 8 9 9 9 9 9 9 8 9 3 9 5 9 9 6        8 8 9 4                                                                          Wild oat 5 0 8 4 9 9 0 4 2 2 0 0 6 6 7 8 7 7 0 3 0 6 5 5 3 2 2 2                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        230 231 232 240 241 242 243 244 245 252 254 256 258 259 261 266 267 268 2      69 270 271 272 274 275 276 283 284 285                                           PREEMERGENCE Rate (31 g/ha)                                                     Barley Igri 0 9 9 9 9 6 9 8 9 0 5 9 8 4 9 1 9 5 0 6 9 2 0 9 0 9 -- 0               Bedstraw 5 10 10 10 10 10 10 10 10 9 9 9 10 6 10 8 10 10 2 8 8 8 0          10 0 10 10 4                                                                     Blackgrass 9 9 9 10 10 10 10 10 10 10 9 10 10 10 10 10 10 10 9 10 10 10        8 10 4 10 10 9                                                                   Chickweed 5 5 0 9 10 9 9 10 9 9 9 6 10 9 9 6 7 9 0 0 10 10 0 10 0 10 10        10                                                                               Corn 2 4 5 9 9 9 10 10 9 8 4 9 10 10 9 5 5 3 0 9 4 2 0 10 0 9 9 4                     Cotton 2 9 5 6 5 6 10 9 6 0 9 5 8 7 9 3 8 8 0 8 3 7 0 8 0 6 8 7             Crabgrass 5 7 5 9 9 9 7 9 8 2 6 7 8 7 7 5 7 5 0 8 9 10 0 9 0 6 8 2               Downy brome 4 9 10 10 10 9 10 10 10 8 9 9 8 10 10 7 10 10 -- 8 10 10        0 10 0 10 10 3                                                                   Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 4 6 4 8 9 9 7 9 8 3 5 7 8 7 8 4 6 3 0 5 9 9 1 9 2 8 8 3             Lambsquarters -- 9 9 10 10 9 10 9 10 7 8 9 10 10 9 9 9 9 9 8 8 7 0 9         0 10 10 10                                                                       Morningglory 0 9 8 7 7 6 9 9 8 0 9 5 7 2 8 8 8 9 0 2 6 0 0 4 0 6 5 5               Pigweed 5 8 9 9 9 10 10 10 9 5 8 7 9 9 9 7 9 8 5 9 9 10 0 9 0 9 9 8           Rape 3 0 0 9 9 9 10 10 10 8 10 9 8 4 9 4 6 9 0 5 8 8 0 9 0 8 9 9                     Ryegrass 0 8 7 10 10 9 10 10 10 3 7 9 9 9 9 0 6 4 0 4 6 8 0 9 0          10 8 3                                                                           Sorghum 7 10 9 9 9 9 10 10 10 3 9 10 9 9 10 9 9 9 2 5 9 6 2 10 5 9 9 2           Soybean 2 8 7 7 9 7 9 10 7 4 8 7 7 5 5 5 7 8 0 2 2 0 0 3 0 7 3 2                     Speedwell 5 6 0 10 10 8 10 0 10 10 8 9 7 6 9 7 10 2 9 8 7 0 0 9          -- 10 10 4                                                                       Sugar beet 4 9 9 10 10 9 9 10 9 4 9 9 7 9 9 3 9 9 -- 10 7 9 0 10 0 9 10        9                                                                                Velvetleaf 2 9 5 7 7 9 9 8 7 3 5 7 8 7 7 8 8 3 0 2 3 6 2 3 2 5 8 5                   Wheat 3 9 8 9 5 5 9 9 9 0 0 9 5 8 8 0 8 4 0 7 9 8 0 9 0 9 -- 0                 Wild buckwheat 9 7 6 9 9 10 -- 9 9 8 9 9 9 7 9 8 9 9 8 9 9 -- -- 10        0 9 10 10                                                                        Wild oat 0 9 5 8 5 6 9 8 8 0 7 8 8 5 9 2 5 4 0 7 7 2 0 8 0 9 2 2                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        286 287 288 289 291 292 300 301 302 305 310 1 2 3 5 7 11 13 14 25 26 27 2      8 29 30 31 34 35                                                                 PREEMERGENCE Rate (31 g/ha) Rate (16 g/ha)                                      Barley Igri 10 2 2 5 4 0 3 1 5 8 0 4 6 4 3 0 0 0 0 0 0 0 0 0 0 0 0 0               Bedstraw 10 10 10 8 3 0 2 6 9 8 7 7 9 10 10 0 5 8 7 8 8 8 8 9 10 2 6        9                                                                                Blackgrass 10 10 9 9 8 0 8 9 10 10 8 7 7 6 5 0 6 6 0 8 8 9 7 7 4 3 3 7           Chickweed 10 10 10 9 8 2 4 9 10 9 7 6 10 9 9 0 10 8 10 5 9 9 7 9 9 0 7        10                                                                               Corn 6 4 4 2 4 0 3 1 3 3 4 0 6 7 3 0 4 6 2 8 9 5 9 10 10 8 0 2                  Cotton 9 9 7 0 3 0 4 7 8 7 8 0 3 5 7 0 3 6 2 5 7 7 5 9 8 0 0 7                  Crabgrass 9 9 8 0 7 0 4 4 7 7 0 0 6 6 6 0 0 0 0 7 9 8 7 9 9 2 4 4                     Downy brome 10 10 9 7 8 0 5 8 10 8 0 6 7 5 10 4 0 5 0 2 2 3 5 5 5        0 0 7                                                                            Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 9 8 7 7 8 0 7 4 9 9 0 2 7 6 3 0 5 0 0 6 8 8 7 8 9 6 4 2             Lambsquarters 9 10 10 0 8 0 3 9 10 10 10 9 9 9 10 -- 8 9 8 3 8 7 5 9         8 5 -- 10                                                                        Morningglory 9 9 6 0 0 0 2 5 5 7 5 0 0 5 7 0 1 2 0 6 6 2 5 9 9 0 0 3               Pigweed 9 9 9 9 9 0 9 8 9 9 8 6 9 7 8 4 3 5 5 7 8 8 8 9 9 7 8 7                   Rape 10 10 9 0 6 0 5 6 8 3 0 6 8 8 10 0 3 8 6 5 2 5 7 7 8 2 0 3               Ryegrass 10 9 5 3 7 0 2 0 8 3 0 4 2 0 6 0 3 5 2 3 4 4 4 3 4 0 0 4               Sorghum 9 9 8 6 6 0 5 4 8 9 0 4 7 8 8 3 3 5 4 10 10 9 9 10 10 3 3 9           Soybean 9 6 3 0 0 0 0 2 5 3 5 3 4 3 6 0 0 0 0 3 3 4 2 9 8 0 2 0                       Speedwell 10 2 10 10 9 4 7 10 10 10 10 6 9 -- 10 0 4 8 6 8 8 0 7        9 0 0 5 8                                                                        Sugar beet 10 10 10 7 9 0 9 9 10 10 10 6 8 7 10 0 8 8 7 5 9 8 8 9 10 2         6 10                                                                             Velvetleaf 9 2 8 3 5 0 5 5 8 5 6 3 7 -- 8 0 1 5 0 7 7 7 7 8 8 0 0 5                 Wheat 10 8 5 0 2 0 4 5 9 0 0 5 6 4 7 0 0 0 0 2 2 0 0 2 1 0 0 0                   Wild buckwheat 9 9 9 8 3 2 4 7 9 9 9 9 9 9 10 0 4 8 5 4 7 2 5 8 8         0 0 9                                                                            Wild oat 9 4 1 2 4 0 2 3 3 0 0 1 3 0 2 0 0 0 0 2 2 0 2 2 2 0 0 3                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        36 50 51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103 107           108 109 110 111 112 114                                                          PREEMERGENCE Rate (16 g/ha)                                                     Barley Igri 0 5 9 9 1 6 2 8 8 0 1 3 6 5 4 2 4 5 6 5 6 9 8 8 6 2 0 5                 Bedstraw 10 9 10 10 8 10 9 9 9 9 0 8 6 9 9 0 9 9 9 8 9 10 10 9 10 9        10 9                                                                             Blackgrass 7 8 8 9 7 8 6 9 9 5 6 7 9 9 9 8 9 9 9 8 9 9 9 10 10 9 9 9               Chickweed 10 9 10 10 9 10 10 9 8 7 2 7 6 9 10 2 8 9 9 5 9 9 9 9 9 8         9 8                                                                              Corn 2 0 9 3 4 6 3 9 9 0 0 4 -- -- -- 9 3 3 7 2 0 10 9 5 8 2 3 9                       Cotton 8 7 10 8 3 9 9 8 9 6 0 6 -- -- -- 8 9 -- 4 2 8 10 10 9 9         5 8 2                                                                            Crabgrass 8 7 10 9 5 4 0 9 9 0 0 5 -- -- -- 2 4 0 5 0 0 8 8 8 6 0 3 7             Downy brome 7 5 9 9 5 7 6 9 8 0 5 2 6 7 5 3 5 4 5 3 6 9 7 9 9 4 6 5             Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --          -- -- -- -- -- -- -- -- --                                                       Giant foxtail 8 7 8 9 4 0 0 9 9 0 3 5 -- -- -- 2 7 5 5 4 5 9 7 8 9 4 3         8                                                                                Lambsquarters 10 10 10 10 8 10 10 10 10 8 2 6 9 9 9 -- 10 6 9 9 9 10 10        9 10 9 9 9                                                                       Morningglory 8 9 9 5 0 10 10 8 9 8 0 8 -- -- -- 5 8 5 6 7 7 10 10 6 7 6        8 8                                                                              Pigweed 9 10 10 10 9 9 9 9 9 9 8 8 -- -- -- 3 8 8 8 8 9 9 10 9 10 9 9 9         Rape 7 9 9 9 10 10 10 10 10 9 8 9 9 9 9 3 9 9 9 9 9 9 10 9 9 7 9 9                   Ryegrass 6 9 9 9 7 10 8 9 9 3 2 5 4 4 5 4 5 5 6 0 0 10 9 9 9 4 7 8         Sorghum 8 7 10 9 9 8 7 9 9 6 5 7 -- -- -- 9 9 9 8 8 9 9 10 9 9 4 5 9               Soybean 5 6 8 6 3 7 7 8 8 7 2 6 -- -- -- 7 5 7 6 0 2 10 8 8 6 4 3 3           Speedwell 7 9 10 10 8 10 8 9 8 2 0 0 9 9 9 7 9 9 9 9 8 10 7 9 10 8 9 9         Sugar beet 10 9 9 9 9 10 10 10 10 9 2 9 9 9 9 3 9 9 9 9 9 10 10 9 9 9 9        9                                                                                Velvetleaf 5 7 9 7 6 10 7 8 9 9 0 6 -- -- -- 4 7 4 5 5 8 10 9 9 7 7 3 7         Wheat 0 5 9 9 0 5 3 7 8 0 0 1 5 4 3 3 3 2 3 2 5 8 0 8 7 3 2 0                   Wild buckwheat 9 8 9 9 3 9 8 9 8 5 1 6 9 9 8 0 8 9 8 8 9 9 9 -- 7 -- 9         9                                                                                Wild oat 0 4 9 7 2 6 6 5 4 0 0 0 5 4 2 3 2 0 0 2 3 7 7 7 8 0 0 4                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        115 116 117 118 119 120 121 122 125 166 167 170 172 173 203 204 205 206 2      07 208 209 211 212 213 214 217 218 219                                           PREEMERGENCE Rate (16 g/ha)                                                     Barley Igri 0 7 3 0 9 6 9 8 0 2 0 0 0 0 5 8 8 5 6 8 0 3 0 4 4 5 4 0                 Bedstraw 9 9 9 7 9 -- 9 10 5 9 7 9 3 0 5 8 10 9 9 9 0 9 2 10 10 2 6        8                                                                                Blackgrass 9 9 7 5 10 10 10 9 5 8 8 7 7 9 7 9 9 9 8 8 0 8 7 8 7 8 7 5             Chickweed 8 9 9 7 10 10 10 10 8 9 9 9 2 2 7 9 9 8 9 9 0 9 10 10 9 3          10 9                                                                             Corn 4 8 4 3 9 7 10 9 0 6 4 10 2 3 3 7 10 10 9 8 0 6 5 10 10 3 3 0                   Cotton 2 9 9 3 7 6 10 9 0 5 0 9 4 -- 6 4 8 8 8 7 0 4 4 10 10 5 --         2                                                                                Crabgrass 2 8 2 0 6 5 2 5 0 8 4 8 5 5 7 8 10 8 8 8 0 8 5 7 4 3 3 0                   Downy brome 3 6 4 2 10 5 8 8 0 5 4 6 4 0 8 9 9 9 8 9 0 8 3 8 7 9 6        5                                                                                Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 4 8 2 0 8 6 2 2 0 7 2 8 7 7 0 9 9 8 9 9 0 8 4 7 2 3 4 0             Lambsquarters 8 9 8 9 10 10 10 9 9 8 9 9 9 9 8 9 10 10 9 9 0 9 -- 10         9 7 -- 8                                                                         Morningglory 7 9 10 5 8 8 9 9 2 5 2 8 3 2 4 7 9 8 8 8 0 0 4 10 9 2 3 0           Pigweed 9 9 8 6 9 8 9 9 8 8 6 9 9 8 8 10 10 10 9 10 0 9 6 10 9 7 8 6             Rape 8 9 9 4 10 10 10 10 8 9 -- 9 2 0 10 9 9 6 8 10 0 8 1 10 10 6 3 5         Ryegrass 3 8 5 4 8 5 9 9 0 6 3 6 2 5 7 8 9 9 8 9 0 3 0 7 5 5 2 2                       Sorghum 7 9 9 0 9 4 9 9 0 9 9 9 4 4 7 9 9 10 10 10 0 10 5 10 8 9        5 0                                                                              Soybean 0 8 6 0 8 5 10 7 0 5 0 8 2 3 4 6 7 7 6 6 0 5 3 9 8 2 4 2                       Speedwell 8 10 7 9 10 9 10 4 8 10 2 10 9 9 4 7 7 9 3 9 0 9 9 10         5 9 -- 0                                                                         Sugar beet 7 9 9 4 10 10 10 10 9 10 9 10 6 6 8 10 9 9 9 9 2 9 -- 10 9 8        7 8                                                                              Velvetleaf 7 9 8 0 8 7 8 8 3 6 4 9 4 4 7 7 8 9 8 8 0 7 2 10 7 5 4 0                 Wheat 0 0 0 0 8 6 9 8 0 3 0 6 2 0 5 8 6 9 8 9 0 5 0 7 2 5 6 0                     Wild buckwheat 9 9 9 9 10 10 9 10 8 5 7 8 9 9 9 9 9 8 7 8 3 8 4 9        9 2 0 8                                                                          Wild oat 0 7 4 0 6 3 9 8 0 2 0 0 0 0 5 6 7 4 5 5 0 2 0 5 4 3 2 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        225 229 230 231 232 240 241 242 243 244 245 252 254 256 258 259 261 266 2      67 268 269 270 271 272 274 275 276 283                                           PREEMERGENCE Rate (16 g/ha)                                                     Barley Igri 2 8 0 8 4 7 7 4 7 5 9 0 4 8 4 2 9 0 8 4 0 6 8 1 0 9 0 9                 Bedstraw 7 3 0 8 7 9 9 10 10 10 10 6 9 9 9 0 9 7 9 9 0 5 8 8 0 10 0        10                                                                               Blackgrass 5 5 6 8 7 10 10 10 10 10 10 9 8 10 10 9 9 9 9 9 8 9 10 10 6         10 0 10                                                                          Chickweed 7 2 5 0 0 9 10 9 9 10 8 9 9 0 9 0 9 4 6 3 0 0 8 10 0 10 0 10           Corn 3 1 0 0 5 9 9 9 10 10 9 6 4 8 5 8 9 0 5 3 0 4 3 0 0 5 0 4                         Cotton 9 0 0 8 4 3 3 5 10 9 6 0 9 3 5 5 4 0 7 8 0 8 2 5 0 7 0 5         Crabgrass 0 2 2 4 4 8 9 9 7 9 8 0 0 6 4 7 5 2 5 4 0 7 7 8 0 8 0 6                     Downy brome 4 5 0 9 10 9 10 9 10 9 9 6 8 9 8 9 9 4 10 9 0 8 10 9         0 9 0 10                                                                         Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 2 4 1 3 3 6 9 9 7 9 7 0 0 6 8 5 6 0 5 -- 0 5 7 9 0 9 0 6           Lambsquarters 8 -- 4 4 2 10 10 9 9 9 10 7 7 8 10 9 9 9 9 8 2 7 8 7 0 6        0 9                                                                              Morningglory 7 0 0 8 7 6 5 6 9 8 8 0 9 3 4 2 8 2 7 7 0 0 6 0 0 2 0 5               Pigweed 6 9 5 8 8 8 9 10 10 10 9 5 8 5 8 8 8 2 7 7 0 9 9 10 0 9 0 9           Rape 4 0 0 0 0 9 9 7 10 9 9 6 9 9 7 3 9 3 6 5 0 0 0 7 0 9 0 --                         Ryegrass 0 0 0 3 2 7 9 9 10 8 10 0 6 9 9 8 6 0 6 0 0 4 3 5 0 6         0 10                                                                             Sorghum 9 7 2 9 9 9 9 9 10 10 9 3 8 9 7 8 9 5 9 8 0 2 3 2 0 10 2 9                   Soybean 7 1 0 8 7 5 6 7 9 8 5 2 8 4 5 4 2 2 5 6 0 0 0 0 0 2 0 2               Speedwell 9 7 5 0 0 9 10 4 10 0 10 10 8 8 0 4 9 6 10 0 9 8 4 0 0 7 5        10                                                                               Sugar beet 8 0 4 4 3 9 9 9 9 9 9 4 9 9 7 8 8 1 8 8 -- 9 5 9 0 9 0 9                 Velvetleaf 8 5 0 8 2 6 7 6 9 8 7 0 2 6 8 5 3 6 5 3 0 2 3 3 0 2 0 5           Wheat 0 5 3 9 5 8 5 3 9 4 9 0 0 8 4 7 7 0 3 0 0 6 8 6 0 9 0 9                  Wild buckwheat 8 4 4 0 -- 9 9 8 9 9 8 3 9 9 9 7 9 7 8 8 3 8 9 -- -- 10         -- 9                                                                             Wild oat 0 0 0 3 2 -- 4 3 9 3 8 0 3 8 4 2 6 0 5 0 0 7 6 0 0 4 0 7                     Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        284 285 286 287 288 289 291 292 300 301 302 305 310 1 2 3 5 7 11 13 14         25 26 27 28 29 30 31                                                             PREEMERGENCE Rate (16 g/ha) Rate (8 g/ha)                                       Barley Igri 9 0 9 0 0 2 3 0 0 0 0 3 0 2 5 3 0 0 0 0 0 0 0 0 0 0 0 0                 Bedstraw 8 -- 10 10 10 6 2 0 0 5 7 7 4 -- 4 6 10 0 5 7 5 5 6 3 5 5         8 2                                                                              Blackgrass 10 9 10 9 9 9 7 0 7 7 9 9 0 5 6 6 3 0 4 3 0 7 7 7 5 5 4 2               Chickweed 10 10 10 10 10 8 8 2 3 9 10 6 4 4 8 9 7 0 8 8 10 2 8 4 5 9        8 0                                                                              Corn 4 2 6 0 3 2 2 0 2 0 2 3 2 0 4 3 0 0 4 0 0 4 4 4 4 6 8 2                    Cotton 5 6 9 8 7 0 3 0 2 3 8 5 8 0 2 2 7 0 2 5 2 4 6 7 5 8 8 0                  Crabgrass 6 0 8 7 7 0 5 0 0 0 7 3 0 0 5 5 5 0 0 0 0 4 8 7 6 7 8 0                     Downy brome 9 0 10 10 9 5 4 0 3 3 7 3 0 5 6 0 6 0 0 3 0 0 0 0 4 3        4 0                                                                              Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 6 1 9 4 6 2 8 0 2 2 9 5 0 0 5 3 3 0 2 0 0 2 7 4 3 7 9 4             Lambsquarters 10 9 9 10 10 0 8 0 2 9 10 8 0 8 8 8 10 0 6 8 7 0 7 2 5         5 8 5                                                                            Morningglory 5 2 9 5 5 0 0 0 0 3 3 6 2 0 0 3 6 0 0 0 0 5 6 2 4 5 7 0               Pigweed 9 8 9 9 9 8 9 0 7 7 9 8 3 4 7 6 6 0 3 4 2 7 8 8 8 8 9 2                   Rape 9 6 10 10 9 0 5 0 4 4 4 0 0 4 4 6 5 0 0 7 6 4 2 3 5 4 8 0                 Ryegrass 2 0 9 4 5 0 4 0 0 0 4 0 0 0 0 0 0 0 0 3 0 0 2 2 4 0 3 0               Sorghum 6 0 9 5 4 2 4 0 2 2 5 8 0 3 4 4 8 0 0 2 3 7 9 5 9 10 9 2                 Soybean 0 1 9 2 3 0 0 0 0 0 4 0 2 0 3 2 5 0 0 0 0 3 3 3 2 6 4 0                 Speedwell 10 2 10 0 10 9 7 -- 5 10 10 10 9 -- 7 5 10 0 4 7 6 7 8 0         7 9 0 0                                                                          Sugar beet 8 9 10 10 10 7 9 0 6 9 10 9 -- 5 8 7 10 0 4 8 6 3 8 3 5 5 9          Velvetleaf 7 5 9 0 7 0 2 0 3 3 6 5 6 0 4 3 6 0 0 4 0 7 6 4 5 8 3 0                   Wheat 9 0 9 3 4 0 2 0 2 4 2 0 0 2 5 3 5 0 0 0 0 2 0 0 0 0 0 0                   Wild buckwheat 9 9 9 9 9 7 3 0 3 6 9 8 9 6 9 9 10 0 2 7 3 2 2 0 5         5 7 0                                                                            Wild oat 0 0 0 2 0 2 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        34 35 36 50 51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103         107 108 109 110 111                                                              PREEMERGENCE Rate (8 g/ha)                                                      Barley Igri 0 0 0 4 6 6 0 6 0 7 7 0 0 0 4 3 0 0 3 3 5 5 4 8 4 8 6 0                 Bedstraw 3 3 8 8 10 9 7 10 9 7 9 8 0 7 5 9 9 0 8 4 9 7 9 10 10 9 10        3                                                                                Blackgrass 0 5 6 7 8 9 7 7 6 9 9 5 3 5 8 9 9 7 9 9 9 6 8 9 9 10 9 9                 Chickweed 4 8 10 9 10 10 9 10 10 7 8 7 0 5 3 9 9 0 5 7 9 3 6 9 9 9         9 8                                                                              Corn 0 0 2 0 7 0 0 5 2 4 9 0 0 3 -- -- -- 8 2 1 4 0 0 10 9 5 7 2                       Cotton 0 4 7 6 9 7 0 9 9 6 8 5 0 4 -- -- -- 8 -- 5 2 0 8 10 10 6        8 5                                                                              Crabgrass 2 2 5 6 9 9 4 3 0 8 8 0 0 4 -- -- -- 2 4 0 4 0 0 8 7 7 4 0               Downy brome 0 4 4 5 8 9 3 6 5 9 8 0 2 0 5 5 4 2 0 3 5 2 5 8 5 8 9 0           Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- --                                                          Giant foxtail 2 0 6 6 7 8 3 0 0 9 9 0 0 3 -- -- -- 2 4 2 5 3 2 8 6 7 8         3                                                                                Lambsquarters 6 10 10 9 10 9 7 10 10 9 10 7 2 5 9 9 9 5 -- -- 9 5 9 10         9 9 10 9                                                                         Morningglory 0 3 5 9 9 5 0 9 9 6 9 7 0 7 -- -- -- 4 5 3 6 4 7 10 9 6 5         5                                                                                Pigweed 7 6 8 10 10 9 7 9 9 9 9 9 8 8 -- -- -- 2 7 7 8 8 9 9 9 9 9 8               Rape 0 0 5 7 9 9 9 10 10 10 9 8 5 8 9 9 8 0 9 8 9 7 7 9 9 9 9 6                   Ryegrass 0 3 3 7 9 9 3 10 7 6 8 0 0 1 4 4 3 3 4 4 5 0 0 10 9 9 9 3         Sorghum 0 4 5 6 9 8 5 7 6 9 9 4 4 6 -- -- -- 9 9 5 8 7 9 9 9 7 9 4                   Soybean 0 0 4 5 7 5 2 6 6 7 7 6 0 4 -- -- -- 6 5 5 4 0 0 10 8 6 5         3                                                                                Speedwell 3 7 6 9 10 10 3 10 8 7 7 0 0 0 7 9 9 6 9 9 8 8 7 10 2 9 9 7             Sugar beet 5 8 9 9 9 9 8 10 10 10 10 9 0 9 9 9 9 0 9 9 9 9 9 10 10 9         9 9                                                                              Velvetleaf 0 3 5 6 9 7 5 9 6 8 9 8 0 6 -- -- -- 3 6 2 3 5 6 10 8 5 5 5           Wheat 0 0 0 5 6 6 0 4 0 6 6 0 0 0 3 3 0 0 0 0 0 2 0 7 0 6 6 3                  Wild buckwheat 0 7 7 8 9 9 3 8 8 8 7 5 0 6 7 8 7 0 8 3 7 8 8 9 9 -- --         8                                                                                Wild oat 0 0 0 3 8 6 0 6 4 0 3 0 0 0 5 0 2 0 0 0 0 2 3 6 4 5 7 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        112 114 115 116 117 118 119 120 121 122 125 166 167 170 172 173 203 204 2      05 206 207 208 209 211 212 213 214 217                                           PREEMERGENCE Rate (8 g/ha)                                                      Barley Igri 0 2 0 5 2 0 9 3 7 0 0 0 0 0 0 0 2 5 4 3 4 8 0 2 0 3 2 4                 Bedstraw 9 9 8 9 9 0 4 2 8 8 3 9 7 8 3 0 3 7 9 9 8 9 0 8 0 10 9 2             Blackgrass 8 8 8 8 7 5 10 10 9 6 4 7 6 3 7 8 6 8 9 9 8 8 0 7 6 7 5 7           Chickweed 8 8 7 9 8 6 10 9 10 9 7 9 9 7 -- 0 2 9 9 7 9 8 0 9 7 10 8 0           Corn 2 8 4 7 4 3 8 5 10 7 0 5 2 6 0 3 0 5 7 9 6 7 0 5 5 10 6 2                         Cotton 5 -- 0 9 8 0 7 6 9 8 0 4 0 8 2 3 5 0 7 7 6 4 0 3 0 10 9         3                                                                                Crabgrass 0 5 2 7 0 0 5 5 0 5 0 7 4 6 3 3 5 7 10 5 7 8 0 7 5 5 0 2                   Downy brome 3 5 2 5 3 0 9 5 8 5 0 4 4 5 0 0 7 9 7 8 7 8 0 6 2 7 7         6                                                                                Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 0 8 3 6 0 0 6 5 0 0 0 6 0 6 5 5 0 7 9 6 6 8 0 6 2 6 0 0             Lambsquarters 9 8 6 9 8 8 10 10 10 9 9 2 8 9 9 7 7 8 10 8 8 7 0 8 6          10 9 --                                                                          Morningglory 5 7 7 9 9 3 8 8 9 8 0 4 0 7 2 0 3 6 9 7 7 8 0 0 4 9 9 0               Pigweed 8 9 9 9 8 6 9 8 8 8 5 8 6 9 5 5 7 10 9 8 8 9 0 8 3 9 9 6                 Rape 9 9 7 9 9 4 10 9 10 10 5 8 4 9 0 0 8 8 9 5 3 9 0 8 0 10 10 4             Ryegrass 4 8 0 8 5 0 8 4 8 0 0 5 0 5 0 0 3 7 8 8 7 8 0 0 0 7 3 3                   Sorghum 5 8 4 9 9 0 8 4 9 8 0 8 4 9 3 2 4 8 9 9 10 10 0 6 3 10 8 7         Soybean 1 2 0 8 5 0 8 5 8 6 0 2 0 6 0 0 3 3 6 6 4 4 0 3 2 8 7 0                         Speedwell 9 9 7 10 7 9 10 9 10 3 7 10 0 9 8 4 0 3 7 8 0 8 0 8 5        10 3 9                                                                           Sugar beet 9 9 7 9 9 3 10 10 10 10 8 9 7 9 4 5 6 9 9 9 8 8 0 8 4 10 9 7         Velvetleaf 3 7 5 9 6 0 7 6 8 6 0 4 4 8 2 0 3 5 7 8 7 8 0 6 0 9 3 2                   Wheat 2 0 0 0 0 0 7 3 9 3 0 0 0 0 0 0 3 5 4 8 7 8 0 4 0 5 0 4                   Wild buckwheat 7 8 9 9 8 3 10 -- -- 10 8 3 6 7 -- 3 4 9 8 8 5 7 3         8 0 9 9 2                                                                        Wild oat 0 2 0 5 3 0 5 2 8 4 0 0 0 0 0 0 2 4 4 3 3 3 0 0 0 4 3 2                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        218 219 225 229 230 231 232 240 241 242 243 244 245 252 254 256 258 259 2      61 266 267 268 269 270 271 272 274 275                                           PREEMERGENCE Rate (8 g/ha)                                                      Barley Igri 0 0 0 3 0 5 2 5 3 4 2 2 8 0 4 8 0 0 7 0 6 2 0 4 4 0 0 9                 Bedstraw 0 8 0 2 0 6 3 9 8 9 9 9 10 6 9 8 6 0 7 0 9 7 0 3 3 0 0 8             Blackgrass 5 4 4 0 2 8 5 9 10 9 10 10 10 9 7 9 9 7 9 3 9 3 3 9 9 9 0         10                                                                               Chickweed 9 8 -- 0 3 0 0 9 9 9 9 10 8 5 9 0 9 0 7 0 0 0 0 0 2 9 0 9                 Corn 2 0 2 0 0 0 3 6 9 6 10 10 9 4 -- 5 5 4 6 0 5 3 0 2 0 0 0 2                 Cotton 2 0 8 0 0 5 2 3 2 5 10 5 4 0 7 2 3 5 3 0 2 3 0 7 0 2 0 7                 Crabgrass 2 0 0 2 0 2 3 6 9 5 5 7 6 0 0 4 4 5 3 0 2 0 0 3 7 7 0 7             Downy brome 5 3 0 0 0 9 5 9 6 8 8 6 9 4 7 9 7 9 9 0 9 9 0 5 3 8 0 9             Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --          -- -- -- -- -- -- -- -- --                                                       Giant foxtail 4 0 0 2 0 0 2 4 8 4 6 5 5 0 0 5 7 3 5 0 4 0 0 2 5 8 0 4             Lambsquarters 7 5 7 6 -- 0 0 10 10 8 9 9 10 7 7 4 9 8 9 8 0 6 0 5 6 0        0 4                                                                              Morningglory 2 0 2 0 0 4 5 5 5 3 9 6 7 0 9 0 2 0 2 0 3 7 0 0 2 0 0 0               Pigweed 7 6 3 2 2 3 4 8 9 8 9 8 8 2 7 5 8 5 8 0 7 0 0 7 7 8 0 5                   Rape 0 5 0 0 0 0 0 9 9 -- 9 9 9 5 8 8 4 0 5 0 0 2 0 0 0 6 0 2                   Ryegrass 0 0 0 0 0 0 0 5 6 6 9 7 9 0 3 9 8 6 6 0 0 0 0 3 2 2 0 4             Sorghum 5 0 7 5 0 9 9 9 7 4 10 10 9 0 6 9 4 8 9 3 9 7 0 0 0 0 0 9                 Soybean 2 2 4 0 0 7 5 2 4 6 8 5 3 0 7 0 2 3 0 0 3 3 0 0 0 0 0 0                 Speedwell 0 0 6 6 5 0 0 9 9 0 10 0 9 9 8 7 0 0 8 2 4 0 0 7 4 0 0 7           Sugar beet 6 8 6 0 2 2 2 9 9 9 9 9 9 2 9 8 5 8 7 1 4 6 -- 9 5 7 0 7               Velvetleaf 3 0 7 2 0 7 0 4 2 5 8 6 4 0 2 2 5 2 0 3 3 0 0 0 2 1 0 0             Wheat 3 0 0 0 2 7 3 5 5 3 5 2 3 0 0 7 3 4 5 0 0 0 0 5 5 5 0 9                         Wild buckwheat 0 7 2 0 0 0 5 9 9 -- -- 9 8 3 9 9 9 6 9 -- 0 8          -- 5 6 -- -- --                                                                  Wild oat 0 0 0 0 0 0 0 4 4 3 6 0 3 0 -- 8 3 0 6 0 2 0 0 2 0 0 0 4                     Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        276 283 284 285 286 287 288 289 291 292 300 301 302 305 310 1 3 5 11 13 1      4 25 26 27 28 29 30 31                                                           PREEMERGENCE Rate (8 g/ha) Rate (4 g/ha)                                        Barley Igri 0 3 1 0 1 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0                 Bedstraw 0 9 7 3 10 9 10 2 0 0 0 2 5 4 2 2 4 7 4 4 3 2 2 0 2 5 2 0           Blackgrass 0 9 9 5 10 9 9 9 5 0 5 3 8 6 0 4 4 0 2 0 0 4 4 4 3 4 2 0               Chickweed 0 9 10 10 10 10 10 7 5 0 0 5 10 4 4 0 6 6 8 8 7 0 2 -- --         9 5 0                                                                            Corn 0 3 2 0 6 0 3 0 0 0 0 0 1 2 0 0 2 0 4 0 0 4 2 4 2 4 4 0                    Cotton 0 3 3 3 9 8 6 0 1 0 -- 0 3 2 4 0 2 5 0 3 0 4 5 6 5 8 7 0                         Crabgrass 0 3 3 0 8 3 7 0 3 0 0 0 4 2 0 0 3 4 0 0 0 2 6 4 4 5 8         Downy brome 0 6 3 0 7 5 9 4 3 0 0 0 3 0 0 2 0 6 0 0 0 0 0 0 3 0 0 0                 Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       Giant foxtail 0 3 4 0 7 3 4 0 5 0 0 0 5 2 0 0 0 0 0 0 0 0 3 2 2 7 4 2             Lambsquarters 0 9 10 9 9 9 10 0 7 0 0 6 8 6 -- 4 6 10 4 7 6 0 5 0 3 5        5 5                                                                              Morningglory 0 5 4 2 8 2 4 0 0 0 0 0 3 4 0 0 3 3 0 0 0 4 4 1 3 4 3 0               Pigweed 0 8 8 8 8 8 8 7 8 0 5 5 8 8 3 0 5 5 0 2 0 7 7 7 7 8 9 0                   Rape 0 5 5 2 9 9 9 0 2 0 1 3 2 0 0 2 3 0 0 6 4 4 2 2 4 4 4 0                     Ryegrass 0 8 0 0 7 2 2 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0           Sorghum 0 7 3 0 9 5 3 0 2 0 0 0 2 7 0 0 2 6 0 0 2 5 3 3 4 10 4 0                     Soybean 0 0 0 0 6 0 2 0 0 0 0 0 0 0 0 0 0 2 0 0 0 2 0 2 0 5 2 0             Speedwell 2 9 10 0 10 0 10 9 7 0 3 9 9 9 4 0 3 10 4 7 5 7 7 0 4 9 0 0         Sugar beet 0 9 6 4 10 10 10 7 6 0 0 9 8 9 9 5 6 9 3 7 3 0 4 0 5 4 5 0             Velvetleaf 0 4 3 2 8 0 6 0 0 0 2 0 4 3 2 0 0 3 0 0 0 3 5 2 3 8 2 0               Wheat 0 4 4 0 0 0 2 0 0 0 0 2 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0                       Wild buckwheat 0 9 9 8 7 9 9 5 0 0 0 4 8 8 5 5 4 7 0 3 0 0 0 0 2        4 5 0                                                                            Wild oat 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        34 35 36 50 51 53 58 59 60 63 64 71 77 78 81 82 83 84 86 88 89 102 103         107 108 109 110 111                                                              PREEMERGENCE Rate (4 g/ha)                                                      Barley Igri 0 0 0 3 5 6 0 5 0 5 5 0 0 0 2 3 0 0 0 3 0 3 3 4 0 6 5 0                 Bedstraw 0 3 8 7 10 8 7 9 9 6 9 8 0 4 0 8 9 0 6 4 9 2 8 10 10 8 6 3         Blackgrass 0 4 5 7 7 9 5 7 4 9 9 3 2 3 7 9 9 3 8 8 8 4 8 9 9 9 9 8                   Chickweed 3 6 8 9 10 9 7 9 10 5 7 7 0 3 0 9 9 0 4 7 7 3 6 9 9 8 9         7                                                                                Corn 0 0 0 0 7 0 0 4 2 3 9 0 0 0 -- -- -- 5 0 0 0 0 0 10 8 4 6 2                       Cotton 0 0 6 4 9 7 0 9 9 4 8 4 0 -- -- -- -- 4 3 2 0 0 3 10 9 6         4 4                                                                              Crabgrass 0 0 2 5 8 7 3 0 0 5 8 0 0 4 -- -- -- 0 1 0 1 0 0 7 6 4 3 0               Downy brome 0 3 3 3 7 7 2 6 3 9 8 0 0 0 4 4 3 0 0 3 4 0 4 7 2 8 5 0           Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- --                                                          Giant foxtail 0 0 3 4 7 7 0 0 0 8 8 0 0 0 -- -- -- 0 0 0 2 0 0 7 4 4 6          Lambsquarters 6 8 8 9 10 9 5 10 8 9 10 7 0 2 8 9 8 3 -- 0 8 3 1 9 9 8 9        9                                                                                Morningglory 0 0 3 7 9 3 0 8 9 6 8 5 0 6 -- -- -- 2 2 2 3 0 3 9 8 6 5 5         Pigweed 0 3 8 10 10 9 6 8 9 9 9 8 4 7 -- -- -- 0 7 2 7 7 8 9 9 9 9 8               Rape 0 0 4 7 9 9 8 10 9 9 9 6 4 6 6 9 8 0 6 7 9 6 7 9 9 9 8 5                       Ryegrass 0 0 0 5 9 7 2 8 6 4 6 0 0 0 0 4 -- 0 3 0 0 0 0 9 5 7 6          Sorghum 0 2 3 4 9 6 4 7 5 9 9 0 3 3 -- -- -- 9 9 5 6 5 7 9 9 6 9 0                   Soybean 0 0 2 4 7 3 0 6 5 2 6 4 0 3 -- -- -- 4 2 4 1 0 0 9 7 5 4 0         Speedwell 0 5 4 9 10 10 3 10 5 5 5 0 0 0 6 9 7 6 8 8 7 3 3 10 2 9 9 3             Sugar beet 4 8 8 8 9 9 8 9 10 9 9 8 0 8 8 9 9 -- 8 9 8 7 9 10 10 9 9         9                                                                                Velvetleaf 0 0 2 4 9 7 4 9 6 7 9 8 0 4 -- -- -- 0 6 2 2 4 5 10 8 5 3 4           Wheat 0 0 0 0 5 6 0 3 0 5 5 0 0 0 0 3 0 0 0 0 0 0 0 5 0 6 5 3                  Wild buckwheat 0 7 7 8 9 8 2 8 8 8 7 4 0 4 4 8 -- 0 7 3 6 2 8 9 9 -- --        6                                                                                Wild oat 0 0 0 2 5 3 0 5 3 0 2 0 0 0 3 0 2 0 0 0 0 0 0 3 0 4 4 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        112 114 115 116 117 118 119 120 121 122 166 167 170 172 173 203 204 205 2      06 207 208 211 212 213 214 217 218 219                                           PREEMERGENCE Rate (4 g/ha)                                                      Barley Igri 0 0 0 4 0 0 7 3 6 0 0 0 0 0 0 0 3 0 0 2 7 0 0 2 0 3 0 0                 Bedstraw 8 8 7 9 9 0 0 2 4 8 0 2 8 0 0 0 3 8 8 6 8 5 0 9 9 0 0 3               Blackgrass 7 8 7 8 5 4 9 9 3 5 6 2 3 5 8 5 8 8 8 4 8 4 4 6 3 6 5 0             Chickweed 8 8 7 8 8 4 9 9 9 9 8 8 7 0 0 2 8 9 5 3 8 8 7 9 8 0 8 6                 Corn 0 6 0 6 0 0 7 4 10 7 4 2 0 0 -- 0 4 0 7 3 0 3 5 8 0 0 0 0                   Cotton 3 2 0 9 8 0 7 6 9 8 3 0 7 0 0 3 0 7 5 4 3 0 0 10 8 3 0 0               Crabgrass 0 3 0 5 0 0 5 3 0 2 6 4 2 0 0 3 6 8 4 5 7 5 3 3 0 0 0 0               Downy brome 0 4 0 5 0 0 8 2 5 5 0 0 0 0 0 6 5 6 7 5 7 4 0 7 6 5 5 2           Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- --                                                          Giant foxtail 0 6 0 5 0 0 6 3 0 0 4 0 2 3 2 0 5 7 5 3 7 3 0 4 0 0 2 0             Lambsquarters 9 8 5 9 8 5 10 9 8 8 0 2 8 9 0 3 8 10 3 3 7 7 -- 9 8 6         -- 2                                                                             Morningglory 5 7 6 9 9 2 8 7 9 7 2 0 7 0 0 0 4 7 5 6 7 0 2 8 8 0 0 0               Pigweed 8 8 7 8 8 5 9 8 8 7 8 6 9 5 5 4 9 9 7 5 9 7 3 9 9 2 5 5                   Rape 5 8 5 9 8 3 9 7 8 10 4 4 8 0 0 6 5 8 3 2 8 5 0 10 8 3 0 3                 Ryegrass 0 6 0 7 2 0 0 0 3 0 2 0 0 0 0 0 4 5 8 4 7 0 0 5 0 0 0 0               Sorghum 3 7 4 8 5 0 7 2 8 7 4 4 8 2 0 3 6 7 9 9 10 3 0 10 7 5 3 0               Soybean 1 0 0 7 3 0 7 4 7 5 0 0 2 0 0 0 0 5 4 0 2 0 0 7 6 0 0 0                   Speedwell 9 8 7 10 3 7 10 8 8 0 9 0 9 7 4 0 0 3 3 0 7 7 0 9 3 0 0          Sugar beet 9 9 6 9 9 3 10 8 9 9 0 4 9 4 2 2 7 8 8 2 8 7 4 9 9 4 5 7                 Velvetleaf 3 6 5 9 6 0 5 2 8 0 2 2 7 0 0 0 3 6 7 4 8 5 0 8 0 0 0 0           Wheat 0 0 0 0 0 0 6 0 8 3 0 0 0 0 0 0 3 3 6 2 7 4 0 4 0 3 2 0                  Wild buckwheat -- 8 8 8 8 -- 10 8 9 9 3 4 6 0 -- 1 8 8 7 3 7 3 0 9 8 0         0 3                                                                              Wild oat 0 2 0 4 2 0 4 0 0 0 0 0 0 0 0 0 3 3 0 2 2 0 0 2 0 0 0 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        225 229 230 231 232 240 241 242 243 244 245 252 256 258 259 261 266 267 2      68 270 271 272 274 275 276 283 284 285                                           PREEMERGENCE Rate (4 g/ha)                                                      Barley Igri 0 0 0 0 2 4 0 0 0 0 3 0 4 0 0 5 0 4 0 3 2 0 0 7 0 0 0 0                 Bedstraw 0 0 0 3 2 5 6 7 8 8 9 4 3 6 0 5 0 5 0 0 0 0 0 5 0 8 7 --             Blackgrass 0 0 0 3 5 9 10 9 9 10 9 6 9 9 6 9 3 8 3 6 8 6 0 9 0 9 6 4           Chickweed 2 0 0 0 0 4 9 9 8 10 8 5 0 7 0 0 0 0 0 0 0 7 0 0 0 9 10 9               Corn 0 0 0 0 3 4 8 4 10 8 6 0 2 5 0 4 0 0 0 0 0 0 0 0 0 3 0 0                       Cotton 4 0 0 3 0 0 1 4 7 5 4 0 0 0 -- 2 0 0 0 3 0 0 0 2 0 2 2 2           Crabgrass 0 0 0 0 0 4 5 3 3 4 5 0 0 3 0 2 0 2 0 0 3 4 0 3 0 0 0 0                   Downy brome 0 0 0 6 2 4 5 7 5 4 9 3 7 6 4 6 0 8 6 0 0 3 0 9 0 2 0          Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 0 0 0 0 0 1 3 2 4 3 4 0 3 4 0 4 0 4 0 0 2 8 0 2 0 0 1 0             Lambsquarters 0 6 3 0 0 9 9 8 8 9 9 -- 4 9 8 -- 3 0 0 -- 6 0 0 3 0 9         9 5                                                                              Morningglory 0 0 0 1 2 4 2 2 8 4 5 0 0 0 0 0 0 2 2 0 0 0 0 0 0 3 4 0               Pigweed 0 0 0 0 0 7 8 8 8 7 8 0 0 7 3 7 0 6 0 2 3 2 0 3 0 8 8 7                   Rape 0 0 0 0 0 6 6 3 9 7 8 3 4 3 0 3 0 0 0 0 0 2 0 2 0 -- 3 0                   Ryegrass 0 0 0 0 0 4 4 3 6 2 2 0 4 5 4 4 0 0 0 0 0 0 0 3 0 3 0 0             Sorghum 3 4 0 9 9 3 4 2 10 10 9 0 8 4 7 8 3 8 5 0 0 0 0 4 0 2 0 0                 Soybean 2 0 0 4 2 0 1 6 7 0 2 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0                 Speedwell -- 2 4 0 0 8 9 0 9 0 9 7 7 0 0 3 2 -- 0 0 3 0 0 0 0 -- 9          Sugar beet 5 0 0 0 2 8 9 7 9 9 9 1 0 5 2 6 0 1 0 2 -- 0 0 7 0 6 6 4                 Velvetleaf 2 2 0 3 0 2 2 2 8 4 0 0 0 3 0 0 2 0 0 0 2 0 0 0 0 4 2 0           Wheat 0 0 0 2 2 3 5 0 4 0 3 0 6 3 0 5 0 0 0 3 0 0 0 4 0 0 0 0                  Wild buckwheat 2 0 0 0 3 9 9 -- 9 8 7 0 9 9 -- 9 7 -- 8 5 6 5 -- -- 0 9        8 7                                                                              Wild oat 0 0 0 0 0 4 0 0 3 0 0 0 5 2 0 4 0 0 0 0 0 0 0 0 0 0 0 0                       Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        286 287 288 289 291 300 301 302 305 310 25 26 27 28 29 30 31 34 36 107         204 205 206 207 240 241 242 243                                                  PREEMERGENCE Rate (4 g/ha) Rate (2 g/ha)                                        Barley Igri 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 2 0 -- 0 2 0 0 0               Bedstraw 9 8 10 0 0 0 2 4 0 2 0 0 0 0 3 0 0 0 7 10 0 7 5 2 3 2 6 7             Blackgrass 4 5 7 8 3 3 2 4 3 0 0 0 0 2 3 0 0 0 3 9 7 8 7 0 8 5 9 7               Chickweed 9 10 9 7 2 0 5 5 0 0 0 0 -- 5 7 4 0 0 6 9 8 8 5 2 0 6 9 8           Corn 5 0 0 0 0 0 0 0 2 0 2 0 4 2 4 2 0 0 0 10 2 0 3 3 3 2 3 10                         Cotton 7 4 2 0 0 0 0 2 0 0 3 5 5 4 5 5 0 0 6 10 0 4 3 3 0 0 4 6         Crabgrass 6 0 4 0 2 0 0 0 0 0 0 3 3 2 4 7 0 0 0 7 4 7 3 3 0 3 0 0                     Downy brome 4 0 8 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 2 4 -- 3 3 0         0 0                                                                              Duck salad -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- --                                                          Giant foxtail 7 0 0 0 3 0 0 2 0 0 0 2 0 0 3 3 0 0 0 5 3 5 3 0 0 0 0 0             Lambsquarters 9 9 10 0 5 0 4 7 0 0 0 2 0 2 2 0 2 3 7 9 7 7 0 3 8 7 7         8                                                                                Morningglory 7 0 2 0 0 0 0 0 0 0 3 2 0 3 2 0 0 0 0 9 3 6 3 0 0 0 2 7               Pigweed 8 8 8 7 6 3 0 7 5 0 7 2 4 3 4 8 0 0 3 9 6 8 6 0 5 8 3 8                   Rape 9 9 8 0 2 0 0 0 0 0 3 0 0 2 1 0 0 0 3 8 2 5 -- 0 5 4 3 5                   Ryegrass 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 3 -- 2 2 4 0 2           Sorghum 8 2 0 0 2 0 0 0 5 0 4 2 0 4 5 4 0 0 0 9 4 4 9 8 2 0 0 10                     Soybean 4 0 0 0 0 0 0 0 0 0 2 0 2 0 4 0 0 0 0 8 0 4 3 0 0 0 2 5             Speedwell 10 0 10 9 2 0 5 8 0 4 4 2 0 0 8 0 0 0 3 10 0 0 3 0 5 4 0 8           Sugar beet 9 9 8 5 3 0 7 6 4 2 0 0 0 3 4 4 0 3 7 10 7 8 7 2 8 8 7 9               Velvetleaf 8 0 3 0 0 0 0 0 2 0 2 4 0 0 4 0 0 0 0 9 3 3 5 0 0 0 0 7             Wheat 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 3 2 0 -- 0 2 2 0 0                       Wild buckwheat 4 8 8 5 0 0 4 7 7 -- 0 0 0 0 3 0 0 0 5 8 7 3 7 3         9 9 -- 4                                                                         Wild oat 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 -- 0 3 0 0 0                     Barnyardgrass -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- -- -- --                                                 Rice Japonica -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --         -- -- -- -- -- -- -- -- --                                                       Umbrella sedge -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --        -- -- -- -- -- -- -- -- --                                                       COMPOUND                                                                        244 245 272 283 284 285 286 287 288 291                                         PREEMERGENCE Rate (2 g/ha)                                                      Barley Igri 0 3 0 0 0 0 0 0 0 0                                                 Bedstraw 7 9 0 5 7 2 9 6 4 0                                                    Blackgrass 7 8 4 6 5 2 3 3 6 0                                                  Chickweed 9 5 3 9 9 7 9 9 9 0                                                   Corn 5 5 0 3 0 0 4 0 0 0                                                        Cotton 2 3 0 0 0 0 6 3 0 0                                                      Crabgrass 0 2 3 0 0 0 3 0 0 0                                                   Downy brome 3 5 3 0 0 0 4 0 5 0                                                 Duck salad -- -- -- -- -- -- -- -- -- --                                        Giant foxtail 0 3 2 0 0 0 5 0 0 0                                               Lambsquarters 3 9 0 9 0 -- -- 9 8 0                                             Morningglory 0 2 0 0 3 0 5 0 0 0                                                Pigweed 7 7 0 8 5 2 7 7 8 2                                                     Rape 4 3 0 3 3 0 2 3 5 0                                                        Ryegrass 2 0 0 0 0 0 2 0 0 0                                                    Sorghum 9 6 0 0 0 0 4 0 0 2                                                     Soybean 0 0 0 0 0 0 3 0 0 0                                                     Speedwell 0 9 0 9 7 0 8 0 10 0                                                  Sugar beet 9 8 0 -- 6 3 6 8 7 0                                                 Velvetleaf 2 0 0 4 0 0 6 0 2 0                                                  Wheat 0 0 0 0 0 0 0 0 0 0                                                       Wild buckwheat -- 7 -- 4 8 4 4 5 2 0                                            Wild oat 0 0 0 0 0 0 0 0 0 0                                                    Barnyardgrass -- -- -- -- -- -- -- -- -- --                                     Rice Japonica -- -- -- -- -- -- -- -- -- --                                     Umbrella sedge -- -- -- -- -- -- -- -- -- --                             

TEST C

Plastic pots were partially filled with silt loam soil. The soil was then saturated with water. Japonica rice (Oryza sativa) seedlings at the 2.0 and 2.5 leaf stage, seeds selected from barnyardgrass (Echinochloa crus-galli), duck salad (Heteranthera limosa), umbrella sedge (Cyperus difformis), and tubers selected from arrowhead (Safittaria spp.), waterchestnut (Eleocharis spp.), were planted into this soil. After planting, water levels were raised to 3 cm above the soil surface and maintained at this level throughout the test. Chemical treatments were formulated in a non-phytotoxic solvent and applied directly to the paddy water. Treated plants and controls were maintained in a greenhouse for approximately 21 days, after which all species were compared to controls and visually evaluated. Plant response ratings, summarized in Table C, are reported on a 0 to 10 scale where 0 is no effect and 10 is complete control. A dash (--) response means no test result.

                  TABLE C                                                          ______________________________________                                                        COMPOUND                                                        Rate (64 g/ha    6      58                                                     PADDY                                                                          Barnyardgrass    5      9                                                      Duck salad       --     10                                                     Japonica rice    8      8                                                      Umbrella sedge   9      9                                                      Waterchestnut    8      8                                                                  COMPOUND                                                           Rate (32 g/ha)                                                                               6     27         58  205                                         PADDY                                                                          Arrowhead     --    --         --  8                                           Barnyardgrass 3     4          5   10                                          Duck salad    --    10         10  --                                          Japonica rice 7     8          7   8                                           Umbrella sedge                                                                               8     9          9   10                                          Waterchestnut --    7          8   8                                                       COMPOUND                                                           Rate (16 g/ha)                                                                               6     27         58  205                                         PADDY                                                                          Arrowhead     --    --         --  7                                           Barnyardgrass 0     2          6   10                                          Duck salad    --    10         10  --                                          Japonica rice 6     6          6   7                                           Umbrella sedge                                                                               7     9          9   9                                           Waterchestnut 4     6          7   8                                                       COMPOUND                                                           Rate (8 g/ha) 6     27         58  205                                         PADDY                                                                          Arrowhead     --    --         --  5                                           Barnyardgrass 0     2          4   10                                          Duck salad    --    10         10  --                                          Japonica rice 5     5          5   7                                           Umbrella sedge                                                                               5     9          9   9                                           Waterchestnut 3     5          6   8                                                       COMPOUND                                                           Rate (4 g/ha) 6     27         58  205                                         PADDY                                                                          Arrowhead     --    --         --  3                                           Barnyardgrass 0     2          0   9                                           Duck salad    --    10         9   --                                          Japonica rice 1     1          4   7                                           Umbrella sedge                                                                               2     9          9   9                                           Waterchestnut 3     4          6   8                                                          COMPOUND                                                        Rate (2 g/ha     27     205                                                    PADDY                                                                          Arrowhead        --     1                                                      Barnyardgrass    0      4                                                      Duck salad       3      --                                                     Japonica rice    0      5                                                      Umbrella sedge   0      9                                                      Waterchestnut    2      5                                                      ______________________________________                                    

Test D

Compounds evaluated in this test were formulated in a non-phytoxic solvent and applied to the soil surface before plant seedlings emerged (preemergence application) and to plants that were in the one-to-four leaf stage (postemergence application). A sandy loam soil was used for the preemergence test while a mixture of sandy loam soil and greenhouse potting mix in a 60:40 ratio was used for the postemergence test. Test compounds were applied within approximately one day after planting seeds for the preemergence test. Plantings of these crops and weed species were adjusted to produce plants of appropriate size for the postemergence test. All plant species were grown using normal greenhouse practices. Crop and weed species include winter barley (Hordeum vulgare cv. `Igri`), bedstraw (Galium aparine), blackgrass (Alopecurus myosuroides), chickweed (Stellaria media), downy brome (Bromus tectorum), field violet (Viola arvensis), green foxtail (Setaria viridis), kochia (Kochia scoparia), lambsquarters (Chenopodium album), Persian speedwell (Veronica persica), rape (Brassica napus cv. `Jet Neuf`), ryegrass (Lolium multiflorum), sugar beet (Beta vulgaris cv. `USI`), sunflower (Helianthus annuus cv. `Russian Giant`), spring wheat (Triticum aestivum cv. `ERA`), winter wheat (Triticum aestivum cv. `Talent`), wild buckwheat (Polygonum convolvulus), wild mustard (Sinapis arvensis), wild oat (Avena fatua), and wild radish (Raphanus raphanistrum). Blackgrass and wild oat were treated postemergence at two growth stages. The first stage (1) was when the plants had two to three leaves. The second stage (2) was when the plants had approximately four leaves or in the initial stages of tillering. Treated plants and untreated controls were maintained in a greenhouse for approximately 21 to 28 days, after which all treated plants were compared to untreated controls and visually evaluated. Plant response ratings, summarized in Table D, are based upon a 0 to 10 scale where 0 is no effect and 10 is complete control. A dash response (-) means no test result.

    TABLE D                                                                           - COMPOUND                                                                      36 59 60 83 89 107 108 214 229 230 232 244 252 269 288 289 36 59 60 83         89 107 108 214 229 230 232 244                                                   POSTEMERGENCE Rate (125 g/ha) Rate (60 g/ha)                                    Blackgrass (1) -- 10 7 10 10 10 7 10 7 8 10 10 10 4 10 10 -- 9 6 10 9          10 6 8 5 7 10 10                                                                 Blackgrass (2) -- 10 7 10 9 10 6 10 7 9 10 10 10 4 10 10 -- 9 5 9 7 10         5 8 6 8 10 10                                                                    Chickweed -- 10 10 10 8 10 10 10 7 6 9 10 4 0 10 10 -- 10 10 10 4 10 10        10 5 4 8 10                                                                      Downy brome -- 7 7 5 3 7 5 10 7 9 10 10 10 5 10 10 -- 6 5 3 2 5 3 10 6         8 10 10                                                                          Field violet -- 10 9 8 2 10 10 10 6 8 8 10 8 0 9 6 -- 10 7 6 0 10 10 8         4 7 6 10                                                                         Galium (1) -- 10 10 10 9 10 10 10 9 9 10 10 10 4 10 9 -- 10 9 8 7 10 10        10 8 8 10 10                                                                     Galium (2) -- 10 10 10 8 10 10 10 9 9 10 10 10 3 10 10 -- 10 9 9 6 10          10 10 7 7 10 10                                                                  Green foxtail -- 9 7 9 5 10 5 8 6 9 5 10 10 3 10 10 -- 8 5 7 3 10 3 7 4        7 3 10                                                                           Kochia -- 10 10 10 2 10 10 10 3 6 4 6 4 6 10 10 -- 10 10 10 0 10 10 9 2        4 3 5                                                                            Lambsquarters -- 8 6 7 5 10 4 6 7 10 3 7 4 0 10 8 -- 7 3 6 2 8 2 4 6 8         2 5                                                                              Persn Speedwell -- 10 3 0 2 10 0 4 0 0 3 2 4 0 7 4 -- 10 2 0 0 10 0 2 0        0 0 0                                                                            Rape -- 10 10 10 10 10 10 10 10 10 10 10 10 7 10 7 -- 10 10 10 10 10 10        10 10 10 10 10                                                                   Ryegrass -- 10 8 7 4 10 10 10 5 2 10 10 6 3 9 9 -- 10 7 6 2 10 10 8 3 0        10 10                                                                            Sugar beet -- 10 10 10 9 10 10 10 6 8 9 10 5 2 10 10 -- 10 10 10 7 10          10 10 5 6 7 10                                                                   Sunflower -- 10 10 10 10 10 10 10 10 10 10 10 10 6 10 10 -- 10 10 10 10        10 10 10 10 10 10 10                                                             Wheat (Spring) -- 6 4 7 3 8 5 5 7 6 10 10 8 2 10 10 -- 4 2 5 2 6 2 4 6         5 9 10                                                                           Wheat (Winter) -- 5 3 6 3 7 4 5 8 7 10 10 8 2 10 10 -- 4 2 4 2 5 2 4 7         6 10 10                                                                          Wild buckwheat -- 10 10 8 4 10 10 10 6 7 5 10 3 10 10 6 -- 10 10 6 2 10        10 10 4 6 2 10                                                                   Wild mustard -- 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 -- 10 10          10 10 10 10 10 10 10 10 10                                                       Wild oat (1) -- 10 8 4 2 10 8 10 10 10 10 10 9 3 10 10 -- 8 6 2 0 10 5         9 10 10 10 10                                                                    Wild oat (2) -- 9 8 3 2 10 7 10 10 10 10 10 8 2 10 10 -- 8 6 2 0 10 5          10 10 10 10 10                                                                   Wild radish -- 10 10 10 10 10 10 10 9 9 10 10 10 9 10 10 -- 10 10 10 10        10 10 10 7 7 10 10                                                               Winter Barley -- 9 7 7 4 9 7 9 10 10 10 10 8 4 10 10 -- 7 5 6 2 7 5 8 9        9 9 10                                                                           COMPOUND                                                                        252 269 288 289 36 59 60 83 89 107 108 214 229 230 232 244 252 269 288         289 36 59 60 83 89 107 108 214                                                   POSTEMERGENCE Rate (64 g/ha) Rate (32 g/ha) Rate (16 g/ha)                      Blackgrass (1) 10 2 10 10 -- 8 5 8 6 8 4 6 4 6 9 10 9 0 9 10 5 7 3 6 3         7 3 4                                                                            Blackgrass (2) 10 2 10 10 -- 7 4 7 4 8 4 7 4 6 10 10 8 0 8 10 4 6 2 5 2        6 2 3                                                                            Chickweed 3 0 10 10 -- 10 10 10 2 10 10 10 4 2 4 10 2 0 8 10 5 10 10 8         0 10 10 10                                                                       Downy brome 10 4 10 10 -- 5 4 2 0 3 2 8 4 6 9 10 8 2 10 10 10 3 3 0 0 2        0 6                                                                              Field violet 6 0 8 5 -- 10 4 4 0 10 8 5 2 5 5 10 4 0 6 2 5 9 2 2 0 10 6        3                                                                                Galium (1) 9 2 10 8 -- 10 8 7 4 10 10 9 7 6 9 10 7 0 9 7 7 9 7 4 2 10          10 7                                                                             Galium (2) 9 2 10 8 -- 10 8 8 3 10 10 10 6 6 9 10 8 0 8 6 -- 10 6 5 2          10 10 8                                                                          Green foxtail 10 0 10 10 -- 7 3 6 0 10 0 5 3 6 2 10 8 0 10 10 10 6 0 4         0 7 0 3                                                                          Kochia 2 4 10 10 -- 10 9 8 0 10 8 7 0 2 0 3 0 2 10 10 4 10 6 6 0 10 7 6         Lambsquarters 3 0 8 7 -- 6 0 5 0 6 0 2 4 6 0 2 2 0 6 5 5 4 0 2 0 4 0 0           Persn Speedwell 2 0 4 2 -- 10 0 0 0 9 0 0 0 0 0 0 0 0 2 0 0 10 0 0 0 6        0 0                                                                              Rape 10 4 10 5 -- 10 10 10 10 10 10 10 8 9 10 10 9 2 10 3 10 10 10 9 10        8 10 10                                                                          Ryegrass 4 2 8 8 -- 10 6 5 0 10 9 6 2 0 8 10 2 0 7 5 10 9 3 3 0 10 7 4           Sugar beet 4 0 10 9 -- 10 10 10 5 10 10 10 3 3 4 10 3 0 9 7 10 10 10          10 4 10 10 10                                                                    Sunflower 10 3 10 10 -- 10 10 10 10 10 10 10 10 10 10 10 10 0 10 10 10         10 10 10 10 10 10 10                                                             Wheat (Spring) 7 0 9 10 -- 3 0 3 0 4 0 2 5 4 8 10 4 0 8 10 6 2 0 2 0 0          Wheat (Winter) 7 0 9 10 -- 4 0 3 0 3 0 2 6 3 8 10 4 0 8 10 4 3 0 2 0 2         0 0                                                                              Wild buckwheat 0 9 10 5 -- 10 8 3 0 10 10 10 2 3 0 10 0 7 8 3 2 10 5 2         0 10 8 10                                                                        Wild mustard 10 10 10 10 -- 10 10 10 10 10 10 10 10 10 10 10 10 7 10 10        10 10 10 10 10 10 10 10                                                          Wild oat (1) 8 2 10 10 -- 7 5 0 0 8 4 8 8 8 10 10 4 0 10 10 10 5 3 0 0         5 2 6                                                                            Wild oat (2) 6 0 10 10 -- 7 5 0 0 7 4 9 8 8 10 10 3 0 9 10 9 5 4 0 0 5         2 7                                                                              Wild radish 10 7 10 10 -- 10 10 10 10 10 8 10 4 5 10 10 10 5 10 8 9 10         10 10 10 8 5 10                                                                  Winter Barley 6 3 9 10 -- 6 2 5 0 5 3 6 8 7 7 9 3 2 7 10 4 5 0 3 0 3 2         3                                                                                COMPOUND                                                                        229 230 232 244 252 269 288 289 36 59 60 83 89 107 108 214 229 230 232         244 252 269 288 289 36 59 60 83                                                  POSTEMERGENCE Rate (16 g/ha) Rate (8 g/ha) Rate (4 g/ha)                        Blackgrass (1) 3 4 7 9 7 0 7 9 3 4 2 3 2 3 0 2 2 2 4 7 4 0 6 8 0 2 0 2           Blackgrass (2) 2 3 8 9 5 0 6 8 2 4 0 2 0 3 0 2 0 2 5 7 3 0 4 6 0 2 0 0         Chickweed 2 0 2 10 0 0 6 8 3 10 10 6 0 10 9 10 0 0 0 10 0 0 4 6 0 10 8         3                                                                                Downy brome 3 5 7 10 5 0 8 10 9 2 2 0 0 0 0 5 2 3 5 9 2 0 7 9 7 0 0 0             Field violet 0 2 3 8 2 0 3 0 3 8 0 0 0 8 3 0 0 0 2 6 0 0 2 0 2 5 0 0           Galium (1) 6 3 7 8 6 0 7 5 4 8 8 4 0 10 10 5 3 0 3 4 3 0 5 2 2 4 2 0             Galium (2) 5 3 6 8 7 0 7 4 -- 7 4 2 0 10 9 5 4 0 3 5 4 0 4 2 -- 4 2 0         Green foxtail 2 4 0 10 6 0 8 8 9 4 0 3 0 3 0 2 0 2 0 8 4 0 7 6 7 2 0 2           Kochia 0 0 0 2 0 0 9 9 2 10 3 4 0 10 5 4 0 0 0 0 0 0 7 7 0 8 2 2                     Lambsquarters 2 4 0 0 0 0 4 4 4 2 0 0 0 2 0 0 0 2 0 0 0 0 2 2 2 0        0 0                                                                              Persn Speedwell 0 0 0 0 0 0 0 0 0 10 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 8 0          Rape 6 7 10 10 7 0 10 2 10 10 9 7 9 6 8 10 3 3 9 10 4 0 10 0 9 10 4 5             Ryegrass 0 0 6 8 0 0 5 3 9 7 2 2 0 10 5 2 0 0 4 5 0 0 3 2 5 5 0 0                 Sugar beet 2 0 2 10 0 0 8 6 10 10 9 10 2 10 10 10 0 0 0 10 0 0 7 5         7 10 6 9                                                                         Sunflower 10 10 10 10 10 0 9 10 10 10 10 10 10 10 10 10 9 8 10 10 10 0         8 10 10 10 10 10                                                                 Wheat (Spring) 3 2 6 7 2 0 7 8 3 0 0 0 0 0 0 0 0 0 3 5 0 0 5 7 0 0 0 0           Wheat (Winter) 3 2 6 8 2 0 6 8 2 0 0 0 0 0 0 0 0 0 4 5 0 0 4 7 0 0 0 0         Wild buckwheat 0 0 0 8 0 4 6 0 0 8 3 0 0 9 5 8 0 0 0 7 0 2 5 0 0 6 0 0           Wild mustard 9 10 10 10 10 6 10 10 8 10 10 10 10 10 9 10 7 9 8 10 10 4        10 10 6 10 10 10                                                                 Wild oat (1) 7 6 10 10 2 0 9 9 7 4 2 0 0 4 0 4 4 5 9 10 0 0 8 8 4 2 0 0         Wild oat (2) 6 6 10 10 2 0 8 10 7 3 2 0 0 3 0 5 5 4 8 10 0 0 6 7 4 2 0          Wild radish 3 4 10 10 10 2 10 5 6 10 9 10 9 7 3 10 0 3 8 10 10 0 10 5 5        10 7 10                                                                          Winter Barley 6 5 6 6 2 0 5 9 2 4 0 0 0 2 0 2 4 2 3 4 0 0 4 6 0 2 0             COMPOUND                                                                        89 107 108 214 229 230 232 244 252 269 288 289 36 107 108 232 252              289                                                                              POSTEMERGENCE Rate (4 g/ha) Rate (2 g/ha)                                       Blackgrass (1) 0 0 0 0 0 0 2 5 2 0 4 6 0 0 0 0 0 0                              Blackgrass (2) 0 0 0 0 0 0 3 6 2 0 2 4 0 0 0 0 0 0                              Chickweed 0 7 5 7 0 0 0 9 0 0 2 4 0 3 2 0 0 2                                   Downy brome 0 0 0 3 0 0 4 7 0 0 5 7 3 0 0 2 0 3                                 Field violet 0 5 2 0 0 0 0 4 0 0 0 0 0 3 0 0 0 0                                Galium (1) 0 7 7 2 2 0 0 2 0 0 2 0 0 3 3 0 0 0                                  Galium (2) 0 10 6 2 2 0 0 3 2 0 3 0 -- 3 3 0 0 0                                Green foxtail 0 0 0 0 0 0 0 4 2 0 6 3 4 0 0 0 0 0                               Kochia 0 6 3 3 0 0 0 0 0 0 5 5 0 3 0 0 0 2                                      Lambsquarters 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0                               Persn Speedwell 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0                             Rape 8 5 7 6 0 0 7 10 3 0 10 0 5 3 5 5 0 0                                      Ryegrass 0 10 3 0 0 0 2 3 0 0 2 0 2 7 0 0 0 0                                   Sugar beet 0 10 10 7 0 0 0 10 0 0 6 2 3 9 9 0 0 0                               Sunflower 7 10 9 10 7 7 10 10 9 0 6 7 9 10 5 10 5 4                             Wheat (Spring) 0 0 0 0 0 0 2 3 0 0 4 5 0 0 0 0 0 2                              Wheat (Winter) 0 0 0 0 0 0 2 3 0 0 3 5 0 0 0 0 0 2                              Wild buckwheat 0 5 3 6 0 0 0 5 0 0 4 0 0 2 2 0 0 0                              Wild mustard 10 10 7 9 3 8 6 8 8 2 10 8 4 10 3 4 5 7                            Wild oat (1) 0 2 0 2 2 3 6 8 0 0 7 4 2 0 0 2 0 2                                Wild oat (2) 0 2 0 2 3 2 6 9 0 0 5 3 3 0 0 3 0 2                                Wild radish 7 5 2 7 0 0 5 10 8 0 9 4 3 2 0 2 5 0                                Winter Barley 0 0 0 0 2 0 0 2 0 0 2 5 0 0 0 0 0 3                               COMPOUND                                                                        36 36 59 60 83 89 107 108 214 229 230 232 244 252 269 288 289 36 59 60         89 107 108 214 229 230 232                                                        Rate (250 g/ha)                                                                 (250                                                                           PREEMERGENCE g/ha) Rate (125 g/ha) Rate (64 g/ha)                               Blackgrass (1) 10 10 10 9 9 8 10 8 9 6 8 8 10 9 2 9 9 10 10 7 8 6 9 7 7 3       4 5                                                                             Blackgrass (2) 10 10 10 9 10 7 10 8 8 8 7 6 10 9 2 8 9 10 10 9 9 6 9 6         7 5 4 4                                                                          Chickweed 10 10 10 10 10 10 10 10 10 10 9 8 10 10 4 10 10 10 10 10 10          10 10 10 10 6 4 5                                                                Downy brome 10 10 9 8 6 2 9 8 10 10 8 10 10 9 3 8 9 10 9 7 4 0 8 6 10 9        6 9                                                                              Field violet 10 10 10 10 10 10 10 10 10 8 9 5 10 10 0 10 9 10 10 10 10         8 10 10 10 5 7 3                                                                 Galium (1) 10 10 10 10 10 10 10 10 10 10 9 8 10 8 2 10 9 10 10 10 10 10        10 10 10 9 7 4                                                                   Galium (2) 10 -- 10 10 10 10 10 10 10 -- 8 8 10 9 2 10 9 -- 10 10 10 10        10 10 10 -- 7 4                                                                  Green foxtail 10 10 10 10 10 6 10 8 10 6 3 8 10 7 0 8 10 10 10 8 10 5          10 7 9 4 2 6                                                                     Kochia 10 9 10 10 10 8 10 10 9 4 2 4 10 3 0 10 8 7 10 10 10 5 10 10 8 2        0 3                                                                              Lambsquarters 10 10 10 10 10 10 10 10 10 7 9 2 10 10 0 10 6 10 10 10 10        10 10 10 10 4 4 0                                                                Persn Speedwell 9 7 10 9 10 8 10 10 8 5 4 5 8 9 0 10 8 4 10 9 9 6 10 10        7 4 2 3                                                                          Rape 10 10 10 10 10 10 10 10 10 6 2 6 10 8 2 10 2 10 10 10 10 10 10 10         10 3 0 3                                                                         Ryegrass 10 10 10 9 10 6 10 10 8 0 0 7 10 5 0 9 8 10 10 8 8 3 10 9 6 0         0 5                                                                              Sugar beet 10 10 10 10 10 10 10 10 10 6 9 5 10 6 2 10 9 10 10 10 10 10         10 10 10 4 7 3                                                                   Sunflower 10 10 10 10 10 10 10 10 10 3 0 10 10 9 0 10 10 10 10 10 10 10        10 10 10 0 0 8                                                                   Wheat (Spring) 10 7 9 7 5 2 10 7 3 10 6 9 10 6 0 9 5 5 8 6 3 0 8 6 3 9         3 8                                                                              Wheat (Winter) 10 7 9 7 4 2 10 8 3 10 7 9 10 6 0 9 4 5 7 5 3 0 8 6 2 10        4 7                                                                              Wild buckwheat 10 10 10 10 10 8 10 10 10 5 7 6 10 2 0 10 8 10 10 10 10         6 10 10 10 2 5 4                                                                 Wild mustard 10 10 10 10 10 10 10 10 10 7 7 10 10 10 6 10 9 8 10 10 10         10 10 10 10 3 3 8                                                                Wild oat (1) 10 9 10 10 4 2 10 9 8 8 6 10 10 4 0 6 6 6 10 9 3 0 10 8 6         7 4 7                                                                            Wild oat (2) 10 9 10 10 5 3 10 9 8 9 6 10 10 4 2 6 5 7 10 9 3 0 10 8 6         6 4 8                                                                            Wild radish 10 10 10 10 10 10 10 10 10 4 5 7 10 10 3 10 8 10 10 10 10          10 10 10 8 3 2 4                                                                 Winter Barley 10 10 10 9 10 10 10 10 10 9 9 10 8 3 8 5 9 10 8 8 2 10 10        8 9 6 6                                                                          COMPOUND                                                                        244 252 269 288 289 36 59 60 83 89 107 108 214 229 230 232 244 252 269         288 289 36 59 60 83 89 107 108                                                   PREEMERGENCE Rate (64 g/ha) Rate (32 g/ha) Rate (16 g/ha)                       Blackgrass (1) 10 8 0 7 8 9 9 6 7 3 8 5 5 0 3 2 10 6 0 4 6 6 8 5 5 2 6         3                                                                                Blackgrass (2) 10 8 0 6 8 9 9 7 7 4 8 5 6 2 2 2 9 6 0 3 5 8 8 6 6 2 6 3         Chickweed 10 8 2 10 9 10 10 10 10 8 10 10 9 3 2 2 10 5 0 10 8 10 10 10         9 6 10 10                                                                        Downy brome 10 7 0 6 7 10 8 6 3 0 7 4 8 7 4 7 10 4 0 4 4 8 7 5 2 0 5 3           Field violet 10 9 0 10 6 10 10 10 10 6 10 10 10 2 3 2 10 6 0 10 3 8 10        10 10 5 10 10                                                                    Galium (1) 10 6 0 10 7 9 10 10 10 10 10 10 10 5 5 3 10 4 0 9 5 7 10 10         9 8 10 8                                                                         Galium (2) 10 7 0 10 8 -- 10 10 10 10 10 10 10 -- 3 2 10 4 0 8 4 -- 10         10 10 8 10 10                                                                    Green foxtail 10 6 0 6 8 9 9 7 9 2 9 6 7 2 0 4 10 5 0 4 7 7 8 5 7 0 7 3         Kochia 9 2 0 10 6 4 10 9 8 2 10 9 5 0 0 2 7 0 0 10 5 2 10 8 5 0 8 7                 Lambsquarters 10 9 0 10 3 10 10 10 10 7 10 10 9 2 2 0 10 7 0 10 2          10 10 9 10 4 10 9                                                                Persn Speedwell 6 8 0 10 7 2 10 8 6 5 10 8 5 2 0 0 4 5 0 10 5 0 10 7 4         3 10 6                                                                           Rape 10 6 0 10 0 10 10 10 10 10 10 10 10 0 0 0 10 4 0 10 0 8 10 10 10 8        10 9                                                                             Ryegrass 9 2 0 7 5 8 10 7 6 2 10 7 4 0 0 2 7 0 0 5 3 4 9 5 4 0 10 5                 Sugar beet 10 4 0 10 8 10 10 10 10 9 10 10 10 2 4 2 10 3 0 10 6 9          10 10 10 5 10 10                                                                 Sunflower 10 5 0 10 7 10 10 10 10 10 10 10 9 0 0 4 10 3 0 10 4 8 10 10         10 7 10 10                                                                       Wheat (Spring) 8 4 0 7 3 3 6 5 2 0 6 4 2 8 2 4 5 3 0 4 0 0 4 3 0 0 5 3           Wheat (Winter) 8 5 0 8 2 3 6 4 2 0 7 4 2 8 2 4 6 3 0 6 0 0 4 3 0 0 4 3         Wild buckwheat 10 0 0 10 6 7 10 10 10 4 10 10 10 0 2 2 8 0 0 8 4 5 10 9        8 3 10 9                                                                         Wild mustard 10 10 3 10 7 7 10 10 10 10 10 10 10 0 0 4 10 8 0 10 5 5 10        10 10 10 10 10                                                                   Wild oat (1) 10 2 0 5 5 3 10 8 2 0 10 7 3 4 2 4 8 0 0 3 3 0 8 6 0 0 10         6                                                                                Wild oat (2) 10 2 0 5 4 3 10 8 0 0 10 7 4 5 2 5 8 0 0 3 2 0 9 6 0 0 10         6                                                                                Wild radish 10 8 0 10 5 7 10 10 10 10 10 10 7 2 0 2 10 6 0 10 3 6 10 10        10 10 10 9                                                                       Winter Barley 10 5 2 7 4 4 9 7 7 0 10 10 6 8 3 3 8 3 0 5 2 2 8 5 4 0 9         9                                                                                COMPOUND                                                                        214 229 230 232 244 252 269 288 289 36 59 60 83 89 107 108 214 229 230         232 244 252 269 288 289 36 59 60                                                 PREEMERGENCE Rate (16 g/ha) Rate (8 g/ha) Rate (4 g/ha)                         Blackgrass (1) 4 0 0 0 8 5 0 2 2 4 7 4 3 0 3 0 2 0 0 0 6 2 0 0 0 2 6 2           Blackgrass (2) 4 0 0 0 7 4 0 2 2 4 7 5 4 0 3 0 2 0 0 0 5 2 0 0 0 2 6 3         Chickweed 8 0 0 0 10 3 0 10 6 9 10 10 7 3 10 10 6 0 0 0 10 2 0 8 4 6 9         8                                                                                Downy brome 6 3 2 5 9 2 0 2 2 5 6 2 0 0 4 2 3 0 0 3 7 0 0 0 0 2 5 0                 Field violet 10 0 0 0 8 3 0 10 0 6 10 10 8 2 10 10 9 0 0 0 6 0 0 8         0 3 9 9                                                                          Galium (1) 8 2 2 0 9 2 0 4 3 5 10 10 8 5 9 5 6 0 0 0 6 0 0 2 2 2 9 8               Galium (2) 9 -- 0 0 9 2 0 5 3 -- 10 10 8 4 10 7 7 -- 0 0 7 0 0 3 0          -- 9 8                                                                           Green foxtail 4 0 0 2 9 3 0 2 5 5 7 2 4 0 5 0 2 0 0 0 6 2 0 0 3 2 6 0             Kochia 2 0 0 0 3 0 0 7 3 0 9 7 3 0 6 5 0 0 0 0 0 0 0 5 2 0 8 5                       Lambsquarters 7 0 0 0 8 4 0 8 0 7 10 8 9 2 9 6 4 0 0 0 7 2 0 7 0        4 8 7                                                                            Persn Speedwell 4 0 0 0 2 3 0 10 2 0 10 6 2 2 10 3 3 0 0 0 0 2 0 8 0 0         10 5                                                                             Rape 10 0 0 0 9 2 0 8 0 6 10 10 10 7 10 6 10 0 0 0 5 0 0 6 0 4 10 10               Ryegrass 3 0 0 0 6 0 0 2 0 2 8 3 3 0 8 3 2 0 0 0 4 0 0 0 0 0 7 2                 Sugar beet 10 0 2 0 10 2 0 9 4 6 10 10 9 2 10 9 9 0 0 0 10 0 0 7 3         4 10 10                                                                          Sunflower 6 0 0 2 10 0 0 9 2 4 10 10 10 3 10 10 5 0 0 0 10 0 0 5 0 2 10        10                                                                               Wheat (Spring) 0 5 0 2 2 2 0 2 0 0 3 2 0 0 3 2 0 2 0 0 0 0 0 0 0 0 2 0           Wheat (Winter) 0 6 0 2 3 2 0 3 0 0 3 2 0 0 3 2 0 3 0 0 0 0 0 0 0 0 2 0         Wild buckwheat 10 0 0 0 4 0 0 7 2 3 10 8 6 0 9 7 8 0 0 0 2 0 0 5 0 0 8         7                                                                                Wild mustard 10 0 0 2 10 6 0 10 3 2 10 10 10 10 10 10 9 0 0 0 9 3 0 10         2 0 10 10                                                                        Wild oat (1) 2 2 0 3 5 0 0 2 0 0 7 4 0 0 8 4 0 0 0 2 2 0 0 0 0 0 6 2               Wild oat (2) 2 2 0 3 4 0 0 2 0 0 7 5 0 0 8 5 0 0 0 2 2 0 0 0 0 0 5 2         Wild radish 5 0 0 0 7 4 0 10 0 4 10 9 10 10 9 6 4 0 0 0 4 2 0 8 0 2 9 7         Winter Barley 3 4 2 2 5 2 0 3 0 0 7 2 3 0 7 7 2 2 0 0 3 0 0 0 0 0 6             COMPOUND                                                                        83 89 107 108 214 229 230 232 244 252 269 288 289 36 107 108 232 252           289                                                                              PREEMERGENCE Rate (4 g/ha) Rate (2 g/ha)                                        Blackgrass (1) 2 0 0 0 0 0 0 0 3 0 0 0 0 -- 0 0 0 0 0                           Blackgrass (2) 3 0 0 0 0 0 0 0 3 0 0 0 0 -- 0 0 0 0 0                           Chickweed 5 2 10 9 3 0 0 0 8 0 0 6 2 -- 8 7 0 0 0                               Downy brome 0 0 2 0 2 0 0 0 3 0 0 0 0 -- 0 0 0 0 0                              Field violet 6 0 8 8 7 0 0 0 3 0 0 7 0 -- 6 5 0 0 0                             Galium (1) 6 2 6 3 4 0 0 0 4 0 0 0 0 -- 4 0 0 0 0                               Galium (2) 6 3 7 5 4 -- 0 0 4 0 0 2 0 -- 5 2 0 0 0                              Green foxtail 2 0 2 0 0 0 0 0 5 0 0 0 0 -- 0 0 0 0 0                            Kochia 0 0 4 2 0 0 0 0 0 0 0 2 0 -- 2 0 0 0 0                                   Lambsquarters 6 0 6 5 3 0 0 0 3 0 0 5 0 -- 5 3 0 0 0                            Persn Speedwell 0 0 10 2 2 0 0 0 0 0 0 6 0 -- 8 0 0 0 0                         Rape 8 4 8 5 8 0 0 0 3 0 0 4 0 -- 5 2 0 0 0                                     Ryegrass 2 0 6 2 0 0 0 0 2 0 0 0 0 -- 3 0 0 0 0                                 Sugar beet 8 0 10 8 8 0 0 0 8 0 0 6 0 -- 9 5 0 0 0                              Sunflower 9 0 10 10 3 0 0 0 7 0 0 2 0 -- 9 9 0 0 0                              Wheat (Spring) 0 0 2 0 0 0 0 0 0 0 0 0 0 -- 0 0 0 0 0                           Wheat (Winter) 0 0 2 0 0 0 0 0 0 0 0 0 0 -- 0 0 0 0 0                           Wild buckwheat 4 0 8 4 5 0 0 0 0 0 0 4 0 -- 6 3 0 0 0                           Wild mustard 10 7 10 9 7 0 0 0 8 0 0 10 0 -- 9 7 0 0 0                          Wild oat (1) 0 0 4 2 0 0 0 0 0 0 0 0 0 -- 2 0 0 0 0                             Wild oat (2) 0 0 4 3 0 0 0 0 0 0 0 0 0 -- 2 0 0 0 0                             Wild radish 10 9 8 4 2 0 0 0 2 0 0 6 0 -- 6 2 0 0 0                             Winter Barley 0 0 5 5 0 0 0 2 0 0 0 0 8 -- 3 2 0 0 0                      

What is claimed is:
 1. Compounds of the formula ##STR67## wherein: J is ##STR68## W is O or S; R is H or CH₃ ;R¹ is H; CH₃ ; CH₂ OCH₃ ; CH₂ OC₂ H₅ ; CH₂ CN; CH₂ SCH₃ ; CH₂ SC₂ H₅ ; C₂ -C₆ alkyl optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; C₃ -C₄ alkenyl; C₃ -C₄ haloalkenyl; C₃ -C₆ cycloalkyl; C(O)R⁵ ; N(CH₃)₂ ; or Q¹ ; R² is C₁ -C₄ alkyl optionally substituted with one CN, C₂ -C₃ alkylcarbonyl, methoxycarbonyl, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, C₁ -C₂ alkylsulfonyl, S(O)₂ NR⁶ R⁷, OH or one or more halogens; C₂ -C₄ alkenyl optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; (CH₂)_(m) Q² ; CN; C(O)R⁸ ; C(O)OR⁹ ; C(O)NR¹⁰ R¹¹ ; C(R¹²)═NOR¹³ ; C(R¹⁴)(OR¹⁵)(OR¹⁶); S(O)_(n) R¹⁷ ; S(O)₂ NR¹⁸ R¹⁹ ; NO₂ ; halogen; or OR⁷³ ; R³ is H, halogen or C₁ -C₄ alkyl; R⁴ is H, C₁ -C₄ alkyl optionally substituted with one CN, C₂ -C₃ alkylcarbonyl, methoxycarbonyl, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, C₁ -C₂ alkylsulfonyl, S(O)₂ NR⁶ R⁷, OH or one or more halogens; C₂ -C₄ alkenyl optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; CN; C(O)R⁸ ; C(O)OR⁹ ; C(O)NR¹⁰ R¹¹ ; C(R¹²)═NOR¹³ ; S(O)_(n) R¹⁷ ; S(O)₂ NR¹⁸ R¹⁹ ; or halogen; R⁵ is C₁ -C₄ alkyl, C₁ -C₄ alkoxy or NR²⁰ R²¹ ; R⁶ is H, C₁ -C₂ alkyl or OCH₃ ; R⁷ is C₁ -C₂ alkyl; or R⁶ and R⁷ can be taken together as --(CH₂)₃ -- or --(CH₂)₄ --; R⁸ is H, C₁ -C₃ alkyl or cyclopropyl; R⁹ is CH₃ ; C₂ -C₃ alkyl optionally substituted with one C₁ -C₂ alkoxy, OH, CN or one or more halogens; C₃ -C₄ alkenyl; or propargyl; R¹⁰ is H, C₁ -C₃ alkyl or OCH₃ ; R¹¹ is C₁ -C₃ alkyl; or R¹⁰ and R¹¹ can be taken together as --(CH₂)₃ --, --(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₂ O(CH₂)₂ --; R¹² is H, C₁ -C₃ alkyl, allyl, halogen, CN, N₃, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio or SCN; R¹³ is C₁ -C₃ alkyl or allyl; R¹⁴ is H or C₁ -C₃ alkyl; R¹⁵ and R¹⁶ are independently C₁ -C₂ alkyl; R¹⁷ is C₁ -C₄ alkyl, optionally substituted with one C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, CN or one or more halogens; C₃ -C₄ alkenyl; or cyclopropylmethyl; R¹⁸ is H, C₁ -C₃ alkyl or OCH₃ ; R¹⁹ is H or C₁ -C₂ alkyl; or R¹⁸ and R¹⁹ can be taken together as --(CH₂)₃ --, --(CH₂)₄ -- or --(CH₂)₅ --; R²⁰ and R²¹ are independently C₁ -C₂ alkyl; or R²⁰ and R²¹ can be taken together as --(CH₂)₃ --, --(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₂ O(CH₂)₂ --; R⁷¹ is H, halogen or CF₃ ; R⁷³ is C₁ -C₄ alkyl optionally substituted with one or more halogens, CN, C₁ -C₂ alkoxy, or C₁ -C₂ alkylthio; C(O)R⁷⁴ ; SO₂ R⁷⁵ ; C₃ -C₄ alkenyl; or propargyl; R⁷⁴ is C₁ -C₄ alkyl optionally substituted with C₁ -C₂ alkoxy, one or more halogens, or CN; C₃ -C₄ alkenyl; or C₁ -C₃ alkoxy; R⁷⁵ is C₁ -C₃ alkyl or CF₃ ; m is 0 or 1; n is 0, 1 or 2; Q¹ is ##STR69## r is 0 or 1; R⁴⁵ and R⁴⁶ are independently H, CH₃ or Cl; R⁴⁷ is H or C₁ -C₃ alkyl; R⁴⁸ is H or CH₃ ; R⁴⁹ and R⁵⁰ are independently H or CH₃ ; R⁵¹ is H, CH₃ or OCH₃ ; R⁵² is H or CH₃ ; R⁵³, R⁵⁴ and R⁵⁵ are independently H, CH₃ or OCH₃ ; R⁵⁶, R⁵⁷ and R⁵⁸ are independently H, CH₃, CH₂ CH₃, Cl, Br, OCH₃ or OCH₂ CH₃ ; R⁵⁹ is H or C₁ -C₂ alkyl; R⁶⁰ is CH₃ ; R⁶¹ is H, C₁ -C₂ alkyl, OCH₃ or SCH₃ ; R⁶² is H, CH₃ or CH₂ CH₃ ; R⁶³ and R⁶⁴ are independently H or CH₃ ; R⁶⁵ is H, CH₃, CH₂ CH₃ or C₃ H₇ ; W³ is O or S; W⁴ is O, S or NR⁶⁶ ; and R⁶⁶ is H or CH₃ ; A is ##STR70## Y¹ is O or CH₂ ; X¹ is CH₃, OCH₃ or OCF₂ H; Y³ is H or CH₃ ; q is 0 or 1; R²⁵ and R²⁶ are independently H, CH₃ or Cl; R²⁷ and R²⁸ are independently H, F, or CH₃ ; R²⁹ is H, CH₃ or OCH₃ ; R³⁰ is H or CH₃ ; R³¹, R³² and R³³ are independently H, CH₃ or OCH₃ ; R³⁴, R³⁵ and R³⁶ are independently H, CH₃, CH₂ CH₃, Cl, Br, OCH₃ or OCH₂ CH₃ ; R³⁷ is H or C₁ -C₂ alkyl; R³⁸ is CH₃ ; R³⁹ is H, C₁ -C₂ alkyl, OCH₃ or SCH₃ ; R⁴⁰ is H, CH₃ or CH₂ CH₃ ; R⁴¹ and R⁴² are independently H or CH₃ ; R⁴³ is H, CH₃, CH₂ CH₃ or C₃ H₇ ; W¹ is O or S; W² is P, S or NR⁴⁴ ; and R⁴⁴ is H or CH₃ ; and their agriculturally suitable salts; provided that:(a) when m is zero, Q² is bound through carbon to the pyrrole ring in J and (b) when J is J-1 and R¹ is C(O)R⁵, then R² is other than alkyl.
 2. Compounds of claim 1 wherein:W is O; and R¹ is H, C₁ -C₆ alkyl, allyl, CH₂ OCH₃, CH₂ OC₂ H₅, CH₂ SCH₃ phenyl, 2-pyridyl, 3-pyridyl, 4-pyridyl, C(O)OCH₃ or C(O)N(CH₃)₂.
 3. Compounds of claim 2 wherein:R³ is H, CH₃, Cl or Br; and R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)NR¹⁰ R¹¹, C(R¹²)═NOR¹³, C(R¹⁴)(OR¹⁵)(OR¹⁶), S(O)_(n) R¹⁷, S(O)₂ NR¹⁸ R¹⁹, F, Cl or Br; R⁸ is H or C₁ -C₂ alkyl; R⁹ is C₁ -C₂ alkyl or CH₂ CH₂ Cl; R¹⁰ is H or CH₃ ; R¹¹ is CH₃ ; R¹² is H, CH₃, C₂ H₅ or Cl; R¹³ is CH₃ ; R¹⁴ is H or C₁ -C₂ alkyl; R¹⁵ and R¹⁶ are CH₃ ; R¹⁷ is C₁ -C₂ alkyl; R¹⁸ is H or CH₃ ; R¹⁹ is CH₃ ; and n is 0 or
 2. 4. Compounds of claim 3 wherein:R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)NR¹⁰ R¹¹, C(R¹²)═NOR¹³, C(R¹⁴)(OR¹⁵)(OR¹⁶), S(O)_(n) R¹⁷, S(O)₂ NR¹⁸ R¹⁹, F, Cl, Br, or OR⁷³.
 5. Compounds of claim 4 wherein:R⁷¹ is H.
 6. Compounds of claim 5 wherein:J is J-1.
 7. Compounds of claim 5 wherein:J is J-2.
 8. Compounds of claim 5 wherein:J is J-3.
 9. Compounds of claim 6 wherein:R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH2SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H₅, S(O)₂ N(CH₃)₂, C₁ -C₂ alkoxy, OC(O)CH₃, or OSO₂ CH₃ ; R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H₅ or S(O)₂ N(CH₃)₂ ; R⁸ is C₁ -C₂ alkyl; R⁹ is C₁ -C₂ alkyl; Q² is Q² -1, Q² -4, Q² -5, Q² -6, Q² -10, Q² -11, Q² -20 or Q² -21; R⁴⁵, R⁴⁶, R⁴⁹, R⁵⁰, R⁵⁶, R⁵⁷ and R⁵⁸ are H; R⁶⁵ is CH₃ ; W³ is S; and r is
 0. 10. Compounds of claim 9 wherein:R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H₅, S(O)₂ N(CH₃)₂, C₁ -C₂ alkoxy, OC(O)CH₃, or OSO₂ CH₃ ; R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃ or S(O)₂ N(CH₃)₂ ; R⁸ is C₁ -C₂ alkyl; R⁹ is C₁ -C₂ alkyl; Q² is Q² -1, Q² -4, Q² -5, Q² -6, Q² -10, Q² -11, Q² -20 or Q² -21; R⁴⁵, R⁴⁶, R⁴⁹, R⁵⁰, R⁵⁶, R⁵⁷ and R⁵⁸ are H; R⁶⁵ is CH₃ ; W³ is S; and r is
 0. 11. Compounds of claim 8 wherein:R² is C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ SCH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃, S(O)₂ C₂ H₅, S(O)₂ N(CH₃)₂, C₁ -C₂ alkoxy, OC(O)CH₃, or OSO₂ CH₃ ; R⁴ is H, C₁ -C₂ alkyl, CH₂ CN, CH₂ OCH₃, CH₂ S CH₃, CH₂ S(O)₂ CH₃, Q², C(O)R⁸, C(O)OR⁹, C(O)N(CH₃)₂, S(O)₂ CH₃ or S(O)₂ N(CH₃)₂ ; R⁸ is C₁ -C₂ alkyl; R⁹ is C₁ -C₂ alkyl; Q² is Q² -1, Q² -4, Q² -5, Q² -6, Q² -10, Q² -11, Q² -20 or Q² -21; R⁴⁵, R⁴⁶, R⁴⁹, R⁵⁰, R⁵⁶, R⁵⁷ and R⁵⁸ are H; R⁶⁵ is CH₃ ; W³ is S; and r is
 0. 12. An agriculturally suitable composition for controlling the growth of undesired vegetation comprising a herbicidally effective amount of a compound in any of claims 1, 4, 5, 6 or 5 and at least one of the following: surfactant, solid diluent or liquid diluent.
 13. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected a herbicidally effective amount of a compound in any of claims 1, 4, 5, 6 or
 5. 